• Title/Summary/Keyword: $NH_4{^+}$ mineralization

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Incorporation of Winter Rapeseed (Brassica napus) as Green Manure on Mineralization and Uptake of Nitrogen to Succeeding Corn (Zea mays L.) (유채의 녹비 환원에 의한 질소무기화 및 옥수수의 질소 흡수)

  • Choi, Bong-Su;Hong, Ki-Chan;Sung, Jwa-Kyung;Nam, Jae-Jak;Lim, Jung-Eun;Lee, Hyeon-Yong;Yang, Jae-E.;Ok, Yong-Sik
    • Korean Journal of Organic Agriculture
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    • v.17 no.3
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    • pp.381-391
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    • 2009
  • Crop production can be secured by the cycle of green manure crops as an alternative of the chemical fertilizer. Recently, rapeseed (Brassica napus L.) has been cultivated in the south part of Korea for the production of biodiesel. In this research, we focused on recycling rapeseed residue, which is produced after harvesting the rapeseed for biodiesel, as a potential source of nitrogen to the succeeding crop. Pot experiment was conducted to evaluate the effects of winter rapeseed as green manure on mineralization and uptake of nitrogen to the succeeding corn (Zea mays L.). Result showed that total nitrogen and C/N ratio of rapeseed at the harvesting stage was 0.54% and 63, respectively. The incorporation of rapeseed without decomposition period slightly inhibited nitrogen uptake to the succeeding corn compared to those with 30 days decomposition period. The pH and EC values of soils increased by increasing the period of decomposition of rapeseed from 5.2 to 6.4 and from 0.05 dS/m to 0.21 dS/m, respectively. Significant amounts of $NH_4^+$ and $NO_3^-$ are released by incorporation of rapeseed. The succeeding corn took up 86% and 88% of inorganic nitrogen released from the rapeseed with and without decomposition period, respectively. The overall results suggested that the utilization of rapeseed residue as green manure can be an alternative source of nitrogen in corn-rapeseed double cropping system.

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Performance and Spatial Succession of a Full-Scale Anaerobic Plant Treating High-Concentration Cassava Bioethanol Wastewater

  • Gao, Ruifang;Yuan, Xufeng;Li, Jiajia;Wang, Xiaofen;Cheng, Xu;Zhu, Wanbin;Cui, Zongjun
    • Journal of Microbiology and Biotechnology
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    • v.22 no.8
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    • pp.1148-1154
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    • 2012
  • A novel two-phase anaerobic treatment technology was developed to treat high-concentration organic cassava bioethanol wastewater. The start-up process and contribution of organics (COD, total nitrogen, and $NH_4^+$-N) removal in spatial succession of the whole process and spatial microbial diversity changing when sampling were analyzed. The results of the start-up phase showed that the organic loading rate could reach up to $10kg\;COD/m^3d$, with the COD removal rate remaining over 90% after 25 days. The sample results indicated that the contribution of COD removal in the pre-anaerobic and anaerobic phases was 40% and 60%, respectively, with the highest efficiency of 98.5%; TN and $NH_4^+$-N had decreased to 0.05 g/l and 0.90 g/l, respectively, and the mineralization rate of total nitrogen was 94.8%, 76.56% of which was attributed to the anaerobic part. The microbial diversity changed remarkably among different sample points depending on the physiological characteristics of identified strains. Moraxellaceae, Planococcaceae, and Prevotellaceae were dominant in the pre-anaerobic phase and Bacteroidetes, Campylobacterales, Acinetobacter, Lactobacillus, Clostridium, and Bacillus for the anaerobic phase. Methanosarcinaceae and Methanosaeta were the two main phylotypes in the anaerobic reactor.

Photocatalytic Degradation of Methylene Blue by ACF/TiO2 and ACF/ZnO Composites under UV Light

  • Zhang, Kan;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.20 no.1
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    • pp.31-36
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    • 2010
  • Methylene blue (MB) was degraded by $TiO_2$ and ZnO deposited on an activated carbon fiber (ACF) surface under UV light. The ACF/$TiO_2$ and ACF/ZnO composites were characterized by BET, SEM, XRD, and EDX. The BET surface area was related to the adsorption capacity for composites. The SEM results showed that titanium dioxide and zinc oxide are distributed on the ACF surface. The XRD results showed that the ACF/$TiO_2$ and ACF/ZnO composites contained a unique anatase structure for $TiO_2$ and a typical hexagonal phase for ZnO respectively. These EDX spectra showed the presence of peaks of Ti element on ACF/$TiO_2$ composite and peaks of Zn element on the ACF/ZnO composite. The blank experiments for either illuminating the MB solution or the suspension containing ACF/$TiO_2$ or ACF/ZnO in the dark showed that both illumination and the catalyst were necessary for the mineralization of organic dye. Additionally, the ACF/$TiO_2$ composites proved to be efficient photocatalysts due to degradation of MB at higher reaction rates. The addition of an oxidant $([NH_4]_2S_2O_8)$ led to an increase of the degradation rate of MB for ACF/$TiO_2$ and ACF/ZnO composites.

Effects of the Fractionated Raw Cow Manure on Mobility of NO3--N in A Double-Layered Soil Column with Constant Water Head (상존수두상태의 이중토양토주에서 질산태질소 이동에 대한 분쇄우분의 효과)

  • Chung, Doug-Young;Lee, K.S.;Baek, M.J.
    • Korean Journal of Soil Science and Fertilizer
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    • v.34 no.1
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    • pp.26-32
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    • 2001
  • Influence of various rates of fractionated raw cow manure on hydraulic conductivity of the soil was observed. The fractionated raw cow manure(hereafter as FRCM) incorporated into soil. The hydraulic conductivity was measured for the double-layered soil while maintaining the water head by 5 cm over the soil surface. The influence on the mobility of $NO_3{^-}$-N transformed from the FRCM was analyzed. The upper layers (Wolgok series) were made with FRCM ranging from 0% to 10.4 % on weight basis for air-dried soil while the organic matter in the bottom layers (Chungwon series) was removed by combustion. The initial bulk densities for both layers were adjusted to $1.25g\;cm^{-3}$. In this experiment the $K_{sat}$ for the upper layer gradually decreased from $4.71{\times}10^{-3}cm\;min^{-1}$ to $1.2{\times}10^{-3}cm\;min^{-1}$ with increasing the rate of the FRCM from 0 % to 10.4%, while the Ksat of the bottom layer was maintained as $3.7cm\;min^{-1}$. For the double-layered soil columns, the $K_{sat}$ decreased with increasing rate of FRCM at the upper layer from $1.7{\times}10^{-3}cm\;min^{-1}$ to $8{\times}10^{-4}cm\;min^{-1}$ as the rate of organic matter increased from 0 % to 10.4 %, while it took almost 7 days to 64 days to obtain the steady state $K_{sat}$ The elution patterns of $NO_3{^-}$-N and $NH_4{^+}$-N showed that the amounts of both $NO_3{^-}$-N and $NH_4{^+}$-N rapidly approached to the maximum ranging from $14.8mmol_c\;kg^{-1}$ to $0.58mmol_c\;kg^{-1}$ as the rate of FRCM decreased from 10.7 % to 0 % which is equivalent to indigenous amount of $NO_3{^-}$-N and $NH_4{^+}$-N. And the amounts of $NO_3{^-}$-N were approximately three or four time than those of $NH_4{^+}$-N, indicating that the transformation rate of $NO_3{^-}$-N was improved by the higher FRCM rate. Thus, the ability of a soil to supply N can be predicted from its mineralization parameters and leaching potentials influenced by water flow regime in soil.

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Variation Patterns in Concentration of Inorganic Nitrogen from Liquid Grass Fertilizer during Aerobic Incubation (항온 호기 배양 조건에서 잔디 예초물 액비로부터 무기화된 질소의 농도 변화)

  • Lee, Tae-Kyu;Park, Ji-Suk;Lee, Min-Jin;Kim, Jong-Sung;Ro, Hee-Myong;Kim, Sang-Jun;Jeon, Seung-Woo;Seo, Sang-Gug;Kim, Kil-Yong;Lee, Geon-Hyoung;Jeong, Byung-Gon
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.6
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    • pp.1120-1125
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    • 2012
  • To assess fertilizer value of an quasi-aerobically fermented liquid clipped-grass fertilizer, aerobic incubation experiment using two texturally contrasting loam (L) and sandy loam (SL) soils was conducted for 60 days to investigate temporal variations in N mineralization pattern of the liquid fertilizer applied. To do so, the quasi-aerobically fermented liquid clipped-grass fertilizer was prepared, applied to each soil at a rate of 200 kg-N $ha^{-1}$ and aerobically $25^{\circ}C$ in the dark. During incubation, soil water content was adjusted to field moisture capacity (-33 kPa of soil matric potential) by adding distilled water as necessary to maintain their initial weights. At desired time of incubation (0, 1, 5, 10, 20, 40, and 60 days after incubation), soil was sampled and analyzed for inorganic nitrogen ($NH_4{^+}$-N and $NO_3{^-}$-N) concentrations, pH, EC, total carbon contents and total nitrogen contents. Concentrations of $NH_4{^+}$-N began to decrease right after incubation for L soils, and 10 days after incubation for SL soils, while those of $NO_3{^-}$-N began to increase onset of $NH_4{^+}$-N disappearance. The results of this study showed that quasi-aerobically fermented liquid clipped-grass fertilizer could serve as an alternative to chemical N fertilizer.

Change of Nutrition Loss of Long-term Application with Different Organic Material Sources in Upland Soil (유기물원이 다른 퇴비연용 밭토양에서 양분유실량 변화)

  • Kim, Jong-Gu;Lee, Kyeong-Bo;Kim, Jae-Duk;Han, Sang-Su;Kim, Seong-Jo
    • Korean Journal of Soil Science and Fertilizer
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    • v.33 no.6
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    • pp.432-445
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    • 2000
  • The objective of this study was to determine the effects of various kinds of composts on the change of nutrition loss in upland soils. Field experiments were conducted in the loam and sandy loam soils, while the clay loam and sandy loam soils were used for laboratory experiments. Various kinds of composts such as poultry manure compost(PMC), cow manure compost(CMC), human excrement sludge(HES), and food industrial sludge compost(FISC) were applied annually at rates of 0, 40, and $80mg\;ha^{-1}$ to soils grown with soybean and maize plants for 4 years during 1994 to 1997. The results of this study were as follows : The loss of nutrients in the form of cation and anion by run-off water increased with the increase of compost application rate. Compared with bare soils, maize cultivation decreased the nutrient loss by run-off from soils by 43% in anionic form and 32% in cationic form. Amount of cation loss were ordered $K^+$ > $Ca^{2+}$ > $Na^+$ > $Mg^{2+}$ > $NH_4{^+} $ and that of anion loss were ordered $SO_4{^{2-}}$ > $NO_3{^-}$ > $Cl^-$ > $PO_4{^{3-}}$. Nutrient loss of sand loam soil in the cation and anion by percolation water increased 1.7 times compared with loam soil. $NO_3{^-}-N$ contents in percolated water were high at the initial stage after compost application, and the amounts were higher in sandy loam soil than loam soil. The maize cultivation also decreased the $NO_3{^-}-N$ contents in percolated water by 82% in loam soil, and 58% in sand loam soil. Soil pH of composts determined by laboratory incubation test increased pH 6.1~6.8 application with poultry and cow manure compost but application with human excrement sludge decreased pH 4.5~4.7. Soil EC were increased initially composts application and decreased up to 2 weeks, thereafter kept a certain level. Nitrogen mineralization rates of composts determined by laboratory incubation test at $25^{\circ}C$ were 39~76% in sandy loam soil, and 16~48% in clay loam soil.

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Urease and nitrification inhibitors with pig slurry effects on ammonia and nitrous oxide emissions, nitrate leaching, and nitrogen use efficiency in perennial ryegrass sward

  • Park, Sang Hyun;Lee, Bok Rye;Kim, Tae Hwan
    • Animal Bioscience
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    • v.34 no.12
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    • pp.2023-2033
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    • 2021
  • Objective: The present study was conducted to assess the effect of urease inhibitor (hydroquinone [HQ]) and nitrification inhibitor (dicyandiamide [DCD]) on nitrogen (N) use efficiency of pig slurry for perennial ryegrass regrowth yield and its environmental impacts. Methods: A micro-plot experiment was conducted using pig slurry-urea 15N treated with HQ and/or DCD and applied at a rate of 200 kg N/ha. The flows of N derived from the pig slurry urea to herbage regrowth and soils as well as soil N mineralization were estimated by tracing pig slurry-urea 15N, and the N losses via ammonia (NH3), nitrous oxide (N2O) emission, and nitrate (NO3-) leaching were quantified for a 56 d regrowth of perennial ryegrass (Lolium perenne) sward. Results: Herbage dry matter at the final regrowth at 56 d was significantly higher in the HQ and/or DCD applied plots, with a 24.5% to 42.2% increase in 15N recovery by herbage compared with the control. Significant increases in soil 15N recovery were also observed in the plots applied with the inhibitors, accompanied by the increased N content converted to soil inorganic N (NH4++NO3-) (17.3% to 28.8% higher than that of the control). The estimated loss, which was not accounted for in the herbage-soil system, was lower in the plots applied with the inhibitors (25.6% on average) than that of control (38.0%). Positive effects of urease and/or nitrification inhibitors on reducing N losses to the environment were observed at the final regrowth (56 d), at which cumulative NH3 emission was reduced by 26.8% (on average 3 inhibitor treatments), N2O emission by 50.2% and NO3- leaching by 10.6% compared to those of the control. Conclusion: The proper application of urease and nitrification inhibitors would be an efficient strategy to improve the N use efficiency of pig slurry while mitigating hazardous environmental impacts.

Effect of Aluminum Sulfate Addition to Litter and Dietary Protein Levels of Broilers on Litter Nitrogen Content (육계에 급여되는 사료중의 단백질 수준과 깔짚 내의 Aluminum Sulfate 첨가가 깔짚 내의 질소 함량에 미치는 영향)

  • Park, I. H.;K. H. Nahm
    • Korean Journal of Poultry Science
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    • v.30 no.2
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    • pp.119-128
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    • 2003
  • The two experiments in this study compared litter nitrogen (N) contents after broiler chicks were raised for 42 days. Experiment I compared litter treated with aluminum sulfate (alum) [Al$_2$(SO$_4$)$_3$ㆍ14$H_2O$] (T$_1$) with nontreated litter (T$_2$) when the broiler chicks were fed the same levels of dietary protein (23% for 0∼3 weeks, 21% for 4∼6 weeks) Experiment 2 compared the alum treated litters of broiler chicks fed high protein diets (T$_3$) having 20.4% protein for 0∼3 weeks and 19.3% for 4∼6 weeks, with lower protein diets (T$_4$) having protein levels of 18.0% for 0∼3 weeks and 17.0% for 4 6 weeks. Each treatment had four replicate cages. As shown in Table 1, T$_1$ had a significantly (P<0.0l) lower pH and significantly (P<0.05) higher total N (TN), NH$_4$-N and inorganic N (IN) than T$_2$. T$_1$ and T$_2$ had similar moisture, organic carbon (OC), NO$_3$-N and organic N (ON). Alum treatment increased available N (AN) significantly (P<0.05) from 13.75$\pm$0.0l mg/g to 14.90$\pm$0.01 mg/g and predicted available N (PAN) significantly (P<0.05) from 15.00$\pm$0.0l to 16.50$\pm$0.02. The C : N ratios were 18.84$\pm$0.40 (T$_1$) and 19.46$\pm$0.10 (T$_2$) while the C : ON ratios were 28.49$\pm$1.15 (T$_1$) and 28.34$\pm$0.20 (T$_2$) although C : N ratios or C : ON ratios did not show any difference between T$_1$ and T$_2$. In Table 2, T$_3$ had significantly (P<0.05) higher moisture, TN, NH$_4$-N, ON and IN than T$_4$, while the pH, OC and NO$_3$-N were similar in both groups. The AN of T$_3$ increased significantly (P<0.05) from 10.99$\pm$0.0l mg/g to 12.98$\pm$0.03 mg/g, while the PAN increased significantly (P<0.05) from 12.39$\pm$0.10 mg/g (T$_4$) to 14.68$\pm$ 0.30 mg/g (T$_3$). The C : N ratios increased significantly (P<0.0l) from 20.07$\pm$0.20 (T$_3$) to 24.40$\pm$0.10 (T$_3$). The C : ON ratios also increased significantly (P<0.0l) from 28.99$\pm$1.15 (T$_3$) to 35.51$\pm$0.20 (T$_4$). These current research results show increased AN contents and PAN contents in alum treated litter or with increased CP levels regardless of alum treatment. However, none of the litters in this study could initially increase mineralization.

Growth and Soil Chemical Property of Small Apple Trees as Affected by Organic Fertilizers and Mulch Sources (비료원과 멀칭재료에 따른 사과 유묘의 생장 및 토양이화학성 변화)

  • Choi, Hyun-Sug;Rom, Curt;Lee, Youn;Cho, Jung-Lai;Jung, Seok-Kyu;Jee, Hyeong-Jin
    • Korean Journal of Environmental Agriculture
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    • v.30 no.1
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    • pp.9-15
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    • 2011
  • BACKGROUND: This study was conducted to evaluate the effects of the fertilizer sources and ground cover mulches on nutrient release, growth, and photosynthesis in small one-year-old apple (Malus ${\times}$ domestica Borkh.) trees in controlled conditions. METHODS AND RESULTS: Treatments included no fertilizer (NF), commercial organic fertilizer (CF), and poultry litter (PL) for fertilizer treatments, and wood chips (WC), shredded paper (SP), green compost (GC), and grass clippings (GR) for cover mulch treatments. All treatments were applied proportionally based on the volume ratio equivalent to the soil. CF, PL, and GR treatments that had optimum carbon (C) and nitrogen (N) ratios (less than 30:1) for N mineralization through the microbes released the greatest $NH_4^+$ concentrations in the pot media at 90 days after the treatments, but GC mulch with the optimum C:N ratio did not. CF-, PL- and GR-treated plants had the largest leaf area, thickest stem diameter, longest shoot extension, and greater dry matter production. CONCLUSION(s): CF and PL showed an suitable organic nutrient source for improving plant growth in an orchard. Interestingly, GR also could be a nutrient source for tree growth, if vegetation competition is controlled by maintaining vegetation height and recycling enough grass clippings to the soil in an orchard.

The Effect of Popped Rice Hulls Compost Application on Soil Chemical and Physical Properties in Fluvio-marine plain paddy soils (퇴화염토지 논에서 팽화왕겨 퇴비시용이 토양이화학성에 미치는 영향)

  • Yoo, Chul-Hyun;Yang, Chang-Hyu;Kim, Taek-Kyum;Ryu, Jin-Hee;Kim, Byung-Su;Kim, Jae-Duk;Jung, Kwang-Yong
    • Korean Journal of Soil Science and Fertilizer
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    • v.39 no.6
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    • pp.403-408
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    • 2006
  • Fluvio-marine paddy soils in Korea consist of high silt content and have the hardpan located below 20~30 cm from surface soil. This properties cause poor rice rhizosphere conditions such as low permeability and porosity, high bulk density and hardness. The aims of this study was to investigate the effect of popped rice hulls compost(PRHC) on soil fertility changes in the Fluvio-marine plain paddy soils. Total nitrogen content and nitrogen mineralization rate of PRHC were 1.17 and 33.5, respectively, and its C/N ratio was 35.4. Application of PRHC increased the content of organic matter and exchangeable potassium and improved the bulk density and porosity. The content of $NH_4-N$ in soil was high in the PRHC plot until maximum tillering stage. An uptake amount of fertilized nitrogen was greater in standard fertilization plot at early growth stage, however, it was greater more in PRHC plots at the ripening period than in standard fertilization plot. Among the PRHC treated plots, uptake amount was the greatest in 50% PRHC plot during the all growth period. Nitrogen efficiencies were higher in PRHC plot during the all growth period. Rice yields in all PRHC plots were lower than in standard fertilization, however, the yield of 40% PRHC plot was similar with that of standard.