• Title/Summary/Keyword: $N_2$ conversion

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Design of a Broadband Microwave Power Divider/Combiner using Coaxial-Conical-Radial Transmission Line Conversion (동축-원추-방사형 선로변환에 의한 마이크로파 전력분할/합성기의 광대역 설계)

  • Choi, Young-Kyu
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.7
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    • pp.1385-1390
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    • 2011
  • A coaxial-conical-radial transmission line conversion circuits have been investigated to realize a low loss high performance microwave power divider/combiner. In order to optimize the characteristics of the device, the power divider/combiner was designed separately with two parts-the inner part and the outer part. Utilizing the rectangular approximation of the outer part, we can design the low loss device which is not affected by the partition number N of the outer part. The small return loss which is lower than 20dB was obtained on the frequency range of 5.15GHz(7.45~12.60GHz). A conical connector was employed for smooth connection between the central coaxial line and the outer radial line. Making use of the $47^{\circ}$ and $90^{\circ}$ 2-stage conical connector, the return loss lower than 30dB was obtained on the operating frequency range of 5GHz. The total return loss of the designed divider/combiner was lower than 20dB on the frequency range of 5GHz for the partition number N=11, N=12 and N=16.

Overall Conversion Efficiency for Dimethylsulfide to Sulfur Dioxide in the Marine Boundary Layer-An Overview

  • Shon, Zang-Ho
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.E2
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    • pp.107-120
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    • 2002
  • Dimethyl sulfide (DMS) is the major sulfur gas released from the ocean. The atmospheric DMS released from the ocean is oxidized mainly by hydroxyl (OH) radical during the day and nitrate (NO$_3$) radical at night to form sulfur dioxide (SO$_2$) as well as other stable products. The oxidation mechanism of DMS via OH has been known to proceed by two channels; abstraction and addition channels. The major intermediate product of the addition channel has been known to be dimethylsulfoxide (DMSO) based on laboratory chamber studies and field experiments. However, a branching ratio for DMSO formation is still uncertain. The reaction of DMSO with OH ultimately produces SO$_2$and dimethylsulfone. The major product of the abstraction channel has known to be SO$_2$from laboratory chamber studies. But overall conversion efficiency for DMS to SO$_2$from DMS oxidation is still inconsistent in the literature. Based on laboratory and field studies, the conversion efficiency from the abstraction channel is likely to be greater than 0.5, while that from the addition channel is likely to be greater than 0.6. Overall conversion efficiency from DMS to SO$_2$might be greater than 0.5 based on the above two values in the remote marine boundary layer (MBL). This high efficiency in the remote MBL is supported by strong coupling between DMS and SO$_2$measurements with high temporal resolution.

Effect of Propene($C_3H_6$) ON NO-$NO_2$ Conversion Process in a Pulsed Corona Discharge (펄스코로나 방전에서 프로핀($C_3H_6$)이 NO-$NO_2$ 변환에 미치는 영향에 관한 연구)

  • 박광서;전배혁;전광민
    • Transactions of the Korean Society of Automotive Engineers
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    • v.8 no.5
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    • pp.67-77
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    • 2000
  • Investigated was the effect of propene(C3H6) on the NO-NO2 conversion in dry exhaust gases from lean burn engine using a pulsed corona discharge. A kinetic model was developed to characterize the plasma chemistry in simulated exhausts containing propene. The model uses ELENDIF program to solve Boltzmann equation for electron energy distribution function, and CHEMKIN-II program to solve stiff ODE(ordinary differential equation) problems for species concentrations. The corona discharge energy per pulse and the time-space averaged E/N were obtained by fitting the model to experimental data. The model calculation shows good agreement for NO and NO2 concentrations with the experimental data, and predicts the formation of byproducts such as CH2O, CH3HCO, CO AND CH3NO2 Propene enhances the NOx conversion enormously at lower energy density and the NOx conversion increases with the increase of initial propene and oxygen concentration, and temperature.

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The Synthesis of Pyrrolidone-N-sulfonyl Chloride and Its Catalytic Effect in Anionic Polymerization of Pyrrolidone (Pyrrolidone-N-sulfonyl Chloride의 합성 및 Pyrrolidone-N-sulfonyl Chloride / KOH 촉매작용에 의한 Pyrrolidone의 음이온 중합)

  • W.J. Chung;S.K. Choi
    • Journal of the Korean Chemical Society
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    • v.23 no.6
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    • pp.402-411
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    • 1979
  • The synthesis of pyrrolidone-N-sulfonyl chloride has been carried out by the reaction of pyrrolidone with sulfuryl chloride in benzene. It was attempted to study the catalytic effect of pyrroldone-N-sulfonyl chloride as an initiator for anionic polymerization of pyrrolidone. It was found that as a concentration of initiator decreased, inherent viscosity of the resulting polymer increased up to 1.8 dl/g. The highest rate of polymerization and equilibrium conversion was observed when mole ratio of PNSC to KOH was 0.25. In general, the observed value of polymerization and equilibrium conversion in circumstances using PNSC/KOH catalysis system were higher than using $CO_2$/KOH catalysis system.

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Polymerization of Lactams (IX). Anionic Polymerization of 2-Pyrrolidone via Phenylphosphonyl-N,N'-bis-${\varepsilon}$-caprolactam / KOH Catalysis (Lactam의 중합 (제9보). Phenylphosphonyl-N,N'-bis-${\varepsilon}$-caprolactam / KOH 촉매작용에 의한 2-Pyrrolidone 의 음이온 중합)

  • Jung Hag Park;Bal Jung;Sam K. Choi
    • Journal of the Korean Chemical Society
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    • v.24 no.2
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    • pp.167-174
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    • 1980
  • Anionic polymerization of 2-pyrrolidone was carried out via PPBC/KOH catalysis. The effects of PPBC/KOH mole ratio, KOH concentration and temperature on polymerization have been investigated. It was observed that the highest rate of polymerization and maximum conversion were obtained when PPBC/KOH mole ratio was around 0.5. The maximum conversion and the highest viscosity were obtained when the concentration of KOH was 2 mole percent. It was also found that while the rate of polymerization at $50^{\circ}C$ was higher than at $30^{\circ}C$ in the initial stage of polymerization, the conversion and viscosity were decreased as polymerization time was extended. The rate constant $(k_p)$ of polymerization was determined by least square method; the values of $k_p$ obtained were $22.4\;l/mole{\cdot}hr\;at\;30^{\circ}C\;and\;191.9\;l/mole{\cdot}hr\;at\;50^{\circ}C$, respectively.

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Analysis and Design of a Multi-resonant Converter with a Wide Output Voltage Range for EV Charger Applications

  • Sun, Wenjin;Jin, Xiang;Zhang, Li;Hu, Haibing;Xing, Yan
    • Journal of Power Electronics
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    • v.17 no.4
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    • pp.849-859
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    • 2017
  • This paper illustrates the analysis and design of a multi-resonant converter applied to an electric vehicle (EV) charger. Thanks to the notch resonant characteristic, the multi-resonant converter achieve soft switching and operate with a narrowed switching frequency range even with a wide output voltage range. These advantages make it suitable for battery charging applications. With two more resonant elements, the design of the chosen converter is more complex than the conventional LLC resonant converter. However, there is not a distinct design outline for the multi-resonant converters in existing articles. According to the analysis in this paper, the normalized notch frequency $f_{r2n}$ and the second series resonant frequency $f_{r3n}$ are more sensitive to the notch capacitor ratio q than the notch inductor ratio k. Then resonant capacitors should be well-designed before the other resonant elements. The peak gain of the converter depends mainly on the magnetizing inductor ratio $L_n$ and the normalized load Q. And it requires a smaller $L_n$ and Q to provide a sufficient voltage gain $M_{max}$ at ($V_{o\_max}$, $P_{o\_max}$). However, the primary current increases with $(L_nQ)^{-1}$, and results in a low efficiency. Then a detailed design procedure for the multi-resonant converter has been provided. A 3.3kW prototype with an output voltage range of 50V to 500V dc and a peak efficiency of 97.3 % is built to verify the design and effectiveness of the converter.

Photoelectrodchemical Conversion by Polycrystalline $TiO_2$ Electrodes ($TiO_2$ 다결정 전극에 의한 광전기 화학변환)

  • 윤기현;윤상옥
    • Journal of the Korean Ceramic Society
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    • v.20 no.1
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    • pp.31-36
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    • 1983
  • The photoelectrochemical conversion by polycrystalline $TiO_2$ electrodes is effected by applied voltage oxidized $TiO_2$ thickness temperature and concentration of a, P. E. C cell. Anodic current starts at -0.8V in 1N-NaOH solu-tion and photocurrent appears around 420nm frequency. And the emf of the cell drops with the rate of 58.5mV/PH.

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A Study on Error Compensation for Quadrature Modulator in Frequency Direct Conversion Method (주파수 직접변환방식의 직교변조부 에러보정에 관한 연구)

  • 백주기;이일규;방성일;진년강
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.9 no.4
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    • pp.542-551
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    • 1998
  • In this study, a method of error compensation for channel gain imbalance, phase imbalance and local oscillator leakage in the modulator of frequency direct conversion is suggested. The compensation of channel imbalance can be carried out by using the received power after transmitting test signal. By applying this method, the phase imbalance conversion with frequency can be easily compensated since this method is rarely affected by the transmission channel. It is confirmed that the algorithm proposed in this study(iteration coefficient=11) converges faster than conventional algorithm(iteration coefficient=43). From the numerical results, the DC-offset, channel gain, phase imbalance compensation coefficient and iteration number converges into($f_1$=0.0199999, $f_2$=-0.050001, $C_{22}$=0.9133, $C_{12}$=-0.0524, N=13) when the local oscillator leakage is not considered. However, it converges into($f_1$=-0.02, $f_2$=-2.2476, $C_{22}$=0.9133, $C_{12}$=-0.0524, N=16) when the local oscillator leakage is considered.

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Degree of Conversion and Polymerization Shrinkage of Low and High Viscosity Bulk-Fill Giomer-based and Resin-based composites (저점도 및 고점도 Bulk-fill Giomer 복합레진과 Bulk-fill 복합레진의 전환율과 중합수축)

  • Kim, Heera;Lee, Jaesik;Kim, Hyunjung;Kwon, Taeyub;Nam, Soonhyeun
    • Journal of the korean academy of Pediatric Dentistry
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    • v.46 no.1
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    • pp.1-9
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    • 2019
  • The aim of this study was to compare the degree of conversion and polymerization shrinkage of low and high viscosity bulk-fill giomer-based and resin-based composites. Two bulk-fill giomer (Beautifil Bulk Restorative (BBR), Beautifil Bulk Flowable (BBF)), two bulk-fill (Tetric N-Ceram Bulk-fill (TBF), SureFil SDR flow (SDR)) and two conventional resin composites (Tetric N-Ceram (TN), Tetric N-flow (TF)) were selected for this study. The degree of conversion was measured by using Fourier transform infrared spectroscopy. Polymerization shrinkage was measured with the linometer. For all depth, BBR had the lowest degree of conversion and SDR had the highest. At 4 mm, the degree of conversion of low and high viscosity bulk-fill giomer resin composites was lower than that of bulk-fill resin composites (p < 0.05). At the depth between 2 mm and 4 mm, there were significant difference with TBF, TN and TF (p < 0.05), while no significant difference in the degree of conversion was measured for BBR, BBF and SDR. Polymerization shrinkage of six resin composites decreased in the following order: TF > SDR > BBF > TBF > TN and BBR (p < 0.05). Polymerization shrinkage of bulk-fill giomer resin composites was lower than that of bulk-fill resin composites (p < 0.05). From this study, it is found that the bulk-fill giomer resin composites and TBF were not sufficiently cured in 4 mm depth. The degree of conversion of low and high viscosity bulk-fill giomer resin composites was significantly lower than bulk-fill resin composites in both 2 mm and 4 mm depths. Therefore, such features of bulk-fill giomer resin composites should be carefully considered in clinical application.

A study on the n-CdS/p-InP solar cells (n-CdS/p-InP 태양전지에 관한 연구)

  • 송복식;최영복;한성준;문동찬;김선태
    • Electrical & Electronic Materials
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    • v.8 no.4
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    • pp.406-412
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    • 1995
  • A n-CdS thin films were evaporated by thermal evaporation method and their structure, optical transmission spectra and electrical characteristics were investigated. The photovoltaic characteristics of solar cells which were fabricated in optimum conditions measured. The evaporated CdS thin films showed in hexagonal structure and above 80% of optical transmission spectra regardless of impurity doping. The high quality thin films could be obtained at 150.deg. C temperature of substrate, which is useful for solar cell window layer with low resistivity of 6*10$\^$-2/(.ohm.-cm) by In doping We measured the electrical and optical characteristics of the n-CdS/p-InP heterojunction solar cells. The most efficient photovoltaic characteristics of heterojunction solar cells had the open circuit voltage of 0.66V, short circuit current density of 13.85mA/cm$\^$2/, fill factor of 0.576 and conversion efficiency of 8.78% under 60mW/cm$\^$2/ illumination.

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