• Title/Summary/Keyword: $NO_x$ production

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Environmental analysis of present and future fuels in 2D simple model marine gas tubines

  • El Gohary, M. Morsy
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.5 no.4
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    • pp.559-568
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    • 2013
  • Increased worldwide concerns about fossil fuel costs and effects on the environment lead many governments and scientific societies to consider the hydrogen as the fuel of the future. Many researches have been made to assess the suitability of using the hydrogen gas as fuel for internal combustion engines and gas turbines; this suitability was assessed from several viewpoints including the combustion characteristics, the fuel production and storage and also the thermodynamic cycle changes with the application of hydrogen instead of ordinary fossil fuels. This paper introduces the basic environmental differences happening when changing the fuel of a marine gas turbine from marine diesel fuel to gaseous hydrogen for the same power output. Environmentally, the hydrogen is the best when the $CO_2$ emissions are considered, zero carbon dioxide emissions can be theoretically attained. But when the $NO_x$ emissions are considered, the hydrogen is not the best based on the unit heat input. The hydrogen produces 270% more $NO_x$ than the diesel case without any control measures. This is primarily due to the increased air flow rate bringing more nitrogen into the combustion chamber and the increased combustion temperature (10% more than the diesel case). Efficient and of course expensive $NO_x$ control measures are a must to control these emissions levels.

Study on No-tillage Silage Corn Production with Legume Hairy Vetch ( Vicia villosa Roth ) Cover I. Changes of soil mineral nitrogen, yeild and nitrogen uptake of corn by quantity of hairy vetch cover (헤아리베치 피복을 이용한 옥수수 무경재배에 관한 연구 I. 헤아리베치의 피복량별 토양 무기태 질소함량 , 옥수수의 수량 및 질소 흡수량의 변화)

  • 서종호;이호진
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.18 no.1
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    • pp.43-48
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    • 1998
  • No-tillage silage corn with legume hairy vetch(Vicia villosa Roth, HV) has renewed interest in supply of mineral N, soil erosion control at sloping land and weed control by cover of HV killed. This study was conducted to monitor concentration of soil mineral N ($NO_3^-$ -N + $NH_4^+$-N) and to find out variation of growth, yield and N uptake of silage corn according to quantity of HV cover; HV-removed, 1X-HV, 2X-HV at field of Crop Experiment Station in 1996. HV groM in early spring decreased the mineral N of soil depth 7.5 -22cm before corn seeding. But, killed HV cover increased the concentration of soil mineral N at surface soil (0-7.5cm) up to 45.4mglkg at early growth stage of corn. Dry matter(Dh4) of corn at harvest was lower in W-removed than in Okg FNlha. But DM and N uptake of corn at harvest were increased by quantity of HV-cover increasing liom HV-removed to 2X-HV. Hairy vetch could substitute N fertilizer for silage corn by N mineralized h m HV killed, but reduced early growth and N uptake of corn before silk by reducing soil mineral N of plow layer.

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Role of Atmospheric Purification by Trees in Urban Ecosystem -in the Case of Yongin- (도시생태계 수목의 대기정화 역할 -용인시를 사례료-)

  • 조현길;안태원
    • Journal of the Korean Institute of Landscape Architecture
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    • v.29 no.3
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    • pp.38-45
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    • 2001
  • This study quantified annual $CO_2$, SO$_2$ and NO$_2$ uptake and annual $O_2$ production by trees in Yongin´s urban ecosystem, and explored values of urban tree plantings in atmospheric purification. Woody plant cover was only 7.7% with planting density of 1. trees/100$m^2$, and the tree-age structure was largely characterized by a young, growing tree population. Annual per capita pollutant emissions from fossil fuel consumption were 7.3t/yr for $CO_2$, 7.6kg/yr for SO$_2$, and 26.6kg/yr for NO$_{x}$. Carbon dioxide storage per unit urban area by trees was 13.1t/ha and the economic value for $CO_2$ storage was ₩6.6millions/ha. Annual atmospheric purification was 2.0t/ha/yr for $CO_2$ uptake, 2.0kg/ha/yr for SO$_2$ uptake, 4.0kg/ha/yr for NO$_2$ uptake and 1.5t/ha/yr for $O_2$ production, and the annual economic value for the atmospheric purification was ₩1.5millions/ha/yr. Urbantrees stored an amount of $CO_2$ equivalent to about 3.1% of the total annual $CO_2$ emissions, and annually offset total $CO_2$ emissions by 0.5%. Annual SO$_2$ and NO$_2$ uptake by trees equaled 0.5% of total SO$_2$ emissions and 0.3% of total NO$_{x}$ emissions, respectively. Urban trees also played an important role through producing annually 9.2 of the $O_2$ requirement for Yongin´s total population, despite relatively poor tree plantings. Future active plantings and greenspace enlargement in the study city could enhance the role of atmospheric purification by urban trees. The results from this study are expected to be useful in emphasizing environment benefits of urban trees, and in urging the continuous necessity for tree planting and management budget.get.

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Effect of Cut on Forage Production and Grain Yield of Naked Barley Cultivars (예취가 쌀보리 품종의 청초생산과 종실수량에 미치는 영향)

  • 강영길;강형식
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.36 no.4
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    • pp.294-299
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    • 1991
  • Eight naked barley cultivars were grown in three production systems to select proper cultivars for dual production of forage and grain and to determine production system x cultivar interactions. In the forage systems. barley was seeded on September 27 and October 17, harvested for forage on November 1. December 10 and February 12 from the September 27 planting (forage system I) and on December 10 and February 12 from the October 17 seeding(forage system II). In the grain-only system, barley was planted on November 5. In forage system I, oven-dried forage yields of eight cultivars ranged 195 to 296kg/10a and Saessalbori and Naehanssalbori yielded significantly higher than the other cultivars recording 280 and 296kg/ l0a, respectively. In forage system II, oven-dried forage yields of eight cultivars ranged 106 to 143kg/10a showing no significant difference among cultivars. Production system x cultivar interactions were significant for lodging at maturity, powdery mildew rating, 1000 kernel weight and grain yield. Leaf area index and biomass at heading, no. of spikes per $m^2$, no. of kernels per spike and test weight were not affected by the production system. Forage utilization delayed heading by 3 days and reduced culm length, spike length, lodging due to heavy rain on May 5 and lodging at maturity except for Songhagbori and Naehanssalbori. Forage utilization did not significantly affect grain yield from the September 27 planting but reduced 9% from the October 17 planting. while Saessalbori and Hyangcheonggwa 1 yielded significantly less than in the grain-only system. Songhagbori appears to be a proper cultivar for dual production of forage and grain in Cheju, considering forage and grain yields. and lodging and powdery mildew resistance.

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Studies on the Estimation of Leaf production in Mulberry Trees III Estimation of the Leaf production by the Measurement of Some Characters (상엽수확고 측정에 관한 연구 제3보 각형질 가중치(Weight)에 의한 수량의 규정)

  • 한경수;장권열;안정준
    • Journal of Sericultural and Entomological Science
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    • v.9
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    • pp.21-25
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    • 1969
  • Various formulae for estimation of leaf production in mulberry trees were investigated and obtained. Four varieties of mulberry trees were used as the materials, and four characters. namely branch length (X, 1). branch diameter (X, 2). leaf number per branch (X, 3), and leaf area per branch (X, 4). were studies. The formulae to eatimate the leaf yield of mulberry trees are as follows: 1. Y$_1$v$_1$=-115.760+0.068X$_1$+165.756X$_2$ Y$_1$v$_2$=-221.500+1.768X$_1$+38.152X$_2$ Y$_1$v$_3$=-253.826-0.116X$_1$+289.507X$_2$ Y$_1$v$_4$= -157.559+1.063X$_1$+106.088X$_2$ where Y$_1$v$_1$, Y$_1$v$_2$, Y$_1$v$_3$, Y$_1$v$_4$, are showed the estimated yield of the each variety, namely Gaeryang souban, Ilchirye, Nosang. and Suwon Sang No. 4, respectively. X$_1$ and X$_2$ denote the measured values of branch length and branch diameter, respectively. 2. Y$\sub$7/v$_1$=-118.478-0.665X$_1$+184.445X$_2$+2.346X$_3$ Y$\sub$7/v$_2$=-217.432+2.062X$_1$+35.668X$_2$-1.058X$_3$ Y$\sub$7/v$_3$=-206. 249-0.739X$_1$+268.08X$_2$+2.770X$_3$ Y$\sub$7/v$_4$=-153.383+0.009X$_1$+2.024X$_2$+0.171X$_3$where Y$\sub$7/v$_1$, Y$\sub$7/v$_2$, Y$\sub$7/v$_3$, Y$\sub$7/v$_4$, are the estimated yield of the each variety, namely Gaeryang. Souban, Ilichirye, Nosang, and Suwon Sang No. 4, respectively. X$_1$, X$_2$, X$_3$, denote the measured values of each character. branch length, branch diameter and leaf number per branch, respectively. 3. Y$\sub$11/v$_1$=82. 567-1.283X$_1$+15.501X$_2$+0.640X$_3$+3.511X$_4$ Y$\sub$11/v$_2$=136.411+0.311X$_1$+1.921X$_2$-0. 217X$_3$+0.214X$_4$ Y$\sub$11/v$_3$=150.2Z7-0.139X$_1$+11.788X$_2$+0.143X$_3$+0.381X$_4$ Y$\sub$11/v$_4$=160.850+0.323X$_1$+66.076X$_2$-0.794X$_3$+2..614X$_4$ where Y$\sub$11/v$_1$, Y$\sub$11/v$_2$, Y$\sub$11/v$_3$, Y$\sub$11/v$_4$, are the estimated yield values of four varieties, and X$_1$, X$_2$, X$_3$, X$_4$ denote the measured values of four characters. namely branch length, branch diameter. leaf number per branch and leaf area per branch. respectively. The estimation method of mulberry leaf yield by measurement of some characters, branch length. branch diameter. leaf number per branch and leaf area per branch. could be the better method to determine the leaf yield of mulberry trees without destroying the leaves and without weighting the leaves of mulberry trees than the other methods.

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Estimation of Air Pollutant Emission Factors for Motorcycle (이륜자동차의 대기오염물질 배출계수 산정을 위한 연구)

  • Lim, Jae-Hyun;Kim, Hyun-Min;Lee, Sang-Moon;Kang, Hee-Jun;Lim, Yoon-Sung;Seo, Choong-Yeol;Kim, Jong-Choon
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.1
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    • pp.69-76
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    • 2010
  • While increased use of motor cycles in the recent years for various demands could worsen air quality, only few studies have been conducted on estimation of emission factors and characterization of emissions from motorcycle. In this study, emissions from selected six models of motorcycle based on largest market share and production rate were investigated. To investigate gaseous and carbonaceous air pollutants, such as carbon monoxide (CO), total hydrocarbon (THC), nitrogen oxide ($NO_x$), elemental carbon (EC) and organic carbon (OC), total 124 motorcycles between 2003 and 2007 model year were tested with regulatory driving conditions, such as CVS-40 and CVS-47 mode. These motorcycles were further sub-categorized based on their displacement (< 50 cc, 50~150 cc, and $\geq$ 150 cc), type of stroke (2- and 4 strokes) and model year (2003~2005 and 2006~2007). Tested motorcycles with recent model year (2006~2007) exhibited less emissions of regulatory gaseous and carbonaceous air pollutants compared to old model year (2003~2005). Chemical analysis showed that CO present in highest concentration followed by THC and $NO_x$ for all tested motorcycles. Interestingly, two strokes motorcycle produced higher THC emission but less CO and $NO_x$ than those of four strokes. For all types of displacement and stroke, emission factors (gram per kilometer) of THC and CO except $NO_x$ with recent model year (2006~2007) showed decreased trend compared to old model year (2003~2005). In addition to this, due to mixed combustion between gasoline fuel and lubricant, two strokes motorcycle showed OC > EC emission trend.

Characteristics of Ozone Precursor Emissions and POCP in the Biggest Port City in Korea

  • Song, Sang-Keun;Shon, Zang-Ho;Son, Hyun Keun
    • Asian Journal of Atmospheric Environment
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    • v.9 no.2
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    • pp.146-157
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    • 2015
  • Emissions of ozone precursors ($NO_x$ and VOCs) and photochemical ozone creation potentials (POCPs) of VOC emission sources were investigated in the largest port city (i.e., Busan), Korea during the year 2011. This analysis was performed using the Clean Air Policy Support System (CAPSS) national emission inventory provided by the National Institute of Environmental Research (NIER), Korea. For $NO_x$, the emissions from off-road mobile sources in Busan were the most dominant (e.g., $31,202ton\;yr^{-1}$), accounting for about 60% of the total $NO_x$ emissions. The emission from shipping of off-road mobile sources (e.g., $24,922ton\;yr^{-1}$) was a major contributor to their total emissions, amounting to 47% of the total $NO_x$ emissions due to the port-related activities in Busan. For VOCs, the emission source category of solvent usage was predominant (e.g., $36,062ton\;yr^{-1}$), accounting for approximately 82% of the total VOC emissions. Out of solvent usages, the emission from painting was the most dominant ($22,733ton\;yr^{-1}$), comprising 52% of the total emissions from solvent usages. The most dominant VOC species emitted from their sources in Busan was toluene, followed by xylene, butane, ethylbenzene, n-butanol, isopropyl alcohol, and propane. The major emission sources of toluene and xylene were found to be painting of coil coating and ship building, respectively. The value of POCP for the off-road mobile source (61) was the highest in ten major activity sectors of VOC emissions. Since the POCP value of ship transport of off-road mobile source (72) was also high enough to affect ozone concentration, the ship emission can play a significant role in ozone production of the port city like Busan.

Hydrogen Production from Splitting of Methanol/Water Solution Using Perovskite Structured NbxSrTi1-xO3 Photocatalyts (Perovskite NbxSrTi1-xO3 광 촉매를 이용한 메탄올/물 분해로부터 수소제조)

  • Kim, Dongjin;Han, Gi Bo;Park, No-Kuk;Lee, Tae Jin;Kang, Misook
    • Korean Chemical Engineering Research
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    • v.51 no.4
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    • pp.513-517
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    • 2013
  • This study focused on the synthesis of $Nb_xSrTi_{1-x}O_3$ photocatalysts which partially inserted Nb ions with excellent ability of fluorescence into the perovskite structured $SrTiO_3$ frameworks and their photocatalytic hydrogen productions from methanol/water splitting corresponding to the molar ratios of Ti and Nb. The characteristics of the synthesized $SrTiO_3$ and $Nb_xSrTi_{1-x}O_3$ powders were analyzed by X-ray diffraction (XRD), energy dispersive X-ray spectrometer (EDS), and UV-Visible spectrometer. The hydrogen evolution from methanol/water photo-splitting was enhanced over $Nb_{0.05}SrTi_{0.95}O_3$ compared to those over $SrTiO_3$ and another $Nb_xSrTi_{1-x}O_3$; 4.9 mL of hydrogen gases was collected after 8 h when 0.5g of $Nb_{0.05}SrTi_{0.95}O_3$ catalyst was used in pH 10.

The Status and Prospect of Poplar Research in Korea (포플러 연구현황과 전망)

  • 구영본;여진기
    • Journal of Korea Foresty Energy
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    • v.22 no.2
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    • pp.1-17
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    • 2003
  • Populus species have been as a model species in tree breeding and we have enormous varieties resulting from the poplar breeding because of their fast growth performance and short rotation age. New varieties developed in Korea are common italian poplar(P euramericana, I-214, I-476), P euramericana“Eco 28”(Italian poplar No.1) and p. deltoides“Lux”(Italian poplar No.2), which were introduced from foreign countries. As hybrid polars, Hyun-Sasi(p. alba ${\times}$ P. glandulosa No.1, No.2, No.3, No4.), P. nigra x P. maximowiczii and P. koreana x P. nigra val. italica, were developed, and P. davidiana was selected as the result of selection breeding The total plantation areas covered with the new varieties are 935,162ha that include 745,773ha of P. euramericana, 184,636ha of P. alba x P. glandulosa, and other new varieties are 4,735ha. The new poplars are contributed to increase farmer's income as well as bare land tree-planting in Korea. The technologies associated with the poplar species were developed, such as the determination of optimum site for new the poplar species, the crossing method between incompatible poplar species, and the vegetative mass propagation. In the future, poplar species will be considered for phytoremediation species at contaminated areas such as landfill sites or with lives stock's waste water as well as wood production, a shade tree like road-side tree and public park tree.

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Induction of Folate Sensitive Chromosomal Fragile Sites by Fudr in Pakistani Lohi Sheep (Ovis aries)

  • Ali, Ahmad;Babar, Masroor Ellahi;Abdullah, M.
    • Asian-Australasian Journal of Animal Sciences
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    • v.21 no.8
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    • pp.1103-1108
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    • 2008
  • An investigation to determine frequency and distribution of folate sensitive chromosomal fragile sites was carried out in a Pakistani breed of Lohi sheep to uncover fragile site phenomena. The means and standard errors of aberrant cell count (AC) and Number of aberrations (NoA) in Lohi sheep were $0.56{\pm}0.15$ and $0.59{\pm}0.16$ in the control cultures. FUdR treated cells showed significantly higher (p<0.001) AC and NoA means ($2.18{\pm}0.33$ and $2.65{\pm}0.50$). The sex comparison for the frequency of expression indicated that males had significantly higher number of aberrant cells and total number of aberrations in FUdR cultures than the female group in Lohi sheep. The comparison of control cultures was however, not significantly different between the two groups. The regression analysis of FUdR-induced chromosomal fragility data analysis of the fragility data predicted very low ${\beta}$ of 0.325 and 0.412 for AC and NoA respectively. Lohi chromosomes expressed lesions in only 7 and 24 bands in the control and FUdR cultures respectively. The total number of significantly fragile bands in the Lohi genome was only 4. The X-chromosome of the Lohi sheep was highly stable at $5{\mu}g/ml$ FUdR with no fragile sites. The sex comparison for the distribution of fragile sites across the Lohi genome did not reveal any noticeable differences.