• Bulletin of the Korean Chemical Society
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• v.35 no.9
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• pp.2726-2732
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• 2014

The promoting effect of rhodium on the structure and activity of the supported Cu-Co based catalysts for CO hydrogenation was investigated in detail. The samples were characterized by DRIFTS, $N_2$-adsorption, XRD, $H_2$-TPR, $H_2$-TPD and XPS. The results indicated that the introduction of rhodium to Cu-Co catalysts resulted in modification of metal dispersion, reducibility and crystal structure. DRIFTS results of CO hydrogenation at reaction condition (P=2 MPa, $T=260^{\circ}C$) indicated the addition of 1 wt % rhodium improved hydrogenation ability of Cu-Co catalysts. The ethanol selectivity and CO conversion were both improved by 1 wt % Rh promoted Cu-Co based catalysts. The alcohol distribution over un-promoted and rhodium promoted Cu-Co based catalysts obeys A-S-F rule and higher chain growth probability was got on rhodium promoted catalyst.

• Journal of Advanced Marine Engineering and Technology
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• v.34 no.1
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• pp.53-61
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• 2010

In the present study, a laminar natural convection flow of $H_2O$-Cu nanofluid in a two dimensional enclosure has been investigated using a thermal lattice Boltzmann approach with the Bhatnagar-Gross-Krook (BGK) model. The effect of suspended nanoparticles on the fluid flow and heat transfer process have been studied for different controlling parameters such as particle volume fraction ($\Phi$), Rayleigh number (Ra). For this investigation the Rayleigh number changes from 104 to 106 and volume fraction varied from 0 to 10% with three different particle diameters (dp), say 10 nm, 20 nm and 40 nm. It is shown that increasing the Rayleigh number (Ra) and the volume fraction of nanofluid causes an increase of the effective heat transfer rate in terms of average Nusselt number (Nu) as well as the thermal conductivity of nanofluid. On the other hand, increasing the particle diameter causes the decrease of the heat transfer rate and thermal conductivity. The result of the analysis are compared with experimental and numerical data both for pure and nanofluids and it is seen a relatively good agreement.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.06a
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• pp.290-291
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• 2007

In this study, in order to develop the low temperature sintering multilayer piezoelectric actuator, PZW-PMN-PZT system ceramics were manufactured according to variation of sintering aids. At the sintering temperature of $900^{\circ}C$, $0.3wt%Li_2CO_3$, $0.2wt%Bi_2O_3$ and 0.2wt%CuO added specimen showed a maximum value of kp = 0.552, $d_{33}\;=\;344pC/N$ and Qm = 1320, respectively.

• Journal of Convergence for Information Technology
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• v.8 no.2
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• pp.83-90
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• 2018

We have studied the optimal conditions for design and development on the communication device for a bilateral, and it's electrodes for transmitting electric signal are constructed on the $36^{\circ}$ rotated $LiTaO_3$ substrate by evaporating Al-Cu(W 30%) alloy. At first, we manufactured three kind of samples using this method, and selected two samples as similar with frequency, ripple and passband characteristics, and then we connect two samples by series in order to make bilateral devices. As results, we obtained that the electrode structure has better characteristics then the others, when it's width of reflector and electrode are $1{\lambda}/4$, $1{\lambda}/12$ respectively, and it's frequency is approximately 190.3MHz. Near future, I hope to help the manufacture for communication devices for the multi-channel and the duplex filter.

• Journal of Radiation Protection and Research
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• v.43 no.4
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• pp.160-169
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• 2018

Background: This study aims to develop an integrated optical system that can simultaneously or selectively measure the signals obtained from radioluminescence (RL), thermoluminescence (TL), and optically stimulated luminescence (OSL), which are luminescence phenomena of materials stimulated by radioactivity, heat, and light, respectively. The luminescence mechanism of various materials could be investigated using the glow curves of the luminescence materials. Materials and Methods: RL/TL/OSL integrated measuring system was equipped with a X-ray tube (50 kV, $200{\mu}A$) as an ionizing radiation source to irradiate the sample. The sample substrate was used as a heating source and was also designed to optically stimulate the sample material using various light sources, such as high luminous blue light emitting diode (LED) or laser. The system measured the luminescence intensity versus the amount of irradiation/stimulation on the sample for the purpose of measuring RL, TL and OSL sequentially or by selectively combining them. Optical filters were combined to minimize the interference of the stimulation light in the OSL signal. A long-pass filter (420 nm) was used for 470 nm LED, an ultraviolet-pass filter (260-390 nm) was used for detecting the luminescence of the sample by PM tube. Results and Discussion: The reliability of the system was evaluated using the RL/OSL characteristics of $Al_2O_3:C$ and the RL/TL characteristics of LiF:Mg,Cu,Si, which were used as dosimetry materials. The RL/OSL characteristics of $Al_2O_3:C$ showed relatively linear dose-response characteristics. The glow curve of LiF:Mg,Cu,Si also showed typical RL/OSL characteristics. Conclusion: The reliability of the proposed system was verified by sequentially measuring the RL characteristics of radiation as well as the TL and OSL characteristics by concurrent thermal and optical stimulations. In this study, we developed an integrated measurement system that measures the glow curves of RL/TL/OSL using universal USB-DAQs and the control program.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.306-306
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• 2010

21 세기는 언제, 어디에서, 누구나가 정보를 자유롭게 염가에 이용할 수 있는 유비쿼터스 정보사회가 될 것으로 예상하고 있다. 이러한 유비쿼터스 사회가 실현되기 위해서는 필연적으로 대두되고 있는 과제가 에너지 공급원의 문제이다. 휴대용 전자제품이나 소형 에너지 공급원으로 지금까지 주로 전지가 사용되어 왔지만 이것들은 교환 및 충전이 불가피하다. 이러한 불편함을 개선하기위해 교환과 충전이 불필요하거나 아주 장시간동안 공급해주는 형태의 에너지 공급원의 필요성이 대두되고 있다. 이러한 에너지 공급원으로 최근에 많은 연구가 되고 있는 것이 주위의 환경으로부터 버려지는 에너지를 수확(harvesting)하여 전력으로 변환하는 에너지 하베스팅 (energy harvesting)기술이 연구 개발되고 있다. 에너지 하베스팅 응용을 위해서 사용되어지는 압전 세라믹스는 전압출력계수 ($g_{33}$)가 커야하는데 이것은 압전상수 ($d_{33}$)와 유전상수 (${\varepsilon}_{\tau}$)의 값에 영향을 받는 것으로 알려져있다. 그 중에서 우수한 전기적 특성 때문에 PZT를 기반으로 하는 압전 세라믹스가 사용되어져왔다. 그러나 Pb의 높은 유독성과 Pb를 포함하는 제품들의 처분문제들로 인해 제조에 관한 많은 문제점들을 지니고있다. 그리하여, Pb를 포함하지 않는 Pb-free계에 관한 연구가 전세계적으로 활발히 진행되고 있다. 다양한 Pb-free계 후보자들 가운데 $K_{0.5}Na_{0.5}NbO_3$ (KNN)는 높은 큐리온도와 좋은 강유전 특성 및 압전특성 때문에 PZT를 대체할 가장 장래성있는 대안들 중의 하나로 고려되고 있다. 그러나 고온에서 알칼라인 원소들의 높은 휘발성 때문에 보통의 소결공정으로는 소결이 잘되고 치밀한 세라믹스를 얻기가 어렵다. 많은 연구에서 KNN 세라믹스의 소결성을 개선하기 위하여 강유전 또는 반강유전체인 $SrTiP_3$와 $LiTaO_3$를 고용체 형성에 포함시키고 또한 $K_4CuNb_8O_{23}$, $MnO_2$, CuO등과 같은 소결조제를 첨가하여 압전 특성과 소결성을 개선시켰다. 따라서 본 연구에서는 비화학양론적 (1-X)[$[(K_{0.5}Na_{0.5}]_{0.97}(Nb_{0.96}Sb_{0.04})O_3]$ + 0.008CuO + 0.2wt% $Ag_2O$ + X $CeMnO_3$의 조성을 사용하여 A사이트와 B 사이트에 각각 Ce이온과 Mn 이온의 치환량을 변화하여 그에 따른 유전 및 압전특성을 조사하였다.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.20 no.9
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• pp.766-770
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• 2007

In this study, in order to develop low temperature sintering ceramics for multilayer piezoelectric actuator, $0.07Pb(Mn_{1/3}Nb_{2/3})O_3-xPb(Ni_{1/3}Nb_{2/3})O_3-(0.93-x)Pb(Zr,Ti)O_3$ ceramics system were fabricated using $Li_2CO_3-Bi_2O_3-CuO$ sintering aids and the specimens were sintered at $930^{\circ}C$. Thereafter, their piezoelectric and dielectric characteristics were investigated according to the amount of PNN substitution. At 9 mol% PNN substitution, density, electromechanical coupling factor ($k_p$), dielectric constant, mechanical quality factor ($Q_m$) and piezoelectric constant ($d_{33}$) showed the optimum value of $7.86g/cm^3$, 0.60, 1640, 1323 and 387 pC/N, respectively. It is considered that these values are suitable for piezoelectric divece application such ad multilayer piezoelectric actuator and ultrasonic vibrator with pure Ag internal electrode.

• Journal of Advanced Marine Engineering and Technology
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• v.27 no.6
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• pp.714-720
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• 2003

Due to the electric power shortage in summer season and regulation of freon refrigerant, the application of gas absorption refrigeration and hot water systems are considerably increasing trend. But, this system consists of condenser, heat exchanger, supply pipe and radiator etc. which are easily corroded by acidity and dissolved oxygen and gases. In result, this system occurs scale attachment and corrosion damage like pitting and crevice corrosion. In this study, electrochemical polarization test of heat exchanger tubing material (copper, aluminium brass, 30% cupronickel(30% Cu-Ni)) was carried out in 60% lithium bromide solution at $95^{\circ}C$. As a result of polarization test, corrosion behavior by impressed potential and local corrosion. such as galvanic corrosion, pitting corrosion behavior, of tubing materials was investigated. The main results obtained are as follows: (1) The effect of pitting and crevice corrosion control of 30% cupronickel in 60% LiBr solution at $95^{\circ}C$ is very excellent. (2) Dissimilar metal corrosion of 30% cupronickel coupling to aluminium bronze is the most sensitive. (3) Current density behavior of tube materials by impressed potential is high in order of copper > aluminium brass > 30% cupronickel.

• Economic and Environmental Geology
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• v.40 no.6
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• pp.727-738
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• 2007

The present study investigation the geochemical characteristics of the stream sediments in the Unbong area was conducted to enable a understanding the natural background and a prediction the prospects of geochemical disaster as a result of that bed rocks(mylonitic granites, Kim et al., 1992). We systematically collected seventy three stream sediments samples by wet sieving along the primary channels. Major, trace and rare earth element(REE) concentrations, combined with mineralogical characteristics, were determined by XRD, XRF, ICP-AES and NAA analysis methods. Major element concentrations for the stream sediments in the Unbong area were $SiO_2\;36.94{\sim}65.39wt.%,\;Al_2O_3\;10.15{\sim}21.77wt.%,\;Fe_2O_3\;3.17{\sim}10.90wt.%,\;CaO\;0.55{\sim}5.27wt.%,\;MgO\;0.52{\sim}4.94wt.%,\;K_2O\;1.38{\sim}4.54wt.%,\;Na_2O\;0.49{\sim}3.36wt.%,\;TiO_2\;0.39{\sim}1.27wt.%,\;MnO\;0.04{\sim}0.22wt.%,\;P_2O_5\;0.08{\sim}0.54wt.%$. Trace and REE concentrations for the stream sediments were $Cu\;4.8{\sim}134ppm,\;Pb\;24.2{\sim}82.5ppm,\;Sr\;95.9{\sim}739ppm,\;V\;19.9{\sim}124ppm,\;Zr\;52.9{\sim}145ppm,\;Li\;25.2{\sim}3.3ppm,\;Co\;3.87{\sim}50.0ppm,\;Cr\;17.4{\sim}234ppm,\;Hf\;3.93{\sim}25.2ppm,\;Sc\;4.60{\sim}20.6ppm,\;Th\;3.82{\sim}36.9ppm,\;Ce\;45.7{\sim}243ppm,\;Eu\;0.89{\sim}2.69ppm,\;Yb\;1.42{\sim}5.18ppm$. According to the comparison of average major element concentrations, CaO, $Na_2O\;and\;K_2O$ contents are higher in stream sediments than in bed rocks(mylonitic granites, Kim et al., 1992) $Al_2O_3\;and\;SiO_2$ contents show good correlation both stream sediments and bed rocks(mylonitic granites, Kim et al., 1992). Yb and Eu in the stream sediments show a positive correlation with $SiO_2$. In contrast, the stream sediments display a negative correlation.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.11a
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• pp.253-254
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• 2007

In this study, in order to develop low temperature sintering multilayer piezoelectric actuator, PMN-PNN-PZT system ceramics were fabricated using $Li_2CO_3-Bi_2O_3$-CuO as sintering aids and their piezoelectric and dielectric characteristics were investigated as a function of heating rate. At sintering temperature of $900^{\circ}C$, with increasing heating rate, electromechanical coupling factor(kp), mechanical quality factor(Qm) and dielectric constant $({\varepsilon}_r)$ were increased.