• Journal of the Mineralogical Society of Korea
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• v.9 no.2
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• pp.102-112
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• 1996

The precious serpentine, referring to a rare and highly valuable gem variety of serpentine group minerals, is found to occur in serpentinite from Booyo Gren Jade Mine which is located in Oesan-myun, Booyo-gun of Chungchungnam-do. Geommological properties of the precious serpentine have been investigated by use of polarizing microscope, specific gravity balance, refractometer, hardness pencils, X-ray diffractometer, XRF, ICP-MS analyser, and infrared absorption spectroscope.The precious serpentine from Booyo is colored deep green with oily luster and semi-transparent. It is highly tough and Mohs's scale of hardness is measured to be 5-6. Specific gravity is determined to be 2.67, and a single refractive index ND=1.56 is observed by a spot method, using sodium light source. X-ray powder diffraction data is represented by the reflection lines at 7.40(100), 4.64(25), 3.68(68), 2.757(69), 2.530(49), 2.549(32), and 1.710(21${\AA}$), which compares very well with that of antigorite of serpentine group minerals. The major chemical compositions of the precious serpentine group minerals. The major chemical compositions of the precious serpentine are SiO2 42.49%, MgO 39.08%, Fe2O3 3.85%, and H2O 11.87%. Besides, trace elements such as Cr(2188), Ni(1110ppm), Co(58ppm), and Ta (108ppm) are relatively spectrum shows peaks at 3670, 1190, 1070, 980 and 610cm-1. Strong absorption at 3670cm-1 is due to OH stretching, and 1190, 1070 and 980cm-1 due to SiO stretching. The absorption 610cm-1 is formed by alteration of pre-existing ultramafic rock, namely peridotite, with an introduction of fluid with very little content of CO2, under 400$^{\circ}C$ environment. Magnetite inclusions, finely disseminated in the precious serpentine, may be a result of Fe precipitation, during serpentinization of olivine-bearing country rock.

• Korean Journal of Heritage: History & Science
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• v.41 no.1
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• pp.5-19
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• 2008

Thirty six samples of Western asia glass vessel shards which were excavated from South Mound of Hwangnamdaechong were each measured for thickness, pore size and specific gravity and analyzed for ten major compositions and thirteen trace elements. The glass samples with colorless, greenish blue and dark purple blue were well classified by principal component analysis(PCA). All glass shards of Hwangnamdaechong belonged to Soda glass system ($Na_2O-CaO-SiO_2$) which have the range of 14~17% $Na_2O$ and 5~6% CaO. The corelation coefficients of (MgO, $K_2O$) and (MnO, CuO) showed above 0.90. The concentrations of thirteen trace elements apparently differentiated from colorless, greenish blue and dark blue glasses. We found that thirteen trace elements were very important indices for studying raw material of glass and the origin of glass making. Colorless glass : The specific gravity is $1.50{\pm}0.04$. Circle or oval circle pores are observed with regular direction in internal zone and the longest one is about 0.35 mm. The raw material of sodium must be the plant ash because sodium glasses contain HCLA(High CaO, Low $Al_2O_3$) and HMK(high MgO, high $K_2O$) and suggested to Sasanian glass. The total amount of coloring agent of colorless glass is below 1 % which is too small to attribute to the color. Greenish blue glass : The specific gravity is $1.58{\pm}0.04$. The fine pores which are 0.1~0.2mm are dispersed in internal zone. Sodium glasses are distributed to HCLA and HMK. Therefore the greenish blue glass also have used plant ash for raw material of sodium with the same as colorless glass. It was also suggested to the glass of Sasanian. The total amount of coloring agent of greenish blue glass is about 4% under the influence of working MnO, $Fe_2O_3$ and CuO. Dark purple blue glass : The specific gravity is $1.48{\pm}0.19$. There are rarely pores in internal zone. They are distributed to HCLA and LMK(Low MgO, Low $K_2O$) and suggested to Roman glass. The raw material of sodium is estimated to natron. The total amount of coloring agents of greenish blue is about 3% by $Fe_2O_3$ and CuO. These studies for western asia glass shards from South Mound of Hwangnamdaechong could be used in the future as the standard data which could be compared with those of other several graves in Korea and dispersed in foreign areas.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.3 no.4
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• pp.309-317
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• 2005

A study on the separation of $^{99}Tc,\;^{94}Nb,\;^{55}Fe,\;^{90}Sr\;and\;^{59/63}Ni$ in various radioactive wastes discharged from nuclear power plants has been performed for a use in their quantification which is indispensible for the evaluation of the radionuclide inventory Ni was recovered along with Ca, Mg, Al, Cr, Ti, Mn, Ce, Na, K, and Cu through the sequential separation procedure of Re(as a surrogate of $^{99}Tc$), Nb, Fe and Sr by anion exchange and Sr-Spec extraction chromatography. In this research, chemical separation of Ni from the co-existing elements was investigated by cation exchange and Ni-Spec extraction chromatography. Precipitation behaviour of Ni and the co-existing elements with dimethylglyoxime(DMG) was investigated in ammonium $citrate/ethanol-H_2O$ and tartaric $acid/acetone-H_2O$ in order to purify separated Ni fractions and to prepare $^{59/63}Ni$ source for the radioactivity measurement using a gas proportional counter. Recovery of Ni separated through ion exchange chromatographic separation procedure was $92.1\%$ with relative standard deviation of $0.9\%$. In addition, recovery of Ni with DMG in the tartaric $acid/acetone-H_2O$ was $85.6\%$ with relative standard deviation of $1.9\%$.

• Journal of the Korean Geotechnical Society
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• v.26 no.10
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• pp.61-68
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• 2010

A pilot-scale model test was performed to estimate the availability of new material, Fe-loaded zeolite, as the filling material in permeable reactive barrier (PRB) against the contaminated groundwater with both Cd and Cr(VI). Aquifer was simulated by filling up a large scale soil tank with sands, and mobilizing the water flow by the head difference of water level in both ends of the tank. Then, the mixture of concentrated Cd and Cr(VI) solution was injected into the aquifer to form a contaminant plume, and its behavior through Fe-loaded zeolite barrier was monitored. The test results showed that Fe-loaded zeolite barrier successfully treated the contaminant plume containing both Cd and Cr(VI) and that the immobilized contaminants in the barrier were not desorbed or released. The results indicated that the Fe-loaded zeolite could be a promising material in PRBs against the multiple contaminants with different ionic forms like Cr(VI) and Cd.

• Nuclear Engineering and Technology
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• v.54 no.10
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• pp.3778-3787
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• 2022

The stress-assisted oxidation behaviour of Inconel 52 M/316 austenitic stainless-steel (SS) dissimilar weld joints (DMWJ) in a simulated pressurised water reactor environment was investigated. A corrosion galvanic couple formed between the Inconel 52 M and 316 SS due to differences in their nonferrous metal content. The electric field from the corrosion couple attracted metal cations (e.g. Fe²⁺, Cr³⁺) to the Inconel 52 M that were deposited as FeCr₂O₄. An additional corrosion galvanic couple was generated due to variations in the plastic deformation of the DMWJ. The superposition of electric fields from the different couples resulted in ridge-like oxide depositions in the fusion zone.

• Korean Journal of Materials Research
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• v.16 no.10
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• pp.619-623
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• 2006

Selective vapor deposition of conductive poly(3,4-ethylenedioxythiophene) (PEDOT), thin films has been carried out on self assembled monolayers patterned oxide substrate. Since the 3,4-ethylenedioxythiophene(EDOT) monomer can be polymerized only in the presence of oxidant such as $FeCl_3$, the PEDOT thin film is selectively deposited on patterned $FeCl_3$, which only adsorbs on the partly removed SAMs region due to the inability of $FeCl_3$ to adsorb on SAMs. Therefore, the partly removed SAMs can act as an adsorption layer for the $FeCl_3$ and also as a glue layer for the deposition of PEDOT, resulting in the significantly increased adhesion of PEDOT to $SiO_2$ substrate. The use of UV lithography and Cr patterned quartz mask provided the formation of SAMs patterns on oxide substrates, which allowed for the selective deposition of conductive PEDOT thin films.$^{oo}The$ new process was successfully developed for the selective deposition of PEDOT thin films on SAMs patterned oxide substrate, providing a new way for the patterning of vapor phase deposition of PEDOT thin films with accurate alignment and addressing the inherent adhesion issues between PEDOT and dielectrics.

• Environmental Analysis Health and Toxicology
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• v.14 no.4
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• pp.155-163
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• 1999

Heavy metal accumulation in living organisms through food-wed can give serious damage on physiological responses for vital activities. The initiation of heavy metal supposed to begin from the bio-accumulation of plants. To establish basic data fur heavy metal contents in plants at the area without artificial contamination, both woody and herb plants at Mt. Kwang-Duk were studied. The content of heavy metals in various organs of plants were analyzed by ICP. The range of heavy metals in plants for Al, As, Cd, Co, Cr, Cu, Fe. Mn, Pb, Se and Zn were 1.019∼257.200ppm, O∼2.929ppm, 0∼0.079ppm, 0∼0.054ppm, 0.023∼3.007ppm, 0∼1.997ppm, 2.031∼148.500ppm, 1.069∼51.320ppm, O∼126.900ppm, 0.708∼4.927ppm and 0.846∼4.949ppm, respectively. The amount of heavy metals in plants are much less than that of soil except some species. In woody plants, it was detected that the metal contents of leaves were higher than that of stems especially in case of Al and Fe with statistical significance. There were significant differences between shoots and roots of herb plants in metal content of Al, Co and Fe. Those metals have more accumulated in roots comparing with shoots. Some species of plants had shown the difference tendency of heavy metal accumulation. Generally, most species had not exceeded over twice of mean value each other, and had various difference according to the kinds of heavy metals.

• Textile Coloration and Finishing
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• v.15 no.3
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• pp.140-145
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• 2003

The purpose of this study is searching the Elm-Bark dyes' dyeability and antibacterial activities according to the dyeing time, pH, a mordant and the method of mordancy. We used two kinds of Elm-Bark dyes which's extracted by the Electrolytic reduction water and Distilled water. Silk fabric and Cotton/nylon union fabric was used for this study. The results are as follow. K/S value is increased according to the dyeing time and the suitable pH level is pH 3. Dyeability is good with Iron(II) sulfate$(FeSO_4\cdot{7H}_2O)$ on the pre-mordancy and Potassium dichromate$(K_2Cr_2O_7)$ on the post-mordancy. The Elm-Bark dyes by the Electrolytic reduction water has good colorfastness more than by the Distilled water. Antibacterial activities is excellent and the ratio is over than 99.5%.

• Journal of Powder Materials
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• v.10 no.5
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• pp.344-347
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• 2003

Pure tantalum powder has been produced by combining Na as a reducing agent, $K_2$TaF$_{7}$ as feed material, KCl and KF as a diluent in a stainless steel (SUS) bomb, using the method of metallothermic reduction. And we examined various types of after-treatment that affect the high purification of powder. A significant amount of impurities contained in recovered powder was removed in various conditions of acid washing. In particular, 20% (HCl + HNO$_3$) was effective in removing heavy metal impurities such as Fe, Cr and Ni, 8% H$_2$SO$_4$ + 8% $Al_2$(SO$_4$)$_3$ in removing fluorides such as K and F from non-reactive feed material, and 2% $H_2O$$_2$ + 1 % HF in removing oxides that formed during reaction. Significant amounts of oxygen and part of light metal impurities could be removed through deoxidation and heat treatment process. On the other hand, because it is difficult to remove completely heavy metal impurities such as Fe, Cr, and Ni through acid washing or heat treatment process if their contents are too high, it is considered desirable to inhibit these impurities from being mixed during the reduction process as much as possible.

• Transactions of the Korean Society of Pressure Vessels and Piping
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• v.20 no.1
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• pp.49-55
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• 2024

Stainless 630 (or 17-4PH) is a precipitation-hardening martensitic stainless steel that has excellent mechanical properties and corrosion resistance. These characteristics make the STS630 to be used as a consisting material for various components such as spider, pin, spring, and spring retainer, of the control rod drive mechanism (CRDM) in pressurized water reactors (PWRs). In general, it is well known that the oxide layer of stainless steel consists of a duplex layer, a compact inner layer of FeCr₂O₄ spinel, and a coarse-grained outer layer of Fe₃O₄ spinel in PWR primary coolant condition. However, the characteristics of the oxide layer can be sensitively influenced by various water chemistry conditions such as temperature, dissolved oxygen, dissolved hydrogen, pH, pH adjuster type, and exposure time. In this work, we investigate the corrosion properties of the STS630 as a function of coolant temperature in an NH3 alkaline solution for its boron-free application in a small modular reactor, to confirm the feasibility for usage as a boron-free SMR structural material. As a result, oxide layer of corroded STS630 is consist of double-layer oxides consisting of a Cr-rich dense inner oxide and a Fe-rich polyhedral outer particles like as that in commercial PWR primary coolant. The corrosion rate of STS630 increases with increase in test time and temperature and the corrosion rate-time model equation was developed based on experimental data. Overall, it is expected that the results in this study provides useful data for the corrosion behavior of STS630 in alkaline environments, contributing to the development of selecting suitable materials for SMRs.