• 대한화학회지
• /
• 제26권1호
• /
• pp.24-30
• /
• 1982

란탄족 화합물인 Ln$(fod)_3$ (Ln = Pr, Nd, Eu 및 Yb)를 사용하여 contact-only (COM) 및 dipolar-only (DOM) 2성분계 혼합물을 만든 후 기질인 4-picoline의 $F_i$ 및 $G_i$값을 핵자기공명 이동으로 부터 측정하였다. 그 결과 Pr$(fod)_3$ 및 Eu$(fod)_3$의 혼합물인 COM 1 및 DOM 1으로 얻은 값들을 단일 Ln$(fod)_3$로 얻은 값들과 잘 일치하였다. 그러나 $(fod)_3$ 및 Yb$(fod)_3$의 혼합물인 COM 2 및 DOM 2로 얻을 값들을 단일 Ln$(fod)_3$로 얻은 값들과 상당한 오차를 나타내었다. 그 오차는 이테르븀(Yb) 착물에 기인하는 것으로 추정되었다.

• 대한수학회지
• /
• 제43권2호
• /
• pp.271-281
• /
• 2006

The commutative products of the distributions $x^r\;ln^p\;{\mid}x{\mid}\;and\;x^{-r-1}ln^q\;{\mid}x{\mid}$ and of sgn x $x^r\;ln^p\;{\mid}x{\mid}\;and\;sgn\;x\;x^{-r-1}ln^q\;{\mid}x{\mid}$ are evaluated for $r=0,\;\pm1,\;\pm2,...\;and\;p,\;q=0,1,2,....$

• Bulletin of the Korean Chemical Society
• /
• 제17권6호
• /
• pp.511-514
• /
• 1996

The interactions between Ln(dpm)3 [Ln3+=Eu3+, Yb3+, Pr3+, Sm3+, Tb3+and Ho3+; dpm=tris 2,2,6,6-tetramethylheptane-3,5-dionate] and acetamide in CCl4 solution were investigated using near IR absorption spectroscopy. From the measured 2 νC=O+ amide Ⅲ combination band of acetamide in the region of 2130-2180 nm(4695-4587 cm-1), it was found that acetamide is coordinating through its carbonyl oxygen atom to Ln(dpm)3[C=O…Ln(dpm)3)] and forms only 1 : 1 stoichiometric Ln(dpm)3- acetamide complex. The ΔHo values for the formation of Ln(dpm)3-acetamide obtained from the temperature studies are -39.1, -28.4, -25.5, -24.7, -21.1 and -17.7 kJ mol-1 for Eu(dpm)3, Yb(dpm)3, Pr(dpm)3, Sm(dpm)3, Tb(dpm)3 and Ho(dpm)3, respectively, which are larger than those of the hydrogen bond between amide and various hydrogen acceptors. Except Eu(dpm)3 and Yb(dpm)3, -ΔHovalue increases as the ionic size increases.

• 한국추진공학회:학술대회논문집
• /
• 한국추진공학회 2009년도 춘계학술대회 논문집
• /
• pp.233-236
• /
• 2009

산화제는 $LN_2O$, 고체연료는 HDPE(High Density PolyEthlene)를 사용하여 산화제의 상 및 연료포트 직경에 따른 하이브리드 로켓 모터의 연소특성을 비교 분석하였다. 불완전한 액적의 기화와 연료와 산화제의 혼합으로 인해 산화제로 $GN_2O$ 보다 $LN_2O$를 적용했을 때, 연소효율이 낮게 나타났다. O/F비에 따른 화염온도변화 및 끝 단면적에서의 연소반응으로 인해 $LN_2O$와 $GN_2O$를 사용하였을 경우 고체연료의 초기 포트 직경에 따른 후퇴율의 경향이 달리 나타났다.

• Journal of Ecology and Environment
• /
• 제48권2호
• /
• pp.196-206
• /
• 2024

Background: Most of the biomass equations were developed using sample trees collected mainly from pan-tropical and tropical regions that may over- or underestimate biomass. Site-specific models would improve the accuracy of the biomass estimates and enhance the country's measurement, reporting, and verification activities. The aim of the study is to develop site-specific biomass estimation models and validate and evaluate the existing generic models developed for pan-tropical forest and newly developed allometric models. Total of 140 trees was harvested from each diameter class biomass model development. Data was analyzed using SAS procedures. All relevant statistical tests (normality, multicollinearity, and heteroscedasticity) were performed. Data was transformed to logarithmic functions and multiple linear regression techniques were used to develop model to estimate aboveground biomass (AGB). The root mean square error (RMSE) was used for measuring model bias, precision, and accuracy. The coefficient of determination (R² and adjusted [adj]-R²), the Akaike Information Criterion (AIC) and the Schwarz Bayesian information Criterion was employed to select most appropriate models. Results: For the general total AGB models, adj-R² ranged from 0.71 to 0.85, and model 9 with diameter at stump height at 10 cm (DSH₁₀), ρ and crown width (CW) as predictor variables, performed best according to RMSE and AIC. For the merchantable stem models, adj-R² varied from 0.73 to 0.82, and model 8) with combination of ρ, diameter at breast height and height (H), CW and DSH₁₀ as predictor variables, was best in terms of RMSE and AIC. The results showed that a best-fit model for above-ground biomass of tree components was developed. AGB_Stem = exp {-1.8296 + 0.4814 natural logarithm (Ln) (ρD²H) + 0.1751 Ln (CW) + 0.4059 Ln (DSH₃₀)} AGB_Branch = exp {-131.6 + 15.0013 Ln (ρD²H) + 13.176 Ln (CW) + 21.8506 Ln (DSH₃₀)} AGB_Foliage = exp {-0.9496 + 0.5282 Ln (DSH₃₀) + 2.3492 Ln (ρ) + 0.4286 Ln (CW)} AGB_Total = exp {-1.8245 + 1.4358 Ln (DSH₃₀) + 1.9921 Ln (ρ) + 0.6154 Ln (CW)} Conclusions: The results demonstrated that the development of local models derived from an appropriate sample of representative species can greatly improve the estimation of total AGB.

• 방사성폐기물학회지
• /
• 제19권3호
• /
• pp.353-366
• /
• 2021

The solubilities of different multicomponent lanthanide oxide (Ln₂O₃) solid solutions including binary (Ln₁ and Ln₂ = La, Nd, Eu, or Tm), ternary (Ln₁, Ln₂, and Ln₃ = La, Nd, Eu, or Tm), and higher systems (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu) were studied after aging for four weeks at 60℃. Our recent study revealed that the phase transformations in binary ((La, Nd) and (La, Eu)) and ternary (La, Nd, Eu) systems are responsible for the formation of (La, Nd)(OH)₃, (La, Eu)(OH)₃, and (La, Nd, Eu)(OH)₃ solid solutions, respectively. The variations in the mole fractions of La³⁺, Nd³⁺, and Eu³⁺ in the sample solutions of these hydroxide solid solutions indicated that a thermodynamic equilibrium might account for the apparent La, Nd, and Eu solubilities. Conversely, the binary and ternary systems containing Tm₂O₃ as the heavy lanthanide oxide retained the oxide-based solid solutions, and their solubility behaviors were dominated by their congruent dissolutions. In the higher multicomponent system, the X-ray diffraction patterns of the solid phases, before and after contact with the aqueous phase indicated the formation of a stable oxide solid solution and their solubility behavior was explained by its congruent dissolution.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2000년도 하계학술대회 논문집
• /
• pp.726-729
• /
• 2000

Though L $a_{1+x}$S $r_{2-x}$M $n_2$ $O_{7}$ n=2 R-P phases have been well known to have CMR effect, it was generally believed that n=1 phase was insulating. But recently monolayered perovskite $Ca_{2-x}$L $n_{x}$Mn $O_4$phase has been reported to show magnetoresistance. In this study, layered perovskite $Ca_{2-x}$L $n_{x}$Mn $O_4$ (x=0, 0.5, Ln=Pr, Nd, Sm, Gd) phases were synthesized by solid state reaction and their structures were refined by Rietveld method. The space groups of $Ca_2$Mn $O_4$, N $d_{0.5}$C $a_{1.5}$Mn $O_4$phases were refined as C2cb and Fmmm, respectively.y.ely.y.y.y.y.y.y.

• 한국전기전자재료학회논문지
• /
• 제16권2호
• /
• pp.151-156
• /
• 2003

High temperature superconductor can only be applied against an engineering specofication that has to be determined for each particular application form the design requirements for economic viability and for operation margins in service. However, in order to realize the HTS transformer, it is necessary to establish the high voltage insulation technique in cryogenic temperature. Therefore, the composite insulation of double pancake coil type transformer are described and AC breakdown voltage characteristics of liquid nitrogen(LN$_2$) under HTS pancake coil electrode made by Bi-2223/Ag are studied. The Breakdown of LN$_2$ is dominated electrode shape and distance. The influence of pressure on breakdown voltage is discussed with th different electrode. For the electrical insulation design of turn-to-turn insulation for the HTS transformer, we tested breakdown strength of insulation sheet under varying pressure. And we investigated surface flashover properties of LN$_2$ and complex conition of cryogenic gaseous nitrogen(CGN$_2$) obove a LN$_2$ surface. The surface voltage of GFRP was measured as a function of thickness and electrode distance in LN$_2$ and complex condition of CGN$_2$ above a LN$_2$ surface. this research presented information of electrical insulation design for double pancake coil(DPC) type HTS transformer.

• 대한치과기공학회지
• /
• 제35권3호
• /
• pp.193-200
• /
• 2013

Purpose: In this study, in order to provide objective standard of the mixed concentration of the zirconia coloring-liquids, compare the shade differences after colored zirconia blocks from different concentrations. Methods: After immersion for 2 minutes zirconia specimen ($1.5{\times}1.5{\times}0.6{\pm}0.01mm$) in coloring-liquids that produced different concentrations, were sintered in furnace dedicated. Then, it was measured in spectrophotometer and Shadepilot. It has been determined mean and standard deviation of the color difference for each group, and verified by one-way ANOVA using the (version12.0) SPSS WIN Program the difference in shade according to the concentration at the significance level of 95% confidence, it conducted a Tukey's multiple range test to post-test. Results: The mean of $L^*$ was decreased toward LN35 group, however the mean of $a^*$ and $b^*$ was increased(p<.05). There is a statistically significant difference in the results of $L^*$ post hoc test of each group was LN15-LN30/LN35, LN20-LN30/LN35, LN25-LN30/LN35, and LN30-LN35 group. The $a^*$ group, it was found that there is a statistically significant difference in all groups for each(p<.05). The $b^*$ group, it was found that there is a statistically significant difference in all groups except the LN25-LN30(p<.05). Conclusion: In order to make effective use of the coloring-liquids of zirconia, the device objective, accurate concentration measurement is required, from the present study, we presented evidence basic to this.

• Journal of Yeungnam Medical Science
• /
• 제36권2호
• /
• pp.115-123
• /
• 2019

Background: This study aimed to assess the in-field lymph node (LN) failure rate according to LN size and to investigate effect of LN size on the survival outcome of patients with locally advanced cervical carcinoma treated with concurrent chemoradiotherapy (CCRT). Methods: A total of 310 patients with locally advanced cervical carcinoma treated with CCRT were enrolled in retrospective study. LN status was evaluated by magnetic resonance imaging. All patients received conventional external beam irradiation and high-dose rate brachytherapy, and concurrent cisplatin-based chemotherapy. In-field LN failure rate according to LN size was analyzed. Results: The median follow-up period was 83 months (range, 3-201 months). In-field LN failure rate in patients with pelvic LN size more than 10 mm was significantly higher than that in patients with pelvic LN size less than 10 mm (p<0.001). A similar finding was observed in the infield para-aortic LN (PALN) failure rate (p=0.024). The pelvic and PALN size (${\geq}10mm$) was a significant prognostic factor of overall-survival (OS) and disease-free survival rate in univariate and multivariate analyses. The OS rate was significantly different between groups according to LN size (<10 mm vs. ${\geq}10mm$). Conclusion: A LN of less than 10 mm in size in an imaging study is controlled by CCRT. On the other hand, in LN of more than 10 mm in size, the in-field LN failure rate increase and the prognosis deteriorate. Therefore, a more aggressive treatment strategy is needed.