• Title/Summary/Keyword: $MgCl_2$ Solution

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A Study on the Electrochemical Characteristics of Al-Si Casting Alloys in NaCl Solution (NaCl 수용액에서 Al-Si계 주조용 합금의 전기화학적 특성 연구)

  • Woo, Sang-Hyun;Son, Young-Jin;Lee, Byung-Woo
    • Journal of Power System Engineering
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    • v.18 no.6
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    • pp.29-33
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    • 2014
  • The electrochemical characteristics of Al-Si casting alloys (Al-10%Si, Al-9%Si, Al-7%Si) in 3.5% NaCl solution at room temperature was studied using potentiodynamic techniques. The electrochemical values of corrosion potential($E_c$), corrosion current density($I_c$) and corrosion rate(mpy) were examined. The Al-Si alloys had several compounds such as $Mg_2Si$, ${\pi}$-$Al_8Si_6Mg_2Fe$ and $Al_2CuMg$ which could affect corrosion resistance significantly. The potentiodynamic polarization curve exhibited typical active behavior in anodic polarization curve. The major corrosion mechansim for the Al-Si alloys were pitting and grain boundary corrosion. As increasing Si and Cu contents, their corrosion resistance was decreased.

Transport and Distribution of Calcium Salts in Tofu Manufacturing Process -Part II. Mass Balances of Calcium Salt during Tofu Manufacturing Processes by Conductometric Method- (두부 제조(製造) 공정중(工程中) Calcium염(鹽)의 행동(行動)과 분포(分布) -제2보(第二報). 전기 전도도법을 이용한 두부제조 공정중 Ca염의 수지-)

  • Lee, Chon-Ki;Yim, Sang-Bin;Chun, Jae-Kun
    • Applied Biological Chemistry
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    • v.28 no.2
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    • pp.56-61
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    • 1985
  • The mass balances of calcium salts during the manufacturing processes of Tofu were established by conductometric method and chemical analysis method. During the manufacturing processes of soy milk and Tofu, 66% of solid and 63% of calcium was transfered from soy-bean to the soy milk, and 47.8% of total solid from soybean was transfered to the Tofu, respectively. When the $CaCl_2$ was used as coagulant, calcium contents in Tofu $(Y_{Tofu},\;mg{\cdot}Ca/g{\cdot}Tofu,\;wet\;basis)$ and drained solution $(Y_{drained\;soln},\;mg{\cdot}Ca/ml{\cdot}drained\;soln.)$ were linearly increased with the amounts of $CaCl_2(C,g{\cdot}CaCl_2/ml{\cdot}soy\;milk)$ added in soy milk, and correlative equations between them were obtained as $Y_{Tofu}=0.3369\;C+1.2689$ for Tofu$(moisture\;content:\;81.5{\pm}0.5%)$ with r=0.9898, and $Y_{drained\;soln}= 0.2899C+0.0399$ for drained solution with r= 0.9991. It was proved that conductometric method was reasonably applicable to the measurement of calcium contents of the products from every processes of Tofu manufacture except soy-bean. However the conductometric method was not recomendable in the case of $CaSO_4$ as coagulant due to its low solubility ana uneven distribution in soy milk and Tofu tissue.

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Stress Corrosion Cracking Sensitivity of High-Strength 2xxx Series Aluminum Alloys in 3.5 % NaCl Solution (항공용 고강도 2xxx계 알루미늄 합금의 3.5 % 염수 환경에서의 응력부식균열 민감도)

  • Choi, Heesoo;Lee, Daeun;Ahn, Soojin;Lee, Cheoljoo;Kim, Sangshik
    • Korean Journal of Materials Research
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    • v.28 no.12
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    • pp.738-747
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    • 2018
  • For the aerospace structural application of high-strength 2xxx series aluminum alloys, stress corrosion cracking(SCC) behavior in aggressive environments needs to be well understood. In this study, the SCC sensitivities of 2024-T62, 2124-T851 and 2050-T84 alloys in a 3.5 % NaCl solution are measured using a constant load testing method without polarization and a slow strain rate test(SSRT) method at a strain rate of 10-6 /sec under a cathodic applied potential. When the specimens are exposed to a 3.5 % NaCl solution under a constant load for 10 days, the decrease in tensile ductility is negligible for 2124-T851 and 2050-T84 specimens, proving that T8 heat treatment is beneficial in improving the SCC resistance of 2xxx series aluminum alloys. The specimens are also susceptible to SCC in a hydrogen-generating environment at a slow strain rate of $10^{-6}/sec$ in a 3.5 % NaCl solution under a cathodic applied potential. Regardless of the test method, low impurity 2124-T851 and high Cu/Mg ratio 2050-T84 alloys are found to have relatively lower SCC sensitivity than 2024-T62. The SCC behavior of 2xxx series aluminum alloys in the 3.5 % NaCl solution is discussed based on fractographic and micrographic observations.

Effect of Pretreatments on Optimal Harvesting Stage and Harvesting Stages of Cut Roses Bred in Korea (국내 육성 절화 장미의 수확 적기와 수확 단계에 따른 전처리 효과)

  • Choi, Mok Pil;Lee, Poong Ok;Kim, Won Hee
    • Horticultural Science & Technology
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    • v.31 no.5
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    • pp.573-579
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    • 2013
  • This study was conducted to investigate optimal harvesting stage and the effects on cut roses of Korean cultivar harvested at different stages. Cut roses are harvested at three different flowering stages. The optimal harvesting stage of cut roses was different depending on varieties. The vase life of standard type 'Pink Song' and spray type 'Peace One' was extended when they were harvested in one and three stages, respectively. The vase life was generally increased when the cut roses were pretreated with a solution containing 2% sucrose + $200mg{\cdot}L^{-1}$ aluminum sulfate + $200mg{\cdot}L^{-1}$ $Mg(NO_3)_2$ + $50mg{\cdot}L^{-1}$ $CaCl_2$ as compared to the control regardless of the harvesting stage. And this pretreatment solution improved the flower quality of cut roses bred in Korea. But the effects of pretreatment were varied depending on the harvesting stage.

Textural Characteristics and Microstructure of Soybean Curds Prepared with Different Coagulants (응고제를 달리하여 제조한 두부의 질감과 구조 특성)

  • Lee, Hun-Joo;Hwang, In-Kyeong
    • Korean journal of food and cookery science
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    • v.10 no.3
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    • pp.284-290
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    • 1994
  • To prepare soybean curds, the concentration of $CaCl_2,\;MgCl_2,\;CaSO_4$ and glucono-%{\delta}$-lactone fresh solution as coagulants were determined by transmittance of whey using spectrophotometer. The concentrations of four coagulants at which the transmittance had the highest value were chosen. Moisture content, yield and protein recovery of soybean curds prepared with four coagulants were investigated. The textural properties were examined by Instron Universal Testing Machine, and sensory evaluation was carried out. The microstructure of soybean curds was examined by SEM. Soybean curds obtained with $CaCl_2\;and\;MgCl_2$ were hard and coarse, and had roasted nutty taste, whereas those with $CaSO_4$ and GDL revealed very smooth, soft and uniform. Soybean curd prepared with GDL had the lowest acceptability because of sour taste. The texture and acceptability of soybean curds were influenced by the type of coagulant.

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Optimization of RNA Purification Method from Ecklonia cava Kjellman (Laminariales, Phaeophyceae)

  • Ahn, Jong-Sung;Woo, Seon-Ock;Kim, Jeong-Ha;Oh, Yoon-Sik;Oak, Jung-Hyun;Yum, Seung-Shic
    • ALGAE
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    • v.19 no.2
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    • pp.123-127
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    • 2004
  • A more rapid and efficient method to extract RNA from Ecklonia cava Kjellman (Laminariales, Phaeophyceae) was introduced in this study. Each step of the procedure was evaluated and the optimal concentration of each chemical in the lysis solution was determined. Tissue pulverization with PVPP and β-mercaptoethanol in the lysis solution were not essential for RNA extraction of this species. The highest yield and purity of E. cava RNA were obtained by the lysis solution containing 1% CTAB, 1 M NaCl, 0.7% PVP, 10mM EDTA and 100mM Tris-Cl (pH 9.0). Approximately 8μg of RNA was obtained from 200 mg of ground tissue. The ratios of the absorbance at 260 nm and 280 nm were from 1.6 to 1.8 and those of at 230 nm and 260 nm were from 1.8 to 2.0. The extracted RNAs obtained in this study turned out to have a sufficient quality for cDNA synthesis.

The effect of welding methods on the stress corrosion behavior of the welded austenitic stainless steel (오스테나이트 스테인리스강 용접부의 응력부식 거동에 미치는 용접 방법의 영향)

  • 백신영
    • Journal of Advanced Marine Engineering and Technology
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    • v.19 no.4
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    • pp.42-50
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    • 1995
  • To study the effect of welding methods on the Stress Corrosion Cracking (SCC) behavior of welded AISI type 316L and 304 austenitic stainless steel, the Slow Strain Rate Technique(SSRT) has been adopted in the boiling 45 wt% $MgCl_2$ solution. The results are as follows. 1) Welded sections are more susceptible than base metal in SCC, and the rank of SCC, and the rasistance in welding method is TIG, MIG, $CO_2$ and ARC. 2) The Ultimate tensile strength(UTS) and the strain of both base metal and welded joint are reduced as decreasing extension rate. 3) The SCC resistance of 316L base metal and welded sections are superior than that of 304. 4) The tendency of pitting and the SCC suseptibility are agreed well, and the SCC site is welded deposit section in 316L whereas HAZ in 304.

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Effects of Chitosan on the Mouse Hepatotoxicity Toxicated by Mercury (수은으로 중독된 흰쥐의 간독성에 대한 키토산의 효과)

  • Roh, Young-Bok;Yoon, Jung-Sik;Chung, Kyung-Ah;Chung, Min-Ju;Kim, Young-Ho
    • Applied Microscopy
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    • v.31 no.2
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    • pp.175-184
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    • 2001
  • This study aims demonstrate the effect of chitosan, one of the natural chelator, on the ultrastructural changes in the mouse liver caused by $HgCl_2$. The experimental group was divided in two groups; group A and group B. The group A administrated $HgCl_2$ (5.0 mg/kg) to the oral. The group B treated with $HgCl_2$ (5.0 mg/kg) and chitosan (3%) solution, 2 times/day). Each group was observed 24, 48, 72 and 96 hours after treated $HgCl_2$ and chitosan. Histological changes of the livers were investigated by electron microscope. 1. Croup A Nuclear membrane was shrinked. The inner and outer membrane of the mitochondria were dilated. Destruction of lamellae of rough endoplasmic reticulum showed. Smooth endoplasmic reticulum showed over cytoplasm. 2. Group B Nuclear membrane was more rounded, The cristae of the mitochondria were almost normal shape and electron-density showed compacted. Dilation of inner cavity of rough endoplasmic reticulum showed at the pre-time but formed typical lamellae at the 48Hrs. Smooth endoplasmic reticulum showed over cytoplasm. Therefore, we concluded that chitosan has significantly protective effects in liver to harmful $HgCl_2$.

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A study on the mechanism of stress corrosion cracking of stainless steel (스테인레스 강판의 응력부식균열 전파기구에 관한 연구)

  • 임우조;김영식
    • Journal of Advanced Marine Engineering and Technology
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    • v.9 no.2
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    • pp.153-158
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    • 1985
  • The dependence of the corrosion potential on the stress corrosion cracking of 304 austenitic stainless steel was inspected by using the specimen of constant displacement type under the environment of 42% $MgCl_2$ boiled solution. The relationship of the corrosion potential to the intermittent propagation behaviour in stress corrosion cracking was cleared. As the results, a possible model of stress corrosion cracking of 304 austenitic stainless steel in $MgCl_2$ boiled solution was presented on the basis of the Film Rupture Model. This model is specified by the following process. Rupturing of passive film at notch tip .rarw. Dissolution of metal ion and formation of tunnel .rarw. Initiation of microcrack .rarw. Propagation of main crack .rarw. Recreation of passive film at new crack surface.

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Galvanic Corrosion of AZ31 Mg Alloy Contacting with Copper

  • Phuong, Nguyen Van;Moon, Sungmo
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.151.1-151.1
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    • 2017
  • This work studied the corrosion behavior of AZ31 Mg alloy galvanically coupled with Cu during immersion in 0.1 and 0.5 M NaCl solutions by in-situ observation and galvanic corrosion current measurement using a zero resistance ammeter. The corrosion behavior of AZ31 Mg alloy was also studied by salt spray test. The average galvanic corrosion density during 2 h immersion in 0.1 NaCl solution was found to decrease as an exponential function with increasing the surface area ratios between AZ31:Cu or with increasing the distance between AZ31 and Cu. The corrosion of electrodeposited Cu on AZ31 Mg alloy was concentrated at the area next to Cu (about 5 mm for immersion test and 2 mm for salt spray test) and pitting corrosion was accelerated at the area beyond the severely corroded area by the galvanic coupling effect.

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