• Title/Summary/Keyword: $Mg_{2}Si$

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The Crystallization of $Li_2O-MgO-MgF_2-SiO_2$ Glass System by $B_2O_3$ addition (B$_2$O$_3$의 첨가에 따른 저온 소결기판용 $Li_2O-MgO-MgF_2-SiO_2$)

  • 박대현;강원호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.39-43
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    • 1997
  • Effects of B$_2$O$_3$ addition in the Li$_2$O-MgO-MgF$_2$-SiO$_2$g1ass system were investigated in order to make glass-ceramics for low temperature firing substrate. Base glass was made by melting at 145$0^{\circ}C$ . This glass was analyzed by THA and DTA to settle nucleation and crystallization temperature. After crystallization. crystal phase and microstructure were absorvated by XRD and SEM. Glass powders were made by water swelling method. Average particle size was 5.44${\mu}{\textrm}{m}$

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A Study on the Synthesis and Properties of Additives Coated BaTiO3 (첨가제가 Coating된 BaTiO3의 합성 및 특성에 관한 연구)

  • Park, Jae-Sung;Kim, Young-Tae;Hur, Kang-Heon;Han, Young-Ho
    • Journal of the Korean Ceramic Society
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    • v.46 no.2
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    • pp.189-199
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    • 2009
  • The Powder characteristics and sintering behavior of $SiO_2$ coated $BaTiO_3$ were studied. $BaTiO_3$ powders were synthesized by the liquid mix method developed by Pechini, and silica coating was prepared by alkoxide hydrolysis method with TEOS and ethanol. The particle size of the $BaTiO_3$ powders was 35 nm and the thickness of the $SiO_2$ coating layer was 5 nm. As the $SiO_2$ content increased, the $SiO_2$ layers improved the powder dispersion by increasing electrostatic repulsion between the $BaTiO_3$ particles. Effects of MgO coating on microstructure and dielectric properties of $BaTiO_3$ have been studied compared with mechanically MgO mixed $BaTiO_3$. MgO coated $BaTiO_3$ particles were prepared by a homogeneous precipitation method using $MgCl_2\cdot 6H_2O$ and urea. MgO coated $BaTiO_3$ exhibited homogeneous microstructure compared with mixed samples. XRD analysis revealed that Mg substitution for the Ti site in the MgO mixed sample was much greater than in the coated one. Electrical properties of MgO mixed and coated $BaTiO_3$ were affected by the diffusion behavior of Mg in $BaTiO_3$ lattice.

Fabrication and Mechanical Properties of $SiC_p/Al$ Composites by Pressureless Infiltration Technique (무가압침투법에 의한 $SiC_p/Al$ 복합재료의 제조 및 기계적 특성)

  • Jin, H.G.;Oh, M.S.;Kim, Y.S.
    • Journal of Power System Engineering
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    • v.5 no.4
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    • pp.74-81
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    • 2001
  • The infiltration behavior of molten Al-alloy, microstructures, hardness, and the interfacial reactions of $SiC_p/Al$ composites fabricated by the pressureless infiltration technique were investigated. It was made clear that both the weight fraction of SiC reinforcement and additive Mg content considerably influenced on the infiltration behavior of the molten Al-alloy matrix. Complete infiltration of molten Al-alloy achieved under the conditions that weight fraction of SiC content is more than 30wt%, and additive Mg content is more than 9wt%. Interfacial region of Al-alloy matrix and SiC reinforcement phase, $Mg_2Si$ was formed by the reaction between Mg and SiC. Another reaction product AlN was also formed by the reaction between Al-alloy matrix and gas atmosphere nitrogen.

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A study on the squeeze casting of Al-7.0Si-0.4Mg alloy for fuel system parts

  • Kim Soon-Ho;Kim Seong-Soo
    • International Journal of Precision Engineering and Manufacturing
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    • v.6 no.3
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    • pp.56-59
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    • 2005
  • Aluminum alloy casting is gaining increased acceptance in automotive and electronic industries and especially, squeeze casting is the most efficient method of mass manufacturing of such parts. In this study, the microstructures and mechanical properties of Al-7.0Si-0.4Mg(AC4C) alloy fabricated by squeeze casting process for development of fuel system parts (fuel rail) are investigated. The microstructure of squeeze cast specimen was composed of eutectic structure aluminum solid solution and $Mg_2Si$ precipitates. The tensile strength of as-solid solution treatment Al-7.0Si-0.4Mg alloy was 298.5MPa. It was found that Al-7.0Si-0.4Mg alloy had good corrosion resistance in electrochemical polarization test.

Hot-dipped Al-Mg-Si Coating Steel - Its Structure, Electrochemical and Mechanical Properties -

  • Tsuru, Tooru
    • Corrosion Science and Technology
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    • v.9 no.6
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    • pp.233-238
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    • 2010
  • Hot-dipped Al-Mg-Si coatings to alternate Zn and Zn alloy coatings for steel were examined on metallographic structure, corrosion resistance, sacrificial ability, formation and growth of inter-metallic compounds, and mechanical properties. Near the eutectic composition of quasi-binary system of Al-$Mg_2Si$, very fine eutectic structure of ${\alpha}$-Al and $Mg_2Si$ was obtained and it showed excellent corrosion resistivity and sacrificial ability for a steel in sodium chloride solutions. Formation and growth of Al-Fe inter-metallic compounds at the interface of substrate steel and coated layer was suppressed by addition of Si. The inter-metallic compounds layer was usually brittle, however, the coating layer did not peel off as long as the thickness of the inter-metallic compounds layer was small enough. During sacrificial protection of a steel, amount of hydrogen into the steel was more than ten times smaller than that of Zn coated steel, suggesting to prevent hydrogen embrittlement. Al-Mg-Si coating is expected to apply for several kinds of high strength steels.

The study on dielectric Properties of Li$_2$O-MgO-MgF$_2$-SiO$_2$system glass ceramics (Li$_2$O-MgO-MgF$_2$-SiO$_2$계 Glass-Ceramics 의 유전특성에 관한 연구)

  • 이승준;강원호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.11a
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    • pp.18-21
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    • 1995
  • In this study, crystallization, water swelling and dielectric properties of Li$_2$O-MgO-MgF$_2$-SiO$_2$System glass ceramics were investigated. Base glass melted at 1450$^{\circ}C$ and crystallized through heat treatment. The optimum heat treatment schedule was 460$^{\circ}C$ for nucleation and 640$^{\circ}C$, 1100$^{\circ}C$ for crystallization. The Principle crystalline phase was lithium fluorhectorite. Lithium fluorhectorite was the crystal phase which it was influenced water swelling. Samples progressed 2 minutes later they have rapid hydration at forced water swelling condition. Also value of dielectric constants have approximately 10 at 100kHz.

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Floating-Zone Growth of Single Crystal Olivine $[(Mg_{1-x}Fe}_{x})_2SiO_4]$ (Floating Zone법에 의한 올리빈 $[(Mg_{1-x}Fe}_{x})_2SiO_4]$단결정 성장)

  • 정광철;강승민;신재혁;한종원;최종건;오근호;박한수;문종수
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.3 no.1
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    • pp.85-92
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    • 1993
  • Large single crystals of olivine were grown by using image furnace(floating zone furnace)under controlled partial pressure of oxygen. The transparent crystals have maximum sizes 65mm in length by 7mm in diameter. When partial pressure of oxygen was decreased, the portion of secondary phases in crystals were increased so that it made crystals dark brown. The secondary phases were proved to be solid solution of Mg, Si, and Fe by electron microprobe analysis. Mg was major portion and the rest was minor.

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Growth Mode Study of Mg on the Si(111)$7 {\times}7$ Surface (Si(111)$7{\times}7$ 표면에서 Mg 성장양상 연구)

  • 안기석;여환욱;이경원;이순보;조용국;박종윤
    • Journal of the Korean Vacuum Society
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    • v.2 no.4
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    • pp.399-403
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    • 1993
  • Si(111)7 $\times$ 7 위에 Mg를 흡착시켜 표면구조의 변화를 RHEED(Reflection High Energy Electron diffraction) 와 XPS(X-ray PhotoelectronSpectroscopy)를 이용하여 연구하였다. RT ~20$0^{\circ}C$까지의 기판온도에서 증착량의 증가에 따라 표면구조는 (7$\times$7)에서 diffused (1$\times$1) 그리고 (2 3 3 $\times$2√3√3-R30$^{\circ}$) 구조로 변화하였다. 또한, 기판온도를 증가시킴에 따라 (1$\times$1), three domain(3$\times$1) 등의 구조를 볼 수 있었고, 특히 , $450^{\circ}C$의 기판온도에서는 single domain (3$\times$1) 구조를 최초로 관측하였다. 이렇게 형성된 각 구조에 대한 Mg KLL과 Si2p의 XPS peak intensity ratio를 증착량의 증가에 따라 측정하여 각기 다른 온도에서의 Mg 성장에 대한 메카니즘을 제시하였다.

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The Cathodoluminance Properties of $Y_2SiO_5$:Ce Blue Phosphor with Surface Coatings ($Y_2SiO_5$:Ce 청색 형광체의 표면 코팅에 따른 음극선 발광특성)

  • 음현중;김성우;이임렬
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.590-593
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    • 1999
  • $Y_2SiO_5$:Ce was considered as blue phosphor for field emission display because it had an excellent resistance against brightness saturation. But unfortunately It hadn't a sufficient brightness to be applied to FED. In this experiment It-$In_2O_3$, MgO and $SiO_2$ were coated onto $Y_2SiO_5$:Ce phosphor in order to improve the cathodoluminance(CL properties. The coating structures were identified to be the crystalline phases of $In_2O_3$ and MgO respectively. They had fine particle-like shape and were distributed on the surface of $Y_2SiO_5$:Ce phosphor. It was found that the CL efficiency of $Y_2SiO_5$:Ce phosphors were decreased after coatings with In20:j and MgO in voltage range from 500 V to 5 kV. But the brightness of $Y_2SiO_5$:Ce phosphor was increased after coating of 5 0 2 . And also the aging test showed that $In_2O_3$ coating improved the life time of $Y_2SiO_5$:Ce phosphor.

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Effects of CellCaSi and Inorganic Additives on Phosphorus Removal in Water (규산질다공체와 무기첨가물의 수중 인 제거 효과)

  • Park, Myung-Hwan;Han, Myung-Soo;Lee, Seog-June;Ahn, Chi-Yong;Yoon, Byung-Dae;Oh, Hee-Mock
    • Korean Journal of Ecology and Environment
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    • v.35 no.3 s.99
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    • pp.213-219
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    • 2002
  • The CellCaSi, a porous silicate material, was tested for the removal of phosphorus (P as phosphate) in water. The effect of the CellCaSi was investigated on the basis of both particle size (under 1,2, and 4 mm) and added amount (0, 1, 2.5, 5, and 10 g/1) of the CellCaSi. The removal efficiency of phosphorus was highest with a particle size of under 1 mm and also increased with an increasing amount of the CellCaSi. The pH change showed little effect on the phosphorus removal of the CellCaSi. The calcium ion was eluted from the CellCaSi into the water, while the aluminium and iron were not. The eluted calcium ion was combined with dissolved phosphorus and then precipitated. The highest removal efficiency of phosphorus was obtained by the combined addition of the CellCaSi, calcium chloride, and ferric chloride. That is, the phosphorus concentrations of 0.10 and 1.0 mg/1 decreased to 0.03 and 0.47 mg/l by the addition of the CellCaSi (1 g/l), calcium ion (30 mg/l), and ferric ion (1 mg/l) at day 8 after treatment. The water qualities at the end of the experiment were as follows: pH was 8.1 and conductivity was 318 ${\mu}$S/cm (a registered maximum conductivity of 500${\mu}$S/cm for raw and potable wafers).