• Title/Summary/Keyword: $H_2$ storage

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Covalent Organic Frameworks for Extremely High Reversible $CO_2$ and $H_2$ Uptake Capacity : A Multiscale Simulation Approach (우수한 가역적 이산화탄소 및 수소 저장성능을 가지는 공유결합성 유기적 골격구조체에 관한 다중스케일 접근법을 이용한 연구)

  • Choi, Yoon Jeong;Choi, Jung Hoon;Choi, Kyung Min;Kang, Jeung Ku
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.113.2-113.2
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    • 2010
  • We report that the novel covalent organic frameworks (COFs) are capable of reversibly providing an extremely high uptake capacity of carbon dioxide and hydrogen at room temperature. These COFs are designed based on the multiscale simulations approach via the combination of ab initio calculations and force-field calculations. For this goal, we explore the adsorption sites of carbon dioxide and hydrogen on COFs, their porosity, as well as carbon dioxide adsorption isotherms. We identify the binding sites and energies of $CO_2$ on COFs using ab initio calculations and obtain the carbon dioxide adsorption isotherms using grand canonical ensemble Monte Carlo calculations. Moreover, the calculated adsorption isotherms are compared with the experimental values in order to build the reference model in describing the interactions between the $CO_2/H_2$ and the COFs and in predicting the $CO_2$ and $H_2$ adsorption isotherms of COFs. Finally, we design three new COFs, 2D COF-05, 3D COF-05 (ctn), and 3D COF-05 (bor), for the high capacity $CO_2/H_2$ and $H_2$ storage.

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Effects of Addition of Varied Levels of Sodium Chloride and Phosphates on pH, Tenderness, Moisture and Mineral Contents in Spent Layer Meat (산란노계육의 저장중 소금과 인산염 첨가가 pH, 수분, 연도 및 무기물에 미치는 영향)

  • 박구부;송또준;이정일;김영직;김용곤;박태선
    • Korean Journal of Poultry Science
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    • v.21 no.4
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    • pp.239-247
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    • 1994
  • A study was conducted to investigate the effects of the addition of varied levels of NaCi and phosphates on the physicochernical properties of the breast meat of the spent layers(2 \pm 0.2 kg) which were stabilized for over 24 h before slaughter. Within 1 h after slaughter, breast meats were removed and treated with NaGl(0, 1, 2, 3%) and phosphates(0.25% and 0.5%) using a hot-salted method. The breast meat was stored at 4 \pm $1^{\circ}C$ for 3 d. The results obtained were summarized as follows. 1. The pH values of salt-treated groups were significantly higher than that of the control(P<0.05) ; the higher the salt level, the higher the pH. The pH values were significantly increased in both control and treatment groups during storage(P<0.05). Among salt-treated groups, the 0.5% phosphates level showed significantly high pH(P<0.05) compared to other levels of salt groups. 2. The moisture contents were significantly lower in all salt4reated groups than the control(P<0.05), and showed a negative relationship with the levels of salt. It decreased in control group gradually as the storage period extended, but not significantly changed in salt-treated groups. 3. The shear force values in salt-treated groups were lower than that of the control and showed a negative relationship with salt levels. At a constant level of NaCI, the shear force value was higher in 0.25% phosphates level than in 0.5% level. It decreased in both control and salt-treated groups during storage. 4. The salt treatments tended to increase the sodium content proportionately. The sodium content decreased in both control and salt treatment groups during storage(P<0.05). In addition, the combination of high levels of NaCl and phosphates rather than those of low levels of NaCI and phosphates resulted in elevated levels of sodium. 5. The phosphorus contents in salt-treated groups were higher than that of control. Between 0.5% and 0.25% phosphates levels this value showed significant difference(P<0.05). Its contents in both control and treatment groups were significantly decreased during storage (P<0.05).

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Changes in the Water-Holding Capacity Extractability of Proteins and pH Value of Ovine Muscle During Storage (저장중면양근육내(貯藏中緬羊筋肉內)에서의 보수성(保水性), 단백질추출성(蛋白質抽出性) 및 pH의 변화(變化))

  • Chae, Young-Seok
    • Applied Biological Chemistry
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    • v.21 no.2
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    • pp.109-111
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    • 1978
  • This study was undertaken in order to observe the differences of the changes in the water-holding capacity (WHC), extractability of proteins (EP) and pH value of ovine muscle during storage. WHC decreased gradually after slaughter, reached to minimum at about 2-4hr after death as well as that of pH value and then these were recovered along with the progress of the storage. The same tendency was observed in EP but the degree of the changes in pH value up to 6hr after slaughter was more rapid this that of WHC and EP. After the fourth day, the rate of recovery in WHC, EP and pH value in ovine muscle during storage showed similar pattern.

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Physico-chemical Properties of Commercial Yoghurt In Korea (시판 요구르트의 특성 비교 연구)

  • Kim, Moon-Suk;Ahn, Eun-Suk;Shin, Dong-Hwa
    • Korean Journal of Food Science and Technology
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    • v.25 no.4
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    • pp.340-344
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    • 1993
  • Gel type yoghurts from 5 representative manufacturers were collected at market and evaluated their physico-chemical properties during storage at $5^{\circ}C$. The range of pH, acidity, Brix and viscosity of each product were $3.87{\sim}4.19,\;0.97{\sim}1.42%,\;16.2{\sim}22.2\;and\;7,850{\sim}21,000 cp$ respectively. The pH of each product decreased gradually during storage time and reached around pH 4.1 after 16 days with proportional acidity increasing. The viscosity of all test products showed increasing trend by lactic acid bacterial action. Total lactic acid bacteria were $10^8{\sim}10^9\;CFU/ml$ at the beginning storage and increased or decreased depending upon each product. But all product maintained over than $10^8 CFU/ml$ which meets regulatory level after 16 days storage.

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Quality Changes in Unripe Peaches Jangachi according to Cultivar during Storage (품종별 복숭아 유과 장아찌의 저장 중 품질특성 변화)

  • Hong, Min-Seo;Kim, Kyoung-Hee;Yook, Hong-Sun
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.41 no.11
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    • pp.1577-1583
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    • 2012
  • This study was carried out to examine changes in the quality characteristics of unripe peach Jangachi made from different cultivars during storage at room temperature for 60 days. Based on the results, unripe peach Jangachi-showed decreases in pH of pulps and soaking solutions of all varieties during storage. Salinity of Jangachi tended to increase during storage, whereas it decreased in soaking solutions. Soluble solid contents decreased during storage in all varieties, both in pulps and soaking solutions. Among Hunter's color values, L values decreased, a values increased, and b values decreased during storage in all varieties. Hardness decreased for 30 days of storage and increased slightly thereafter. During storage, yeast and mold counts increased and decreased within the range from 2.30~5.55 log CFU/g, respectively. In the sensory evaluation, Madoka and Nagasawa Hakuho were evaluated as good in overall acceptability.

Quality Characteristics of Kochujang During Storage by the Level of Naked Oat Flours Added (쌀귀리 분말 첨가수준에 따른 고추장의 저장 중 품질특성)

  • Jeon, Eun-Raye;Jung, Lan-Hee
    • Journal of Korean Home Economics Education Association
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    • v.34 no.1
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    • pp.17-34
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    • 2022
  • The quality characteristics of kochujang by the level of roasted naked oat flours added were periodically examined during storage for 20 weeks at 25℃(± 2 ℃). The water contents of kochujang with roasted naked oat flours decreased gradually as the level of added roasted naked oat flours increased (p<.05), whereas they increased gradually by time during storage. The pH of kochujang with roasted naked oat flours increased gradually according to the added level(p<.001), whereas pH decreased gradually by time during storage. But the acidity changed opposite of pH. The L(lightness), a(redness) and b(yellowness)-values of samples increased according to the amount of added naked oat flours, while decreased gradually by time during storage. The salinity and sweetness of samples decreased gradually according to the amount of added naked oat flours(p<.001). Amino acid composition of kochujang with roasted naked oat flours was higher than that of the control sample during storage. In the kochujang with roasted naked oat flours after 20 weeks of storage at 25℃(± 2 ℃), 17 kinds of amino acid contents were examined, and the glutamic acid was found to increase as the level of added naked oat flours increased: 959.69 mg/100 g for control, 983.55 mg/100 g, 1,070.72 mg/100 g for 5%, 10% and 1,169.62 mg/100 g for 15%. As a result of the above results, it was found that the quality characteristics of kochujang by addition level of roasted naked oat flours could be improved, and the possibility of developing kochujang beneficial to health was confirmed.

Analysis of the Phase Change Temperatures and the Latent Heat Characteristics of $H_2O$-NaCl Mixtures for the Cold thermal Energy Storage (냉축열을 위한 $H_2O$-NaCl 혼합물의 상변화 온도와 잠열 특성분석)

  • Song, H.K.;Ro, J.G.
    • Solar Energy
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    • v.19 no.2
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    • pp.57-65
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    • 1999
  • In this study $H_2O$-NaCl mixture was selected as a cold thermal storage material and its phase change temperature($liquid{\Leftrightarrow}solid$) was controlled with the molar concentration of NaCl. Ion dipole interaction mechanism and the fusion and crystallization structure of $H_2O$-NaCl were visualized with the low and high concentration of NaCl in the heating and cooling processes. In this study, the original cause of the appearance of two steps phase change period in heating and cooing processes were found by the visualization of the ion dipole interaction mechanism of $H_2O$-NaCl, and the theoretical equation of the phase change temperature variation in the NaCl high molar concentration was rearranged.

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Changes of Vitamin C and Chlorophyll Contents in Oi-Kimchi with Storage time (저장기간에 따른 오이김치의 비타민 C 및 클로로필 함량변화)

  • Park, Mi-Lan;Lee, Yeon-Jung;Kozukue, Nobuyuki;Han, Jae-Sook;Choi, Suk-Hyun;Huh, Sung-Mee;Han, Gyeong-Phil;Choi, Soo-Keun
    • Journal of the Korean Society of Food Culture
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    • v.19 no.5
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    • pp.566-572
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    • 2004
  • This study was carried out to examine the changes of pH, chlorophyll, chlorophyll patterns and ascorbic acid contents, and sensory evaluation in Oi-Kimhi by the different periods of storage. The contents of chlorophyll a and b were 52.2% and 14.44% at storage 0 days, 20.67% and 16.99% at storage 11 days,0% at storage 14 days, and decreased with storage times increased. But, phephorbide a and b were increased with storage times increased until storage 11 days, and were 28.44% and 1.25% at storage 0 days,42.63% and 15.79% at storage 11 days,0% at storage 12, 14 days. The contents of ascorbic acid were increased until storage 4 days, but afterwards were decreased with storage times increased, and were 2.57mg% at storage 0 days, 5.49mg% and 2.95mg% at storage 11 days, 0% at storage 14 days. Sensory evaluations of appearance, flavor, taste, texture, overall acceptability showed the highest at storage 8 days, and disliked after storage 10 days.

Quality Factors Affecting Egg Freshness and Palatability During Storage (계란의 저장에 따른 물리화학적 특성 평가 및 품질 인자 설정)

  • Kim, Bum-Keun;Park, Chan-Eun;Kim, Byung-Sam;Kim, Yoonsook
    • Korean Journal of Food Science and Technology
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    • v.46 no.3
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    • pp.295-302
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    • 2014
  • This study investigated the effects of storage temperature and time on the physicochemical properties of eggs, and the corelationship of quality factors with egg freshness and the palatability during storage. As storage temperature and time increased, weight loss significantly increased (p<0.05), while the specific gravity, Haugh unit, yolk index, albumen index, and yolk viscosity decreased significantly (p<0.05). A multiple regression equation of $Y_1$ (freshness)=$106.50286-0.81196X_1$ (weight loss)-$77.51667X_5$ (specific gravity)-$2.27156X_8$ (yolk pH)+$0.00178X_{16}$ (yolk viscosity) with $r^2$=0.89 was obtained for the evaluation of egg freshness. Also, sensorial palatability through the multiple regression equation was determined as $Y_2$ (palatability)=$104.98174-0.81466X_1$ (weight loss)-$76.53434X_5$ (specific gravity)-$2.20338X_8$ (yolk pH)+$0.00178X_{16}$ (yolk viscosity) with $r^2$=0.89 indicating that weight loss, specific gravity, yolk pH and yolk viscosity are major factors that affect the freshness and palatability of eggs during storage.

Effect of Gaseous Ozone Exposure on the Bacteria Counts and Oxidative Properties of Ground Hanwoo Beef at Refrigeration Temperature

  • Cho, Youngjae;Muhlisin, Muhlisin;Choi, Ji Hye;Hahn, Tae-Wook;Lee, Sung Ki
    • Food Science of Animal Resources
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    • v.34 no.4
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    • pp.525-532
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    • 2014
  • This study was designed to elucidate the effect of ozone exposure on the bacteria counts and oxidative properties of ground Hanwoo beef contaminated with Escherichia coli O157:H7 at refrigeration temperature. Ground beef was inoculated with 7 Log CFU/g of E. coli O157:H7 isolated from domestic pigs and was then subjected to ozone exposure ($10{\times}10^{-6}kg\;O_3h^{-1}$) at $4^{\circ}C$ for 3 d. E. coli O157:H7, total aerobic and anaerobic bacterial growth and oxidative properties including instrumental color changes, TBARS, catalase (CAT) and glutathione peroxidase (GPx) activity were evaluated. Ozone exposure significantly prohibited (p<0.05) the growths of E. coli O157:H7, total aerobic and anaerobic bacteria in ground beef samples during storage. Ozone exposure reduced (p<0.05) the CIE $a^*$ value of samples over storage time. The CIE $L^*$ and CIE $b^*$ values of the samples fluctuated over storage time, and ozone had no clear effect. Ozone exposure increased the TBARS values during 1 to 3 d of storage (p<0.05). The CAT and GPx enzyme activities were not affected by ozone exposure until 2 and 3 d of storage, respectively. This study provides information about the use of ozone exposure as an antimicrobial agent for meat under refrigerated storage. The results of this study provide a foundation for the further application of ozone exposure by integrating an ozone generator inside a refrigerator. Further studies regarding the ozone concentrations and exposure times are needed.