• Title/Summary/Keyword: $NH_3-N$ 제거율

Search Result 107, Processing Time 0.024 seconds

Fate of Nitrogen and Phosphorous in Hydroponic Waste Solution Applied to the Upland Soils (시설하우스 폐양액의 토양 처리에 따른 질소 및 인의 이동)

  • Yang, Jae-E.;Park, Chang-Jin;Yoo, Kyung-Yoal;Kim, Kyung-Hee;Ok, Yong-Sik
    • Korean Journal of Environmental Agriculture
    • /
    • v.24 no.2
    • /
    • pp.132-138
    • /
    • 2005
  • Objective of this research was to evaluate the fate of nitrogen and phosphorous in hydroponic waste solution from the plastic film house cultivation applied to the upland soil by column leaching and field experiment. The pH and EC of leachate were decreased by the reaction with the upland soil in the column leaching experiment. The EC and concentrations of $H^+,\;K^+,\;and\;{NH_4}^+$ of leachate were decreased as the column length (soil depth) was increased. But these were increased as the amounts of the hydroponic waste solution were increased field experiment growing red pepper (Capsicum annum L.) to monitor the nutrients movement using ion exchange resin capsule demonstrated that the nutrient concentration of soil solution was increased in the orders of $PO_4-P. Nitrate concentration of resin capsule inserted into the soil was relatively higher than other nutrients $(NH_4-N\;and\;PO_4-P)$ at the 45 cm of soil depth. The overall results demonstrated that the hydroponic waste solution could be recycled as plant nutrients to enhance fertility of soils. But nitrate leaching was a major factor for safe use of the hydroponic waste solution in soil.

A Study on the Impacts of Paste Type Torrefied Wood Flour Coagulants on Water Ecosystem (반탄화목분 Paste상 응집제의 수생태계 미치는 영향에 관한 연구)

  • YANG, Seung Min;LEE, Seok Eon;PARK, Hae Keum;KANG, Seog Goo
    • Journal of the Korean Wood Science and Technology
    • /
    • v.47 no.6
    • /
    • pp.709-720
    • /
    • 2019
  • Due to global warming and abnormal climate, the incidence and scale of green tracts in rivers and water intake dam are increasing every year. Therefore, in this study, developed eco friendly positively charged Torrefied Wood Flour(TWF) coagulant by reusing wood damaged by blight as a natural material. In order to evaluate the effect of coagulant on water ecosystem, green algae contaminated water was collected and TOC showed high removal rate of 86% ~ 92% under 1% and 5% TWF C-PAM treatment condition. The $NH_3-N$ showed 53% removal efficiency. The average pH of the polluted water was 7.9 in the case of hydrogen ion concentration, and the pH of the treated water was in the range of 6.5 ~ 7.7, It was found to be suitable for water quality standards. In ecotoxicity tests, all the results of the experiment showed that both the number of green algae and that of treated water were not affected by the survival of the daphnia. Therefore, as a result of the analyzing, developed paste type TWF coagulants is considered to be able to remove algae using natural resources.

Characteristics of Microbial Distribution of Nitrifiers and Nitrogen Removal in Membrane Bioreactor by Fluorescence in situ Hybridization (막/생물반응기에서 Fluorescence in situ Hybridization 기법을 이용한 질산화 미생물 분포특성 및 질소제거 연구)

  • Lim Kyoung-Jo;Kim Sun-Hee;Kim Dong-Jin;Cha Gi-Cheol;Yoo Ik-Keun
    • Microbiology and Biotechnology Letters
    • /
    • v.34 no.3
    • /
    • pp.257-264
    • /
    • 2006
  • An aerobic submerged membrane bioreactor (MBR) treating ammonium wastewater was studied in respect of nitrification characteristics and distribution of nitrification bacteria over a period of 350 days. MBR was fed with ammonium concentration of 500-1000 mg $NH_4-N/L$ at a nitrogen load of $1-2kg\;N/m^3{\cdot}d$. Overall ammonium oxidation rate increased with dissolved oxygen (DO) concentration, temperature, and sludge retention time (SRT). Under a higher concentration of free ammonia ($NH_3-N$) due to the decrease of ammonium oxidation rate, the nitrite ratio ($NO_2-N/NO_x-N$) in the effluent increased. The sudden collapse of nitrification efficiency accompanied by sludge foaming and the increase of sludge volume index (SVI) was observed unexpectedly during the operation. At the later stage of operation, additional carbon source was fed to the MBR and resulted in twice higher value of SVI and the decrease of ammonium oxidation rate. In fluorescence in situ hybridization (FISH) analysis, genus Nitrosomonas which is specifically hybridized with probe NSM156 was initially the dominant ammonia oxidizing bacteria and the amount of Nitrosospira gradually increased. Nitrospira was the dominant nitrite oxidizing bacteria during whole operational period. Significant amount of Nitrobacter was also detected which might due to the high concentration of nitrite maintained in the reactor.

Nutrients Removal Efficiency by Vegetation Density on Constructed Wetland from Small Watershed (소수계 유역 인공습지에서 식생 밀도 차이에 다른 영양염류 제거효율)

  • Ko, Jee-Yeon;Kang, Hang-Won;Lee, Jae-Sang;Kim, Chun-Song;Sakadevan, K.;Bavor, H.J.
    • Korean Journal of Environmental Agriculture
    • /
    • v.22 no.4
    • /
    • pp.266-272
    • /
    • 2003
  • This study was conducted to evaluate effects of 2 constructed wetlands with different vegetation states (plumpton park wetland and Woodcroft park wetland) for reducing non-point source pollution from small watershed consisted of residential and agricultural area in suburban district of Sydney, Australia. The total nitrogen and phosphate removal efficiency of Plumpton park constructed wetland, composed of stable and dense vegetation, were 38.3% and 26.2% and Woodcroft park constructed wetland having still poor vegetation due to the short time to settle down transplanted plants after construction, showed relatively low removal efficiency of 20.2% and 14.0%. The removal efficiency of inorganic nutrients such as $NH_4-N$, $NO_3-N$, $PO_4^{-3}$ were higher than total nitrogen and phosphate because plants and microorganisms in rhizosphere of constructed wetlands took up inorganic nutrients shortly. According to the type of wetland inflow, the nutrients removal efficiency of storm water flow was lower than base flow.

Effects of Pre-Oxidation for Recirculation of Aquaculture Wastewater (양어용수 재이용을 위한 전 산화처리의 효과)

  • Lim, Jae-Lim;Shin, Hang-Sik
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.22 no.1
    • /
    • pp.103-111
    • /
    • 2000
  • Ozonation and advanced oxidation($H_2O_2/O_3$) process were investigated under various experimental conditions to improve the efficiency of biological filter used for the treatment of recycled wastewater from aquaculture. Ammonia removal followed the first-order reaction whose reaction rate constant(k) was $2.0{\times}10^{-2}min^{-1}$ in ozonation. The ammonia removal rate increased according as the bicarbonate alkalinity is increased. About 46% $NH_3$ was oxidized by ozone at 200 mg/L as $CaCO_3$. When alkalinity existed in wastewater, ammonia removal rate by advanced oxidation was very low due to the inhibition effect of bicarbonate. However, when initial pH was adjusted to about 8.2 by 0.1 N KOH, ammonia removal rate was improved higher than that by ozonation. Especially. ammonia removal rate was the highest at $H_2O_2/O_3$ of 0.25 and about 90% of ammonia was removed in 30 min at this ratio as pH was maintained over 9. In the case of wastewater containing ammonia and organic constituents, ammonia removal efficiency by both ozonation and advanced oxidation decreased seriously because organic constituents consumed the oxidant faster than ammonia. In addition the optimal $H_2O_2/O_3$ ratio was changed. Like ammonia removal, DOC(dissolved organic carbon) increased for first 10 min and then decreased slowly because the particulate organic constituents were oxidized rapidly and then produce DOC. Even when the ammonia concentration by twice, oxidation of DOC was not retarded.

  • PDF

Wastewater Treatment Using Ultrafiltration (UF) and Reverse Osmosis (RO) Process (침지형 한외여과 막공법과 역삼투 공법을 이용한 하.폐수처리)

  • Choi, H.J.;Park, Y.J.;Lee, S.M.
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.34 no.10
    • /
    • pp.678-683
    • /
    • 2012
  • One of alternatives to solve the global water shortages is the reuse of wastewater. The aim of this study was to evaluate whether it can be reused for industrial water from wastewater in "A" City with ultrafiltration (UF) and reverse osmosis (RO) process. The results obtained in this study were that the inorganics such as Na, Mg, Cl, Ca, Mn, $PO_4$, $SO_4$, etc. were removed with high treatment efficiency (more than 97%), respectively. However, the removal of $NH_4$-N, TN, $NO_3$-N, BOD was found to be 35.71%, 85.21%, 87.05% and 56%, respectively. The removal efficiency of nutrients was relatively low compared to other metal ions. Despite low nutrients removal, the treated wastewater is recommended to reuse, because the nutrient contents in influent from the secondary wastewater treatment plant were small amount. In addition, all other metrics in the wastewater were found to be lower amount than wastewater reuse criteria. Therefore, the wastewater treated by UF-RO could be sufficient to reuse for industrial waster.

Removal Characteristic of Ammonia Nitrogen and Behavior of Nitrogen in Synthetic Wastewater Using Leclercia Adecarboxylata (Leclercia Adecarboxylata를 이용한 합성폐수의 암모니아성질소 제거특성 및 질소거동)

  • Lee, Hyun-Hee;Phae, Chae-Gun
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.29 no.4
    • /
    • pp.460-465
    • /
    • 2007
  • In this study, the removal characteristic of ammonia nitrogen and behavior of nitrogen was investigated using Leclercia adecarboxylata, which was derived from the culture contaminated by ammonia nitrogen of high concentration. The method of ammonia nitrogen removal was not biological nitrification and denitrification but elimination of nutrient salt with internal synthesis of microorganisms which use ammonia nitrogen as substrate. L. adecarboxylata(one of ammonia synthesis microorganisms) was highly activated and showed the most high removal efficiency in free salt condition but the removal efficiency decreased badly in salt concentration of more than 4%. About 80 mg/L of $NH_3-N$ was mostly removed within 20 hours and 500 mg/L of $NH_3-N$ showed less then removal efficiency of 50% because carbon source was not enough. However, ammonium nitrogen concentration was decreased again when the carbon source was inserted additionally thus, ammonium nitrogen removal efficiency by L. adecarboxylata, was related to amount of carbon source. pH decreased from 8.0 to 6.36 according to growth of L. adecarboxylata. Concentration of nitrite nitrogen and nitrate nitrogen did not increase and TKN concentration showed no variation while ammonia nitrogen was removed by L. adecarboxylata. In addition to, when content of protein in organic nitrogen was measured, protein was not detected at the beginning of microorganism synthesis but protein of 193.1 mg/L was detected after 48 hours. Hence, ammonium nitrogen was not decomposed as nitrate nitrogen and nitrite nitrogen but synthesized by L. adecarboxylata, which has excellent ability of nitrogen synthesis and can threat ammonia nitrogen of high concentration in wastewater.

Advanced Wastewater Treatment on ship's sewage with new MARPOL73/78 ANNEX IV (MARPOL73/78 ANNEX IV의 개정발효에 따른 선박 오수의 고도처리)

  • Park, Sang-Ho;Lim, Jae-Dong;Park, Sung-Jeng;Kim, In-Soo
    • Proceedings of KOSOMES biannual meeting
    • /
    • 2007.05a
    • /
    • pp.91-96
    • /
    • 2007
  • Lab scale experimental study was carried out for SBR process, to investigate the effects of influent ship sewage organic compound removal and Bacillus sp. state on design parameters. This process was able to remove nitrogen and phosphorus as well as organic matter efficiently. More than 95% of chemical oxygen demand(COD) were removed. In addition, about 97% of total nitrogen (T-N) was reduced. The total phosphorus(T-P) reduction averaged 93%. The performance load of SBR process was shown to be $0.095kg{\cdot}TOC/m^3{\cdot}day$. The pH was decreased from 8.1 to 7.0 within 30 min and increased to 7.3 at the end of anoxic stage, and these phenomena were explained. The sludge produced in the SBR process is characterized by low generation rate (about $0.36kg{\cdot}MLSS/kg{\cdot}TOC$) and excellent settleability. The number of Bacillus sp. in the SBR was 24.2%, indicating that Bacillus sp. was a predominant species in the reactor.

  • PDF

Effects of MLSS Concentration and Influent C/N Ratio on the Nitrogen Removal Efficiency of Alternately Intermittently Aerated Nonwoven Fabric Filter Bioreactors (교차 간헐 포기식 부직포 여과막 생물반응조에서 MLSS 농도 및 유입수 C/N 비가 질소 제거효율에 미치는 영향)

  • Jung, Kyoung-Eun;Bae, Min-Su;Lee, Jong-Ho;Cho, Yun-Kyung;Cho, Kwang-Myeung
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.28 no.5
    • /
    • pp.501-510
    • /
    • 2006
  • To investigate the effects of MLSS concentration and influent C/N ratio on the nitrogen removal efficiency of alternately intermittently aerated nonwoven fabric filter bioreactors, the MLSS concentrations of the reactors were maintained at approximately 5,500 mg/L, 10,000 mg/L and 15,000 mg/L, and the influent TCOD/TKN ratio was decreased gradually from 5 to 2 by adding $NH_4Cl$. The influent was prepared by diluting a food waste leachate to a TCOD concentration of about 300 mg/L. The results of the experiment showed F/M ratios less than 0.112 g TCOD/g MLSS-day, average TCOD removal efficiencies of above 95%, and an average observed microbial yield coefficient of 0.283 g MLSS/g COD removed. The nitrification efficiencies were computed to be always better than 96% except one case where the nitrification efficiency was 90.5% when the MLSS concentration and the influent TCOD/TKN ratio was 5,500 mg/L and 2, respectively. The denitrification efficiency deteriorated as the influent TCOD/TKN ratio decreased. The average denitrification efficiency at the MLSS concentration of 10,000 mg/L was 10.7% better than that at the MLSS concentration of 5,500 mg/L, and the denitrification rate improved at a rate of 2.66 mg NL as the MLSS concentration increased by 1,000 mg/L. When the MLSS concentration was 15,000 mg/L, however, the average denitrification efficiency was merely 4.6% higher compared to when the MLSS concentration was 5,500 mg/L, and the denitrification rate increased at a rate of 0.75 mg N/L per 1,000 mg/L MLSS increase. Therefore, no strict proportional relationship was found between MLSS concentration and endogenous denitrification rate. The average alkalinity consumption rate was 3.36 mg alkalinity/mg T-N removed, which is similar to the theoretical value of 3.57 mg alkalinity/mg T-N removed, but the rate increased as the influent TCOD/TKN ratio decreased.

Isolation of Microorganisms and Development of Microbial Augmentation for Treatment of Industrial Wastewater containing Ammonium Nitrogen (암모니아성 질소함유 산업폐수처리를 위한 미생물의 분리 및 복합미생물제제의 개발)

  • Lee, Myoung-Eun;Mun, Seo-Jin;Kwon, Do-Hyuck;Suh, Hyun-Hyo
    • Journal of Life Science
    • /
    • v.30 no.2
    • /
    • pp.129-136
    • /
    • 2020
  • For effective treatment of wastewater containing ammonium nitrogen (NH4-N), AT2, AT9, and AT12 strains, having high total organic carbon (TOC) removal capability, and FN47, possessing excellent ammonia nitrogen removal capability present in the activated sludge in the aeration tank of food wastewater treatment plants, were isolated and identified. The cells of these isolated strains were used for microbial augmentation with FIW-1 in the defatted rice bran as a medium to treat industrial wastewater. The investigation of the cultural characteristics of these isolated strains in the aeration tank showed that the affinities for substrate of the isolated strains were extremely high, of which AT12 (Alcaligenes sp. AT12) was the highest among the isolated strains. Ammonium nitrogen removal efficiency in the food wastewater was 71% in the isolated strain FN47 (Microbacterium sp. FN47) treatment group. When only activated sludge was added in the lab scale pilot using food wastewater during continuous culture experiment, the TOC removal efficiency was 63%. Meanwhile, the removal efficiency of 92% was obtained when the microbial augmentation FIW-1 for wastewater treatment was applied. In addition, the chemical oxygen demand (COD) level from the effluent wherein microbial augmentation FIW-1 was input for the initial three days in the wastewater treatment site experiment showed a treatment rate of about 43%, which was increased to 62% after an elapse of 5 days.