• Proceedings of the SAREK Conference
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• 2009.06a
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• pp.272-278
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• 2009

The characteristics of hybrid type absorption chiller are studied numerically to use a waste hot water effectively. In the case of the full load, the concentration and temperature of LiBr solution are increase about $11^{\circ}C$, 1.3% respectively at the single effect generator by hot water. As a result, the heat of the high temperature generator are decrease, so the energy can be saved. As the partial load decreased the consumption ratio of fuels are decreased and the reduction ratio of fuels are increased. The variation of COP with the inlet temperature of hot water is higher than that of the flow rate of hot water. The effect of mean temperature difference with solution and hot water of the generator are higher that of flow rate of hot water, it can effect on COP which is sensitive to heat of generator.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.24 no.11
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• pp.1428-1436
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• 2000

The absorption of vapor involves simultaneous heat and mass transfer in the vapor/liquid system. In this paper, a numerical study for vapor absorption process into LIBr-H$_2$O solution film flowing over helical absorber has been carried out. Axisymmetric cylindrical coordinate system was adopted to model the helical tube and the transport equations were solved by the finite volume method. The effects of operating conditions, such as the cooling water temperature. the system pressure, the film Reynolds number and the solution inlet concentration have been investigated in view of the absorption mass flux and the total absorption mass flux and the total absorption rate. The results for the temperature and concentration profiles, as well as the local absorption mass flux at the helical absorber are presented. It is shown that solution inlet concentration affected other than operation conditions for a mass flux.

• Bulletin of the Korean Chemical Society
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• v.31 no.12
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• pp.3588-3592
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• 2010

Second-order rate constants ($k_N$) have been measured spectrophotometrically for nucleophilic substitution reactions of 2-pyridyl X-substituted benzoates 8a-e with a series of alicyclic secondary amines in $H_2O$ at $25.0{\pm}0.1^{\circ}C$. The $k_N$ values for the reactions of 8a-e are slightly smaller than the corresponding reactions of 4-nitrophenyl X-substituted benzoates 1a-e (e.g., $kN^{1a-e}/k_N^{8a-e}$ = 1.1 ~ 3.1), although 2-pyridinolate in 8a-e is ca. 4.5 $pK_a$ units more basic than 4-nitrophenolate in 1a-e. The Br$\o$nsted-type plot for the aminolysis of 8c (X = H) is linear with $\beta_{nuc}$ = 0.77 and $R^2$ = 0.991 (Figure 1), which is typical for reactions reported previously to proceed through a stepwise mechanism with breakdown of a zwitterionic tetrahedral intermediate $T^{\pm}$ being the rate-determining step (RDS), e.g., aminolysis of 4-nitrophenyl benzoate 1c. The Hammett plot for the reactions of 8a-e with piperidine consists of two intersecting straight lines (Figure 2), i.e., $\rho$ = 1.71 for substrates possessing an electron-donating group (EDG) while $\rho$ = 0.86 for those bearing an electron-withdrawing group (EWG). Traditionally, such a nonlinear Hammett plot has been interpreted as a change in RDS upon changing substituent X in the benzoyl moiety. However, it has been proposed that the nonlinear Hammett is not due to a change in RDS since the corresponding Yukawa-Tsuno plot exhibits excellent linear correlation with $\rho$ = 0.85 and r = 0.62 ($R^2$ = 0.995, Figure 3). Stabilization of substrates 8a-e in the ground state has been concluded to be responsible for the nonlinear Hammett plot.

• Bulletin of the Korean Chemical Society
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• v.34 no.9
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• pp.2616-2622
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• 2013

A novel zwitterionic monomer 3-[(2-acrylamido)dimethylammonio]propanesulfonate (DMADAS) was designed and synthesized in this study. Then it was polymerized with acrylamide (AM) by free radical polymerization in 0.5 mol/L NaCl solution with ammonium persulfate ($(NH_4)_2S_2O_8$) and sodium sulfate ($NaHSO_3$) as initiator. The structure and composition of DMADAS and acrylamide-3-[(2-acrylamido)-dimethylammonio]propanesulfonate copolymer (P-AM-DMADAS) were characterized by FT-IR spectroscopy, $^1H$ NMR and elemental analyses. Isoelectric point (IEP) of P-AM-DMADAS was tested by nanoparticle size and potential analyzer. Solution properties of copolymer were studied by reduced viscosity. Antipolyelectrolyte behavior was observed and was found to be enhanced with increasing DMADAS content in copolymer. The results showed that the viscosity of P-AM-DMADAS is 5.472 dl/g in pure water. Electrolyte was added, which weakened the mutual attraction between sulfonic acid group and quaternary ammonium group. The conformation became loose, which led to the increase of reduced viscosity. The ability of monovalent and divalent cation influencing the viscosity of zwitterionic copolymer obeyed the following sequence: $Li^+$ < $Na^+$ < $K^+$, $Mg^{2+}$ < $Ca^{2+}$ < $Ba^{2+}$, and that of anion is in the order: $Cl^-$ < $Br^-$ < $I^-$, $CO{_3}^{2-}$ > $SO{_3}^{2-}{\approx}SO{_4}^{2-}$.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.23 no.10
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• pp.1347-1354
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• 1999

Recently, the markets of the air conditioner are enlarging. The market size will reach 2.0 billion won in 2000. Electric heat pumps have been utilized as main residential air conditioners. especially in Korea. They cause a surge up electric power demand during summer. Moreover, the use of HCFCs and HFCs causes serious problem to the global environment such as global warming and ozone layer destruction. Absorption chiller and heater could solve such problems. It was built and tested for analyzing the performance of the generator for absorption chiller and heater. Experiment was done with a high temperature generator, a low temperature generator, heat exchangers, a condenser and a solution tank. It was tested that the double effect series flow cycle with two kinds of solution cycle. Solution cycle B showed better than solution cycle A. Two kinds of heat exchanger were used, where one's heat transfer area is bigger than the other. Bigger one increased a little performance of absorption chiller and heater. But it was not economical. From this study, we got that the coefficient of performance(COP) is 0.82 and the capacity is 7.24 kW for an absorption chiller and heater.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.18 no.9
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• pp.738-744
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• 2006

In order to utilize the condensation heat of refrigerants in condenser on the absorption chiller system, the solution cooled condenser (SCC) was proposed using the weak solution of absorber as a cooling medium. The increase of COP with the increase of UA of the solution cooled condenser was approximately 0.009 in maximum with single effect one, and is about maximum 0.008 in occasion of double effect one with series flow compared to that without. In the case of heat exchanger, effectiveness is about 0.85, it's increments are 0.008 and 0.0072, respectively. And solution cooled condenser is more effective device in the single effect absorption system than double effect system for the principle of operation. On the other hand, as the solution split ratio increases when the value of UA is fixed, COP is increased and as the solution split ratio increases when the value of UA is fixed, COP is increased. If the flow rate of cooling water or the value of UA is reduced in order to increases the heat recovery of solution cooled condenser, heat recovery of solution cooled condenser is increased a little but COP is decreased as the system pressure is increased.

• Journal of the Korean Solar Energy Society
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• v.27 no.4
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• pp.19-26
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• 2007

This paper concerns the study of absorption refrigeration and heat pump cycle to use sewage. Simulation analysis on the double-effect absorption refrigeration cycle with parallel and two-stage heat pump cycle has been performed. The working fluid is Lithium Bromide and water solution. The absorption refrigeration cycle use sewage as a cooling water for the absorber and condenser, and absorption refrigeration cycle does that as a chilled water for the evaporator of the first stage cycle. And the two-stage cycle consists of coupling double-effect with parallel and single effect cycle so that the first stage absorber and condenser produces heating water to evaporate refrigerant in the evaporator of the second stage. The effects of operating variables such as a absorber temperature on the coefficient of performance have been studied for absorption refrigeration and heat pump cycle.

• Proceedings of the SAREK Conference
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• 2006.06a
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• pp.46-51
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• 2006

In order to utilize the refrigerants condensation heat of condenser on the absorption chiller system, the solution cooling condenser(SCC) were proposed, which weak solution of absorber outlet use as a cooling water. As the UA of the solution cooling condenser increased, increasement of COP is about maximum 0.09 in occasion of single effect and is about maximum 0.08 in occasion of double effect series flow. In the case of heat exchanger efficiency is about 0.85, it's increments are 0.08 and 0.072, each. And solution cooling condenser is a more effective device in the single effect absorption system more than double effect system for the principle of operation. In order to increases the heat of solution cooling condenser, if reduce the flow rate of cooling water or the value of UA, it makes COP increase a little, but it brought COP decrease because of increasing the pressure of system.

• Bulletin of the Korean Chemical Society
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• v.16 no.11
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• pp.1067-1074
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• 1995

Reaction of arachno-S2B7H8- with either THF or 1,2-dimethoxyethane upon refluxing condition results in the formation of the previously known compound hypho-S2B7H10-. Protonation of hypho-S2B7H10- with HCl/Et2O generates hypho-2,5-S2B7H11 in good yield. This hypho-S2B7H10- anion has been employed to generate a series of new nido-, arachno-, and hypho-metalladithiaborane clusters. Reaction of the anion with Cp(CO)2FeCl results in direct metal insertion and the formation of a complex containing the general formula (η5-C5H5)FeS2B7H8. Spectroscopic studies of nido-6-CpFe-7,9-S2B7H8 Ⅰ demonstrated that compound Ⅰ was shown to have an nido-type cage geometry derived from an octadecahedron missing one vertex, with the iron atom occupying the three-coordinate 6-position in the cage and the two sulfurs occupying positions on the open face of the cage. Reaction of hypho-S2B7H10- with CoCl2/Li+[C5H5]- gave the previously known complex arachno-7-CpCo-6,8-S2B6H8 Ⅱ. Also, the reaction of the anion with [Cp*RhCl2]2 gave the complex arachno-7-Cp*Rh-6,8-S2B6H8 Ⅲ, the structure of which was shown to be that of complex Ⅱ. The similarity of the NMR spectra of Ⅱ and Ⅲ suggest that Ⅲ adopts cage structure similar to that previously confirmed for Ⅱ. A series of 9-vertex hypho clusters in which the sulfur atoms are bridged by different species isoelectronic with a BH3 unit, such as HMn(CO)4 or SiR2 have been prepared. Compounds Ⅳ,Ⅴ and Ⅵ are each 2n+4 skeletal electron systems and would be expected according to skeletal electron counting theory to adopt hypho-type polyhedral structures derived from an icosahedron missing three vertices. The complex hypho-1-(CO)4Mn-2,5-S2B6H9 Ⅳ was obtained by the reaction of the anion with (CO)5MnBr and has been shown from spectroscopic data to consist of a (CO)4Mn fragment bound to the two sulfur atoms S2 and S5 of hypho-S2B7H10-. Also, similar hypho-type complexes hypho-1-R2Si-2,5-S2B6H8 (R=CH3 Ⅴ, R=C6H5 Ⅵ) have been prepared from the reaction of hypho-S2B7H10- with R2SiHCl.

• Proceedings of the SAREK Conference
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• 2008.06a
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• pp.304-308
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• 2008

The optimal design of two stage evaporation & absorption system which is related to the large temperature difference system was investigated numerically in the absorption refrigeration system. The concentrations at inlet & oulet of absorber are 62.9% and 56.9%, but in two stage absorption system the values are 62.2% and 56.2%. Therefore strong solution & weak solution became diluted than the standard value. The amount of weak solution circulation can be reduced in absorption refrigeration system, and the sensible heat load is more reduced to enhance the COP of system. As UAR is increased, COP becomes larger, and this means the role of top section is more important than bottom section in two stage evaporation & absorption system. But the increase of COP becomes slower at 0.7 of UAR ratio. The performance of Type2 is higher than Type1 in COP with the flow direction of cooling waters. This phenomena is due to the active absorption of vapor -absorption & lower temp. cooling water is more effective. The pressure at bottom section becomes higher & that at top section becomes lower and therefore the circulation rate can be diminished more.