• 제목/요약/키워드: $NO_x$ emissions

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A Study on Numerical Simulation of Gaseous Flow in SCR Catalytic Filter of Diesel Exhaust Gas Aftertreatment Device

  • Bae, Myung-Whan;Syaiful, Syaiful;Mochimaru, Yoshihiro
    • Journal of Advanced Marine Engineering and Technology
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    • 제34권3호
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    • pp.360-368
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    • 2010
  • A SCR catalytic filter system is used for reducing $NO_x$ and soot emissions simultaneously from diesel combustors. The amount of ammonia (as a reducing agent) must be controlled with the amount of $NO_x$ to obtain an optimal $NO_x$ conversion. Hence, gas mixing between ammonia and exhaust gases is vital to ensure that the SCR catalyst is optimally used. If ammonia mass distribution is not uniform, slip potential will occur in rich concentration areas. At lean areas, on the other hand, the catalyst is not fully active. The better mixing is indicated by the higher uniformity of ammonia mass distribution which is necessary to be considered in SCR catalytic filter system. The ammonia mass distributions are depended on the flow field of fluids. In this study, the velocity field of gaseous flow is investigated to characterize the transport of ammonia in SCR catalytic filter system. The influence of different injection placements on the ammonia mass distribution is also discussed. The results show that the ammonia mass distribution is more uniform for the injector directed radially perpendicular to the main flow of inlet at the gravitational direction than that at the side wall for both laminar (Re = 640) and turbulent flows (Re = 4255). It is also found that the mixing index decreases as increasing the heating temperature in the case of ammonia injected at the side wall.

스월 예혼합 버너의 연소 특성 및 NO 배출에 관한 수치적 연구 (Numerical Study of Combustion Characteristics and NO Emission in Swirl Premixed Burner)

  • 백광민;조천현;조주형;김한석;손채훈
    • 대한기계학회논문집B
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    • 제37권10호
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    • pp.911-918
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    • 2013
  • Double cone 버너를 장착한 가스터빈용 EV (Environmental Vortex)버너의 연소 특성과 NO 배출 특성을 수치적으로 조사하였다. NO 배출 저감을 위해 연료와 공기의 혼합 특성을 예측하였다. 혼합도와 NO 배출과의 상관관계를 예측하기 위해 메탄 1단계 화학반응식과 2단계 반응식에 적용하여 연소 해석을 수행하였다. 1단계 반응식을 적용한 결과, 혼합도가 저하된 모델에서 NO 배출량이 약 2% 증가하였으며, 혼합도가 향상된 모델의 경우 cone 상부에서 과다한 고온의 화염 영역이 형성되어 NO가 약 169%나 증가하였다. 2단계 반응식의 경우 첫 번째 모델에서 약 3% NO 배출량이 증가하였으며, 두 번째 모델에서 cone 내부의 고온 영역이 형성되지 않고 NO가 약 5% 감소하였다. 이 결과는, 혼합 특성이 저감된 모델에서 NO가 약 63% 증가하였고, 혼합 특성이 향상된 모델에서 NO가 약 11% 감소한 실험결과와 잘 부합하였다. 정량적인 오차가 있음에도, NO 배출의 정성적 경향성이 유사하므로 2단계 반응식을 적용한 수치해석을 통해 설계 변경 방안을 제시하는 것은 타당할 것으로 판단된다.

발전소 증설이 환경, 지역사회 및 경제에 미치는 영향 - 제 3차 전력 수급계획에 의한 인천 지역의 화력발전소 증설을 중심으로 - (The Impact of Power Plants on the Environment and Region - Focus on Incheon Area according to the 3rd Electric Support Action Plan -)

  • 정창훈;;이희관
    • 환경영향평가
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    • 제18권4호
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    • pp.195-208
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    • 2009
  • The power plant is well known to influence air pollution as well as emission of green house gas. Because of increasing demand on electricity, the government set up the electric support action plan every 2 years. In this research, the impacts of power plants on the environment and region was studied. The study was focused on the establishment of power plant in Incheon area based on the 3rd electric support action plan. According to the 3rd electric support action plan, almost 80% of power plant in metropolitan area is planned to be built in Incheon area. The main influences of establishment of power plant are emissions of $SO_x$, $NO_x$ and PM and exceed the allocated local industry emissions, which means the emission allocation of other industry is difficult. In additions, the power plant exhaust $CO_2$ much more than other types of fuel such as waterpower generation, atomic power station. Although several supports are given in local government, these cannot cover the whole cost due to establishment of power plant. Subsequently, this study suggest the additional policy based on local consideration is needed and the current electricity distribution system should be reconsidered fundamentally in the lang term.

전기점화 엔진에서 개질가스 첨가에 의한 희박연소특성 연구 (Lean Operation Characteristics of a Spark Ignition Engine with Reformed Gas Addition)

  • 오승묵;김창업;강건용;최영
    • 한국자동차공학회논문집
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    • 제14권3호
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    • pp.170-177
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    • 2006
  • Hydrogen can extend the lean misfire limit to a large extent when it is mixed with conventional fuels for a spark ignition engine. In this study, hydrogen-enriched gaseous fuels by reforming process were simulated according to their proportions of $H_2$, CO, $CO_2$ and $N_2$ gases. Pure hydrogen and two different hydrogen-enriched gaseous mixtures(A-, B-composition) were tested for their basic effects on the engine performances and emissions in a single cylinder research engine. A- and B-composition showed different results from 100% $H_2$ addition because air/fuel mixtures were more diluted by their additions. Even though the energy fraction of reformed gases was increased, combustion stabilities and lean misfire limits were not sensitively improved. It means that combustion augmentation by $H_2$ addition was offset by the charge dilution of $N_2$ and $CO_2$. In addition, the low flammability of CO gas deteriorated thermal efficiencies. CO emission was drastically increased with B-composition which included higher CO component. However, $NO_x$ was reduced as energy fraction($X_e$) rised except for the case of 100% $H_2$ addition at $\lambda=1.2$ and was, for A-composition, lowered to a factor of ten when compared with that of $H_2$ addition. HC emissions were largely influenced by $COV_{imep}$ due to misfire and partial burns.

바이오에탄올 SI 엔진에서 에탄올-가솔린 연료 혼합비율에 따른 희박연소 및 배기 특성 (Effect of Ethanol-gasoline Blending Ratio on Lean Combustion and Exhaust Emissions Characteristics in a SI Engine Fueled with Bioethanol)

  • 윤승현;김대성;이창식
    • 한국자동차공학회논문집
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    • 제19권1호
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    • pp.82-88
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    • 2011
  • Lean combustion and exhaust emission characteristics in a ethanol fueled spark-ignited engine according to ethanol-gasoline fuel blending ratio were investigated. The test engine was $1591cm^3$ and 10.5 of compression ratio SI engine with 4 cylinders. In addition, lambda sensor system was connected with universal ECU to control the lambda value which is varied from 1.0 to 1.5. The engine performance and lean combustion characteristics such as brake torque, cylinder pressure and rate of heat release were investigated according to ethanol-gasoline fuel blending ratio. Furthermore, the exhaust emissions such as carbon monoxide (CO), unburned hydrocarbon (HC), nitrogen oxides ($NO_x$) and carbon dioxide ($CO_2$) were measured by emission analyzers. The results showed that the brake torque, cylinder pressure and the stability of engine operation were increased as ethanol blending ratio is increased. Brake specific fuel consumption (BSFC) was increased in higher ethanol blending ratio while brake specific energy consumption (BSEC) was decreased in higher ethanol blending ratio. The exhaust emissions were decreased as ethanol blending ratio is increased under overall experimental conditions, however, some specific exhaust emission characteristics were mainly influenced by lambda value and ethanol-gasoline fuel blending ratio.

4실린더 커먼레일 디젤엔진에서 바이오디젤 혼합연료와 EGR율에 따른 연소 및 배기특성 (Combustion and Emission Characteristics of Biodiesel Blended Fuel by EGR Rate in a 4-cylinder CRDI Diesel Engine)

  • 정규수;이동곤;연인모;노현구;박성욱;이창식
    • 한국자동차공학회논문집
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    • 제19권4호
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    • pp.130-136
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    • 2011
  • This study describes the effect of EGR rate on the combustion and emissions characteristics of a four cylinder CRDI diesel engine using biodiesel (soybean oil) blended diesel fuel. The test fuel is composed of 30% biodiesel and 70% ULSD (ultra low sulfur diesel) by volumetric ratio. The experiment of engine emissions and performance characteristics were performed under the various EGR rates. The experimental results showed that ignition delay was extended, the maximum combustion pressure and heat release gradually were decreased with increasing EGR rate. Comparing biodiesel blended fuel to ULSD, the injection quantity of biodiesel blended fuel was further increased than ULSD. The emission results showed that $NO_x$ emission of biodiesel blended fuel becomes higher according to the increase of EGR rate. However, in the case of biodiesel blended fuel, HC, CO and soot emissions were decreased compared to ULSD.

파일럿 규모 기포 유동층 반응기를 이용한 하수 슬러지 연소 특성 분석 (Investigation on Combustion Characteristics of Sewage Sludge using Pilot-scale Bubbling Fluidized Bed Reactor)

  • 김동희;허강열;안형준;이영재
    • 청정기술
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    • 제23권3호
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    • pp.331-342
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    • 2017
  • 하수 슬러지 고형연료 및 우드 펠렛의 연소 특성을 평가 하기 위하여 열중량 분석(TGA), 회 융점(AFT) 분석, 그리고 회분 성분 분석을 수행하였다. TGA 분석 결과, 하수 슬러지 고형연료의 연소성이 우드 펠렛에 비해 상대적으로 좋지 않았다. 또한 AFT 분석을 통해 하수 슬러지 고형연료의 슬래깅 가능성이 매우 높은 것을 확인하였다. 또한 연소성 평가를 위해 pilot-scale 기포 유동층 반응기를 적용하였으며, 장치는 예열기, 유동층 반응기, 연료 공급장치, 사이클론, 회분 포집 장치, 그리고 가스분석기로 구성되었다. 반응기는 직경 400 mm, 높이 4300 mm이며, 하수 슬러지는 $54.5{\sim}96.5kW_{th}$의 열량으로 실험을 수행하였고 우드 펠렛은 $96.1kW_{th}$ 실험을 수행하였다. 실험 결과, 하수 슬러지 고형연료 연소의 경우 평균적으로 우드 펠렛의 연소 보다 배기가스 중 $NO_x$는 10.1배, CO는 3.5배 높았다. 또한 사이클론에서 포집한 회분을 분석한 결과, 모든 실험 조건에서 연소 효율은 99% 이상이었고, 회분의 성분 분석을 통해 슬래깅/파울링 가능성이 높은 것을 확인하였다.

IPCC SRES A2와 B1 시나리오에 따른 한반도지역의 여름철 지표 오존의 수치모의 (Simulations of Summertime Surface Ozone Over the Korean Peninsula Under IPCC SRES A2 and B1 Scenarios)

  • 홍성철;최진영;송창근;홍유덕;이석조;이재범
    • 한국대기환경학회지
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    • 제29권3호
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    • pp.251-263
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    • 2013
  • The surface ozone concentrations changes were investigated in response to climate change over the Korean peninsula for summertime using the global-regional one way coupled Integrated Climate and Air quality Modeling System (ICAMS). The future simulations were conducted under the Intergovernmental Panel on Climate Change (IPCC) Special Report on Emissions Scenarios (SRES) A2 and B1 scenarios. The modeling system was applied for four 10-year simulations: 1996~2005 as a present-day case, 2016~2025, 2046~2055, and 2091~2100 as future cases. The results in this study showed that the mean surface ozone concentrations increased up to 0.5~3.3 ppb under the A2, but decreased by 0.1~10.9 ppb under the B1 for the future, respectively. However, its increases were lower than an increase of the average daily maximum 8-hour (DM8H) surface ozone concentrations which was projected to increase by 2.8~6.5 ppb under the A2. The DM8H surface ozone concentrations seem to be therefore far more affected by the climate and emissions changes than mean values. The probability of exceeding 60 ppb was projected to increase by 6~19% under the A2. In the case of B1, its changes were presented with an increase of 2.9% in the 2020s but no occurrence in the 2100s due to the effect of the reduced emissions. Future projection on surface ozone concentrations was generally shown to have almost the similar trend as the emissions of $NO_x$ and NMVOC.

CO2를 포함한 Simulated-EGR 압축착화엔진에서 당량비 변화에 따른 성능 예측 (Performance Prediction according to Equivalence Ratio Change in Simulated-EGR Compression Ignition Engine Containing CO2)

  • 서현규
    • 한국분무공학회지
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    • 제25권1호
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    • pp.21-26
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    • 2020
  • The objective of this work is to numerically reveal the effect of equivalence ratio change on the simultaneous reduction of NOX and soot emissions from the simulated-EGR compression ignition engine containing CO2. An experiment was conducted by using a single-cylinder common-rail injection system engine, an intake control system, and exhaust emissions analyzers. The numerical analysis results were validated under the same experimental conditions. To investigate the effect of equivalence ratio by simulated-EGR containing CO2, the O2, N2, and CO2 mole fraction were changed in the initial air conditions to the cylinder. The results were analyzed in terms of peak cylinder pressure, indicated mean effective pressure, indicated specific nitrogen oxide, and indicated specific soot. It was revealed that ignition delay characteristics and heat release rate (ROHR) characteristics were not significantly different according to the equivalence ratio. However, as the equivalence ratio increased from 0.68 to 0.83, the maximum combustion pressure and IMEP decreased by about 6.5% and 9.4%, respectively. In the case of ISFC, as is well known, the trend is opposite of IMEP. In the case of ISNO, as the equivalence ratio increased, less NO was generated, and as the equivalence ratio increased by 0.05, the ISSoot value of about 10% increased.

유동층 연소로에서 유$cdot$무연탄 혼합 연소시 대기오염물질 배출에 관한 연구 (A Study on Contaminant Emission and Combustion of Anthracite-Bituminous Coal Blend in a Fluidized Bed Coal Combustor)

  • 조상원;정종현;손병현;김영식;오광중
    • 한국환경보건학회지
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    • 제22권3호
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    • pp.28-36
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    • 1996
  • The objects of this study were to investigate emissions of air pollutant the particles as well as the combustibility of the low grade domestic anthracite coal and imported high-calorific bituminous coal in the fluidized bed coal combustor. The production of air pollution from anthracite-bituminous coal blend combustion in a fluidized bed coal combustor was evaluated. The effects of air velocity and anthracite fraction on the reaching time of steady state condition was also evaluated. We used coal samples the domestic low grade anthracite coal with heating value of 2,010 kcal/kg and the imported high grade bituminous coal with heating value of 6,520 kcal/kg. The experimental results are presented as follows. The time of reaching to steady state was affected by the temperature variation. The steady state time was about 120 minute at 0.3 m/s which was the fastest. It has been found that $O_2$ and $CO_2$ concentration were reached steady state at about 100 minute. As the height of fluidized bed becomes higher, the concentration s of $SO_2$ and $NO_x$ mainly increased. The concentration of freeboard was the highest and emission concentration was diminished. Also, as anthracite fraction increased, the emission of $SO_x$ concentration was increased. But, it has been found that the variation of $NO_x$ concentration with anthracite fraction was negligible and the difference of emission concentration according to air flow rates was negligible, too. It has been found that $O_2$ concentration decreased and $CO_2$ concentration increased as the height of fluidized bed increased. As anthracite fraction increased, the mass of elutriation particles increased, and $CO_2$ concentration decreased. Also, as air velocity increased, $O_2$ concentration decreased and $CO_2$ concentration increased. Regardless-of anthracite fraction and flow rate, the combustible weight percentage in elutriation particles were high in the case of fine particles.

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