• Journal of Korean Society for Atmospheric Environment
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• v.32 no.4
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• pp.422-434
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• 2016

This study was conducted to understand roles of $NO_x(=NO+NO_2)$ on high $O_3$ episodes at an urban monitoring station in Seoul. Concentrations of NO, $NO_2$, $NO_y$ and $O_3$ were measured intensively at KIST monitoring station which located at urban center in Seoul metropolitan area during May 18~June 13, 2015. Sampling period was planed because high $O_3$ and PM occurred frequently during from late spring to early summer months in Seoul. The experimental site locates in NW from center of Seoul and is surrounded by residential area. Belt highway of the city runs from north to west side nearby experimental site. Vehicle exhaust emissions due to heavy traffic influenced $NO_x$ concentration at the site during northwesterly wind. Specific $NO_2$ concentration was measured by Blue Light photolytic converter, and it was compared to $NO_2$ concentration measured by molybedenum converter. $[NO_2]_{phtolysis}$ was usually lower than $[NO_2]_{molybedenum}$ during the experiment period; however their diurnal variations were very similar. The linear relationship between these $NO_2$ concentrations was found to be $[NO_2]_{phtolysis}$=0.64 $[NO_2]_{molybedenum}$ - 2.6, $r^2$=0.83 during May 16~8, 2015. The difference between $NO_2$ by molybdenum converter and by photolytic converter (${\Delta}NO_2=[NO_2]_{molybedenum}-[NO_2]_{phtolysis}$) accounted for residual $NO_y$ which can represent $NO_z$ (=$NO_y-NO_x$). $O_3$ concentration showed typical daily trend which has maximum at late afternoon and minimum during the night. $O_3$ increased at a rate of 7 ppb/hr since 8 am. and reached the maximum concentration (~80 ppb) at 3 pm.. The diurnal pattern of $O_3$ was inversely related with that of $NO_2$, suggesting that the formation of $O_3$ was the result of photochemical activity of $NO_2$.

• Journal of Korean Society for Atmospheric Environment
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• v.1 no.1
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• pp.83-92
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• 1985

In odrder to survey the emission level of air pollutants from diesel vehicles, was measured CO, HC, NOx and smoke of 4 types of domestic-use diesel engines under various conditions. The emission of CO, HC and NOx tested by 6-Mode test method and smoke emission by full load test met the permissible vehicle emission standard. Pollutant emission rates of diesel engines were different according to engine operating conditions, that is, engine load and engine speed. Generally, CO and HC was emitted more at low load and NOx at high load but the trend was quite different by the type of engines. In exhaust gas, $NO_2$ portion of NOx emission was high, specially at low speed and low load. The correlation equation between CLD(NOx) and NDIR(NO) method of nitrogen of nitrogen oxides analysis was y = 1.10x - 3.48 (y: CLD method) as a result of 6-mode test.

• 한국연소학회:학술대회논문집
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• 2004.11a
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• pp.175-180
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• 2004

Improving furnace efficiency is a high priority need for aluminum, glass, steel and other metal casting industries. Oxy-fuel combustion is considered to be one of the most effective method to improve thermal efficiency and reduce $NO_x$, SOx and $CO_2$ emissions for high temperature furnaces. The characteristics of an oxy-fuel flame, in particular its shape, radiation profile and exhaust gas composition are considerably different to those of an air-fuel burner. For this reason, a new approach is needed regarding factors such as burner design, power input levels, number and positioning strategies of burners and also control philosophies. In this paper will discuss the latest developments of high performance oxy-fuel combustion reheating furnace system. This high performance oxy-fuel combustion system will be shown to be technologically superior to other types of combustion systems in the areas of fuel efficiency, emissions and productivity.

• Transactions of the Korean Society of Automotive Engineers
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• v.21 no.4
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• pp.106-112
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• 2013

Compression ratio is an important factor affecting engine performance and emission characteristics since thermal efficiency of spark ignition engine can be theoretically improved by increasing compression ratio. In order to evaluate the effect of compression ratio change in HCNG engine, natural gas engine was employed using HCNG30 (CNG 70 vol%, hydrogen 30 vol%). Combustion and emission characteristics of CNG and HCNG fuel was analyzed with respect to the change of compression ratio at each operating condition. The results showed that thermal efficiency improved and $CH_4$, $CO_2$ emission decreased with the increase in compression ratio while $NO_x$ emissions were decreased at a certain excess air ratio condition. Higher thermal efficiency and further reduction of exhaust emissions can be achieved by the increase of compression ratio and the retard of spark timing.

• Journal of ILASS-Korea
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• v.24 no.4
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• pp.163-170
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• 2019

In this study, feedback logic using dual O₂ sensor values were developed to increase the purification capability of a three-way catalyst (TWC) in a compressed natural gas (CNG) engine. A heavy-duty inline 6-cylinder engine was used and the CNG was supplied to the engine through a mixer. This study consists of two main parts, namely, the proportional integral (PI) control with a front O₂ sensor and the feedback control with dual O₂ sensors. In the PI control experiment, effects of various parameters, such as P gain, I gain, and lean delay, on the TWC capability were identified. Based on the results of the PI control experiment, the feedback logic using dual O₂ sensor values were developed. In both cases, the nitrogen oxides (NO_X) emissions were nearly zero. However, the carbon monoxide (CO) emissions were reduced significant in the feedback logic with dual O₂ sensors than in the PI control with the front O₂ sensor.

• Transactions of the Korean Society of Automotive Engineers
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• v.13 no.2
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• pp.22-28
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• 2005

Exhaust gas emissions from internal combustion engines are one of the major sources of air pollution. And, it is extremely difficult to increase gasoline engine efficiency and to reduce $NO_X$ and PM(particulate matter) simultaneously in diesel combustion. This paper offers some basic concepts to overcome the above problems. To solve the problems, a recommended technique is CAI(controlled auto-ignition) combustion. In this paper, a flame trap was used to simulate internal EGR(exhaust gas recirculation) effect. An experimental study was carried out to find combustion characteristics using homogeneous premixed gas mixture in the constant volume combustion chamber(CVCC). Flame propagation photos and pressure signals were acquired to verify the flame trap effect. The flame trap creates high speed burned gas jet. It achieves higher flame propagation speed and more stable combustion due to the effect of geometry and burned gas jet.

• Transactions of the Korean Society of Automotive Engineers
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• v.19 no.3
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• pp.99-105
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• 2011

This paper described the effect of the multiple injections on the emission characteristics and combustion stability in a common rail diesel engine. In order to investigate the influence of multiple injections in a passenger car diesel engine, the injection strategy was varied with pilot injection, post injection and one main injection at various conditions. Based on the experimental results, the combustion and emissions characteristics were analyzed for the various injection strategies such as main, pilot-main, double-pilot-main, double- pilot-main-post injection strategy. It is revealed that the $NO_X$, HC and CO emissions are reduced by double pilot and post injection at medium load, however, soot emission is increased. Also, in the case of multiple injection, the combustion pressure is increased smoothly near the TDC and the coefficient of variation and fuel consumptions are decreased.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.30 no.12 s.255
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• pp.1181-1187
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• 2006

Stringent regulations of exhaust emission from vehicles become a major issue in automotive industries. In SI engines, it is one of the crucial factor to reduce exhaust emissions during cold start in order to meet stringent regulations such as SULEV or EURO-4, because SI engines emit a large portion of total harmful exhaust compounds when they are cold. At early stages of cold start in gasoline engines, exhaust gas temperature plays a key role to improve three way catalyst by virtue of fast warmup. Therefore, this study focused on the increase of exhaust gas temperature under controls of engine operating parameters such as spark ignition timing, valve overlap by virtue of intake VVT and catalyst heating function. Furthermore, effects on harmful emission due to these parameters are also investigated. Experiments showed that retarded spark ignition timings and increased valve overlap may be helpful to increase exhaust gas temperature. It was also found that $NO_x$ was decreased with increased valve overlap. This study also showed that sudden changes in ISA and amount of fuel due to the deactivation of catalyst heating function cause temporal increase of harmful emissions.

• Corrosion Science and Technology
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• v.21 no.6
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• pp.514-524
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• 2022

Carbon emissions from fuel consumption have been pointed by scientists as the cause of global warming. In particular, fossil fuels are known to emit more carbon when burned than other types of fuels. In this regard, International Maritime Organization has announced a regulation plan to reduce carbon dioxide emissions. Therefore, recently, Liquefied Natural Gas propulsion ships are responding to such carbon reduction regulation. However, from a long-term perspective, it is necessary to use carbon-free fuels such as hydrogen and ammonia. Nitrogen oxides might be generated during ammonia combustion. There is a possibility that incompletely burned ammonia is discharged. Therefore, rather than being used as a direct fuel, Ammonia is only used to reduce NO_X such as urea solution in diesel vehicle Selective Catalyst Reduction. Currently, LPG vehicle fuel feed system studies have evaluated the durability of combustion injectors and fuel tanks in ammonia environment. However, few studies have been conducted to apply ammonia as a ship fuel. Therefore, this study aims to evaluate corrosion damage that might occur when ammonia is used as a propulsion fuel on ships.

• Fire Science and Engineering
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• v.29 no.4
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• pp.49-56
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• 2015

Toxic gases from five types of interior building materials were investigated according to Naval Engineering Standard (NES) 713. The materials were plywood, indoor wall coverings (wood wall plate members and pine wood), reinforced Styrofoam insulation, laminate flooring, and PVC. Specimens were measured using an NES 713 toxicity test apparatus to analyze the hazardous substances in combustion gas from the materials. We used the US Department of Defense standard (MIL-DTL, Military Standard) to calculate the toxicity index of the combustion gas. Emissions of $CO_2$ from all specimens did not exceed the NES 713 limit of 100,000 ppm. The amount of CO gas emissions from reinforced Styrofoam insulation was 6,098 ppm. 25 ppm and 49 ppm of formaldehyde were released from the reinforced Styrofoam insulation and PVC flooring, respectively. These values were less than the limit of 400 ppm. The highest emissions were from $NO_X$ emitted by plywood and were above the limit of 250 ppm. The toxicity index of the specimens were calculated as 5.19 for plywood, 4.13 for PVC flooring, 2.35 for reinforced Styrofoam insulation, 2.34 for laminate flooring, and 1.22 for indoor wall coverings (pine wood). Our research helps us to understand the properties of these five interior materials by analyzing the combustion gas and explaining the toxicity of constituents and the toxicity index. Also, it would be useful for giving fundamentals to guide the safe use of interior materials for applications.