• Microbiology and Biotechnology Letters
• /
• v.51 no.2
• /
• pp.203-207
• /
• 2023

The N₂O-reducing rhizobacterium, Pseudomonas sp. M23, was isolated from maize rhizosphere soil. The maximum N₂O reduction rate of the strain M23 was 15.6 mmol·g-dry cell weight^-1·h^-1. Its N₂O reduction activity was not inhibited by diesel contaminant, and it was enhanced by the addition of the root exudates of maize and tall fescue. The remediation efficiency of diesel-contaminated soil planted with maize or tall fescue was not inhibited by inoculating with the strain M23. Root weights in the soil inoculated with the strain M23 were greater than those in the non-inoculated soil. These results suggest that Pseudomonas sp. M23 is a promising bacterium to mitigate N₂O emissions during the remediation of diesel-contaminated soil.

• Clean Technology
• /
• v.20 no.1
• /
• pp.28-34
• /
• 2014

In this study, we synthesized $TiO_2$ supports with nanosized crystalline structure by solvothermal method and prepared $TiO_2$ supported Pd-Cu catalysts. It was shown that the crystalline size of $TiO_2$ support in the catalyst influenced on the catalytic activity of nitrate reduction in water. The catalyst with the smaller crystalline size of $TiO_2$ support presented faster nitrate reduction rate, but had low nitrogen selectivity due to high pH environment of reaction medium during the reaction. Through injection of carbon dioxide as a pH buffer, the nitrogen selectivity increased by about 60%. Furthermore, we investigated that the relationships between the catalytic performance and the physicochemical properties of the prepared catalysts characterized by $N_2$ adsoprtion-desorption, X-ray diffraction (XRD), $H_2$-temperature programmed reduction (TPR), X-ray photoelectron spectroscopy (XPS).

• Microbiology and Biotechnology Letters
• /
• v.49 no.2
• /
• pp.225-238
• /
• 2021

CH₄-oxidizing and N₂O-reducing bacterial consortia were enriched from the rhizosphere soils of maize (Zea mays) and tall fescue (Festuca arundinacea). Illumina MiSeq sequencing analysis was performed to comparatively analyze the bacterial communities of the consortia with those of the rhizosphere soils. Additionally, the effect of root exudate on CH₄ oxidation and N₂O reduction activities of the microbes was evaluated. Although the inoculum sources varied, the CH₄-oxidizing and N₂O-reducing consortia derived from maize and tall fescue were similar. The predominant methanotrophs in the CH₄-oxidizing consortia were Methylosarcina, Methylococcus, and Methylocystis. Among the N₂O-reducing consortia, the representative N₂O-reducing bacteria were Cloacibacterium, Azonexus, and Klebsiella. The N₂O reduction rate of the N₂O-reducing consortium from maize rhizosphere and tall fescue rhizosphere increased by 1.6 and 2.7 times with the addition of maize and tall fescue root exudates, respectively. The CH₄ oxidization activity of the CH₄-oxidizing consortia did not increase with the addition of root exudates. The CH₄-oxidizing and N₂O-reducing consortia can be used as promising bioresources to mitigate non-CO₂ greenhouse gas emissions during remediation of oil-contaminated soils.

• Journal of the Korean Electrochemical Society
• /
• v.10 no.2
• /
• pp.110-115
• /
• 2007

Solid oxide fuel cell(SOFC) has high fuel flexibility due to its high operating temperatures. Hydrocarbonaceous fuels such as diesel has several advantages such as high energy density and established infrastructure for fuel cell applications. However diesel reforming has technical problems like coke formation in a reactor, which results in catastrophic failure of whole system. Performance degradation of diesel autothermal reforming (ATR) leads to increase of undesirable hydrocarbons at reformed gases and subsequently degrades SOFC performance. In this study, we investigate the degradation of SOFC performance(OCV, open circuit voltage) under hydrocarbon(n-Butane) feeds and characteristics of diesel performing under various ratios of reactants($H_2O/C,\;O_2/C$ molar ratios) for improvement of SOFC performance. Especially we achieved relatively high performance of diesel ATR under $H_2O/C=0.8,\;O_2/C=3$ condition.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2002.02a
• /
• pp.167-167
• /
• 2002

• Clean Technology
• /
• v.24 no.3
• /
• pp.212-220
• /
• 2018

Oxy-fuel combustion is considered as a promising greenhouse gas reduction technology in power plant. In this study, the behaviors of NO and $SO_2$ were investigated under the condition that in-furnace $deNO_x$ and $deSO_x$ methods are applied in oxy-fuel circulating fluidized bed combustion condition. In addition, the generation trends of $SO_3$, $NH_3$ and $N_2O$ were observed. For the purpose, limestone and urea solution were directly injected into the circulating fluidized bed combustor. The in-furnace $deSO_x$ method using limestone could reduce the $SO_2$ concentration in exhaust gas from ~403 to ~41 ppm. At the same experimental condition, the $SO_3$ concentration in exhaust gas was also reduced from ~3.9 to ~1.4 ppm. This trend is mainly due to the reduction of $SO_2$. The $SO_2$ is the main source of the formation of $SO_3$. The negative effect of $CaCO_3$ in limestone, however, was also appeared that it promotes the NO generation. The NO concentration in exhaust gas reduced to ~26 - 34 ppm by appling selective non-catalytic reduction method using urea solution. The $NH_3$ concentration in exhaust gas was appeared up to ~1.8 ppm during injection of urea solution. At the same time, the $N_2O$ generation also increased with increase of urea solution injection. It seems that the HNCO generated from pyrolysis of urea converted into $N_2O$ in combustion atmosphere. From the results in this study, the generation of other pollutants should be checked as the in-furnace $deNO_x$ and $deSO_x$ methods are applied.

• Journal of Power System Engineering
• /
• v.19 no.3
• /
• pp.16-21
• /
• 2015

Nitrous oxide($N_2O$) concentration in the atmosphere has been constantly increased by the human activities with industrial growth after the industrial revolution. One of factors to increase $N_2O$ concentration in the atmosphere is the $N_2O$ emission caused by the combustion of marine fuel. Especially, a sulfur component included in marine fuel oils is known as increasing the $N_2O$ formation in diesel combustion. Form this point of view, $N_2O$ emission from a ship is not negligible. On the other hand, Exhaust gas recirculation(EGR) that have thermal, chemical and dilution effect is effective method for reducing the NOx emission. In this study, an author investigated $N_2O$ reduction by using EGR on a direct injection diesel engine. The test engine was a 4-stroke diesel engine with maximum output of 12 kW at 2600rpm, and operating condition of the engine was a fixed load of 75%. The experimental oil was a blend-fuel that were adjusted with sulfur ratio of 3.5%, and EGR ratio of 0%, 10%, 20% and 30%. In conclusion, diesel fuel that contained 3.5% sulfur component increased $SO_2$ emission in exhaust gas, and increment of EGR ratio reduced NO emission. Moreover, $N_2O$ emission was decreased as over 50% at EGR ratio of 10% and reduced 100% at EGR ratio of 30% compared with $N_2O$ emission of 0% EGR ratio.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2011.02a
• /
• pp.392-392
• /
• 2011

현재의 태양전지에 사용되는 wafer는 원가저감을 위해 점점 얇아지고 있는 추세이다. 하지만 wafer가 얇아질수록 장파장 영역의 광자는 충분히 활용할 수 없게 된다. 대부분의 광자는 50um 지점에 도달하였을 때 그 역할을 다하고 소멸하게 되며, 특히 800nm 이상의 장파장에 대한 generation rate는 wafer 두께에 따라 급격한 차이를 보이게 된다. 따라서 장파장 영역의 광자를 효율적으로 사용할 뿐만 아니라 원가 저감을 위해 더욱 얇아지고 있는 추세의 wafer의 장파장 이용을 보상하기 위해서 TCO를 이용한 back-reflector의 역할은 가장 좋은 해결책이 될 것이다. 본 연구에서는 Macleod를 이용하여 ZnO, Al-doped ZnO, TiN, TiO2와 같은 다양한 TCO 물질에 대한 다양한 simulation을 실시 하여 reflectance 특성을 알아보았다. 상기 simulation결과로써 Al-doped ZnO가 가장 reflectance 특성이 좋게 나타났었으며 이를 이종접합 태양전지에 적용하여 광학적 및 전기적 특성 변화에 대해서 분석하였다.

• Journal of Korean Society of Transportation
• /
• v.32 no.2
• /
• pp.93-105
• /
• 2014

This study evaluated the relative efficiency of mobile emission reduction countermeasures through a Data Envelopment Analysis (DEA) approach and determined the priority of countermeasures based on the efficiency. Ten countermeasures currently applied for reducing greenhouse gases and air pollution materials were selected to make a scenario for evaluation. The reduction volumes of four air pollution materials(CO, HC, NOX, PM) and three greenhouse gases($CO_2$, $CH_4$, $N_2O$) for the year 2027, which is the last target year, were calculated by utilizing both a travel demand forecasting model and variable composite emission factors with respect to future travel patterns. To estimate the relative effectiveness of reduction countermeasures, this study performed a super-efficiency analysis among the Data Envelopment Analysis models. It was found that expanding the participation in self car-free day program was the most superior reduction measurement with 1.879 efficiency points, followed by expansion of exclusive bus lanes and promotion of CNG hybrid bus diffusion. The results of this study do not represent the absolute data for prioritizing reduction countermeasures for mobile greenhouse gases and air pollution materials. However, in terms of presenting the direction for establishing reduction countermeasures, this study may contribute to policy selection for mobile emission reduction measures and the establishment of systematic mid- and long-term reduction measures.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.14 no.4
• /
• pp.1022-1032
• /
• 1990

본 연구에서는 기체연료 연소시 산소부화연소의 적용에 대한 연구를 시작하는 단계에서 상용 프로판을 산소부화연소 시킴으로써 첨가된 산소에 의한 반응시간의 단 축과 공급 공기량중의 질소량 저감에 희한 연소가스중의 NO농도를 측정하고, 이에 따 른 화염장의 온도 및 연소가스중의 $O_{2}$ 및 N$_{2}$농도를 측정하여 그들의 상관관 계를 가지고 NO의 배출특성을 고찰함으로써 기체연료의 산소부화연소에 따른 효율적인 에너지 이용을 위한 연소장치개발과 오염물질 저감대책에 기초자료를 제공하는데 그 목적이 있다.