• 제목/요약/키워드: $H_2PO_4^-$

검색결과 1,234건 처리시간 0.033초

궁궐(宮闕) 정전(正殿)에서 기둥과 공포의 구조적(構造的) 비례특성(比例特性)에 관한 연구(硏究) (A study on the Characteristics of Structural Proportion of Pillar and 'Kong-po' in 'Main Hall of Royal Palace(正殿)' of the Royal Palace)

  • 박언곤;최효식
    • 건축역사연구
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    • 제14권1호
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    • pp.71-87
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    • 2005
  • 4 royal palaces are currently remained from capital city (Seoul) of 'Cho-Sun(朝鮮)' period. In these palaces, 'Main hall of Royal Palace(正殿)' is the center of the Royal Palaces. The 'Main hall of Royal Palace' of the Royal Palace was the best building of that time. Therefore there were many studies about the 'Main hall of Royal Palace'. But these studies were individual studies of these 'Main hall of Royal Palace'. Therefore, this study is to analyze and compare 4 'Main hall of Royal Palace' of the Royal palaces. It is to study the proportion regarding the Diameter of the pillar, the Height, the pillar and pillar Interval's Distance, and the arrangement of 'Kong-Po(bracket sets)'. With these studies, it is to prove that the 'Main hall of Royal Palace' is the building which high construction technique of this time is expressed. Result of this study is as followings; First, the proportion of pillar height(H) to its diameter(D) average from H=8.0 to 8.5D. Only the Myeong-Jeong-Jeon omitted the 'Go-Ju(高柱)' in the 'Toi-Kan (退間)' to place Ea-Jwa(御座). Second, Second, the proportion of diameter of the pillar of 'Eoi-Bu-Pyeong-Ju(外部平柱)' and 'Nae-Jin-Go-Ju(內陣高柱)' average D1(Diameter of 'Eoi-Bu-Pyeong-Ju') =0.91D2 (Diameter of 'Nae-Jin-Go-Ju'). In regards to the height, the single floor 'Main hall of Royal Palace' and double floor 'Main hall of Royal Palace' seems to be different. The height proportion of the double floor 'Main hall of royal palace' is H1(Height of 'Eoi-Bu-Pyeong-Ju')=0.34H2(Height of 'Nae-Jin-Go-Ju') and single floor 'Main hall of Royal Palace' has a proportion of H1=0.62H2. Third, in Geun-Jeong-Jeon, with the proportion of height and diameter of the pillar, interval's distance between pillars and diameter, the pillar interval distance and height, of 'Ea-kan(御間)' from the 'Toi-Kan' is different from 'Main hall of Royal Palace'. This is because the structure of 'Toi-Kan' of Geun-Jeong-Jeon is not stable. In order to reinforce this, 'Gui-Go-Ju(隅高柱)' of the Geun-Jeong-Jeon jut out $4{\sim}7%$ more compared to In-Jeong-Jeon. Fourth, when comparing double floor 'Main hall of royal palace' of Geun-Jeong-Jeon and In-Jeong-Jeon, based on distance of 'Eoi-Bu-Pyeong-Ju' and 'Nae-Jin-Go-Ju' of lower level, the 'Sang-Bu-Pyeong-Ju(上部平柱)' of Geun-Jeong-Jeon jut out $4{\sim}7%$ more compared to the In-Jeong-Jeon and also It becomes thicker. Fifth, the arrangement of 'Kong-Po' on the front row of 'Gan(間)' had to do with the change of side 'Gan'. Even though the Geun-Jeong-Jeon and the In-Jeong-Jeon were double floors, the arrangement of the 'Kong-Po' is different because the number of side bay is different.

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Ganoderma lucidum으로부터 Polygalacturonase의 생산 (Production of Polygalacturonase from Ganoderma lucidum)

  • 윤숙;김명곤;홍재식;김명숙
    • 한국균학회지
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    • 제22권4호
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    • pp.286-297
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    • 1994
  • Ganoderma lucidum이 생산하는 polygalacturonase의 유용 활용 방안을 위한 최적 생산조건을 검토한 결과는 다음과 같다. Polygalacturonase 생산을 위한 최적 배양조건은 $30^{\circ}C$, pH5.5에서 14일이었다. Polygalacturonase 생산을 위한 최적 영양조건은 pectin 10 g, soluble starch 10 g, yeast extract 1 g, peptone 2 g, phenylalanine 1 g, $KH_2PO_4$ 2 g, $MgSO_4$ 0.2 g, $CaCI_2$ 50 mg, $thiamin{\cdot}HCI\;100{\mu}g$, D.W. 1000ml이었다.

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수용액 분사법에 의한 용융아연 도금강판의 미니스팡글 형성 (Minispangling of a Hot Dip Galvanized Sheet Steel by a Solution Spray Method)

  • 김종상;전선호;박정렬
    • 한국표면공학회지
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    • 제27권3호
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    • pp.149-157
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    • 1994
  • The formation of spangles on a hot dip galvanized sheet steel by spray cooling the molten zinc coating with air, water and 2.0wt% $NH_4H_2PO_4$ solution has been studied performing laboratory experiments, and their coating properties have been evaluated. Minimized spangles were easily formed by mist spraying the solution for 1 second at the low nozzle spray pressure onto the molten zinc at 420~$422^{\circ}C$ because the solute $NH_4H_2PO_4$ in the sprayed solution imparted a highly rapid cooling effect to the coating through its endothermic de-composition reactions and because the decomposed products acted as numerous nucleation sites for the mini-mized spangles on the coating. Good surface appearances sand sound coating properties were obtained on this coating. Only regular spangles were formed on the coating by the forced convective air cooling. At the high nozzle spray pressure, zero spangles were formed on the coating by the pure water spray cooling. However, the coating had a dull and rough surface with craters sand cracks.

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수소이온 흡착밀도의 고찰을 통한 고농도 알루미나 현탁액의 제조 (Preparation of Highly Concentrated Alumina Suspension through Investigstion of Proton Adsorption Density)

  • 김덕준;김환
    • 한국세라믹학회지
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    • 제33권2호
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    • pp.163-168
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    • 1996
  • Measurements of proton adsorption density have been conducted in preparing alumina suspensions with aqueous solutions of HCL, HNO3, H2SO4 and H3PO4 And effects of anion acid concentration proton adsorption density and solid loading on the viscosity of the alumina suspensions have been investigated. Aqueous solutions of HCl. or HNO3 were suitable for the preparation of highly concentrated suspensions as the generation of surface charge on alumina particles was depressed by the specific adsorption of {{{{ {SO }`_{4 } ^{2- } }} and {{{{ { PO}`_{4 } ^{3- } }} Optimum conditions for maximizing solid loading were dependent upon proton adsorption density and acid concentration.

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Rhizopus japonicus S-62가 생성(生成)하는 단백질분해효소(蛋白質分解酵素)에 관(關)한 연구(硏究) (Studies on the Proteolytic Enzyme Produced by Rhizopus japonicus S-62)

  • 정만재
    • 한국식품과학회지
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    • 제9권1호
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    • pp.31-35
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    • 1977
  • Rhizopus japonicus S-62가 생산(生産)하는 acid protease에 관(關)한 연구(硏究)로서, 효소(酵素)의 생산조건(生産條件) 및 조효소(粗酵素)의 특성(特性)을 검토(檢討)하여 다음과 같은 결과(結果)를 얻었다. 1. 밀기울에 배양(培養)하는 경우 최적배양(最適培養) 시간(時間)은 48시간(時間) 첨수량(添水量)은 $100{\sim}120%$이었다. 2. 각종(各種) 배지중(培地中) 밀기울 배지(培地)가 가장 우수(優秀)하였다. 3. 밀기울에 sucrose, fructose, $NH_4Cl$, $NaH_2PO_4$의 첨가(添加)는 protease생산(生産)을 크게 증가(增加)시켰다. 4.본효소(本酵素)의 작용최적(作用最適)pH는 $2.4{\sim}2.6$, Opt. temp.는 약(約) $40^{\circ}C$, 안정(安定) pH 범위(範圍)는 $2.5{\sim}5.0$이고, $40^{\circ}C$이하(以下)에서는 안정(安定)하나 그 이상(以上)의 온도(溫度)에서는 급격(急激)하게 불활성화(不活性化)되었다.

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A STUDY ON ADSORPTION AND DESORPTION BEHAVIORS OF 14C FROM A MIXED BED RESIN

  • Park, Seung-Chul;Cho, Hang-Rae;Lee, Ji-Hoon;Yang, Ho-Yeon;Yang, O-Bong
    • Nuclear Engineering and Technology
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    • 제46권6호
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    • pp.847-856
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    • 2014
  • Spent resin waste containing a high concentration of $^{14}C$ radionuclide cannot be disposed of directly. A fundamental study on selective $^{14}C$ stripping, especially from the IRN-150 mixed bed resin, was carried out. In single ion-exchange equilibrium isotherm experiments, the ion adsorption capacity of the fresh resin for non-radioactive $HCO_3{^-}$ ion, as the chemical form of $^{14}C$, was evaluated as 11mg-C/g-resin. Adsorption affinity of anions to the resin was derived in order of $NO_3{^-}$ > $HCO_3{^-}{\geq}H_2PO_4{^-}$. Thus the competitive adsorption affinity of $NO_3{^-}$ ion in binary systems appeared far higher than that of $HCO_3{^-}$ or $H_2PO_4{^-}$, and the selective desorption of $HCO_3{^-}$ from the resin was very effective. On one hand, the affinity of $Co^{2+}$ and $Cs^+$ for the resin remained relatively higher than that of other cations in the same stripping solution. Desorption of $Cs^+$ was minimized when the summation of the metal ions in the spent resin and the other cations in solution was near saturation and the pH value was maintained above 4.5. Among the various solutions tested, from the view-point of the simple second waste process, $NH_4H_2PO_4$ solution was preferable for the stripping of $^{14}C$ from the spent resin.

대동맥 차단시 저온 산소화 심정지액이 심근보호에 미치는 영향 (An Experimental Study on the Effect of Hypothermic Oxygenated Cardioplegic Solution on Myocardial Protection during Prolonged Aortic Cross-clamping)

  • 왕영필;이홍균
    • Journal of Chest Surgery
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    • 제18권4호
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    • pp.759-770
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    • 1985
  • This study was experimentally undertaken to evaluate the effect of hypothermic oxygenated cardioplegic solution on myocardial protection during prolonged aortic cross clamping under cardiopulmonary bypass. Dogs were divided into two groups control group [received hypothermic unoxygenated cardioplegic solution] and experimental group [received hypothermic oxygenated cardioplegic solution]. Coronary sinus effluent was obtained at once and 30, 60, 90 minutes after cross-clamping for the determination of pH, PCO2,PO2 and lactate level during the infusion of cardioplegic solution and myocardial biopsies were obtained after cessation of 90 minutes of aortic cross-clamping. The results obtained were as follows: 1. There was no significant differences in the pH and PCO2 between the oxygenated and unoxygenated cardioplegic solution but the PO2 of the oxygenated solution was 4 times greater than unoxygenated solution, and also the oxygenated solution had a significantly greater oxygen content [2.020.05 ml 02/min] and had much more oxygen delivery than unoxygenated solution. 2. The myocardial oxygen consumption and the myocardial oxygen extraction in oxygenated group were 1.63 ml 02/100 ml and 67.32% respectively, which was greater than those in unoxygenated group. 3. Regarding to pH and PCO2 of coronary sinus effluent, there was no significant differences between two groups in early period of infusion of cardioplegic solution, but the pH shifted to acidosis from 60 minutes, PCO2 increased from 90 minutes of aortic cross-clamping, and PO2 markedly decreased from 90 minutes of aortic cross-clamping in unoxygenated group. 4. The lactate concentration of coronary sinus effluent revealed relatively normal in both groups, but showed slight increase up to 27.54.56 mg/100 ml at 90 minutes of aortic cross-clamping in unoxygenated group. 5. On electron microscopic study, the ultrastructural integrity of myocardial cells in oxygenated group was well preserved within 90 minutes. Slight swelling and deformity of mitochondria, interfibrillar widening, and disarrangement of myofibrils were observed at 90 minutes after aortic cross-clamping in unoxygenated group. From these results, the use of hypothermic oxygenated cardioplegic solution seemed to be effective and better method for the preservation of ischemic myocardium during the prolonged aortic cross-clamping.

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NaF 전해용액을 이용한 양극산화에 의한 타이타늄 표면의 나노튜브구조의 형성에 관한 연구 (Investigation on Formation of Nanotube Titanium Oxide Film by Anodizing on Titanium in NaF Electrolytes)

  • 임현필;박남순;박상원
    • 구강회복응용과학지
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    • 제25권2호
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    • pp.183-190
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    • 2009
  • 본 연구의 목적은 NaF와 $H_3PO_4$를 사용하여 양극산화과정을 통해 나노튜브 제작 조건을 찾는 것이다. 절삭된 직경 15 mm, 두께 1.5 mm의 티타늄 디스크를 양극에, 백금을 음극에 연결하고 전극간의 거리는 10 mm가 되도록 하였다. $H_3PO_4$와 NaF 용액을 전해질로 하여 양극산화를 시행하였는데 전압, 전해질 농도, 산화시간을 달리하여 티타늄 디스크에 나노튜브를 형성하였다. 양극산화 후 24시간 동안 증류수로 세척한 후 24시간 동안 $40^{\circ}C$ 오븐에서 건조하고 시편의 표면구조 형상을 관찰 분석하였다. 실험 결과 0.5 wt % NaF에서 전압과 시간이 증가함에 따라 pore 형태의 초기 나노튜브 형성되었다. 1.0 wt % NaF에서 20 V, 20 분과 25 분에서 나노튜브가 생성되었고, 30 V에서 튜브의 형태가 커지면서 터지는 양상을 보였다. 2.0 wt % NaF에서 전압과 시간에 상관없이 적절한 나노튜브형태가 형성되지 않았다. $1M\;H_3PO_4$, 1.0 wt % NaF 전해용액, 20 V, 20분 양극산화 조건에서 티타늄 디스크 상에 가장 잘 정렬된 형태의 나노튜브 구조가 형성되었다. 양호한 형태의 나노튜브 형성을 위해서는 전해질의 종류에 따라 적절한 농도, 전압, 시간의 형성조건이 필요할 것으로 사료된다.

호알칼리성, 고온성 Bacillus sp. TA-11 에 의한 $\beta$-Fructofuranosidase의 생산 (Producton of $\beta$-Fructofuranosidase from Alkalophilic, Thermophilic Bacillus sp. TA-11)

  • 최영준;이종수
    • 한국미생물·생명공학회지
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    • 제23권2호
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    • pp.197-202
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    • 1995
  • The conditions for the $\beta$-fructofuranosidase production from alkalophilic, thermophilic Bacillus sp. TA-11 were investigated. The maximal enzyme production was obtained when the strain was cultured at 50$\circ$C for 36 hrs with batch culture in the optimal medium containing 1.0% sucrose, 0.6% yeast extract, 0.1% each of KH$_{2}$PO$_{4}$, K$_{2}$HP0$_{4}$, NaH$_{2}$PO$_{4}$, and initial pH 9.5, and the final enzyme activity under the above condition was 102 units per ml of cell free extract.

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Comparison of Various Single Chemical Extraction Methods for Predicting the Bioavailability of Arsenic in Paddy Soils

  • Go, Woo-Ri;Jeong, Seon-Hee;Kunhikrishnan, Anitha;Kim, Gyeong-Jin;Yoo, Ji-Hyock;Cho, Namjun;Kim, Kwon-Rae;Kim, Kye-Hoon;Kim, Won-Il
    • 한국토양비료학회지
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    • 제47권6호
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    • pp.464-472
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    • 2014
  • The Codex Committee of Contaminants in Food (CCCF) has been discussing a new standard for arsenic (As) in rice since 2010 and a code of practice for the prevention and reduction of As contamination in rice since 2013. Therefore, our current studies focus on setting a maximum level of As in rice and paddy soil by considering bioavailability in the remediation of As contaminated soils. This study aimed to select an appropriate single chemical extractant for evaluating the mobility of As in paddy soil and the bioavailability of As to rice. Nine different extractants, such as deionized water, 0.01 M $Ca(NO_3)_2$, 0.1 M HCl, 0.2 M $C_6H_8O_7$, 0.43 M $HNO_3$, 0.43 M $CH_3COOH$, 0.5 M $KH_2PO_4$, 1 M HCl, and 1 M $NH_4NO_3$ were used in this study. Total As content in soil was also determined after aqua regia digestion. The As extractability of the was in the order of: Aqua regia > 1 M HCl > 0.5 M $KH_2PO_4$ > 0.43 M $HNO_3$ > 0.2 M $C_6H_8O_7$ > 0.1 M HCl > 0.43 M $CH_3COOH$ > deionized water > 1 M $NH_4NO_3$ > 0.01 M $Ca(NO_3)_2$. Correlation between soil extractants and As content in rice was in the order of : deionized water > 0.01 M $Ca(NO_3)_2$ > 0.43 M $CH_3COOH$ > 0.1 M HCl > 0.5 M $KH_2PO_4$ > 1 M $NH_4NO_3$ > 0.2 M $C_6H_8O_7$ > 0.43 M $HNO_3$ > 1M HCl > Aqua regia. BCF (bioconcentration factor) according to extractants was in the order of : 0.01M $Ca(NO_3)_2$ > 1 M $NH_4NO_3$ > deionized water > 0.43 M $CH_3COOH$ > 0.1 M HCl > 0.43 M $HNO_3$ > 0.2 M $C_6H_8O_7$ > 0.5 M $KH_2PO_4$ > 1 M HCl > Aqua regia. Therefore, 0.01 M $Ca(NO_3)_2$ ($r=0.78^{**}$) was proven to have the greatest potential for predicting As bioavailability in soil with higher correlation between As in rice and the extractant.