• Proceedings of the Korean Vacuum Society Conference
• /
• 2007.02a
• /
• pp.38-38
• /
• 2007

• The Magazine of the IEIE
• /
• v.34 no.12
• /
• pp.30-37
• /
• 2007

• Journal of the Korean Electrochemical Society
• /
• v.11 no.3
• /
• pp.197-210
• /
• 2008

The cathode materials for lithium ion battery have been developed in accordance with the battery performance. $LiCoO_2$ initially adapted at lithium ion battery is going to be useful even at the charging voltage of 4.3 V by surface treatment or doping which drastically improved the performance of $LiCoO_2$. On the other hand, the complicate and multiple functions of recent electronic equipments required higher operational voltage and higher capacity than ever, which is going to be driving force for developing new cathode materials. Some of them are $LiNi_{1-x}{M_xO_2}$, $Li[Ni_{x}Mn_{y}Co_{z}]O_{2}$, $Li[{Ni}_{1/2}{Mn}_{1/2}]O_{2}$. Other new type of cathode materials having high safety is also developed to apply for HEV (hybrid electrical vehicle) and power tool applications. ${LiMn}_{2}{O}_{4}$ and $LiFePO_4$ are famous for highly stable material, which are expected to give contribution to make safer battery. In near future, the various materials having both capacity and safety will be developed by new technology, such as solid solution composite.

• Proceedings of the KIPE Conference
• /
• 2011.11a
• /
• pp.301-302
• /
• 2011

본 논문에서는 리튬 폴리머 배터리($LiFePO_4/C$)의 개방전압(OCV;open-circuit voltage) 히스테리시스 특성을 이용한 확장 칼만 필터(EKF;extended Kalman filter) 기반 state-of-charge(SOC) 추정방법을 소개한다. 배터리 등가회로의 중요 요소인 OCV 모델링을 위해 충전 및 방전 각각의 OCV 히스테리시스 특성을 고려하였고 더불어 OCV-SOC 관계의 SOC 간격을 10%에서 5%로 조정하여 EKF 기반 SOC 추정알고리즘의 성능이 향상되었다. 축소된 하이브리드 자동차용 전류프로파일을 적용했을 때 SOC 추정이 잘 이루어지지 않는 영역은 EKF의 측정방정식에 노이즈 모델 및 데이터 리젝션(data rejection)을 구축하였다. 제안된 방법을 이용하여 SOC 추정결과 전류적산법 대비 5%이내의 SOC 추정에러를 만족하였다.

• Proceedings of the KIPE Conference
• /
• 2017.07a
• /
• pp.126-127
• /
• 2017

An accurate State Of Charge (SOC) estimation of battery is the most important technique for Electric Vehicles (EVs) and Energy Storage Systems (ESSs). In this paper a new integrated Unscented Kalman Filter-Particle Filter (UKF-PF) is employed to estimate the SOC of a $LiFePO_4$ battery cell and a significant improvement is obtained as compared to the other methods. The parameters of the battery is modeled by the second order Auto Regressive eXogenous (ARX) model and estimated by using Recursive Least Square (RLS) method to calculate value of each element in the model. The proposed algorithm is established by combining a parameter identification technique using RLS method with ARX model and an SOC estimation technique using UKF-PF.

• Proceedings of the Korean Magnestics Society Conference
• /
• 2016.11a
• /
• pp.64-65
• /
• 2016

• Proceedings of the Korean Magnestics Society Conference
• /
• 2016.05a
• /
• pp.93-93
• /
• 2016

• Proceedings of the Korean Magnestics Society Conference
• /
• 2016.05a
• /
• pp.94-94
• /
• 2016

• Journal of Electrochemical Science and Technology
• /
• v.2 no.1
• /
• pp.14-19
• /
• 2011

Quasi-equilibrium profiles are analyzed through galvanostatic intermittent titration technique (GITT) and potentiostatic intermittent titration technique (PITT) to study the charge/discharge mechanism in multicomponent olivine structure ($LiMn_{1/3}Fe_{1/3}Co_{1/3}PO_4$). From GITT data, the degree of polarization is evaluated for the three regions corresponding to the redox couples of $Mn^{2+}/Mn^{3+}$, $Fe^{2+}/Fe^{3+}$ and $Co^{2+}/Co^{3+}$. From PITT data, the current vs. time responses are examined in each titration step to find out the mode of lithium de-intercalation/intercalation process. Furthermore, lithium diffusivities at specific compositions (x in $Li_xMn_{1/3}Fe_{1/3}Co_{1/3}PO_4$) are also calculated. Finally, total capacity ($Q^{total}$) and diffusional capacity ($Q^{diff}$) are obtained for some selected voltage steps. The entire study consistently confirms that the charge/discharge mechanism of multicomponent olivine cathode is associated with a one-phase reaction rather than a biphasic reaction.

• Bulletin of the Korean Chemical Society
• /
• v.32 no.12
• /
• pp.4205-4209
• /
• 2011

The $Li_2Mn_{0.5}Fe_{0.5}SiO_4$ silicate was prepared by blending of $Li_2MnSiO_4$ and $Li_2FeSiO_4$ precursors with same molar ratio. The one of the silicates of $Li_2FeSiO_4$ is known as high capacitive up to ~330 mAh/g due to 2 mole electron exchange, and the other of $Li_2FeSiO_4$ has identical structure with $Li_2MnSiO_4$ and shows stable cycle with less capacity of ~170 mAh/g. The major drawback of silicate family is low electronic conductivity (3 orders of magnitude lower than $LiFePO_4$). To overcome this disadvantage, carbon composite of the silicate compound was prepared by sucrose mixing with silicate precursors and heat-treated in reducing atmosphere. The crystal structure and physical morphology of $Li_2Mn_{0.5}Fe_{0.5}SiO_4$ was investigated by X-ray diffraction, scanning electron microscopy, and high resolution transmission electron microscopy. The $Li_2Mn_{0.5}Fe_{0.5}SiO_4$/C nanocomposite has a maximum discharge capacity of 200 mAh/g, and 63% of its discharge capacity is retained after the tenth cycles. We have realized that more than 1 mole of electrons are exchanged in $Li_2Mn_{0.5}Fe_{0.5}SiO_4$. We have observed that $Li_2Mn_{0.5}Fe_{0.5}SiO_4$ is unstable structure upon first delithiation with structural collapse. High temperature cell performance result shows high capacity of discharge capacity (244 mAh/g) but it had poor capacity retention (50%) due to the accelerated structural degradation and related reaction.