• 한국산학기술학회논문지
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• 제3권3호
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• pp.183-188
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• 2002

Antibacterial glass ceramics composed of $5Li_2O{\cdot}36CaO{\cdot}20TiO_2{\cdot}27P_2O_5$ were Prepared. After ion exchange in the $AgNO_3$solution, crystallization phases were $AgTi_2(PO_4)_3$, $LiTi_2(PO_4)_3$ and $Ca_3(PO_4)_2$. In case of ion exchange, the crystallization phases started to be transformed from $LiTi_2(PO_4)_3$ to $AgTi_2(PO_4)_3$in 0.5 mole $AgNO_3$ solution and the transformation was almost completed in 1.0 mole. ion exchange rate of glass-ceramics powder, considering ion exchange time, was more fast than that of bulk. The bacteriostatic effect of the glass-ceramics on Staphyloroccus aureus and Salmonella typhi bacteria was more excellent than that of glass when the crystallization phase was transformed from LTP to AgTP.

• 한국전기화학회:학술대회논문집
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• 한국전기화학회 2001년도 춘계총회 및 학술발표회
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• pp.40-40
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• 2001

• 대한전기학회:학술대회논문집
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• 대한전기학회 2005년도 제36회 하계학술대회 논문집 C
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• pp.1989-1991
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• 2005

Lithium titanium oxide as anode material for energy storage prepared by novel synthesis method. $Li_4Ti_5O_{12}$ based spinel-framework structures are of great interest material for lithium-ion batteries. We describe here $Li_4Ti_5O_{12}$ a zero-strain insertion material was prepared by novel sol-gel method and by high energy ball milling (HEBM) of precursor to from nanocrystalline phases. According to the X-ray diffraction and scanning electron microscopy analysis, uniformly distributed $Li_4Ti_5O_{12}$ particles with grain sizes of 100nm were synthesized. Lithium cells, consisting of $Li_4Ti_5O_{12}$ anode and lithium cathode showed the 173 mAh/g in the range of $1.0{\sim}3.0V$. Furthermore, the crystalline structure of $Li_4Ti_5O_{12}$ didn't transfer during the lithium intercalation and deintercalation process.

• 한국전기전자재료학회논문지
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• 제14권3호
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• pp.190-196
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• 2001

The microwave dielectric properties and a sintering behavior of MgTiO$_3$-CaTiO$_3$ ceramics doped with Li were investigated. The main composition was fixed as 0.94MMgTiO$_3$-0.06CaTiO$_3$ and Li$_2$CO$_3$was added excessively in the range of 0~10 mol% (with reference to Li atoms) and the specimens were sintered at 1200~140$0^{\circ}C$ for 4 hours. When the amount of Li was small the quality factor and dielectric constant were reduced, while those tow properties increased if the Li amount was above 1 mol%. But if Li was overly added those dielectric properties decreased again. Li, if added in the composition range of 1.0~3.0 mol%, can increase the quality factor of MgTiO$_3$-CaTiO$_3$ ceramics. The optimum amount of Li was 1.5mol% and sinterign condition was 1275$^{\circ}C$/4hr, at which we cudl obtain following results ; dielectric constant ($\varepsilon$$_{r}$) of f20.0, quality factor(Qxf$_{0}$) of 78,000 GHz and temperature coefficient of resonant frequency($\tau$$_{f}$) of -1.6 ppm/$^{\circ}C$.>.>.>.

• 청정기술
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• 제20권4호
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• pp.433-438
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• 2014

전기자동차와 하이브리드 전기자동차에 요구되는 높은 충 방전 속도, 안전성, 대형화에 적합한 충 방전 전지의 개발은 많은 관심을 받고 있다. 스피넬 구조의 $Li_4Ti_5O_{12}$는 리튬이온이차전지의 음극활물질로 충 방전 시 부피변화가 거의 없기 때문에 수명특성이 뛰어나고, 전해액이 분해되는 전위보다 높은 작동 전압을 갖기 때문에 안정한 장점이 있다. 본 실험에서는 $Li_4Ti_5O_{12}$의 단점인 전기전도성을 향상시키고자 소량의 Ru를 첨가하여 $Li_4Ti_5O_{12}$를 고상법으로 제조하여 테스트하였다. TGA-DTA, XRD, SEM, 충 방전 테스트를 통해 분석을 실시하였다. Ru를 첨가하였을 때 용량은 약간 감소하였지만, 분극현상이 감소하는 것을 확인하였다. 그리고 Ru를 3%와 4% 첨가하였을 때 높은 전류밀도인 10 C-rate 충 방전에서 용량감소율이 줄었다.

• 한국전기전자재료학회논문지
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• 제19권6호
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• pp.524-530
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• 2006

$xCa(Li_{1/4}Nb_{3/4})O_{3}-(1-x)CaTiO_{3}$ ceramics were sintered under the presence of zinc-borosilicate(ZBS) glass and resultant microwave dielectric properties were investigated with a view to applying the composition to low-temperature co-fired ceramic(LTCC) technology. The addition of $5{\sim}15wt%$ ZBS glass ensured successful sintering below $900\;^{\circ}C$. In general, increased addition of ZBS glass increased sinterability but it decreased the quality factor($Q{\times}f_{0}$) significantly due to the formation of an excessive liquid and second phases. As for the addition of $CaTiO_3$, the dielectric constant(${\epsilon}_r$) and temperature coefficient of resonant frequency(${\tau}_f$) increased, while the quality factor($Q{\times}f_{0}$) did not show an apparent change. The sintered $0.9Ca(Li_{1/4}Nb_{3/4})O_{3}-0.1CaTiO_{3}$ specimen at $900\;^{\circ}C$ with 10 wt% ZBS glass demonstrated 39.6 in dielectric constant(${\epsilon}_r$), 4,400 in quality factor$(Q{\times}f_{0}),\;and\;-11ppm/^{\circ}C$ in temperature coefficient of resonant frequency(${\tau}_f$).

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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• pp.44-45
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• 2006

초고용량 캐패시터(Supercapacitor)는 이차전지와 더불어 차세대 전지로 분류되는 신형에너지 장치로서 충 방전 속도가 다르고 순간 전력공급이 가능하며 충 방전 수명이 반영구적으로 길고 고출력을 내기 때문에 이차전지가 갖지 못하는 영역에서 동력에너지원으로 사용된다. 본 연구에서는 초고용랑 캐패시터의 전극소재인 탄소계 재료를 대신하여 비탄소계 전극소재인 $Li_4Ti_5O_{12}$의 고상법 제조를 위한 Li/Ti의 최적 조성과 혼합 방법으로 Li-Ti 계에 $Fe_2O_3$, NiO, $Nb_2O_5$, $Sb_2O_3$ 그리고 ZnO와 같은 금속산화물로 치환시켜 합성된 Li -Ti계 금속산화물의 특성 및 충 방전 효과에 미치는 영향을 관찰하고자 하였다.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2006년도 춘계학술발표대회 및 제10회 신소재 심포지엄 논문개요집
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• pp.33.2-33.2
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• 2006

• Bulletin of the Korean Chemical Society
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• 제31권2호
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• pp.360-364
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• 2010

$Li_4Ti_5O_{12}$ thin film with inverse hemispheric structure was fabricated on a Pt/Ti/$SiO_2$/Si substrate by the sol-gel and dip coating method for use as an anode for 3-dimensional (3D) thin-film batteries. Polystyrene (PS) beads of 400 nm diameter were used to prepare the template for the inverse hemispheric structure. A coating solution prepared using precursor sources was dropped on the template-deposited substrates, which were then calcinated at $400^{\circ}C$. The template was removed by calcination, and the inverse hemispheric structure was successfully formed by an annealing process. The cyclic performance during high-rate charge/discharge processes of the $Li_4Ti_5O_{12}$ film with inverse hemispheric structure was superior to that of the flat $Li_4Ti_5O_{12}$ film.

• 한국재료학회지
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• 제9권10호
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• pp.1041-1046
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• 1999

(Zr(sub)0.8Sn(sub)0.2)$TiO_4$세라믹스와 소결조제로서 ($B_2$$O_3$.Li$_2$O)의 첨가에 따른 마이크로파 유전특성 및 미세구조에 미치는 영향에 대하여 연구하였다. 1.0 mol.% $Sb_2$O(sub)5를 첨가하고 130$0^{\circ}C$에서 5시간 소결한 (Zr(sub)0.8Sn(sub)0.2)$TiO_4$세라믹스의 경우 ($B_2$$O_3$.Li$_2$O)첨가량 증가에 따라 치밀화 및 결정립 성장에 의해 유전상수와 Q.f값은 증가하여 첨가량이 0.35wt.%에서 최대값인 38과 59,000을 각각 나타내었으며, 0.50wt.% 이상 첨가한 경우에서는 제 2상의 생성으로 인하여 감소하였다. 1.0 mol% Sb$_2$O(sub)5와 0.35wt.% ($B_2$$O_3$.$Li_2$O)를 첨가한 (Zr(sub)0.8Sn(sub)0.2)TiO$_4$세라믹스를 125$0^{\circ}C$와 135$0^{\circ}C$에서 5시간 소결한 경우에는 각각 미반응 TiO$_2$의 존재와 과대입자성장에 의한 결정립내기공의 생성으로 인하여 마이크로파 유전특성은 저하되었다.