• Title/Summary/Keyword: $Ni_{3}Al$

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Acoustic Emission Characteristics of Plasma Sprayed Ceramic Coating Layer after Salt Spray (플라즈마용사 세라믹코팅 피막부식재의 음향방출 특성)

  • 김귀식;박경석;홍용의
    • Journal of Ocean Engineering and Technology
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    • v.15 no.3
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    • pp.69-74
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    • 2001
  • This paper was to investigate of a adhesiveness for the plasma sprayed coating materials did salt spray by acoustic emission method in tensile loadings. The powders used for the coating were nickel aluminum composite powder Ni-4.5wt.%Al and titanium dioxide powder $TiO_2$. These powders were coated on a carbon steel S45C by plasma spray method. The result solution was a 5% NaCl and the slat spray times were 2, 5 and 10 hours respectively. The salt solution penetrated into the surface of the substrate through pore of the coating layer built in the process of plasma spay. Corrosion productions formed on the surface of substrate. The adhesiveness between the substrate and the coating layer is weaken by corrosion and the exfoliation initiated chiefly at the corrosion surface of the substrate. The AE events and energy of the corroded coating specimens decreased as the salt spray times increased.

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Acoustic Emission Characteristics of Ceramic Coated Steel by Plasma Spraying (플래즈머용사에 의한 세라믹 코팅 강재의 음향방출 특성)

  • Kim, G.S.
    • Journal of Power System Engineering
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    • v.2 no.3
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    • pp.49-54
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    • 1998
  • This paper is investigated of hardness and adhesiveness of plasma sprayed coating steels by AE(Acoustic Emission) testing when loading a tensile. AE Parameters used are Event, Count, Energy and Amplitude. Test specimens are carbon steel(S45C) with sprayed coating layers of Ni-4.5wt.%Al(bond coating) and $TiO_2$(top coating), and carry out heat treatment at $800^{\circ}C\;and\;1000^{\circ}C$, respectively. The micro-hardness of the heat treatment specimen have been improved more than that of non-heat treatment. On the tensile test, the process and occurence of the exfoliation of the sprayed coating layer can be estimated by AE Characteristics of AE parameters, such as event, count, amplitude and energy, on the layer exfoliation are shown the similar aspects. The exfoliation of bond coating occure at about 20% of strain and top coating is about 5% of strain.

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Hydrogen Supplying System using Metal Hydride (금속 수소화물을 이용한 수소공급시스템)

  • Bae, Sang-Chul;Katsuta, Masafumi
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.13-19
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    • 2007
  • To find out the optimum design of hydrogen storage and supply tank using Metal Hydride (briefly MH) and to make clear the performance characteristics under various conditions are our research purpose. In order to use the low-temperature exhaust heat, $LaNi_{4.7}Al_{0.3}$ which operates under the low pressure of 1 MPa is chosen, and we measure the basic properties, namely density, specific heat, PCT(Pressure-Concentration-Temperature) characteristics, and effective thermal conductivity. Then, a numerical calculation model of hydrogen storage using MH alloy is suggested and this thermal diffusion equation of model is solved by the backward difference method. This calculation results are compared with the experimental results of the systems which installed 1kg MH alloy and, it is found out that our calculation model can well predict the experimental results. By the experimental using MH alloy, it is recognized that the hydrogen flow rate can control by the step adjustment of brine temperature.

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AN EXPERIMENTAL STUDY OF LASER EFFECTS ON A BASE METAL ALLOY FOR DENTAL CASTING (레이저가 치과주조용 비귀금속합금에 미치는 영향에 관한 실험적 연구)

  • Kim, Kyoung-Nam
    • The Journal of the Korean dental association
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    • v.22 no.9 s.184
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    • pp.781-792
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    • 1984
  • The purpose of this experiment was to study the effects of laser on a base metal alloy for dental casting. In this study, microhardness, corrosion resistance, wear resistance, interaction behavior of metal-ceramic interface, and bond strength were tested before and after the laser treatment for metal-ceramic alloy. The conclusion arised from this study are as follows: 1. The hardness of lased area was higher than that of unlased area. 2. The corrosion resistance was higher in lased specimen than in unlased specimen. 3. the wear resistance was higher in Iased specimen than in unlased specimen. 4. The EDAX showed that Mo, Si and Al were increased in lased surface but Ni and Cr not increased. 5. The SEM of lased area revealed a typical microstructure. 6. The bond strength of lased specimen was increased in 11.2% than of unlased specimen.

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[ PM10 ] Concentration and Chemical Composition in a Western Region of Susan during the Spring 2003 (2003년 봄철 부산 서부지역의 PM10 농도 특성과 화학적 조성)

  • Jeon Byung-Il;Hwang Yong-Sik
    • Journal of Environmental Science International
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    • v.14 no.5
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    • pp.463-471
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    • 2005
  • This study is designed to investigate the characteristics of $PM_{10}$ concentration and the chemical composition of heavy metallic components in the $PM_{10}$ sampled in western Busan from March to May, 2003. $PM_{10}$measurement was done during springtime of 2003, totaling 29 days: 9 days in March, 10 days in April and 10 days in May. With a sampling time of 24 hours, it started 9:00 AM on that day and ended 9:00 AM the next day. The mean contribution ratio of soil during springtime was $10.3\%$. Al had a significant correlation with Ca, Fe, Mg and Si and little correlation with Na, Ni and Zn.

Electrical Characteristics of n-GaN Schottky Diode fabricated by using Electrochemical Metallization (Electrochemical Metallization방법을 이용한 GaN Schottky Diode의 제작과 전기적 특성 향상 및 분석)

  • ;Daejun Fu
    • Proceedings of the IEEK Conference
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    • 2001.06b
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    • pp.205-208
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    • 2001
  • Schottky barrier diodes are fabricated on a intrinsic GaN(4${\mu}{\textrm}{m}$) epitaxial structure grown by rf plasma molecular beam epitaxy (MBE) on sapphire substrates. First, We make Ohmic electrodes (Ti/Al/Ti/Au) by evaporator. Next, we contact RuO$_2$ by dipping in the solution (RuCl$_3$.HClO$_4$), and then we deposit Ni/Au on the surface of RuO$_2$ by evaporator. We study the electrical characteristics of GaN Schottky barrier diodes made by these methods. Measurements are C-V, I-V, SEM, EDX, and XRD for the characteristics of devices. Thickness of RuO$_2$ layer depends on supplied voltage and dipping time. Device of thinner RuO$_2$ layer have a good Schottky characteristics compare with device of thicker RuO$_2$ layer

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Determination of Trace Elements in Animal Feed by Inductively Coupled Plasma-Mass Spectrometry (유도결합 플라즈마 질량분석기를 이용한 동물사료중의 극미량원소의 분석)

  • Park, Jeoung-Hwa;Kim, Hyo-Jin
    • YAKHAK HOEJI
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    • v.36 no.3
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    • pp.199-204
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    • 1992
  • The trace elements in animal feed were analyzed by Inductively Coupled Plasma Mass Spectrometer (ICP-MS, VG-PlasmaQuad Co.) to find possible sources of heavy metals accumulation in rat organ. The study about spectral interference was performed by analysis of a background spectrum of ICP-MS. Recovery test using standard of Cd and Se (100 ppb) was found to be better than 90%. Twenty elements (Ca, Fe, Mg, Ti, Cr, Ni, Cu, Zn, Ba, Al, Mn, Pb, B, Ce, Bi, U, V, Cd, and W)are determined.

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Performance of a direct methanol fuel cell (DMFCs)Using Nation 115 (Nafion 115를 사용한 DMFC MEA 의 성능실험)

  • Choi, Hoon;Hwang, Yong-Sheen;Cha, Suk-Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.43-46
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    • 2007
  • To find out the optimum design of hydrogen storage and supply tank using Metal Hydride (briefly MH) and to make clear the performance characteristics under various conditions are our research purpose. In order to use the low-temperature exhaust heat, $LaNi_{4.7}Al_{0.3}$ which operates under the low pressure of 1MPa is chosen, and we measure the basic properties, namely density, specific heat, PCT(Pressure-Concentration-Temperature) characteristic, and effective thermal conductivity. Then, a numerical calculation model of hydrogen storage using MH alloy is suggested and this thermal diffusion equation of model is solved by the backward difference method. This calculation results rate compared with the experimental results of the systems which installed 1kg MH alloy and, it is found out that our calculation model can well predict the experimental results. By the experimental using MH alloy, it is recognized that the hydrogen flow rate can control by the step adjustment of brine temperature.

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Interactions between Hydrodesulfurization of Thiophene and Hydrodenitrogenation of Pyridine and the Kinetic Analysis (수첨탈황과 탈질반응에서 Thiophene과 Pyridine의 상호영향과 그 속도론적 해석)

  • 박종희;한창훈;김경림
    • Journal of Korean Society for Atmospheric Environment
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    • v.4 no.1
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    • pp.13-22
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    • 1988
  • Interactions between hydrodesulfurization of thiophene and hydrodenitrogenation of pyridine and the kinetic analysis were studied over $Ni-W/\gamma-Al_2O_3$ catalysts and this study was made at temperatures ranging from 473-673 K and at total pressures ranging from 10-25 $\times 10^5$ Pa. Hydrodesulfurization of thiophene was inhibited by presence of pyridine at all temperatures studied, and the rate of pyridine hydrodenitrogenation was slower than that of thiophene hydrodesulfurization in the operating conditions. Pyridine hydrodenitrogenation was also inhibited by the presence of thiophene at low temperatures but was enhanced by the thiophene at temperatures higher than 613K. Thiophene reaction rate was determined by multiple linear regression analysis using Langmuir-Hinshelwood-Hougen-Watson model and the result was given to be $r = kP_T^p_H/(1+K_Tp_T+K_Pp_P)^2$. At each temperature, reaction rate constants and absorption equilibrium equilibrium constants were determined and the activation energy was 12.98 kcal/gmol from Arrhenius plot.

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Aging of Melt Spun Ribbons in Cu-Based Shape Memory Alloys at High Temperature (Melt Spinning된 Cu-Al-Ni-X계 형상기억합금 리본의 고온시효)

  • 최영택
    • Journal of Powder Materials
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    • v.2 no.3
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    • pp.208-215
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    • 1995
  • The aging effects on the characteristics of the melt spun Cu based shape memory alloys have been investigated by the microhardness test, X-ray diffraction, differential scanning calorimetry, scanning electron microscopy and transmission electron microscopy. After aged for specific times, hardness of the ribbons began to increase and shape memory capacity diminished. At the initial stage of aging the austenitic transformation temperatures increased gradually, but at last became nearly constant: That is, the aging deteriorated the thermal stability. The increase in hardness was due to the formation of the $\gamma_2$ precipitates. The loss in the shape memory capacity was due to the decrement of solute atoms in the matrix by the formation of the $\gamma_2$ precipitates. In this study, it was confirmed that Mn is an effective element for Improving the thermal stability.

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