• Title/Summary/Keyword: $NO_X$ Reduction

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The Influence of Mechanical Milling on the Structure and Magnetic Properties of Sm-Fe-N Powder Produced by the Reduction-Diffusion Process

  • Lee, Jung-Goo;Kang, Seok-Won;Si, Ping-Zhan;Choi, Chul-Jin
    • Journal of Magnetics
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    • 제16권2호
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    • pp.104-107
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    • 2011
  • In the present study, we systematically investigated the effect of mechanical milling on the magnetic properties of $Sm_2Fe_{17}N_x$ powders produced by the reduction-diffusion process. The Sm-Fe powders obtained by the reduction-diffusion process were composed of an $Sm_2Fe_{17}N_x$ single phase. After nitrogenation, the coercivity and saturation magnetization of the powders were 0.48 kOe and 13.32 kG, respectively. The particle size largely decreased down to less than $2\;{\mu}m$ in diameter after ball milling for 30 hours. However, there is no evidence that the $Sm_2Fe_{17}N_x$ was decomposed to Sm-N and ${\alpha}$-Fe even after ball milling for 30 hours. The coercivity was significantly improved up to 8.82 kOe after milling for 60 hours. However, the magnetization decreased linearly with the ball milling time.

히스 노이즈제거를 통한 아날로그의 디지털 복원에 대한 연구 - X-NOISE를 활용한 히스 노이즈리덕션을 중심으로 - (A Research on the Digital Restoration of the Analog by Removing Hiss Noise (Using X-NOISE Based on Hiss-Noise Reduction))

  • 변정민;두일철
    • 디지털산업정보학회논문지
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    • 제10권4호
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    • pp.161-170
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    • 2014
  • Analog cassette tapes are easily changed due to environmental factors. To digitize is the best way to preserve a sound source. The way to digitize is to deal with the original sound to be enhanced to a variety of sources by playing through the audio card after recording. In this process to occur, it's the most important to remove various noise and equalizing sound in a method for preserving. It's studied about how to remove noise by using one of softwares, Cubase 5. 5, to remove hiss noise, which happens changing analog tape into digitalization. A amount of hiss noise is reduced to use X-Noise software of Wave which uses in Cubase 5.0, one of PLUG-IN. The noise is removed changing value of threshold and reduction every 10 times in no change of origin sound. To keep regular condition, the experiment to remove the hiss noise is conducted based on sound meondle, which is one of sound Nonmaegi. The noise is removed easily when the value of threshold is getting high in spite of giving a little value of reduction. However, as it gives a amount of reduction high, the damage rate of the sound source gets high.

대형 경유트럭의 NOx 저감장치에 따른 배출가스 특성비교 (Comparison on Exhaust Gas of Heavy Duty Diesel Trucks; THC and CO Emission Affected by NOx Control Devices (EGR, SCR))

  • 문선희;유흥민;손지환;윤창완;박규태;김정수;이종태
    • 한국분무공학회지
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    • 제20권3호
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    • pp.149-155
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    • 2015
  • With increasing of GDP, the registration number of passenger cars has exceeded 20 million last year in Korea. Especially, the registration number of the diesel engine vehicles has been increasing. However, the WHO(World Health Organization) IARC (International Agency for Research on Cancer) has reported that diesel engine exhaust gas is an one of HAPs, which has carcinogenic for human, and they have designated it to Group 1. To solve this problem, exhaust gas from diesel engines has to be controlled. Thus, it has been controlling by European regulatory standard in Korea. On the other hand, in order to meet the enhanced emission regulations, all manufacturing company applied $NO_x$ control device to vehicles such as EGR (Exhaust Gas Recirculation), SCR (Selective Catalytic Reduction) and so on. However, these devices (EGR, SCR) were operated by difference reaction mechanism respectively, and the composition of exhaust gas would be differenced from that of them. In this study, it was conducted to evaluate variety characteristics on changing of exhaust gas composition by each $NO_x$ control device, and the heavy duty diesel trucks were chosen as experimental vehicles. From the result, it revealed that vehicles (with EGR) were discharged higher THC as 52.5% than that of others (with SCR). However, it did not followed that trend, in the case of CO; it was discharged as 57.2% lower than that of others (with SCR). In the future, these data would be used to apply to efficient $NO_x$ control device for meeting to EURO 6.

안와 전산화단층촬영검사 시 수정체 선량감소 방법과 영상 평가 (Lens Dose Reduction Methods and Image Quality in Orbital Computed Tomography Scan)

  • 문세영;홍상우;서지숙;김영범;곽완신;이성영;김정수
    • 대한방사선기술학회지:방사선기술과학
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    • 제43권5호
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    • pp.343-351
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    • 2020
  • This study analyzed dose reduction and quality of images through dose reduction tools and shielding board to protect sensitive eye lens in radiation during orbit CT examinations for clinical data use. During CT scans of the phantom, surface dose (CT scanner dosimetry phantom, ion chamber-3 times) and quality of image (radiosurgery head phantom, visual assessment-2 times, HU standard deviation) were evaluated using X-care which is dose reduction tools and bismuth shielding board. The results of experiments of eight conditions showed a relatively reduced dose in all other conditions compared to when no conditions were set. In particular, the area corresponding to the ophthalmic part reduced the surface dose by up to 45.7 %. The visual evaluation of images by specialists and the quality evaluation of images analyzed by HU standard deviation were clinically closest to the use of X-care and shielding board (1 cm in height). Therefore, it is believed that the use of shielding board in a suitable location with dose reduction tools while investigating the optimal radiation dose will reduce the exposure dose of sensitive lens at radiation while maintaining the quality of the images with high diagnostic value.

디메틸술폭시드용매중에서 Thorium (IV)-Crown Ether 착물의 산화-환원 반응메카니즘 (Redox Reaction Mechanisms of Thorium (IV) Complexes with Crown Ethers in Dimethylsulfoxide)

  • 정학진;정오진;서혁춘
    • 대한화학회지
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    • 제31권3호
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    • pp.250-257
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    • 1987
  • DMSO와 $H_2O$용매 중에서 결합구조가 밝혀진 동공의 크기를 달리한 토륨(IV) 착물들의 전기전도도를 측정하여 해리현상과 전해질의 행동을 알아 보고 DMSO용매중에서 polarography와 cyclic voltammography적 거동을 조사하여 합성착물의 산화환원반응 메카니즘, 가역성을 알아 보고 환원과정에 관여하는 전자수 및 착물의 확산계수를 계산하였다. 그 결과 반양성자성 용매에서 모든 착물들은 1:1전해질로, 물에서는 1:4전해질로 각각 행동하고, DMSO용매중에서 각 착물의 환원반응은 1전자 1단계의 환원반응으로 가역적이며 확산계수는 착물종에 따라 $5.831{\times}10^{-6}{\sim}6.900{\times}10^{-6}$이었다. 그리고 모든 착물의 물분자는 -1.8V(대조전극, SCE)이상에서 분해를 일으켜 수소기체를 발생한다.

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코로나 방전-EGR 조합시스템에 의한 디젤기관의 배기 가스 특성 (The Characteristics of Exhaust Gas in Diesel Engine by Corana Discharge-EGR System)

  • 박재윤;정장근;김종석;하현진
    • 조명전기설비학회논문지
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    • 제19권7호
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    • pp.39-44
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    • 2005
  • 고연료 중 대부분이 수소와 탄소의 결합물이다. 연료들은 엔진 내부에서 완전 연소되었을 경우는 수분인 증기와 $CO_2$가 발생된다. 그러나 대개 불완전 연소가 일어나 $NO_x$나 Smoke가 발생되어진다. 그리고 이 물질은 인해에 매우 해로운 물질들이다. 본 논문에서는 EGR과 상용주파수를 이용한 플라즈마 장치를 조합하여 배기가스 유해물질 제거 특성을 연구하였다. $NO_x$의 경우에는 전압과 EGR율이 증가할수록 유해물질 제거 특성이 우수하였고, Smoke의 경우에는 EGR 율이 증가하게 되면 Smoke의 발생율이 증가하였으나 전압이 증가하게 되면 발생율이 감소하였다.

HDDM과 BFM을 이용한 NOx와 VOC 배출량에 대한 오존민감도계수 산정 및 결과 비교: 2007년 6월 수도권 사례 (Estimating Ozone Sensitivity Coefficients to NOx and VOC Emissions Using BFM and HDDM for A 2007 June Episode)

  • 김순태
    • 한국환경과학회지
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    • 제20권11호
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    • pp.1465-1481
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    • 2011
  • The accuracy of ozone sensitivity coefficients estimated with HDDM (High-order Decoupled Direct Method) can vary depending on the $NO_x$ (Nitrogen Oxides) and VOC (Volatile Organic Compound) conditions. In order to evaluate the applicability of HDDM over the Seoul Metropolitan Area (SMA) during a high ozone episode in 2007 June, we compare BFM (Brute Force Method) and HDDM in terms of the $1^{st}$-order ozone sensitivity coefficient to explain ozone change in response to changes in NOx and VOC emissions, and the $2^{nd}$-order ozone sensitivity coefficient to represent nonlinear response of ozone to the emission changes. BFM and HDDM estimate comparable ozone sensitivity coefficients, exhibiting similar spatial and temporal variations over the SMAduring the episode. NME (Normalized Mean Error) between BFM and HDDM for the episode average $1^{st}$- and $2^{nd}$-order ozone sensitivity coefficients to NOx and VOC emissions are less than 3% and 9%, respectively. For the daily comparison, NME for the $1^{st}$- and $2^{nd}$-order ozone sensitivity coefficients are less than 4% ($R^2$ > 0.96) and 15% ($R^2$ > 0.90), respectively. Under the emission conditions used in this study, two methods show negative episode average $1^{st}$-order ozone sensitivity coefficient to $NO_x$ emissions over the core SMA. The $2^{nd}$-order ozone sensitivity coefficient to $NO_x$ emissions leads ozone to respond muchnonlinear to the reduction in $NO_x$ emissions over Seoul. Nonlinear ozone response to reduction in VOC emissions is mitigated due to the $2^{nd}$-order ozone sensitivity coefficient which is much smaller than the $1^{st}$-order ozone sensitivity coefficient to the emissions in the magnitude.

메탄-공기 예혼합 화염에서 염화수소의 역할 (The Function of Hydrogen Chloride on Methane-Air Premixed Flame)

  • 신성수;이기용
    • 대한기계학회논문집B
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    • 제29권9호
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    • pp.979-987
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    • 2005
  • Numerical simulations were performed at atmospheric pressure in order to understand the effect of additives on flame speed, flame temperature, radical concentrations, $NO_x$ formation, and heat flux in freely propagating $CH_4-Air$ flames. The additives were both carbon dioxide and hydrogen chloride which had a combination of physical and chemical behavior on hydrocarbon flame. In the flame established with the same mole of methane and additive, hydrogen chloride significantly contributed toward the reduction of flame speed, flame temperature, $NO_x$ formation and heat flux by the chemical effect, whereas carbon dioxide mainly did so by the physical effect. The impact of hydrogen chloride on the decrease of the radical concentration was about $1.4\~3.0$ times as large as that of carbon dioxide. Hydrogen chloride had higher effect on the reduction of $EI_{NO}$ than carbon dioxide because of the chemical effect of hydrogen chloride. The reaction, $OH+HCl{\rightarrow}Cl+H_2O$, played an important role in the heat flux from flames added by hydrogen chloride instead of the reaction, $OH+H_2{\rightarrow}H+H_2O$ which was an important reaction in hydrocarbon flames.

Study on Chemical Removal of Nitric Oxide (NO) as a Main Cause of Fine Dust (Air Pollution) and Acid Rain

  • Seo, Hyeon Jin;Jeong, Rak Hyun;Boo, Jang-Heon;Song, Jimin;Boo, Jin-Hyo
    • Applied Science and Convergence Technology
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    • 제26권6호
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    • pp.218-222
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    • 2017
  • This study was conducted to remove $NO_x$, which is the main cause of fine dust and air pollution as well as acid rain. $NO_x$ was tested using 3% NO (diluted in He) as a simulated gas. Experiments were sequentially carried out by oxidizing NO to $NO_2$ and absorbing $NO_2$. Especially, we focused on the changes of NO oxidation according to both oxidant ($NaClO_2$) concentration change (1~10 M) and oxidant pH change (pH = 1~5) by adding HCl. In addition, we tried to suggest a method to improve $NO_2$ absorption by conducting $NO_2$ reduction reaction with reducing agent (NaOH) concentration (40~60%). It was found that NO removal efficiency increased as both concentration of oxidant and flow rate of NO gas increased, and NO decreased more effectively as the pH of hydrochloric acid added to the oxidant was lower. The $NO_2$ adsorption was also better with increasing NaOH concentration, but the NO removal efficiency was ~20% lower than that of the selective NO reduction. Indeed, this experimental method is expected to be a new method that can be applied to the capture and removal of fine dust caused by air pollution because it is a method that can easily remove NO gas by a simple device without expensive giant equipment.

THE EFFECTS OF EGR AND SPLIT FUEL INJECTION ON DIESEL ENGINE EMISSION

  • Gao, Z.;Schreiber, W.
    • International Journal of Automotive Technology
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    • 제2권4호
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    • pp.123-133
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    • 2001
  • An important goal in diesel engine research is the development of a means to reduce the emission of oxides of nitrogen ($NO_x$) and soot particulate. A phenomenological model based on the multizone concept is used in the current paper to analyze and compare the effects of exhaust gas recirculation (EGR) and split fuel injection on emission from a compression-ignited, direct-injection engine. The present results show that $NO_x$ can be reduced with a minimum penalty of soot particle emission with cooled EGR. Compared with EGR, split fuel injection has a higher soot penalty at a given level of $NO_x$ reduction.

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