• Title/Summary/Keyword: $LN_2$

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Launch of PE/$LN_2O$ Hybrid Rocket Vehicle and Analysis of Flight Path (PE/$LN_2O$ 소형 하이브리드 시험발사 및 비행궤도 분석)

  • Lee, Min-Ho;Kim, Jae-Wook;Sin, Jun-Ho;Um, Yong-Kyung;Oh, Yu-Jin;Lee, Sun-Jae;Jung, Young-Kyu;Jo, Jae-Yun;Choi, Young-Rok;Lee, Jung-Pyo;Kim, Jin-Kon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 한국추진공학회 2010년도 제35회 추계학술대회논문집
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    • pp.820-824
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    • 2010
  • The purpose of this study is to develop basic technology of hybrid rocket vehicle by constructed and launched. This small hybrid rocket using HDPE/LN2O and Aluminium steel for its body (weight : 12.5 kg, diameter : 114 mm, height : 1.8 m) was designed. The fuel grain and injector were designed for 50 kgf thrust and burning time 2.5 sec. This rocket was loaded the data acquisition device for obtaining data of pressure and velocity during its flying and equiped an automatic ejector system using spring/motor and timer to collect the rocket more safely after launching. It was launched successfully, but found some problem that the rocket's weight was heavier than expected and the thrust was not enough to reach the designed altitude and analyzed its flight path way.

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Low Temperature Sintering and Microwave Dielectric Properties of 0.85CaWO4-0.15LnNbO4 (Ln = La, Sm) Ceramics

  • Kim, Su-Jung;Kim, Eung-Soo
    • Korean Journal of Materials Research
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    • 제17권8호
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    • pp.442-446
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    • 2007
  • Microwave dielectric properties of $0.85CaWO_4-0.15LnNbO_4$ (Ln = La, Sm) ceramics were investigated as a function of the sintering temperature and $Li_2WO_4$ content from 0.8 wt.% to 1.5 wt.%. A single phase with tetragonal scheelite structure was obtained at a given composition ranges. For the specimens with $Li_2WO_4$, the sintering temperature could be effectively reduced from $1150^{\circ}C$ to $900^{\circ}C$ due to the enhancement of sinterability. Dielectric constant (K) of the specimens with $LaNbO_4$ and $SmNbO_4$ was increased with the increase of sintering temperature and/or $Li_2WO_4$ content. However, K of the specimens with $LaNbO_4$ was higher than that of $SmNbO_4$ due to the larger dielectric polarizability $(\alpha)$ of $LaNbO_4$ ($18.08{\AA}$) than that of $SmNbO_4$ ($16.75{\AA}$). With an increase of $Li_2WO_4$ content, Qf value of the specimens with $SmNbO_4$ was decreased, while that of the specimens with $LaNbO_4$ was increased. Temperature coefficient of resonant frequency (TCF) was increased with the increase of $Li_2WO_4$ content.

Effects of Aeration Rates and Rheological Properties of Fermentation Broth on Pullulan Fermentation (풀루란 발효시 통기속도의 영향과 발효액의 물성에 관한 연구)

  • Shin, Yong-Chul;Han, Jong-Kwon;Byun, Si-Myung
    • Korean Journal of Food Science and Technology
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    • 제22권5호
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    • pp.533-538
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    • 1990
  • In polysaccharide fermentation with Aureobasidium pullulans, the aeration effects on the production of polysaccharide and the rheological properties of fermentation broth were studied. The increase of the aeration rates from 0.5 to 2.0vvm at 500 rpm yielded the maximum specific production rate of polysaccharide from 0.046 to $0.093 (hr^{-1})$, and the maximum specific growth rate of cells from 0.168 to $0.192 (hr^{-1})$. The viscosity behavior of fermentation broths at the different aeration rates followed the power-law ${\tau}= K({\gamma})^n$. The viscosity attributed by cells was about 10% of the total viscosity of fermentation broth and most of viscosity was attributed by the polysaccharide produced. The relationship between power-law parameters and the concentration of polysaccharide generally satisfied the etㄴrations with the regression coefficient greater than 0.980, $lnK(t)= ln({\tau})_o-n(t)\;ln({\gamma})_o\;and\;K(t)=A P(t)^B$.

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Clinical and Immunohistochemical Characteristics of Thyroid Papillary Cancer with Lateral Neck Lymph Node Metastasis (측경부 림프절 전이를 동반한 갑상선 유두상암의 임상 양상과 면역조직화학적 특성)

  • Lee, Seon-Uk;Jin, Sung-Min;Lee, Sang-Hyuk;Sohn, Jin-Hee;Chae, Seung-Wan;Kim, Dong-Hoon
    • Korean Journal of Head & Neck Oncology
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    • 제27권1호
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    • pp.59-65
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    • 2011
  • Background and Objectives : Papillary thyroid carcinoma(PTC) frequently metastasize to the regional neck, however, lateral neck lymph node metastasis is less common. The aim of this study is to investigate clinical and immunohistochemical features of PTC with lateral LN metastasis, and determine the predictive factors for lateral LN metastases. Material and Methods : We undertook a retrospective study of 83 patients treated between January 2007 and December 2009 for PTC by thyroidectomy with or without lateral neck dissection. The following criteria were used to study the clinical predictive value of lateral LN. metastases : sex, age, tumor size, multifocality, extracapsular spread(ECS) and lymphovascular emboli. Immunohistochemical staining for VEGF-A, VEGF-C, Bax, Bcl-2, Cyclin D1, Cyclin E, $p27^{kip1}$ and $p57^{kip2}$ was performed, and quantified blindly by three pathologists who had no clinical information of the patients. Immunohistochemical expression was scored as high(>50% of cells stained) or low(0-49%). Results : With use of univariate and multivariate analysis, tumor size(>2cm) and ECS were independent correlates of lateral LN metastasis in PTC. Expression of VEGF-C, Bax, and Cyclin D1 in the PTC with lateral LN metastasis was scored higher than in PTC without lateral LN metastasis(p<0.05). Conclusion : The important risk factors for lateral LN metastasis in PTC are primary tumor size and the presence of ECS. And expression of VEGF-C, Bax and cyclin D1 may be considered of lateral LN metastatic potential in PTC.

Studies on the Coordination of Acetamide to Rare Earth Metal Ion (Ln(II) (희토류 금속이온 (Ln(III))과 Acetamide 사이의 상호작용에 대한 연구)

  • Sang-Won Lee;Jeonga Yu;Chang-Ju Yoon;Yoo-Hyek Jun;Young-Sang Choi
    • Journal of the Korean Chemical Society
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    • 제36권2호
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    • pp.205-211
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    • 1992
  • The $2{\nu}_{C=0}$ + amide III combination band spectrum of acetamide (AA) was obtained in very dilute solutions of AA+lanthanide shift reagents (LSR) in carbon tetrachloride over the range of $15^{\circ}$ to $45^{\circ}C$. It was found that only 1 : 1 AA-LSR complex is formed by the interaction between carbonyl oxygen of AA and central metal ion(Ln(Ⅲ)) in LSR. The thermodynamic parameters for Ln(III)${\cdot}$O=C bond were determined by computer analysis of concentration and temperature dependent spectra. ${\Delta}H^{\circ}$ for the coordination of AA to Eu$(dpm)_3$, Yb$(dpm)_3$, and Pr$(dpm)_3$ have been found to be -39.1, -28.4, and -25.5 kJ/mol, respectively. It has shown that this type of ion-dipole interaction is more than twice stronger compared to the dipole-dipole interaction in the amide linkage, and largely depending on the steric hindrence effect by the bulky dpm groups around central metal ion (Ln(III)) rather than the ionic potential effect of central metal ion itself.

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Breakdown Properties of Cryogenic Coolant for Pancake Coil Type High $T_{c}$ Superconducting Equipment (Pancake coil형 고온초전도 기기의 응용을 위한 극저온 냉매의 절연파괴 특성)

  • 백승명;정종만;이진호;김상현
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 한국초전도저온공학회 2002년도 학술대회 논문집
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    • pp.185-188
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    • 2002
  • In the design of superconducting power equipments such as transformer, cable and fault current limit, knowledge of the dielectric behavior of both liquid and gaseous at very low temperatures is very importance. Especially, Electrical properties of liquid nitrogen($LN_{2}$) and gaseous nitrogen($GN_{2}$) have become of great interest again since the discovery of high temperature superconductors. However, many sources of $LN_{2}$and $GN_{2}$ problems in the test of pancake coil model arising form the deficiency of insulation data. Therefore, this paper describes the results of an experimental study on the ac breakdown voltage($V_{B}$) properties of $LN_2$ and Air under the electrode of simulated HTS pancake coil. The ac breakdown voltage of $GN_{2}$ have been measured by pancake coil-pancake coil gaps over the temperature range of 293 K to 77 K.

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Thermal Behavior of Critical Micelle Concentration from the Standpoint of Flory-Huggins Model

  • Lim, Kyung-Hee
    • Bulletin of the Korean Chemical Society
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    • 제30권9호
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    • pp.2001-2006
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    • 2009
  • Temperature dependence of the critical micelle concentration (CMC), $x_{CMC}$, in micellization can be described by ln $x_{CMC}$ = A + BT + C lnT + D/T, which has been derived statistical-mechanically. Here A, B, C, and D are fitting parameters. The equation fits the CMC data better than conventionally used polynomial equations of temperature. Moreover, it yields the unique(exponent) value of 2 when the CMC is expressed in a power-law form. This finding is quite significant, because it may point to the universality of the thermal behavior of CMC. Hence, in this article, the nature of the equation ln $x_{CMC}$ = A + BT + C lnT + D/T is examined from a lattice-theory point of view through the Flory-Huggins model. It is found that a linear behavior of heat capacity change of micellization is responsible for the CMC equation of temperature.

Experiemtnal Tests of Cryogenic Liuid Spill on a Plate (극저온 유체 유출현상에 관한 연구)

  • Ryu, Yong Hee;Hwang, Yun Ji;Lee, Yun Han;Kim, Kwang Seok;Lee, Jae Hun;Sim, Hee Jun
    • Plant Journal
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    • 제16권3호
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    • pp.42-46
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    • 2020
  • In the large LNG process in FLNG or FSRU, sudden temperature drops of the steel in the event of LNG leaks may cause brittle fracture of the structure. In this paper, we investigate the principle and process of forming a cryogenic fluid on a steel plate through a cryogenic spillage experiment, and analyze the correlation of the temperature distribution of the steel plate according to the distance from the nozzle and exposure time. Two types of cryogenic fluids were used: LN2 and LNG. The cyogenic liquid was released on the steel plate at 1.6L/min for LN2 and 1.5L/min for LNG. For the steel, DH was used and the temperature was measured at 10 points in total. The Leidenfrost effect was observed on the steel plate, and the temperature distribution of the steel was varied according the flow path and the heat of evaporation of the fluid.

Manufacture & Launch of Small PE/$LN_2O$ Hybrid Rocket with 50 kgf Thrust Level (추력 50 kgf 급 PE/$LN_2O$ 소형 하이브리드 로켓 제작 및 시험발사)

  • Kim, Hyeon-Woo;Jeon, Min-Ho;Oh, Ji-Sung;Han, See-Hee;Kang, Min-Seok;Jang, Hyoung-Gui;Kim, Hee-Yong;Bae, Tae-Hyun;Lee, Sun-Jae;Kim, Jin-Kon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 한국추진공학회 2009년도 제33회 추계학술대회논문집
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    • pp.507-510
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    • 2009
  • The small size of hybrid rocket using PE-$LN_2O$ was designed, constructed and launched for a development basic technology of Hybrid rocket vehicle. The hybrid engine ignition system was designed with valve system using external actuator and confirmed working without any fault. To design fuel grain an internal ballistics design was carried out, and to estimate rockets flight path an external ballistics analysis was carried out. So the rocket was designed and constructed, and the launch test proves that hybrid rocket's design was suitable. The hybrid rocket(weight : 9kg, diameter : 110 mm, height : 1.7 m) was launched successfully. But parachute was deployed on mid-flight and the mission could not finish its purposed flight. Some of problems were found in this activity but next launch vehicle will be improved.

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