• Title/Summary/Keyword: $NaMnO_4$

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Production of Extracellular Amylase by Bacillus thuringiensis subsp. kurstaki HD-1 and its Characteristics (Bacillus thuringiensis subsp. kurstaki HD-1의 아밀라제 생산과 특성 연구)

  • 김수영;유관희;이영주;이형환
    • Korean journal of applied entomology
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    • v.28 no.2
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    • pp.69-75
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    • 1989
  • The extracellular amylase production by Bacillus thuringiensis subsp. kurstaki HD-l in amylase production media and its characteristics were investigated. The amylase production was highest in the medium composed of 0.2% soluble starch, 1.0% Bacto-peptone, 0.3% beef extract, 0.3% yeast extract, 0.5% NaCl, 0.3% $K_2HPO_4$, 0.1% $KH_2PO_4$, 0.012% $CaCl_2$.$2H_2O$, 0.005% $MnSO_4$.$H_2O$, and 0.03% $MgSO_4$.$7H_2O$. The amylase activity was inhibited by 50mM EDT A. The enzyme was optimally active from pH 6.5 to 7.0 at $55^{\circ}C$, The specific activity of the enzyme in the ethanol precipitate was 2.01 units/mg, and the Km value was approxi-mately 0.8 mg/ml.

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Effects of $Fe_{3}O_{4}$ Addition on Spinel Phase $LiMn_{2}O_{4}$ for $CO_{2}$ Decomposition (($CO_{2}$ 분해용 스피넬상 $LiMn_{2}O_{4}$에 대한 $Fe_{3}O_{4}$ 첨가효과)

  • Yang, Chun-Mo;Rim, Byung-O;Kim, Seung-Ho;Kim, Soon-Tae
    • Journal of the Korean Applied Science and Technology
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    • v.18 no.3
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    • pp.167-173
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    • 2001
  • The spinel $LiMn_{2}O_{4}$ powders were synthesized at $480^{\circ}C$ for 12 h in air by a sol-gel method using manganese acetate and lithium hydroxide as starting material and the $Fe_{3}O_{4}$ powders were synthesized by the precipitation method using $0.2M-FeSO_{4}{\cdot}H_{2}O$ and 0.5M-NaOH. The synthesized $Fe_{3}O_{4}$ powders were mixed at portion of 5, 10, 15 and 20 wt% about $LiMn_{2}O_{4}$ powders through ball-milling followed by drying at room temperature for 48 h in air. The mixed catalysts were reduced at $350^{\circ}C$ for 3 h by hydrogen and the decomposition rate of carbon dioxide was measured at $350^{\circ}C$ using the reduced catalysts. As the results of $CO_{2}$ decomposition experiments, the decomposition rates of carbon dioxide were 85% in all catalysts but the initial decomposition rates of $CO_{2}$ were slightly high in the case of the $5%-Fe_{3}O_{4}$ added catalyst.

Parallel Computation for Extended Edit Distances Using the Shared Memory on GPU (GPU의 공유메모리를 활용한 확장편집거리 병렬계산)

  • Kim, Youngho;Na, Joong Chae;Sim, Jeong Seop
    • KIPS Transactions on Computer and Communication Systems
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    • v.4 no.7
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    • pp.213-218
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    • 2015
  • Given two strings X and Y (|X|=m, |Y|=n) over an alphabet ${\Sigma}$, the extended edit distance between X and Y can be computed using dynamic programming in O(mn) time and space. Recently, a parallel algorithm that takes O(m+n) time and O(mn) space using m threads to compute the extended edit distance between X and Y was presented. In this paper, we present an improved parallel algorithm using the shared memory on GPU. The experimental results show that our parallel algorithm runs about 19~25 times faster than the previous parallel algorithm.

CO oxidation Reaction over copper metal oxide catalysts (구리복합산화물 촉매상에서 일산화탄소의 산화반응)

  • Lee, Hak Beum;Koh, Hyoung Lim
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.1
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    • pp.129-135
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    • 2016
  • CO oxidation was performed with Cu-Mn and Cu-Zn co-precipitated catalysts as differential precipitant, metal ratio and calcination temperature. The effects of differential metal mole ratio and calcination temperature in mixed metal oxide catalyst were investigated with CO oxidation reaction. Physiochemical properties were studied by XRD, $N_2$ sorption and SEM. 2Cu-1Mn with $Na_2CO_3$ catalyst calcined at $270^{\circ}C$ has a large surface area $43m^2/g$ and the best activity for CO oxidation. $Cu_{0.5}Mn_{2.5}O_4$ in XRD peak shows the lower activity than others. The catalytic activity over the catalyst calcined $270^{\circ}C$ displayed the highest conversion, and it was better activity comparing with Pt catalysts CO conversion.

Cyclic Properties of Li[Co0.17Li0.28Mn0.55]O2 Cathode Material

  • Park, Yong-Joon;Hong, Young-Sik;Wu, Xiang-Lan;Kim, Min-Gyu;Ryu, Kwang-Sun;Chang, Soon-Ho
    • Bulletin of the Korean Chemical Society
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    • v.25 no.4
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    • pp.511-516
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    • 2004
  • A Li$[Co_{0.17}Li_{0.28}Mn_{0.55}]O_2$ cathode compound was prepared by a simple combustion method. The X-ray diffraction pattern showed that this compound could be classified as ${\alpha} -NaFeO_2$ structure type with the lattice constants of a = 2.8405(9) ${\AA}$ and c = 14.228(4) ${\AA}$. According to XANES analysis, the oxidation state of Mn and Co ions in the compound were 4+ and 3+, respectively. During the first charge process, the irreversible voltage plateau at around 4.65 V was observed. The similar voltage-plateau was observed in the initial charge profile of other solid solution series between $Li_2MnO_3\;and\;LiMnO_2$ (M=Ni, Cr...). The first discharge capacity was 187 mAh/g and the second discharge capacity increased to 204 mAh/g. As the increase of cycling number, one smooth discharge profile was converted to two distinct sub-plateaus and the discharge capacity was slowly decreased. From the Co and Mn K-edge XANES spectra measured at different cyclic process, it can be concluded that irreversible transformation of phase is occurred during continuous cycling process.

Saturated- and Unsaturated-Azamacrocyclic Complexes $(M = Co^{3+}, Fe^{3+}$ or $Mn^{3+})$ Catalyzed Oxidation of Hindered Phenols by Molecular Oxygen under Sodium Borohydride (Sodium Borohydride 하에서 산소에 의한 포화- 및 불포화-질소주게 거대고리 착물 $(M=Co^{3+},\;Fe^{3+}$$Mn^{3+})$을 촉매로 한 Hindered Phenols의 산화반응)

  • Yu-Chul Park;Seong-Su Kim;Hun-Gil Na
    • Journal of the Korean Chemical Society
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    • v.37 no.7
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    • pp.648-654
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    • 1993
  • $[M(cyclam)X_2]Y(M=Co^{3+},\;Fe^{3+},\;Mn^{3+}\;:\;X=Cl-^,\;Br^-,\;NCS^-\;:\;Y=Cl^-,\;Br^-,\;NCS^-),\;[Co(trans-14-diene)X_2]Y(X=Cl^-,\;Br^-\;:\;Y=ClO_4^-)\;and\;[Co(trans-14-diene)](ClO_4)_2$ were able to activate an molecular oxygen under sodium borohydride. 2,4-di-tert-butylphenol and 2,6-di-tert-butylphenol reacted with activated molecular oxygen to give 2,4-tert-butyl-1,6-benzoquinone(BQ) and 3,5,3',5'-tetra-tert-butyldiphenoquinone(DPQ). The saturated tetraazamacrocyclic complexes, $[Co(cyclam)X_2]Y$, were more an effective catalyst than $[Co(trans-14-diene)X_2]Y$ the unsaturated complexes in the formation of BQ and DPQ. The mole ratio of $O_2$ vs. catalyst $(O_2/M)$ for $[Co(cyclam)X_2]Y$ and [Co(trans-14-diene)X_2]Y$ was 1/1, while it was 1/2 for $[M(cyclam)Cl_2]Cl(M=Fe(III),\;Mn(III))$. The results suggested that Co(III)-macrocyclic complexes activated molecular oxygen as superoxolike ${O_2}^-$ and $[M(cyclam)Cl_2]Cl(M=Fe(III),\;Mn(III))$ activated that as peroxolike $O_2^{2-}$.

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Characteristics of Groundwater Pollution and Contaminant Attenuation at Waste Disposal Sites (폐기물 매립지 주변의 지하수 오염과 오염물질의 지연 특성)

  • 오석영;전효택
    • Journal of the Korean Society of Groundwater Environment
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    • v.3 no.1
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    • pp.37-49
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    • 1996
  • The objectives of this study are to investigate the groundwater and surface water contamination, to interpret the attenuation mechanism of contaminant transport, and to find the appropriate contamination indicator. at the two big landfill sites : Nanjido Landfill and Hwasung Landfill. Leachate from the Nanjido, th, Hwasung and the Kimpo waste disposal sites is characterized by high temperature (31.7-40.1$^{\circ}C$), high electric conductivity (14,650-32,800 ${\mu}$S/cm), somewhat higher pH(7.58-8.45) and low Eh (-119.4-20.4 mV), and is enriched in both major (Na$^{+}$, K$^{+}$, Ca$^{2+}$, Mg$^{2+}$, HC $O_3$$^{-}$, Cl$^{-}$) and minor (Mn, Sr$^{2+}$, Ba$^{2+}$, Li$^{+}$, F$^{-}$, Br$^{-}$) ions. Municipal solid waste leachate and industrial waste leachate are effectively discriminated by the content of S $O_4$$^{2-}$, Fe, and heavy metals. The attenuation mechanism of each component was assessed using the chemical analysis. Cl-normalizing process, WATEQ4F simulation, and preceding flownet analysis. Based on the calculation of Contamination Factor, K, Na, Ca, Mg, B, Zn, HC $O_3$, Cl, F, Br and TOC are effective contamination indicators in the Nanjido landfill site, and K, Na, Ca, Mg, B, S $O_4$, HC $O_3$, Cl, F, Br and TOC in the Habsburg landfill site Particularly, TOC is the best contamination indicator in landfill sites influenced by sea water.

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Determination of Metal Elements in Mongolian Chromite (몽골산 크롬철광 중의 금속성분 분석)

  • Choi, Kwang Soon;Lee, Chang Heon;Pyo, Hyung Yeol;Park, Soon Dal;Joe, Kih Soo
    • Analytical Science and Technology
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    • v.13 no.6
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    • pp.766-774
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    • 2000
  • The major and trace constituents of Mongolian chromite were analyzed by ICP-AES. The dissolution procedures, mixed acid ($HClO_4+H_3PO_4$) digestion and fusion with $Na_2O_2$ flux, have been studied to dissolve the chromite. The optimum dissolution method was found to be a fusion with $Na_2O_2$ flux. The effect of large amount of Na on major and trace constituents was examined when these elements were determined by ICP-AES. There was no effect on major elements at a concentration of Na 250 mg/L solution. The emission intensity of trace constituents containing Na 1,250 mg/L decreased to 1.0-5.2% according to elements and wavelengths. The result of this method was compared with that of neutron activation analysis (NAA) to confirm the accuracy of this procedure. The results between two methods were in a good agreement within less than 5% for $Al_2O_3$, $Cr_2O_3$, MgO and -20 to 8% for Co, Mn, V, Zn, respectively.

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[ $M\ddot{o}ssbauer$ ] Spectroscopy and Crystal Chemistry of Aenigmatite, $Na_4(Fe^{2+},Ti,Fe^{3+}){_{12}}(Fe^{3+},Si){_{12}}O_{40}$ (에이니그마타이트($Na_4(Fe^{2+},Ti,Fe^{3+}){_{12}}(Fe^{3+},Si){_{12}}O_{40}$)의 뫼스바우어 분광분석과 결정화학)

  • Choi, Jin-Beom
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.4
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    • pp.367-376
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    • 2007
  • Aenigmatite, $Na_4(Fe^{2+},Ti,Fe^{3+}){_{12}}(Fe^{3+},Si){_{12}}O_{40}$, is a common constituent of sodium-rich alkaline igneous rocks and is classified a an open-branched single-chain silicate. $M\ddot{o}ssbauer$ spectroscopy of three natural aenigmatite specimens were done and the detailed crystal chemistry was obtained. Fitting of $M\ddot{o}ssbauer$ spectra led to the resolution of nine peaks. They consist of three doublets of $Fe^{2+}/oct$ and one merged peak at low velocity matching to two small peaks at high velocity which were assigned to $Fe^{3+}/tet\;and\;Fe^{2+}/oct$, respectively. Using the peak area for $Fe^{2+}\;and\;Fe^{3+}$ peaks, analytical data were recalculated. Precise assignment of $Fe^{2+}\;and\;Fe^{3+}$ ions in tetrahderal and octahedral sites revealed detailed crystal chemistry of aenigmatite. The existence of significant amounts of $Fe^{3+}/tet$ indicates that $Fe^{3+}$ has preference over $Al^{3+}$ for the tetrahedral sites. Crystal chemistry of aenigmatite (AEN1) yields the formula of $(Na_{3.97}Ca_{0.03})(Ca_{0.11}Mn_{0.59}Fe^{2+}{_{8.07}}Ti_{2.07}Mg_{0.70}Fe^{3+}{_{0.43}}Al_{0.04})(Fe^{3+}{_{0.56}}Al_{0.18}Si_{11.26})O_{40}$.

Effects of Calcinations Temperature on the Electrochemical Properties of Li[Ni0.6Co0.2Mn0.2]O2 Lithium-ion Cathode Materials (리튬 이차전지용 양극활물질 Li[Ni0.6Co0.2Mn0.2]O2의 소성 온도가 전기화학적 특성에 미치는 영향)

  • Yoo, Gi-Won;Jeon, Hyo-Jin;Son, Jong-Tae
    • Journal of the Korean Electrochemical Society
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    • v.16 no.2
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    • pp.59-64
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    • 2013
  • Using $Na_2CO_3$ and $MeSO_4$ (Me = Ni, Co and Mn) as starting materials, the precursor of $[Ni_{0.6}Co_{0.2}Mn_{0.2}]CO_3$ has been synthesized by carbonate co-precipitation. The precursor was mixed with $Li_2CO_3$, and calcined at 750, 850, and$950^{\circ}C$ in air. Effect of calcinations temperature on characteristics of $Li[Ni_{0.6}Co_{0.2}Mn_{0.2}]O_2$ cathode materials was investigated. The structure and characteristics of $Li[Ni_{0.6}Co_{0.2}Mn_{0.2}]O_2$ were determined by X-ray diffraction (XRD), Scanning electron microscopy (SEM) and electrochemical measurements. The X-ray diffraction (XRD) results show that the intensity ratio of $I_{(003)}/I_{(104)}$ increased and the R-factor ratio decreased with the increase of calcinations temperature. And Scanning electron microscopy (SEM) result show that the primary particle size increased. Especially, the $Li[Ni_{0.6}Co_{0.2}Mn_{0.2}]O_2$ calcined at $950^{\circ}C$ for 24 H shows excellent electrochemical performances with reversible specific capacity of $165.3mAhg^{-1}$ [cut-off voltage 2.5~4.3 V, 0.1 C($17mAhg^{-1}$)] and good capacity retention of 95.4% after 50th charge/discharge cycles[cut-off voltage 2.5~4.3 V, 1 C($170mAhg^{-1}$)].