• Title/Summary/Keyword: $H_2$ yield

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Effect of Horse Manure Compost Application Levels on the Forage Productivity of Italian Ryegrass and Volcanic Ash Soil Characteristics (마분 퇴비 시용 수준이 이탈리안 라이그라스의 조사료 생산성과 화산회토양 성분에 미치는 영향)

  • Yoo, Ji-Hyun;Park, Nam-Geon;Hwang, Won-Uk;Woo, Jae-Hoon;Ji, Hee-Chung;Yang, Byoung-Chul
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.41 no.2
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    • pp.96-101
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    • 2021
  • This study was conducted to determine the effect of horse manure compost application on Italian ryegrass (IRG) yield and volcanic ash soil characteristics. Because the number of horses in Korea is growing, the amount of horse manure is growing. Jeju island, where about 55 % of the horses live, is composed of volcanic ash soil. This study was conducted for about 7 months. Sowing was conducted on October 2019. Harvesting was conducted at heading stage(2020.5.). Five treatments were established based on the horse manure compost composition. These were 100 % chemical fertilizer (CF), the combination of 50 % horse manure and 50 % chemical fertilizer (combination), horse manure with 50 % nitrogen (HM 50 %), horse manure with 100 % nitrogen (HM 100 %), and horse manure with 150 % nitrogen (HM 150 %). The plant height and dry matter yield were investigated to determine the forage yield and the soil characteristics of pH, total nitrogen, available phosphate, and organic matter were analyzed. The plant heights in the CF, combination, and HM 150 % treatments were 147.8 cm, 144.3 cm, and 147.1 cm respectively (Table 2). Dry matter yield in the CF treatment was about 23,807 kg/ha, which tended to be the highest dry matter yield. HM 150 % and the combination treatment were about 18,804 and 18,455 kg/ha, respectively, which tended to be the highest dry matter yield of the treatments amended with horse manure compost. The dry matter yield of the HM 100 % and HM 50 % treatments was about 15,801 kg/ha and 14,446 kg/ha, respectively (Table 2). The pH of the surface soil tended to increase after the experiment. The soil pH of the HM 150 % treatment was significantly higher than the soil pH of the other treatments. The pH was affected by the amount of horse manure compost, with a pH of 8.1. The available phosphate in the treatments in which horse manure compost was added was higher than the available phosphate in the CF treatment. And the available phosphate in the HM 150 % treatment was significantly higher than the available phosphate in the other treatments (p < 0.05)(Table 3). These results suggest that 50 % horse manure should be applied to IRG as the basal fertilizer and the remaining 50 % should be chemical fertilizer as the top fertilizer. This can provide the proper IRG dry matter yield with less effect on volcanic ash soil.

The Influence of Pressure and Time on the Preparation of Gumiganghwal-tang Decoctions

  • Kim, Jung-Hoon;Kim, Seong-Sil;Shin, Hyeun-Kyoo;Seo, Chang-Seob
    • The Journal of Korean Medicine
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    • v.34 no.4
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    • pp.12-20
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    • 2013
  • Objectives: This study compared Gumiganghwal-tang (GGT) decoctions produced using different pressure levels for various extraction times to determine the optimal extraction conditions through hydrogen ion concentration (pH), total soluble solids content (TSSC), extraction yield, and content of chemical compounds. Methods: Decoctions were prepared by the pressure levels of 0 or $1kgf/cm^2$ for 30-180 min. The pH and TSSC were measured, the extraction yield was calculated, and the amounts of the chemical compounds were determined using high performance liquid chromatography. Results: The higher pressure and longer extraction time decreased the pH value, while those conditions increased TSSC and extraction yield: the decoction produced in 180 min by pressurized method showed the minimum value of pH, but maximum values of TSSC and extraction yield. The chemical compounds showed higher amounts in decoctions produced by non-pressurized methods than pressurized methods and their amounts were decreased over the peak extraction time in both pressurized and non-pressurized methods. The results of regression analysis confirmed the correlative influences of the pressure and extraction time on pH, TSSC, and extraction yield. Conclusions: This study suggests that pressure and extraction time influence the compositional constituents in GGT decoctions, and the non-pressurized method for 120 min should be chosen as the optimal extraction condition for the preparation of GGT decoction.

Characteristics of Acid-hydrolysis and Ethanol Fermentation of Laminaria japonica (다시마의 산 가수분해와 에탄올 발효 특성)

  • Na, Choon-Ki;Song, Myoung-Ki
    • Korean Chemical Engineering Research
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    • v.50 no.1
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    • pp.141-148
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    • 2012
  • In order to study the utilization of brown seaweed Laminaria japonica as an alternative renewable feedstock for bioethanol production, the properties of acid hydrolysis and ethanol fermentation were investigated. The acid hydrolysis enhanced the final yield of fermentable sugars, which led great increase of ethanol productivity. The maximum yield of reducing sugars reached 135 mg/g-dry Laminaria japonica after 1.0N sulfuric acid-hydrolysis at $130^{\circ}C$ for 6 h. The Saccharomyces cerevisiae (ATCC 24858) could ferment $C_6$-sugars like glucose, galactose and mannose into ethanol, but not $C_5$-sugars like arabinose and xylose. Optimal fermentation time varied with sugars; 48 h for glucose, 72 h for galactose, and 96 h for mannose. Nevertheless, the ethanol yield from the hydrolysate reached 242 mg/g-dry Laminaria japonica after fermentation by the S. cerevisiae at $35^{\circ}C$ for 96 h, which corresponds to approximately 4 times more than the theoretical yield from total reducing sugars in the hydrolysates. It indicates that the non-reducing sugars or oligosaccharides dissolved in the hydrolysate played an important role in producing bioethanol. The ethanol concentration linearly increased from 2.4 to 9.2 g/L, while the ethanol yield per dry weight of biomass decreased from 242 to 185 mg/g, with increasing the ratio of biomass to acid solution from 1 to 5% (w/v). The bioethanol yield estimated was approximately 7,400~9,600 kg/ha/year, and indicated that Laminaria japonica is a promissing feedstock for bioethanol production.

Growth and Chemical Components of Reciprocally Grafted Tobacco Cultivars between Hyangchio and L. A. Burley 21 (향초와 L. A. Burley 21의 상호접목이 담배의 생육 및 화학적 특성에 미치는 영향)

  • 이상하;제상률;김길웅
    • Journal of the Korean Society of Tobacco Science
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    • v.4 no.2
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    • pp.11-16
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    • 1982
  • To investigate the effect of reciprocal grafting between Hyangchio (H) and L. A. Burley 21 (L.A), one a higher producer of nicotine and low yield, the other, a low producer of nicotine and high yield, growth of various parts of each variety and chemical constituents of these parts were evaluated. The results were as follows : The growth of H/H graft was depressed when compared to hyangchio and H/L. A. and L. A. Burley 21 showed most vigorous growth plants having L. A. Burley 21 top. The amount of total alkaloids were low in leaves and stems of plants having L. A. Burley 21 roots (L. A., L. A./L. A., H/L. A.). Plants having Hyangchio roots (H, L. A./H) were high in total alkaloids. The contents of reducing sugar were high in plant having Hyangchio top compared to L. A. Burley 21 tops, but there were not diffences in contents of ether extracts among all treatments.

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Effect of SOx on HC-SCR Kinetics over Ag/Al2O3 Catalyst (SOx 함유 HC-SCR에서 산처리 Ag/Al2O3 촉매의 반응 특성)

  • Lee, Ju-Heon;Park, Jeong-Whan;Kim, Seong-Soo;Yoo, Seung-Joon;Kim, Jin-Gul
    • Journal of Hydrogen and New Energy
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    • v.22 no.5
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    • pp.714-720
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    • 2011
  • Ethanol was used as reducing agent to remove $NO_x$ exhaust from the stationary source. Pre-treatment with sulfuric acid over $Ag/Al_2O_3$ catalyst was dedicated to overcome the $SO_2$ poisoning effect. The $NO_x$ reduction experiment was performed under the simulated condition of power plant The increased surface area with higher CPSI devoted to increase de-$NO_x$ yield. De-$NO_x$ yield of the $NO_x$ exhaust containing 20 ppm of $SO_2$ increased after acid treatment with 0.7% $H_2SO_4$ over 4.0% $Ag/Al_2O_3$, where the increased dispersion of Ag found from the results of XRD and XPS was the dominant factor for the increased de-$NO_x$ yield. However, the reason for the decreased de-$NO_x$ yield with the acid treatment of higher concentration (1.0% and 2.0%) of $H_2SO_4$ was found to be due to the formation of $Ag_2SO_4$ crystallites found from XRD result. Acid-treated $Ag/Al_2O_3$ catalyst showed maximum de-$NO_x$ yield at higher temperature than non-treated $Ag/Al_2O_3$ catalyst did.

Synthesis of Maltosyl-$\beta$-Cyclodextrin through the Reverse Reaction of Pullulanase (Pullulanase의 Reverse Reaction을 이용한 Maltosyl-$\beta$-Cyclodextrin의 합성)

  • 한일근;이용현
    • Microbiology and Biotechnology Letters
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    • v.19 no.5
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    • pp.444-449
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    • 1991
  • Synthesis of maltosyl-$\beta$-cyclodextrin using maltose ($G_2$) and $\beta$-cyclodextrin ($\beta$-CD) as substrates through the reverse reaction of pullulanase was investigated. The optimal conditions for the condensation reaction were as below: mixing ratio of maltose to $\beta$-CD of 12.7, mixed substrate concentration of 70% (w/w, 70 g/100 ml $H_2O$), and amount of pullulanse of 350 units/100 ml. The concentration of synthesized maltosyl-P-CD concentration was reached up to 2.31 g/100 rnl at above reaction conditions, which corresponded the conversion yield of 43% (w/w, g of branched-CD/g of CD). The synthesis of maltosyl-$\alpha >\gamma >\beta$-CD was also attempted, and conversion yield was in the order of a>y>J3-CDs. Condensation reaction between various maltooligosaccharides ($G-1\sim G_6$ showed that maltose was the most effective oligorner for condensation reaction with $\beta$-CD. To increase the conversion yield various alcohols were added into the reaction mixture, amyl alcohol was found to be the most acceptable alcohol for increasement of convesion yield which increased from 43.0 to 83.0% upon addition of same volume of amyl alcohol into the reaction mixture.

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Biomass, Nitrogen, and Phosphorus Productivities of Green Manure by Barley and Hairy Vetch Mixtures (보리와 헤어리베치 혼파재배에 따른 녹비작물 수량과 질소와 인산의 생산성)

  • Lee, Cho-Rong;Kim, Pil-Joo;Oh, Yura;Park, Choong-Bae;Park, Kwang-Lai;Nam, Hong-Sik;Park, Gi-Chun
    • Korean Journal of Organic Agriculture
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    • v.26 no.4
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    • pp.719-729
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    • 2018
  • Green manure crops can be efficient replacements of high nutrient materials such as livestock compost, organic fertilizers, etc. in organic farming. Grass-legume mixtures or mixed cropping of legumes with non-legumes can aid in abating the shortcomings of each plant type under monoculture (i.e. legumes have low biomass yields while grasses are poor at fixing nitrogen). This study was conducted to investigate the effects of barley (B) and hairy vetch (H) mixtures on green manure yield in nutrient accumulated organic upland soils of Korea. In one cropping season, single crops of barley and hairy vetch (Barley: 160 kg/ha, Hairy vetch: 90 kg/ha) as well as mixtures of both crops at different seeding rates (B66:H33, B33: H66) were grown and the obtained results are as shown below. The biomass yield and nutrient productivities were higher in barley-hairy vetch mixture. The biomass yield and total phosphorus content were higher for the mixed crops by 78~132% and 200% respectively than those of the hairy vetch monoculture. Total nitrogen content of the mixed crops was also higher than those of the barley monoculture by 43~44%. The biomass yield (5.60 Mg/ha) and nutrient contents (87.7 kg N/ha, 23 kg $P_2O_5/ha$) were highest in the case of B66:H33 seeding rate. Accordingly, this study concludes that the barley-hairy vetch mixtures cropped at B66:H33 seeding rate is efficient in increasing green manure productivity due to complementary effects observed and the highest biomass yield and nutrient contents.

Preparation and Characterization of Dinuclear Metal Complexes, $[(PPh_3)_2(CO)M({\mu}-E)M(CO)(PPh_3)_2](SO_3CF_3)_2$ (M = Rh, Ir; E = 1,4-Dicyanobenzene and 1,4-Dicyano-2-butene)

  • Moonsik Kim;JaeKyun Chin;Jaejung Ko
    • Bulletin of the Korean Chemical Society
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    • v.13 no.5
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    • pp.556-559
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    • 1992
  • Hydrocarbon solution of $(PPh_3)_2(CO)MOSO_2CF_3$ (M= Rh, Ir) reacts rapidly with 1,4-dicyanobenzene or 1,4-dicyano-2-butene to yield dinuclear metal complexes $[(PPh_3)_2(CO)M({\mu}-dicyanobenzene)M(CO)(PPh_3)_2](SO_3CF_3)_2$ (I: M = Rh; II: M = Ir) or $[(PPh_3)_2(CO)M({\mu}-dicyano-2-benzene)M(CO)(PPh_3)_2](SO_3CF_3)_2$ (III: M = Rh; IV: M = Ir), respectively. Compounds I, II, III, and IV were characterized by $^1H$-NMR, $^{31}P$-NMR, and infrared spectrum. Dichloromethane solution of II and IV reacts with $H_2\;and\;I_2$ to yield oxidative addition complexes $[(PPh_3)_2(CO)IrX_2({\mu}-E)X_2Ir(CO)(PPh_3)_2](SO_3CF_3)_2$ (V; E = 1,4-dicyanobenzene, $X_2$ = $H_2$; VI : E = 1,4-dicyano-2-butene, $X_2$ = $H_2$; VII; E = 1,4-dicyanobenzene, $X_2$ = $I_2$). All metal complexes are bridged by the cyanide groups. Compounds Ⅴ, Ⅵ, and Ⅶ are characterized by conventional methods.

Effects of Soil pH on Growth, Yield and Its Varietal Differences in Soybean Cultivars. (토양산도에 따른 대두품종의 생육 및 수량반응과 그의 품종간 차이)

  • 이홍석;이석하
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.31 no.4
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    • pp.483-492
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    • 1986
  • To find out the responses of plant growth, nodulation, and yield of soybean and their varietal differences to different soil pH, 16 soybean cultivars were examined under three different levels of soil pH. In general, as the soil pH decreased, plant growth, nodulation, yield and yield component and protein con-tents of grains were decreased in most of cultivars studied. But there were significant varietal differences in the responses of the characters investigated to soil pH. Jangbaegkong was evaluated as the most tolerant cultivar to acid soil, and Ulsan, Bongeui, Hwanggeumkong, and LC7852 were also relatively torelant to acid soil. There were significant correlation between soil pH and grain yield in 7 cultivars among 16, but were not in other cultivars.

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Optimal $H_{2}$ design of the one-degree-of-freedom decoupling controllers

  • Park, Ki-Heon
    • 제어로봇시스템학회:학술대회논문집
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    • 2005.06a
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    • pp.2093-2098
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    • 2005
  • In this paper, $H_{2}$ designs for the one-degree-of-freedom decoupling control systems are treated for the generalized plant. The optimal $H_{2}$ controller is obtained together with the ones that yield finite $H_{2}$ cost functions under compact assumptions. It is shown that the optimal closed transfer matrix is strictly proper under the reasonable order assumptions on the generalized plant.

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