• 제목/요약/키워드: $H_2S$ removal

검색결과 781건 처리시간 0.027초

자기분리가 가능한 지르코늄 자성 흡착제의 합성과 인 흡착 특성 (Synthesis and Phosphorus Adsorption Characteristics of Zirconium Magnetic Adsorbent Having Magnetic Separation Capability)

  • 임대석;김은형;김동락;이태구;임학상
    • 상하수도학회지
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    • 제26권3호
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    • pp.431-442
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    • 2012
  • The purpose of this study, is to separate magnetic separation devices using permanent magnets by using magnetization characteristics remaining in treated water after adsorption and synthesizing phosphorus adsorbent capable of magnetic separation for efficient removal of phosphorus. The synthesis of the adsorbent which set Zirconium(Zr) having high friendly features for phosphorus as an element, and by synthesizing Iron Oxide($Fe_3O_4$, another name of $Fe_3O_4$ is magnetite) being able to grant magnetism to Zirconium Sulfate($Zr(SO_4)_2$), zirconium magnetic adsorbent(ZM) were manufactured. In order to consider the phosphorus adsorption characteristics of adsorbent ZM, batch adsorption experiment was performed, and based on the results, pH effect, adsorption isotherm, adsorption kinetics, and magnetic separation have been explore. As the experiment result, adsorbent ZM showed a tendency that the adsorption number was decreased rapidly at pH 13; however, it was showed a high amount of phosphorus removal in other range and it showed the highest amount of phosphorus removal in pH 6 of neutral range. In addtion, the Langmuir adsorption isotherm model is matched well, and D-R adsorption isotherm model is ranged 14.43kJ/mol indicating ion exchange mechanism. The result shown adsorption kinetics match well to the Pseudo-second-order kinetic model. The adsorbent ZM's capablility of regenerating NaOH and $H_2SO_4$, was high selectivity on the phosphorus without impacts on the other anions. The results of applying the treated water after adsorption of phosphorus to the magnetic separation device by using permanent magnets, shows that capture of the adsorbent by the magnetization filter was perfect. And they show the possibility of utilization on the phosphorus removal in water.

30kW급 LFG 가스터빈 발전용 연료화 정제시스템 개발 (Development of Fuel Conditioning System for 30 kW-class LFG Gasturbine Power Generation)

  • 허광범;박정극;임상규;이정빈
    • 신재생에너지
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    • 제6권1호
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    • pp.29-37
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    • 2010
  • Biogas is a carbon neutral energy and consists of mostly methane and carbon dioxide, with smaller amounts of water vapor, and trace amounts of $H_2S$, Siloxane and other impurities. Hydrogen sulfide and Siloxane usually must be removed before the gas can be used for generation of electricity or heat. The goals of this project are to develope the Fuel conditioning system of Land Fill Gas for 30kW-Micro Gas Turbine co-generation system. The fuel conditioning system mainly consists of $H_2S$ removal system, Land Fill Gas compressor, Siloxane removal system and many filtering systems. The fuel requirement of 30kW MGT is at least 32% of $CH_4$, $H_2S$ (<30 ppm), Siloxane (<5ppb) and supply pressure (> 0.6 MPa) from LFG compressor. Main mechnical charateristics of Micro Gas Turbine system by using LFG have the specific performance; 1) high speed turbine speed (96,000 rpm) 2) very clean emmission NOx (<9 ppm) 3) high efficiency of energy conversion rate. This paper focuses on the development of design technology for LFG fuel conditioning system. The study also has the plan to replace the fuel of gas turbine and other distributed power systems. As the increase of Land Fill Gas (LFG), this system help to contribute to spread more New & Renewable Energy and the establishment of Renewable Portfolio Standards (RPS) for Korea.

고분자성 Al(III) 응집제의 특성이 상수원수의 응집특성에 미치는 영향 (Effects of Characterization of Polymeric Al(III) Coagulants on Coagulation of Surface Water)

  • 이선기;한승우;강임석
    • 상하수도학회지
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    • 제12권2호
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    • pp.99-105
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    • 1998
  • This research explored the feasibility of preparing and utilizing a preformed polymeric solution of Al(III) for coagulation in water treatment. Slow base(NaOH) injection into supersaturated aluminum chloride solutions did produce high yields of the type of Al polymers useful to water treatment applications. PACl's characteristic analysis showed that the quantity of polymeric Al produced at value of $r(OH_{added}/Al)=2.2$ was 83% of the total aluminum in solution, as showing maximum contents and precipitate was dramatically increased when r was increased above 2.35. And PACl was stable during sitoring period so aging effect was negligible. Results of the coagulation of Nakdong river waters with three PACls showed that the effectiveness of the three coagulants can be considered as r = 2.2 > r = 2.0 > r = 2.35 which are also the order of higher polymeric aluminum contents. Coagulation results for synthetic water exhibited optimum dose of 0.25mM Al, for three PACls, but above optimum dose, r = 2.0 and 2.2 PACl impaired the coagulation and sedimentation of turbidity and humic acid because of the restabilization of particulate. The effect of pH for on coagulation of Nak Dong River water showed that it had much effect turbidity and TOC removal, especially near pH 7. But pH effect was little for turbidity and TOC removal when r = 2.35 PACl was used for coagulation, that PACl had much more precipitates content.

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Renewable energy powered membrane systems: inorganic contaminant removal from Australian groundwaters

  • Richards, Laura A.;Richards, Bryce S.;Schafer, Andrea I.
    • Membrane and Water Treatment
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    • 제2권4호
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    • pp.239-250
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    • 2011
  • A photovoltaic powered ultrafiltration and reverse osmosis system was tested with a number of natural groundwaters in Australia. The objective of this study was to compare system performance at six remote field locations by assessing the impact of water composition and fluctuating energy on inorganic contaminant removal using a BW30-4040 membrane. Solar irradiance directly affected pressure and flow. Groundwater characteristics (including TDS, salts, heavy metals, and pH), impacted other performance parameters such as retention, specific energy consumption and flux. During continual system operation, retention of ions such as $Ca^{2+}$ and $Mg^{2+}$ was high (> 95%) with each groundwater which can be attributed to steric exclusion. The retention of smaller ions such as $NO_3{^-}$ was affected by weather conditions and groundwater composition, as convection/diffusion dominate retention. When solar irradiance was insufficient or fluctuations too great for system operation, performance deteriorated and retention dropped significantly (< 30% at Ti Tree). Groundwater pH affected flux and retention of smaller ions ($NO_3{^-}$ and $F^-$) because charge repulsion increases with pH. The results highlight variations in system performance (ion retention, flux, specific energy consumption) with real solar irradiance, groundwater composition, and pH conditions.

석면 해체.제거 작업에서 사용되는 장비의 성능 기준에 관한 고찰 (A Review on the Performance Criteria of Equipment Required for Asbestos Removal)

  • 이나루
    • 한국산업보건학회지
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    • 제23권3호
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    • pp.212-221
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    • 2013
  • Objectives: Asbestos fibers are accumulated in negative pressure unit (NPU) or vacuum cleaner in asbestos removal. Failure of operation or poor use performance of the NPU or vacuum cleaner causes asbestos fibers to spread in the air. Asbestos contractors should have an NPU fitted with a HEPA , vacuum cleaner, decontamination area, respirators, wetting equipment, and differential pressure manometer to register with the Ministry of Employment and Labor. There should be performance criteria of equipment used in asbestos removal. But there are none such criteria used in asbestos removal. This study was performed to investigate international or national performance criteria of equipment used in asbestos removal. Methods: Regulations, approved code of practice, guidance and national standards of the UK, USA and Korea were reviewed. A survey was done to investigate the requirements for equipment used in asbestos removal in Korea. Results: Air flow of NPUs used in Korea usually covers from$500m^3/h$ to over $3000m^3/h$. Some requirements for NPUs used in Korea were missing compared to the requirements of British standards for NPUs. All NPUs have different missing requirements. The UK also has separate British standard for leak tests for NPUs. Highly hazardous class vacuum cleaners should be used in asbestos removal in the UK. It has national standards on the operation of vacuum cleaners used in asbestos removal. There is only a certification system for less than 2.5kw rated voltage vacuum cleaners for home use in Korea. Powered (-assisted) respirators with mask are recommended in asbestos removal. Type 5 coveralls should be used in asbestos removal in the UK. There are international standards for requirements and leak tests of type 5 coveralls. A manometer for measuring differential pressure is needed in asbestos removal. The manometer's measuring range should cover less than ${\pm}125$ Pa and the gradation of manometer should be less than 2.5 Pa. The definition of decontamination area should be corrected. Installation of airlock and minimum area should be considered in decontamination area. Conclusions: Equipment should be used in asbestos removal proper performance and no leaks. There should be a certification system for equipment used in asbestos removal. This study can help to a certification system for equipment used in asbestos removal in Korea.

Itaconic acid로 그라프트 공중합한 Chitosan의 beads를 이용한 수계 우라늄의 제거 (Removal of Uranium in Water by Beads of Chitosan the Graft-Copolymerized with Itaconic Acid)

  • 강수정;김남기;김재우;한상문
    • 환경위생공학
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    • 제20권2호
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    • pp.47-55
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    • 2005
  • The World Health Organization(WHO, 1998) and the United States Environmental Protection Agency (USEPA, 1992) recommended $2{\mu}\;guranium/{\ell}$ in drinking water as a guideline. The Korea Institute for Environmental Research recently reported that the radioactive pollution in ground water was almost negligible In Korea$(1999\~2002)$. Cs were cast into beads(2mm in wet form) and treated with hexamethylene diisocyanate for stability in acidic aqueous solution through cross-linking of the beads surfaces. The removal study was carried out in a static batch system and a flow system. In the static system, a certain amount of sample water was confined in a vessel and beads(dry weight 0.5g) were packed into it in order to adsorb uranium for a certain period of time. Afterwards the remaining uranium in water vessel was determined by inductively coupled plasma mass spectrometry. The effective pH range was 4 to 8. The smaller the size of beads, the better the removal efficiency. Furthemore, the lower the flow rates, the higher the removal efficiency. The results showed that chitosan beads can be effectively used for the removal of uranium contained in water.

Low Cholesterol Mozzarella Cheese Obtained from Homogenized and β-Cyclodextrin-Treated Milk

  • Kwak, H.S.;Nam, C.G.;Ahn, J.
    • Asian-Australasian Journal of Animal Sciences
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    • 제14권2호
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    • pp.268-275
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    • 2001
  • The effects of homogenization conditions and $\beta$-cyclodextrin ($\beta$-CD) on cholesterol removal of Mozzarella cheese were examined. The homogenization pressure influenced markedly on the cholesterol removal in milk and, 75.64% of cholesterol, the highest rate, was removed at $70.0kg/cm^2$. In addition, an increase in temperature resulted in an increase of cholesterol removal in the range of 71.75 to 78.22%. Among different concentrations of $\beta$-CD addition, 1.0% showed 78.21% of cholesterol removal. Therefore, cholesterol-reduced Mozzarella cheese was made by cheese milk treated with 70 $70.0kg/cm^2$ homogenization at $70^{\circ}C$ and 1% $\beta$-CD addition for a subsequent study. The cholesterol reduction of cholesterol-reduced Mozzarella cheese was 63.92%. Meltability, stretchability and oiling-off in cholesterol-reduced cheese were significantly lower than those in control. Hardness, gumminess and chewiness were significantly reduced, while cohesiveness and elasticity increased. Appearance and flavor of the cheese were superior, but texture inferior to the control.

Optimization of Cu, Hg and Cd removal by Enterobacter cloacae by ferric ammonium citrate precipitation

  • Singh, Rashmi R.;Tipre, Devayani R.;Dave, Shailesh R.
    • Advances in environmental research
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    • 제3권4호
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    • pp.283-292
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    • 2014
  • Iron precipitating organisms play a significant role in the formation of ferric hydroxide precipitate, which acts as strong adsorbent for toxic metal. In this respect four different iron precipitating cultures were isolated from Hutti gold mine surface winze water sample on citrate agar medium. The best isolate was screened out for metal removal study on the basis of fast visual iron precipitation. The selected isolate was identified as Enterobacter sp. based on routine biochemical tests and Biolog GN microplate results and as Enterobacter cloacae subsp. dissolvens by 16S rRNA gene sequence analysis (GenBank accession number EU429448). Influence of medium composition, medium initial pH, the influence of inoculum size, effect of various media and ferric ammonium citrate concentration were studied on metal removal in shake flask experiments. Under the optimized conditions studied, E. cloacae showed $94{\pm}2$, $95{\pm}2$ and $70{\pm}2%$ of cadmium, copper and mercury removal from a simulated waste in shake flask studies. In lab scale column reactor more than 85% of copper and mercury removal was achieved.

염색폐수 처리를 위한 미생물 선별 및 염료 탈색 (Isolation of Dye-degrading Microbes for the Treatment of Dyeing Wastewater and Dye Decoloring)

  • 최광근;이영락;김의용;유영제;김상용;이진원
    • KSBB Journal
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    • 제14권6호
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    • pp.731-736
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    • 1999
  • 동두천과 반월공단에서 87가지의 균주를 분리하였다. 그 중 5가지 균주가 색도 제거율이 우수함을 보였으며, 동정을 통해 Shewanella putrefaciens, Aeromonas salmonicida(서로 다른 3종), Pseudomonas vesicularis로 각각 동정되었다. 동정된 5종의 미생물들은 성장에 최적인 pH와 온도는 각각 7.0과 30$^{\circ}C$이었으며, Gram negative, catalase nagative, rod shape, 그리고 비운동성을 보였다. 500 mL 플라스크에서 분리된 균주 중 단일균주를 사용하여 염색폐수를 처리한 경우 약 35%의색도 제거율을 보였다. 2균주를 조합하여 적용하였을 때는, 색도 제거율이 65%까지 증가한 반면, 3균주 조합 혹은 그 이상의 균주 조합에서는 2균주 조합보다 더 좋은 효율은 보이지 않았다. 염색폐수 분해시 $Mn^{2+},\;Fe^{3+}$와 같은 중금속의 영향을 조사하였는데, 70 ppm 이하의 농도에서는 별로 영향을 주지 않았다.

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Anaerobic-aerobic granular system for high-strength wastewater treatment in lagoons

  • Hamza, Rania A.;Iorhemen, Oliver T.;Tay, Joo H.
    • Advances in environmental research
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    • 제5권3호
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    • pp.169-178
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    • 2016
  • This study aimed at determining the treatability of high-strength wastewater (chemical oxygen demand, COD>4000 mg/L) using combined anaerobic-aerobic granular sludge in lagoon systems. The lagoon systems were simulated in laboratory-scale aerated and non-aerated batch processes inoculated with dried granular microorganisms at a dose of 0.4 g/L. In the anaerobic batch, a removal efficiency of 25% was not attained until the 12th day. It took 14 days of aerobic operation to achieve sCOD removal efficiency of 94% at COD:N:P of 100:4:1. The best removal efficiency of sCOD (96%) was achieved in the sequential anaerobic-aerobic batch of 12 days and 2 days, respectively at COD:N:P ratio of 200:4:1. Sequential anaerobic-aerobic treatment can achieve efficient and cost effective treatment for high-strength wastewater in lagoon systems.