• Clean Technology
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• v.28 no.1
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• pp.1-8
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• 2022

To confirm the applicability of the water gas shift reaction for the production of high purity hydrogen for petroleum cokes, an unutilized low grade resource, Cu/ZnO/MgO/Al₂O₃ (CZMA), catalyst was prepared using the co-precipitation method. The prepared catalyst was analyzed using BET and H₂-TPR. Catalyst reactivity tests were compared and analyzed in two cases: a single LTS reaction from syngas containing a high concentration of CO, and an LTS reaction immediately after the syngas passed through a HTS reaction without condensation of steam. Reaction characteristics in accordance with steam/CO ratio, flow rate, and temperature were confirmed under both conditions. When the converted low concentration of CO and steam were immediately injected into the LTS, the CO conversion was rather low in most conditions despite the presence of large amounts of steam. In addition, because the influence of the steam/CO ratio, temperature, and flow rate was significant, additional analysis was required to determine the optimal operating conditions. Meanwhile, carbon deposition or activity degradation of the catalyst did not appear under high CO concentration, and high CO conversion was exhibited in most cases. In conclusion, it was confirmed that when the Cu/ZnO/MgO/Al₂O₃ catalyst and the appropriate operating conditions were applied to the syngas composition containing a high concentration of CO, the high concentration of CO could be converted in sufficient amounts into CO₂ by applying a single LTS reaction.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.2
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• pp.179-188
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• 2011

Experiments were conducted in a constant-pressure combustion chamber to investigate the effects of hydrocarbon addition on cellular instabilities of syngas-air flames. The measured laminar burning velocities were compared with the predicted results computed using reliable kinetic mechanisms with detailed transport and chemistry. The cellular instabilities that included hydrodynamic and diffusional-thermal instabilities of the hydrocarbon-added syngas-air flames were identified and evaluated. Further, experimentally measured critical Peclet numbers for fuel-lean flames were compared with the predicted results. Experimental results showed that the laminar burning velocities decreased significantly with an increase in the amount of hydrocarbon added in the reactant mixtures. With addition of propane and butane, the propensity for cell formation was significantly diminished whereas the cellular instabilities for methane-added syngas-air flames were not suppressed.

• Journal of Energy Engineering
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• v.16 no.2
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• pp.83-92
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• 2007

In view of stringent environment regulations to control the emission of green house gases and also depleting fossil fuel reserves, it is high quality desirable to develop alternative technologies to produce high quality fuels. To this end Biomass to Liquid (BTL) technology has received much attention in recent years. BTL process generally consists of gasification of biomass to produce bio-syngas, cleaning and control of $H_{2}/CO$ mole ratio of bio-syngas and Fischer-Tropsch synthesis & upgrading systems. Choren, Germany has first developed the commercial BTL process using unique gasification system i.e., Carbo-V. A new technology to remove tars and BTX has been developed by ECN in Netherlands employing a gasification system combined with OLGA technology. Several other countries including USA and Japan are showing great interest in BTL technology. Thus in view of our national energy security and also the environmental regulations, it is essential to develop alternative technologies like BTL in order to meet the increasing demand of energy though our insufficient biomass resources. In this paper we present an overview and development status of BTL-diesel technology.

• New & Renewable Energy
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• v.19 no.4
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• pp.35-45
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• 2023

Global efforts are focused on achieving carbon neutrality due to the increases in the levels of greenhouse gases. Moreover, the greenhouse gases generated from the disposal of municipal solid waste (MSW) are the primary sources of emissions in South Korea. In this study, we conducted the biological conversion of syngas (CO, H₂, and CO₂) generated from MSW gasification. The MSW-derived syngas was used as a feed source for cultivating Eubacterium limosum KIST612, and pressurization was employed to enhance gas solubility in culture broth. However, the pH of the medium decreased owing to the pressurization because of the CO₂ in the syngas and the cultivation-associated organic acid production. The replacement of conventional HEPES buffer with a phosphate buffer led to an approximately 2.5-fold increase in acetic acid concentration. Furthermore, compared with the control group, the pressurized reactor exhibited a maximum 8.28-fold increase in the CO consumption rate and a 3.8-fold increase in the H2 consumption rate.

• Journal of the Korean Institute of Gas
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• v.4 no.2 s.10
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• pp.27-32
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• 2000

In this study, $Mn_3O_4$ was synthesized by the different equivalent ratios using solution of $MnCL_2 {\cdot} 4H_2O$ and NaOH. We have investigated the crystal structure and surface area by XRD, BET Method, studied on the decompositon and adsorption of carbon dioxide with synthesized $Mn_3O_4$. As the results, we surveyed that main peak was $Mn_3O_4$, some Peaks were $MnO_2$ and $Mn_5O_8$ The specific surface area was ranged from $13.92m^2/g$ to $32.33m^2/g$. The decomposition of $CO_2$ was observed by the differential equivalent ratios at $450^{\circ}C$. $CO_2$ was well decomposed at equivalent ratio of 0.75. The amount of chemisorption of $CO_2$ was ranged from 2.885 to 19.628cc/g. Optimal equivalent ratio was 1.00 for the chemisorption of $CO_2$.

• Journal of Advanced Marine Engineering and Technology
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• v.32 no.5
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• pp.737-746
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• 2008

Numerical study is conducted to grasp preferential diffusion effects on flame characteristics in $H_2/CO$ syn-gas diffusion flames diluted with $CO_2$. The models of Sun et al. and David et al., which have been well known to be best-fitted for $H_2/CO$ synthetic mixture flames. are evaluated for $H_2/CO$ synthetic mixture flames diluted with $CO_2$. Comparison of flame structures with mixture-averaged species diffusion and suppression of the diffusivities of $H_2$ and H was made. The behaviors of maximum flame temperatures with those species diffusion models are not explained by scalar dissipation rate but by the nature of chemical kinetics. Importantly-contributing reaction steps to heat release rate are also compared for the three species diffusion models in $H_2/CO/CO_2$ flames with and without $CO_2$ dilution.

• Korean Chemical Engineering Research
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• v.51 no.3
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• pp.319-324
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• 2013

The partial oxidation reaction of methane was investigated to produce syngas with $Ni/CeO_2-ZrO_2$, $Ni-Ru/CeO_2-ZrO_2$ and $Ni-Pd/CeO_2-ZrO_2$ catalysts. Honeycomb metallic monolith was applied in order to obtain high catalytic activity and stability in partial oxidation reforming. The catalysts were characterized by XRD and FE-SEM. The influence of various catalysts on syngas production was studied for the feed ratio (O/C), GHSV and temperature. Among the catalysts used in the experiment, the $Ni-Pd/CeO_2-ZrO_2$ catalyst showed the highest activity. The 99% of $CH_4$ conversion was obtained at the condition of T=$900^{\circ}C$, GHSV=10,000 $h^{-1}$ and feed ratio O/C=0.55. It was confirmed that $H_2$ yield increased slightly as O/C ratio increased, while CO yield remained almost constant. Also, $CH_4$ conversion decreased as GHSV increased. It was found that the safe range of GHSV for high $CH_4$ conversion was estimated to be less than 10,000 $h^{-1}$.

• Journal of the Korean Society of Combustion
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• v.17 no.4
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• pp.30-37
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• 2012

The flame lengths and NOx emission characteristics of syngas $H_2$/CO turbulent non-premixed jet flames were investigated. The flame length which is the main parameter governs NOx emission was studied for various syngas compositions. The flame length was compared with previous correlation between Froude number and flame height and it shows that they have good agreements. It was confirmed that the turbulent jet flames herein investigated are in the region of buoyancy-momentum transition. NOx emission was reduced with increased Reynolds number and CO contents in syngas fuel and with decreased fuel nozzle diameter which is attributed by decreased flame residence time. Previous EINOx scaling based on flame residence time of $L_f^3/(d_f^2U_f)$ satisfies only the jet flame in momentum-dominated region, not buoyancy-momentum transition region. The simplified flame residence time ($L_f/U_f$) was adopted in modified EINOx scaling. The modified scaling satisfies the jet flames not only in momentum-dominated region but in buoyancy-momentum transition region. The scaling is also satisfied with $H_2$/CO syngas jet flames.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.3
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• pp.269-274
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• 2010

As a preliminary study on a SOFC-GT hybrid system integrated a with coal-gasification system, the influence of the concentrations of $H_2$ and CO in syngas on the performance characteristics of the hybrid system is investigated. It is expected that the differences in the heating values of fuels with different compositions trigger the off-design operation of the gas turbine and result in different performance characteristics of the overall hybrid system. Syngas compositions are found to affect the SOFC performance. Performance of hybrid system with carbon monoxide is poorer than the case with hydrogen. In the case of part-load performance with syngas, performance degradation at part-load operating conditions with hydrogen is more dominant than the case with carbon monoxide.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.136.2-136.2
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• 2011

A dynamic simulation study on SCR process in GTL process was carried out in order to find optimum operation conditions for pilot plant operation. Optimum operating conditions for SCR synthesis gas process were determined by changing operation variables such as feed temperature and pressure. It was also assumed that physical properties of reaction medium were governed by RKS (Redlich-Kwong-Soave) equation. The effect of temperature and pressure on synthesis gas process $H_2$/CO ratio were mainly examined. Dynamic simulation results were fed back to feed operation condition for optimizing productivity, especially for appropriate condition to FT (Fischer-Tropsch) synthesis unit.