• 제목/요약/키워드: $H_2S$ removal

검색결과 779건 처리시간 0.026초

선박 대기오염 저감을 위한 벽면 캐비티 적용 습식 사이클론의 집진특성 (Collection characteristics of wet-type cyclone with wall cavity for air pollutants removal of marine diesel engines)

  • 여석준;권준형
    • 수산해양기술연구
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    • 제50권2호
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    • pp.185-192
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    • 2014
  • The main object of this study was to investigate the collection characteristics of wet-type cyclone with wall cavity. The experiment was executed to analyze the characteristics of pressure drop and collection efficiency for the present system with the experimental parameters such as water spray, water spray type, inlet velocity etc. In results, for the present system of wet-type, the pressure drop represented 35 mm $H_2O$, while in dry-type 33 mm $H_2O$ showing lower 6% at $v_{in}=21m/s$. In case of $v_{in}=21m/s$ and water spray 200 mL/min, the collection efficiency of the present system became significantly higher as 96.8% comparing to that of the conventional wet-type scrubber. Additionally, for 200 mL/min, $SO_2$ removal efficiencies decreased with the increment of inlet velocity representing 75.0, 62.5, 50.0%, at $v_{in}=6,9,12m/s$, respectively.

SNCR의 N Ox 제거효율 향상을 위한 Hybrid SNCR/SCR 공정 응용 (Application of Hybrid SNCR/SCR process for Improved N Ox Removals Efficiency of SNCR)

  • 최상기;최성우
    • 한국환경과학회지
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    • 제12권9호
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    • pp.997-1004
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    • 2003
  • The objective of this research was to test whether, under controlled laboratory conditions, hybrid SNCR/SCR process improves N $O_{x}$ removal efficiency in comparison with the SNCR only. The hybrid process is a combination of a redesigned existing SNCR with a new downstream SCR. N $O_{x}$ reduction experiments using a hybrid SNCR/SCR process have been conducted in simple NO/N $H_3$/ $O_2$ gas mixtures. Total gas flow rate was kept constant 4 liter/min throughout the SNCR and SCR reactors, where initial N $O_{x}$ concentration was 500 ppm in the presence of 5% or 15% $O_2$. Commercial catalysts, $V_2$ $O_{5}$ -W $O_3$-S $O_4$/Ti $O_2$, were used for SCR N $O_{x}$ reduction. The residence time and space velocity were around 1.67 seconds and 2,400 $h^{-1}$ or 6000 $h^{-1}$ in SNCR and SCR reactors, respectively. N $O_{x}$ reduction of the hybrid system was always higher than could be achieved by SNCR alone at a given value of N $H_{3SLIP}$. Optimization of the hybrid system performance requires maximizing N $O_{x}$ removal in the SNCR process. An analysis based on the hybrid system performance in this lab-scale work indicates that a equipment with N $O_{xi}$ =500 ppm will achieve a total N $O_{x}$ removal of about 90 percent with N $H_{3SLIP}$ $\leq$ 5 ppm only if the SNCR N $O_{x}$ reduction is at least 60 percent. A hybrid SNCR/SCR process has shown about 26∼37% more N $O_{x}$ reduction than a SNCR unit process in which a lower temperature of 85$0^{\circ}C$ turned out to be more effective.be more effective.

Optimal effective-site concentration of remifentanil for sedation during plate removal of maxilla

  • Park, Jeong-Hoon;Yoon, Ji-Young;Kim, Eun-Jung;Yoon, Ji-Uk;Choi, Byung-Moon;Ahn, Ji-Hye
    • Journal of Dental Anesthesia and Pain Medicine
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    • 제18권5호
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    • pp.295-300
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    • 2018
  • Background: Removal of the plate following Le Fort I osteotomy and BSSO (bilateral sagittal split osteotomy) is a common procedure. However, patients who undergo plate removal experience intense pain and discomfort. This study investigated the half-maximal effective concentration ($Ce_{50}$) of remifentanil in the prevention of plate removal pain under sedation using dexmedetomidine. Methods: The study evaluated 18 patients, between 18 and 35 years of age, scheduled for elective surgery. Remifentanil infusion was initiated after sedation using dexmedetomidine, and started at a dose of 1.5 ng/mL on the first patient via target-controlled infusion (TCI). Patients received a loading dose of $1.0{\mu}g/kg$ dexmedetomidine over 10 min, followed by a maintenance dose of $0.7{\mu}g/kg/h$. When the surgeon removed the plate, the patient Modified Observer's Assessment of Alertness/Sedation (MOAA/S) score was observed. Results: The Ce of remifentanil ranged from 0.9 to 2.1 ng/mL for the patients evaluated. The estimated effect-site concentrations of remifentanil associated with a 50% and 95% probability of reaching MOAA/S score of 3 were 1.28 and 2.51 ng/mL, respectively. Conclusion: Plate removal of maxilla can be successfully performed without any pain or adverse effects by using the optimal remifentanil effect-site concentration ($Ce_{50}$, 1.28 ng/mL; $Ce_{95}$, 2.51 ng/mL) combined with sedation using dexmedetomidine.

퇴적물 제거가 수질과 식물플랑크톤, 저서성 대형무척추동물에 미치는 영향 (Effects of Sediment Removal on Water Quality, Phytoplankton Communities and Benthic Macroinvertebrate)

  • 윤석제;김헌년;김용진;이은정;변명섭;이병천;이재관
    • 한국물환경학회지
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    • 제34권3호
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    • pp.301-307
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    • 2018
  • This study investigated the effects of sediment removal on water quality and phytoplankton development by setting up mesocosms at Uiam Lake, South Korea, and analyzing the environmental parameters and phytoplankton communities between June and October 2015. The comparison between testbed without sediment removal (TB-1) and testbed after sediment removal (TB-2) gave similar values for water temperature, pH, dissolved oxygen (DO), and electrical conductivity. Nevertheless, the average electrical conductivities of the two testbeds were $139{\mu}S/cm$ and $135{\mu}S/cm$, which were lower than the value obtained from the external control point (TB-con; $154{\mu}S/cm$). The small difference in total phosphorus (TP) and total nitrogen (TN) concentrations between the two testbeds implied that sediment removal did not greatly reduce nutrients; however, the phytoplankton cell count had decreased by approximately 37 % in TB-2 (average 1,663 cells/mL) compared to TB-1 (average 2,625 cells/mL). Compared to TB-con, the phosphorus and nitrogen concentrations of the two testbeds had decreased by 39 % and 30 %, respectively, whereas the phytoplankton abundance had decreased by up to 73 %, perhaps because of the blocked inflow of nutrients and the stabilized body of water caused by the installation of the mesocosm. The concentration of geosmin was lower in testbeds than in the external point, because installation of the structures had reduced the cyanobacteria biomass.

Cr(VI) Resistance and Removal by Indigenous Bacteria Isolated from Chromium-Contaminated Soil

  • Long, Dongyan;Tang, Xianjin;Cai, Kuan;Chen, Guangcun;Shen, Chaofeng;Shi, Jiyan;Chen, Linggui;Chen, Yingxu
    • Journal of Microbiology and Biotechnology
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    • 제23권8호
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    • pp.1123-1132
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    • 2013
  • The removal of toxic Cr(VI) by microorganisms is a promising approach for Cr(VI) pollution remediation. In the present study, four indigenous bacteria, named LY1, LY2, LY6, and LY7, were isolated from Cr(VI)-contaminated soil. Among the four Cr(VI)-resistant isolates, strain LY6 displayed the highest Cr(VI)-removing ability, with 100 mg/l Cr(VI) being completely removed within 144 h. It could effectively remove Cr(VI) over a wide pH range from 5.5 to 9.5, with the optimal pH of 8.5. The amount of Cr(VI) removed increased with initial Cr(VI) concentration. Data from the time-course analysis of Cr(VI) removal by strain LY6 followed first-order kinetics. Based on the 16S rRNA gene sequence, strain LY6 was identified as Pseudochrobactrum asaccharolyticum, a species that had never been reported for Cr(VI) removal before. Transmission electron microscopy and energy dispersive X-ray spectroscopy analysis further confirmed that strain LY6 could accumulate chromium within the cell while conducting Cr(VI) removal. The results suggested that the indigenous bacterial strain LY6 would be a new candidate for potential application in Cr(VI) pollution bioremediation.

2단 망간모래여과에 의한 고농도 망간 처리 (Removal of High Concentration Manganese in 2-stage Manganese Sand Filtration)

  • 김충환;윤종섭;임재림;김성수
    • 상하수도학회지
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    • 제21권4호
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    • pp.503-508
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    • 2007
  • Small scale D-water treatment plant(WTP) where has slow sand filtration was using raw water containing high concentration of manganese (> 2mg/l). The raw water was pre-chlorinated for oxidation of manganese and resulted in difficulty for filtration. Thus, sometimes manganese concentration and turbidity were over the water quality standard. Two stage rapid manganese sand filtration pilot plant which can treat $200m^3/d$ was operated to solve manganese problem in D-WTP. The removal rate of manganese and turbidity were about 38% and 84%, respectively without pH control of raw water. However, when pH of raw water was controlled to average 7.9 with NaOH solution, the removal rate of manganese and turbidity increased to 95.0% and 95.5%, respectively and the water quality of filtrate satisfied the water quality standard. Manganese content in sand was over 0.3mg/g which is Japan Water Association Guideline. The content in upper filter was 5~10 times more than that of middle and lower during an early operation but the content in middle and lower filter was increased more and more with increase of operation time. This result means that the oxidized manganese was adsorbed well in sand. Rapid manganese sand filter was backwashed periodically. The water quality of backwash wastewater was improved by sedimentation. Thus, turbidity and manganese concentration decreased from 29.4NTU to 3.09NTU and from 1.7mg/L to 0.26mg/L, respectively for one day. In Jar test of backwash wastewater with PAC(Poly-aluminum chloride), optimum dosage was 30mg/L. Because the turbidity of filtrate was high as 0.76NTU for early 5 minute after backwash, filter-to-waste should be used after backwash to prevent poor quality water.

혐기성소화 시 발생되는 $H_2S$ 감소에 관한 연구 (Decrease of the Hydrogen Sulfide($H_2S$) in the Produced Biogas by the Anaerobic Digestion)

  • 홍종순;김재우
    • 환경위생공학
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    • 제24권4호
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    • pp.80-89
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    • 2009
  • In the organic waste, food waste is the most difficult controls. In the study, food waste was treatmented to removal only the dockage. To decrease the hydrogen sulfide($H_2S$) in the produced biogas, iron chloride put in the anaerobic digester. Respectively treatment quantity of the food waste, content of the methane($CH_4S$) gas in the biogas, produced gases quantity, put in the quantity of the Iron chloride, pH, TS, Alkalinity, VFA, Ammonia. The results obtained from the experiment are as follows: 1. The produced biogases quantity/the treatment quantity of the food waste was $83.82{\sim}129.41m^3/ton$. 2. The content of the hydrogen sulfide($H_2S$) in the produced biogas is below of the 500ppm. The iron chloride put in the anaerobic digester. 200~300kg of the iron chloride put in the anaerobic digester at the steady-state. 400~850kg of the iron chloride put in the anaerobic digester at the unsteady-state. 3. Factor of the operator was the pH: 7.7~8.4, content of mathane: 55~65%. 4. TS(total solid) of the digestor sludge was 17~20%, Alkalinity was 38,500~41,750ppm, VFA(Volatile Fatty Acids) was 2,800~2,420ppm, Ammonia was 4,300~3,650ppm.

Sorption of Chromium Ions from Aqueous Solution onto Chemically Activated Carbons Developed from Maize Cobs

  • Youssef, A.M.;El-Nabarawy, Th.;Shouman, Mona A.;Khedr, S.A.
    • Carbon letters
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    • 제9권4호
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    • pp.275-282
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    • 2008
  • Chemically activated carbons were prepared from maize cobs, using phosphoric acid of variable concentration. The textural parameters of the activated carbons were determined from the nitrogen adsorption isotherms measured at 77 K. The chemistry of the carbon surface was determined by measuring the surface pH, the pHPZC and the concentration of the carbon - oxygen groups of the acid type on the carbon surface. Kinetics of Cr(VI) sorption/reduction was investigated at 303 K. Two processes were investigated in terms of kinetics and equilibrium namely; Cr(VI) removal and chromium sorption were studied at various initial pH (1-7). Removal of Cr(VI) shows a maximum at pH 2.5. At pH<2.5, sorption decreases because of the proton competition with evolved Cr(III) for ion exchange sites. The decrease of sorption at pH>2.5 is due to proton insufficiency and to the decrease of the extent of Cr(VI) reduction. The chemistry of the surface of activated carbon is an important factor in determining its adsorption capacity from aqueous solutions particularly when the sorption process involves ion exchange.

자기분리가 가능한 지르코늄 자성 흡착제의 합성과 인 흡착 특성 (Synthesis and Phosphorus Adsorption Characteristics of Zirconium Magnetic Adsorbent Having Magnetic Separation Capability)

  • 임대석;김은형;김동락;이태구;임학상
    • 상하수도학회지
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    • 제26권3호
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    • pp.431-442
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    • 2012
  • The purpose of this study, is to separate magnetic separation devices using permanent magnets by using magnetization characteristics remaining in treated water after adsorption and synthesizing phosphorus adsorbent capable of magnetic separation for efficient removal of phosphorus. The synthesis of the adsorbent which set Zirconium(Zr) having high friendly features for phosphorus as an element, and by synthesizing Iron Oxide($Fe_3O_4$, another name of $Fe_3O_4$ is magnetite) being able to grant magnetism to Zirconium Sulfate($Zr(SO_4)_2$), zirconium magnetic adsorbent(ZM) were manufactured. In order to consider the phosphorus adsorption characteristics of adsorbent ZM, batch adsorption experiment was performed, and based on the results, pH effect, adsorption isotherm, adsorption kinetics, and magnetic separation have been explore. As the experiment result, adsorbent ZM showed a tendency that the adsorption number was decreased rapidly at pH 13; however, it was showed a high amount of phosphorus removal in other range and it showed the highest amount of phosphorus removal in pH 6 of neutral range. In addtion, the Langmuir adsorption isotherm model is matched well, and D-R adsorption isotherm model is ranged 14.43kJ/mol indicating ion exchange mechanism. The result shown adsorption kinetics match well to the Pseudo-second-order kinetic model. The adsorbent ZM's capablility of regenerating NaOH and $H_2SO_4$, was high selectivity on the phosphorus without impacts on the other anions. The results of applying the treated water after adsorption of phosphorus to the magnetic separation device by using permanent magnets, shows that capture of the adsorbent by the magnetization filter was perfect. And they show the possibility of utilization on the phosphorus removal in water.