• 지질공학
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• 제15권4호
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• pp.391-405
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• 2005

포항시 흥해읍 일대 지하수의 수리 지화학적 특성 을 파악하기 위하여, 지표수, 천부지 하수 및 중간심도와 심부 지하수를 대상으로 수질 및 안정 동위 원소 분석 을 수행하였다. 심도별 수질 유형은 지표수 및 천부지하수는 Ca-Cl, 중간 심도는 $Na-HCO_3$, 심부지하수는 Na-Cl형이 우세하게 나타난다. $HCO_3^-$ $SiO_2$의 기원은 천부 지하수의 경우 규산염광물의 풍화에서, 심부지하수는 탄산염 광물의 풍화에서 생성되었다. Ca 및 Mg이 온은 천부 및 심부 모두 석회 석 및 백운석에서 기인한다. 천부 지하수의 $SO_4^{2-}$ 기원은 황철석에서 기인하는 것으로 나타난다 심도의 증가에 따라 pH 및 TDS는 증가하나, Eh및 DO는 감소하는 경향을 보인다. 알카리 금속(K, Na, Li.)은 심부로 갈수록 농도가 증가하나, 알카리 토금속(Mg, Ca) 및 AL은 천부로 갈수록 증가하는 양상을 보인다. 음이온인 할로겐 원소(F, Cl, Br) 및 $HCO_3^-$의 농도도 심부로 갈수록 증가함을 보인다. 산소 및 수소 안정동위원소 평균값은 심부 지하수는 평균값: ${\delta}^{18}O=-10.1\%_{\circ},\;{\delta}D=-65.8\%_{\circ}$, 중간심도는 평균값: ${\delta}^{18}O=-8.9\%_{\circ},\;{\delta}D=-59.6\%_{\circ}$ 천부 지하수는 평균값: ${\delta}^{18}O=-8.0\%_{\circ},\;{\delta}D=-53.6\%_{\circ}$지표수는 평균값: ${\delta}^{18}O=-7.9\%_{\circ},\;{\delta}D=-53.3\%_{\circ}$의 값을 각각 보인다.

• Bulletin of the Korean Chemical Society
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• 제16권7호
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• pp.634-641
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• 1995

The metal-carbon σ-bond cluster complexes 1-Mn(CO)5-2-R-1,2-C2B10H10 (R=CH3 Ia, C6H5 Ib) have been prepared in good yields from readily available carboranyl lithium complexes, 1-Li+-2-R-1,2-C2B10H10- (R=CH3, C6H5), by direct reaction with (CO)5MnBr. These manganese metal complexes are rapidly converted to the corresponding manganese metal carbene complexes, 1-[(CO)4Mn=C(OCH3)(CH3)]-2-R-1,2-C2B10H10 (R=CH3 IIIa, C6H5 IIIb), via alkylation with methyllithium followed by O-methylation with CF3SO3CH3. The crystal structure of IIIb was determined by X-ray diffraction. Thus, complex IIIb crystallizes in the orthorhombic space group P212121 with cell parameters a=15.5537(5), b=19.0697(5), c=7.4286(3) Å, V=2203.4(1) Å3, and Z=4. Of the reflections measured a total of 3805 unique reflections with F2>3σ(F2) was used during subsequent structure refinement. Refinement converged to R1=0.053 and R2=0.091. Structural studies showed that the manganese atom had a slightly distorted pseudo-octahedral configuration about the metal center with the carbene and ortho-carborane occupying the equatorial plane cis-orientation to each other.

• 설비공학논문집
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• 제8권2호
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• pp.288-298
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• 1996

The gas-fired absorption refrigeration system to utilize treated sewage is available for environmental protection and energy conservation. Simulation analysis on the double-effect absorption refrigeration cycles with parallel or series flow type has been performed. The working fluid is Lithium Bromide and water solution. The main purpose of this study is evaluating the possibilities of effective utilization of treated sewage as a cooling water for the absorber and condenser. The efficiency of a couple of cycles has been studied and simulation results show that higher coefficient of performance could be obtained for parallel flow type. The other purpose of the present study is to determine the optimum designs and operating conditions based on the operating constraints and the coefficent of performance in the paralledl flow type.

• Bulletin of the Korean Chemical Society
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• 제30권10호
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• pp.2393-2397
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• 2009

Second-order rate constants ($k_{HOO}$‒) have been measured spectrophotometrically for nucleophilic substitution reactions of Y-substituted phenyl benzenesulfonates (1a-g) with $HOO^-$ ion in $H_2O$ at $25.0\;{\pm}\;0.1\;{^{\circ}C}$. The Br$\phi$nsted-type plot is linear with ${\beta}_{lg}$ = ‒0.73. The Hammett plot correlated with with ${\sigma}^-$ constants results in much better linearity than ${\sigma}^o$ constants, indicating that expulsion of the leaving group occurs in the rate-determining step (RDS) either in a stepwise mechanism or in a concerted pathway. However, a stepwise mechanism in which departure of the leaving group occurs in the RDS has been excluded since $HOO^-$ ion is more basic and a poorer leaving group than the leaving Y-substituted phenoxide ions. Thus, the reactions of 1a-g with $HOO^-$ ion have been concluded to proceed through a concerted mechanism. The $\alpha$-nucleophile $HOO^-$ ion is more reactive than its reference nucleophile $OH^-$ ion although the former is ca. 4 p$K_a$ units less basic than the latter (i.e., the $\alpha$-effect). TS stabilization through intramolecular H-bonding interaction has been suggested to be irresponsible for the $\alpha$-effect shown by $HOO^-$ ion, since the magnitude of the $\alpha$-effect is independent of the electronic nature of substituent Y in the leaving group. GS destabilization through desolvation of $HOO^-$ ion has been concluded to be responsible for the $\alpha$-effect found in the this study.

• 대한기계학회논문집
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• 제17권8호
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• pp.2099-2109
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• 1993

A gas-fired 4RT absorption heat pump was designed as an air-conditioner for domestic use during the summer. The absorption heat pump is air-cooled. double-effect, $LiBr-H_{2}O$ system with parallel flow type. The performance of the absorption heat pump in the cooling mode of operation was investigated through cycle modeling and simulation to obtain the system characteristics with parameter changes. System parameters considered in this analysis were the inlet temperature of cooling air to the absorber, the working solution concentrations, the ratio of the amount of the weak solution from the absorber, and the LTD's of each heat exchange component. The optimum designs and operating conditions were determined based on the operating constraints and the coefficient of performance.

• 설비공학논문집
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• 제4권4호
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• pp.332-341
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• 1992

An absorption heat pump cycle has been modeled and simulated to analyze the system performance of water-cooled, series-flow, double-effect absorption heat pump, which can be applied to a direct gas fired cooling system with the medium range of cooling capacity (15RT level). Effect of absorption cooling system parameters, such as concentration difference, inlet temperature of cooling water, 1st generator temperature, leaving temperature differences of condenser and evaporator and efficiency of solution heat exchanger, has been investigated in the view of system cooling performance.

• 한국태양에너지학회:학술대회논문집
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• 한국태양에너지학회 2009년도 춘계학술발표대회 논문집
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• pp.203-208
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• 2009

This paper presents demonstration study results derived through field testing of a solar assisted cooling and heating system for the library of a cultural center building located in Gwangju, Korea. The area of demanded cooling and heating for building was about 350m2. Solar hot water was delivered by means of a 200m2 array of evacuated tubular solar collector (ETSC) to drive a single-effect (LiBr/H2O) absorption chiller of 10RT nominal cooling capacity. From March in 2008 to February in 2009, demonstration test were performed for solar cooling and heating system. After experiments and analysis, this study found that solar thermal system was 84% for the solar hot water supply and 12% for space heating and 4% for space cooling.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2008년도 동계학술발표대회 논문집
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• pp.165-169
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• 2008

Binary nanofluids(Binary mixture + nanoparticles) have been extensively paid attention for application in absorption system as a new working fluid. Thermal property evaluation of the new refrigerants is inevitable to apply them for actual system. The objectives of this paper are to measure the thermal conductivity of the binary nanofluids by the transient hot-wire method, and to assess the application possibility of the binary nanofluids for absorption system. It was found that the thermal conductivity of the binary nanofluids ($H_2O/LiBrAl_2O_3$) increased with increasing the concentration of the nanoparticles ($Al_2O_3$) and enhanced up to 27% at 0.1 vol % of the nanoparticles.

• Journal of Advanced Marine Engineering and Technology
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• 제28권2호
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• pp.252-262
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• 2004

A model of simultaneous heat and mass transfer process in absorption of refrigerant vapor into a lithium bromide solution of water-cooled vertical plate absorber. which was considered to the change of refrigerant vapor pressure along the plate width direction. was developed to evaluate the compactness of plate absorber and supply basis data for optimal design of plate absorber. The effects of plate interval as well as the effect of capacity for one piece of plate absorber on plate absorber size such as plate height. plate heating area and plate absorber volume have been investigated. It is confirmed that there is exist an optimal plate interval minimizing plate absorber volume. And the smaller capacity for one piece of plate absorber. the smaller plate absorber volume is obtained.

• 대한기계학회논문집
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• 제19권1호
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• pp.231-239
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• 1995

This paper describes a computer simulation of the triple effect, water-lithium bromide absorption cooling cycles. The performance of the absorption systems is investigated through cycle simulation to obtain the system characteristics with the cooling water inlet temperature, the working solution concentrations, the ratio of the amount of the weak solution to the high, middle and low temperature generators, and the temperature difference of each solution heat exchanger. The efficiency of different cycles has been studied and the simulation results show that higher coefficient of performance could be obtained for the parallel cycle of constant solution distribution rate. As a result of this analysis, the optimum designs and operating conditions were determined based on the operating conditions and coefficient of performance.