• Title/Summary/Keyword: $Mg_{2}Si$

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A Study on the Development for the Vehicle Engine Mountion Bracket Using Squeeze Casting (스퀴즈 캐스팅 제조법에 의한 자동차 엔진 마운틴 브래킷 개발에 관한 연구)

  • Kim, S.H.
    • Journal of Power System Engineering
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    • v.7 no.4
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    • pp.44-48
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    • 2003
  • Alumium alloys casting are gaining increased acceptance in the automotive and electronic industeries and squeeze casting is the most efficient method of manufacturing such mass produced parts. This study has been investigated the microstructures and mechanical properties of Al-7.0Si-0.4Mg(AC4C)alloy fabricated by squeeze casting process for development of Engine Mountain Bracket. The microstructure of squeeze casted specimen were composed of eutectic structure Alumimim solid solution and $Mg_2Si$ precipitates. The tensile strength of as-solid solution treatment Al-7.0Si-0.4Mg alloy revealed 2985MPa. It was found that Al-7.0Si-0.4Mg alloy have good aging hardening effect results are presented to show the validity of the control method.

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Interface formation between $MgF_2$ and Si(111) studied by LEED, AES, and TPD

  • Y.S. Chung;J.Y. Maeng;Kim, Sehun
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.183-183
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    • 1999
  • The phases and interface formation of MgF2 on Si(111) were studied by using LEED, AES, and TPD. When thick MgF2 film was deposited on the Si(111) surface at RT뭉 annealed at higher temperatures, a sequence of LEED patterns (no LEED pattern $\longrightarrow$1$\times$1$\longrightarrow$3$\times$1$\longrightarrow$7$\times$7) was observed. On the 1$\times$1 model in which Mg adsorbs on T4 site and F on H3 site could explain the simultaneous desorption of SiF2 and Mg. When thin MgF2 film was deposited, and initial $\alpha$-$\times$1 phase transforms to 3$\times$3 and $\beta$-1$\times$1 by thermal annealing with a slow evaporation of F and diffusion of Mg into the surface. the 3$\times$3 surface changes to ${\gamma}$-1$\times$1 by the selective desorptioon of F under e-beam irradiation and subsesquently to a Mg-induced {{{{ SQRT { 3} }}}} structure by annealing at $600^{\circ}C$.

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Green Light-Emitting Phosphor, Ba2xCaMgSi2O8:Eux

  • Kim, Jeong-Seog;Piao, Ji-Zhe;Choi, Jin-Ho;Cheon, Chae-Il;Park, Joo-Suk
    • Journal of the Korean Ceramic Society
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    • v.42 no.3 s.274
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    • pp.145-149
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    • 2005
  • [ $Eu^{2+}$ ]-activated barium magnesium silicate phosphor, $(Ba,Ca)_{3}MgSi_{2}O_{8}:Eu_{x}$, has been known to emit blue-green light. In this study we report the manufacturing processes for producing either pure green or pure blue light-emitting phosphor from the same composition of $Ba_{2-x}Ca_{2}CaMgSi_{2}O_{8}:Eu_{x}$ (0 < x < 1) by controlling heat treatment conditions. Green light emitting phosphor of $Ba_{1.9}CaMgSi_{2}O_{8}:Eu_{0.1}$ can be produced under the sample preparation condition of highly reducing atmosphere of $23\%\;H_2/77\%\;N_2$, while blue or blue-green light emitting phosphor under reducing atmosphere of $5\~20\%\;H_2\;/\;95\~80\%$ N_2. The green light-emitting phosphors are prepared in two steps: firing at $800\~1000^{\circ}C$ for $2\~5$ h in air then at $1100\~1350^{\circ}C$ for 2-5 h under reducing atmo­sphere $23\%$ $H_2/77\%\;N_2$. The excitation spectrum of the green light-emitting phosphor shows a broadband of $300\~410$ nm. The emission spectrum has a maximum intensity at the wavelength of about 501 nm. The CIE value of green light emission is (0.162, 0.528). The pure blue light-emitting phosphors can be produced using the $Ba{2_x}CaMgSi_{2}O_{8}:Eu_{x}$ by introducing additional firing step at $1150\~1300^{\circ}C$ in air before the final reducing treatment. The XRD analysis shows that the green light-emitting phosphor mainly consisted of $Ba_{1.31}Ca_{0.69}SiO_{4}$ (JCPDS $\#$ 36-1449) and other minor phases i.e., $MgSiO_3$ (JCPDS $\#$ 22-0714) and $Ca_{2}BaMgSi_{2}O_{8}$ (JCPDS $\#$ 31-0128). The blue light-emitting phosphor mainly consisted of $Ca_{2}BaMgSi_{2}O_{8}$ phase.

Thermoluminescent Response of Thin LiF:Mg,Cu,Na,Si Detectors to Beta Radiation (얇은 LiF:Mg,Cu,Na,Si 검출기의 베타선장에 대한 TL 반응)

  • Nam, Y.M.;Kim, J.L.;Chang, S.Y.;Cho, H.W.;Kim, H.J.
    • Journal of Radiation Protection and Research
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    • v.24 no.1
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    • pp.39-43
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    • 1999
  • Thermoluminescent (TL) response characteristics of a thin LiF:Mg,Cu,Na,Si Teflon detectors have been studied for use in beta radiation detection. The detectors were fabricated from a mixture of LiF:Mg,Cu,Na,Si phosphor and Teflon powder which was molded into a thin disk form of $50mg/cm^2$ thickness. These detectors were irradiated to beta fields of $^{147}Pm,\;^{204}Tl\;and\;^{90}Sr/^{90}Y$ sources with a covering of Kapton foil ($2mg/cm^2$) and photon irradiation was carried out with a $^{137}Cs$ source at the Korea Atomic Energy Research Institute (KAERI). Batch uniformity was estimated to be 4.7% and the beta dose response presented linear relationship from 0.1 mGy to 100 Gy. The beta energy responses of thin detectors normalized to $^{137}Cs$ were presented as 0.46, 1.09 and 1.06 for $^{147}Pm,\;^{204}Tl\;and\;^{90}Sr/^{90}Y$ beta rays, respectively. The evaluated values for angular responses were $0.93{\pm}0.03\;(^{147}Pm),\;0.94{\pm}0.04\;(^{204}Tl),\;and\;0.92{\pm}0.05\;(^{90}Sr/^{90}Y)$. The results satisfied well a proposed ISO Standard for beta ray dosimeters.

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Photoluminescence Properties of $Zn_{2-x-y}SiO_4:Mn_x,\;M_y$ Phosphors ($Zn_{2-x-y}SiO_4:Mn_x,\;M_y$계 형광체의 발광특성)

  • Cho, Bong Hyun;Sohn, Kee Sun;Park, Hee Dong;Chang, Hyun Ju;Hwang, Taek Sung
    • Journal of the Korean Chemical Society
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    • v.43 no.2
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    • pp.206-212
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    • 1999
  • The main objective of the present investigation is to improve the photoluminescent performance of existing $Zn_2SiO_4:Mn$ phosphors by introducing a new co-dopant. The co-doping effect of Mg and/or Cr upon emission intensity and decay time was studied in the present investigation. The co-dopants incorporated into the $Zn_2SiO_4:Mn$ phosphors are believed to alter the internal energy state so that the change in emission intensity and decay time can be expected. Both Mg and Cr ions have a favourable influence on photoluminescence prpperties, for example, the Mg ion enhances the intensity of manganese green emission and the Cr ion shortens the decay time. The enhancement in emission intensity of $Zn_2SiO_4:Mn,\;Mg$ phosphors was interpreted by taking into account the result from the DV-X${\alpha}$ embedded cluster calculation. On the other hand, the energy transfer between Mn and Cr ions was found to be responsible for the shortening of decay time in$Zn_2SiO_4:Mn,\;Cr$ phosphors.

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Fabrication and Properties of MFSFET′s Using $BaMgF_4$/Si Structures for Non-volatile Memory ($BaMgF_4$/Si 구조를 이용한 비휘발성 메모리용 MFSFET의 제작 및 특성)

  • 이상우;김광호
    • Electrical & Electronic Materials
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    • v.10 no.10
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    • pp.1029-1033
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    • 1997
  • A prototype MFSFET using ferroelectric fluoride BaMgF$_4$as a gate insulator has been successfully fabricated with the help of 2 sheets of metal mask. The fluoride film was deposited in an ultrai-high vacuum system at a substrate temperature of below 30$0^{\circ}C$ and an in-situ post-deposition annealing was conducted for 20 seconds at $650^{\circ}C$ in the same chamber. The interface state density of the BaMgF$_4$/Si(100) interface calculated by a MFS capacitor fabricated on the same wafer was about 8$\times$10$^{10}$ /cm$^2$.eV. The I$_{D}$-V$_{G}$ characteristics of the MFSFET show a hysteresis loop due to the ferroelectric nature of the BaMgF$_4$film. It is also demonstrated that the I$_{D}$ can be controlled by the “write” plus which was applied before the measurements even at the same “read”gate voltage.ltage.

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The Effects of Hydration Retarding of Portland Cement by $MgSiF_6.6H_2O$ (규불화마그네슘에 의한 포틀랜드 시멘트의 수화 지연효과)

  • 한상호;이경희;정성철;김남호
    • Journal of the Korean Ceramic Society
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    • v.34 no.2
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    • pp.163-170
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    • 1997
  • The retarding effects of MgSiF6.6H2O on the hydration of portland cement were studied. The setting time, flow value and compressive strength of mortar were measured and the mechanism of retardation was also studied by ion concentration in solution, SEM, BET, and X-ray diffraction. The results are as follows ; 1. Setting time was delayed by the addition of MgSiF6.6H2O. 2. The flow value of mortar decreases depending upon the amount of MgSiF6.6H2O. 3. The compressive strength was almost same or some increase on 28 days hydration. 4. The main retardation mechanism of MgSiF6 on the hydration of portland cement may be explained by the following hypothesis. MgSiF6 depressing the Ca++ and K+ ion concentration of cement paste solution be-cause of the recrystalization of K2SiF6 and CaF2 phase. The new products of K2SiF6 and CaF2 deposit on the surface of unhydrated cement powder and harzard the mass transfer through these layer. The low con-centration of Ca++, K+ ion in solution was decreasing the hydration rate of portland cement.

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Microstructure and Mechanical Behavior of Al-Mg-Si/Al Hybrid Alloy by Duo-casting (듀오캐스트 Al-Mg-Si/Al 하이브리드 합금의 미세조직과 기계적 변형 특성)

  • Han, Ji-Min;Kim, Chong-Ho;Park, Jun-Pyo;Chang, Si Young
    • Journal of Korea Foundry Society
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    • v.32 no.6
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    • pp.269-275
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    • 2012
  • Al-Mg-Si/Al hybrid alloy was prepared by Duo-casting and the mechanical behavior was evaluated based on their microstructure and mechanical properties. The hybrid aluminum alloy included the Al-Mg-Si alloy with fine eutectic structure, pure Al with the columnar and equiaxed crystals, and the macro-interface existing between Al-Mg-Si alloy and pure Al. The growth of columnar grains in pure Al occurred from the macro-interface. The tensile strength, 0.2% proof stress and bending strength of the hybrid aluminum alloy were almost similar to those of pure Al, and the elongation was much higher than the Al-Mg-Si alloy. The fracture of the hybrid alloy took place in pure Al side, indicating that the macro-interface was well bonded and the mechanical behavior strongly depends on the limited deformation in pure Al side.

펄스 레이저 방식으로 증착된 $MgTiO_3$ 박막의 전기적 특성 분석

  • 안순홍;노용한;강신충;이재찬
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.71-71
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    • 2000
  • 본 연구에서는 차세대 마이크로파 유전체 소자로서의 응용을 목적으로 펄스 레이저 방식에 의하여 증착된 MgTiO3 박막의 전기적 특성을 종합적으로 연구 분석하였다. 이를 바탕으로 MgTiO3 박막의 유전손실 등과 같은 열화를 야기시키는 박막 내부 또는 박막과 기판간의 결함의 특성을 파악하여 열화 메카니즘을 분석하였다. MgTiO3는 마이크로파 영역에서의 우수한 유전특성과 같은 낮은 유전손실을 가지며, 온도 안정성 또한 우수하다. 현재까지 벌크 세라믹 MgTiO3 의 응용 광범위하게 연구되어 왔으나 박막의 제조공정 및 전기적 특성 분석은 미흡한 형편이다. 따라서 벌크 세라믹과는 특성이 상이한 박막의 전기적 특성분석 및 연구가 필요하다. 분석을 위한 소자의 기본 구조로서 Metal-Insulator-Semiconductor(MIS) 구조를 채택하였다. MgTiO3 박막을 증착하기 위한 기판으로는 n형 Si(100)기판과 p형 Si(100)기판을 사용하였고, Si 기판 위에 급속 열처리기 (RTP)를 이용하여 SiO2를 ~100 두께로 성장시킨 것과 성장시키지 않은 것으로 구분하여 제작하였다. MgTiO3 박막은 펄스 레이저 증착 방식(PLD)에 의하여 약 2500 두께로 증착되었으며, 200mTorr 압력의 산소 분위기 하에서 기판의 온도를 40$0^{\circ}C$~55$0^{\circ}C$까지 5$0^{\circ}C$간격으로 변화시키며 제작하였다. 상하부의 전극 금속으로는 Al을 이용하였으며, 열증발 증착기로 증착하였다. 증착된 MgTiO3 박막의 결정구조를 확인하기 위하여 XRD 분석을 수행하였으며, 박막의 전기적 특성을 분석하기 위해 Boonton7200 C-V 측정기와 HP4140P를 이용한 경우에는 C-V 곡선에 이력현상이 나타났으나, MgTiO3/SiO2를 이용한 경우에는 이력현상이 나타나지 않았고, 유전율은 감소하는 것으로 나타났다. I-V 측정 결과, 절연층으로 MgTiO3/SiO2를 이용한 경우에는 MgTiO3만을 절연층으로 사용한 경우에 비해 동일한 전계에서 낮은 누설전류 값을 가짐을 알 수 있었다. 또한 박막의 증착온도가 증가함에 따라서 C-V 곡선의 위치가 양의 방향으로 이동함을 확인하였다. 위의 현상은 기판의 종류에 관계없이 발생하는 것으로 보아 벌크 또는 계면에 존재하는 결함에 의한 것으로 추정된다. 현재 C-V 곡선의 이동 원인과 I-V 곡선의 누설전류 메카니즘을 분석 중에 있으며 그 결과를 학회에서 발표할 예정이다.

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The Physical Characteristics and Preparation of $Mg_2SiO_4(La.Ho)$ Thermoluminescent Phosphor ($Mg_2SiO_4(La.Ho)$열형광체의 제작과 물리적 특성)

  • Noh, Kyung-Suk;Song, Jae-Heung;Koo, Hyo-Geun;Lee, Deog-Kyu
    • Journal of radiological science and technology
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    • v.20 no.1
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    • pp.65-69
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    • 1997
  • [ $Mg_2SiO_4(La.Ho)$ ] thermoluminescent phosphor was made by putting the $MgCl_2.6H_2O$ and $SiO_2$ and by doping the rare earth element of $LaCl_3.7H_2O$ and $HoCl_3$. The heating rate is $10^{\circ}C/sec$ for the thermoluminescent phosphor. Two peaks are found in the measured $Mg_2SiO_4(La.Ho)$ Tl glow curve at $152^{\circ}C$ and $205^{\circ}C$ when the heating rate is $5^{\circ}C/sec$. The peak value at $205^{\circ}C$ is the most sensitive to X-ray among the glow peaks. The activation energy of the main peak has been estimated by the peak shape method. The estimated activation energies for Ho and La are $0.52{\sim}1.77\;eV$ respectively.

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