• 제목/요약/키워드: $CrO_3$

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청송 주왕산지역 대전사 현무암의 암석화학적 연구 (Petrochemical study on the Daejeon-sa basalt in the Mt. Juwang area, Cheongsong)

  • 윤성효;이문원;고정선;김영라;안지영
    • 암석학회지
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    • 제9권2호
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    • pp.84-98
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    • 2000
  • 주왕산 화산암체의 최하부층에 해당하는 대전사 현무암층은 전체적으로 12매의 용암과 9매의 페페라이트가 교호하며, 각 용암과 페페라이트의 암층의 두께는 다양하다. 현무암류는 육안으로 반정이 관찰되지 않으며 기공이 없는 치밀한 현무암이지만, 한 단위의 용암층 내에서 상부에는 다공질의 현무암이 발견되기도 한다. 경하에서의 현무암류는 주된 반정 광물로 가상의 감람석을 가지며, 사장석과 단사휘석의 반정도 보인다. 석기는 주로 서브오피틱 조직을 보인다. 대전사 현무암류는 MgO 함량이 4.8∼7.6 wt.%, Al2O3 함량은 16∼18 wt.%, CaO 함량은 9.1∼10.9 wt.%, 그리고 FeOT 함량은 7.4∼8.7 wt.%의 조성을 보인다. TAS 성분도와 SiO2에 대한 K2O의 성분도 그리고, 알칼리지수에 대한 Al2O3의 관계도에서는 칼크-알칼리 현무암에 도시된다. MgO를 분화 지수로한 각 산화물의 변화 경향은 MgO가 감소함에 따라서 Al2O3와 CaO는 증가하며, FeOT 함량은 감소하고, 호정성 원소는 감소한다. 불호정성 원소 중에서 HFS 원소는 MORB값 비슷한 반면에, LIL 원소는 부화되어 있다. 특히 Ce, P, 및 Sm이 약간 부화되어 있으며, Nb는 뚜렷한 부이상을 보인다. 희토류 원소는 전체적으로 부화되어 있으며, HREE에 비해서 LREE가 부화되어 있다. 조구조 판별도에서는. 지판이 침강 섭입하는 지판경제부 영역의 칼크-알칼리 계열 현무암에 도시되고, 특히 Th/Yb에 대한 La/Yb의 상관도에서는 본 현무암류가 대륙연변호 칼크-알칼리 화산대 환경에서 생성되었음을 알 수 있다. 대전사 현무암류의 초생 마그마는 섭입에 따른 유체의 공급으로 쐐기형 상부맨틀을 구성하는 석류석 감람암이 약 15% 부분용융되어 생성된 현무암질 마그마에서 유래되었다. 이들 마그마는 분출되기 직전에 주로 감람석의 분별 정출작용과 지각 물질이 동화되면서 진화된 후, 분출하였다. 필요가 있다.이 높게 나타났다.들을 대상으로 규칙적인 식사의 중요성과 다양한 식품의 섭취를 홍보하는 영양교육 이 보건소를 통해 강화되어야 하리라고 보여진다.인들의 계절별 식품 섭취량에 있어 겨울철의 식품 섭취량이 다른 계절에 비해 유의하게 높았으며, 남자노인보다는 여자노인이 식품섭취에 계절에 의한 영향을 더욱 더 많이 받는 것으로 나타났다. 또한 장수 노인들은 가공식품보다는 계절마다 제철에 생산 되는 자연 식품의 섭취비율이 높았다. 전반적으로 장수노인들은 소식의 경향을 보였으며 이 와 같은 소식습관과 신선한 식물성 식품들의 일상 섭취가 건강한 장수에 영향을 미쳤을 가 능성도 있을 것으로 사료된다.며, 지방 조직내 지방축적에 영향을 미친다는 것을 말해 준다.에서 하는 부모교육과 반상회의 홍보자료에 반상회의 홍보자료에 반드시환경친화적 음식소비행동에 관한 교육이 포함되어야 한다. 조리사의 경우 정기교육과정에 환경친화적 음식소비행동에 관한 홍보를 함께 함으로써 외식이나 단체급식에서 발행하는 음식물 쓰레기의 양을 줄 일 수 있을 것이다.m its genes controlling host specificity to its population sturctures and dynamics, have begun to provide new insights into the potential mechanisms underlying race variation. In this review we aim to provide an overview on (a) the molecular basis of host specificity of M. grisea, (b) the population structure and dynamics of rice pathogens, and (c) the nature and mechanisms of genetic changes underpinning virulence variation

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소백산변성대(小白山變成帶)와 옥방(玉房) 및 상동중석광상내(上東重石鑛床內)의 각섬석질암(角閃石質岩)의 지화학(地化學) 및 성인(成因)에 관(關)한 연구(硏究) (The Chemistry and Origin of Amphibolitic Rocks in the Sobaegsan Metamorphic Belt and the Ogbang and Sangdong Tungsten Mine Areas, Korea)

  • 소칠섭;김상명
    • 자원환경지질
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    • 제8권3호
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    • pp.147-164
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    • 1975
  • 소백산(小白山) 변성대내(變成帶內)의 옥방(玉房), 선산(善山), 지례(知禮) 및 단성(丹城)일대에 분포하는 각섬석질암(角閃石質岩) 중 옥방지역(玉房地域)의 것은 주변 변성암류(變成岩類)에 상합적(相合的)이며 엽이(葉理)가 잘 발달되어 있고 그외 지역의 것은 심한 화강암화작용(花岡岩化作用)의 영향을 받아 편마암(片磨岩)및 화강암질암내(岡岩質岩內)에 lense 상(狀)의 잔류체(殘留體)로 산출(産出)된다. 본 연구에서는 주로 소백산(小白山) 변성대내(變成帶內)의 각섬석질암(角閃石質岩)옥방중석광상((玉房重石鑛床) 포함)과 그의 경계부에 위치한 옥천지향사대내(沃川地向斜帶內)의 상동광상(上東鑛床)의 염기성변성암(鹽基性變成岩)의 시료를 대상으로 습식(濕式) 및 방출분광분석(方出分光分析)을 수행하여, 24개 주성분(主成分) 및 희유원소(稀有元素)의 정성(定性) 정량적(定量的)인 값을 variation trend와 discriminant function analysis 를 통하여 비교검토함으로써 이들의 성인(成因)을 밝혀보려 하였다. 주성분원소(主成分元素)의 Niggli value를 사용한 각종 도면에서는 화강암화작용(花岡岩化作用)으로 인한 alkali, alumina, 및 silica 등의 증가로 인하여 충분한 data를 얻지못했으나, 연구(硏究) 대상 시료(試料)의 희유원소(稀有元素)들은 alkli, alumina, silica의 증감(增減)에 영향을 받지않아 (도면 12, 13) 성인규명(成因規明)에 만족한 결과를 얻을 수 있었다. 옥방(玉房), 선산(善山), 지례(知禮) 및 단성지역(丹城地域)의 각섬석질암(角閃石質岩)은 각 도표에서 높은 비율의 Cr, Ni, Co, Ti, Sr 및 V의 값을 가지며 염기성(鹽基性) 화성암(火成岩)의 variation trend를 잘 보여주고, 상동지역(上東地域)의 염기성변성암(鹽基性變成岩)은 낮은 Cr, Ni, Co, Ti, Sr 및 V의 값과 낮은 Niggli mg 값을 가져서 화성(火成), 퇴적(堆積)의 두 특징을 동시에 나타내고 있으나 화성기원의 특징을 더욱 강조하여 준다. 한편 Discriminant function test ($X_1$, $X_2$, $X_3$)에서도 옥방(玉房), 선산(善山), 지체(知體), 단성(丹城)지역의 각섬석질암(角閃石質岩)은 한 개의 시료(試料)를 제외하고는 모두 $X_1$, $X_2$, $X_3$ 중 둘이상이 positive값을 가져 화성기원(火成起源)을 지시해주며 상동광상(上東鑛床)의 것은 하나의 시료는 둘이상의 positive 값 ($X_1$=7.08, $X_2$=0.43, $X_3$=-4.42) 을 나타내고 두 개의 시료는 둘 이상의 negative 값($X_1$=7.66, -8.60, $X_2$=-0.78, -2.13, $X_3$=4.62, -1.00) 을 나타낸다. 또한 기원암(起源岩)의 규명에서 본 연구의 대상이 된 모든 염기성(鹽基性) 변성암(變成岩)이 분출암(憤出岩)및 퇴적암(堆積岩)의 특징인 높은 oxidation ratio (2 $Fe_2O_3{\times}100/2$ $Fe_2O_3+FeO$, in mols)를 가지는 것으로 보아 주성분(主成分) 및 희유원소(稀有元素) 연구(硏究)결과와 비교하여 보면 분출암(憤出岩)에서 유래된 것으로 결론 될 수 있으나 소백산변성암(小白山變成帶)의 경우는 oxidation ratio의 증가가 심한 화강암화작용(花岡岩化作用)의 영향 일수도 있으며 야외산출상태와 현미경기재에서도 분출암(憤出岩)의 잔류증거를 찾지못하였다. 결론적으로 소백산변성대내의 옥방(玉房), 선산(善山), 지체(知體), 단성(丹城)일대의 각섬석질암(角閃石質岩)은 염기성(鹽基性) 관입암(慣入岩)으로부터 유래된 것으로 사료되고, 옥천지향사대내(沃川地向斜帶內)의 상동광상(上東鑛床)일대의 염기성변성암(鹽基性變成岩)은 Kamp (1968)와 Orville (1969)가 취급한 연구 결과에서와 같이 탄산염퇴적물(炭酸鹽堆積物)의 퇴적환경에서 침천한 염기성(鹽基性) tuff로부터 유래된 가능성이 많다.

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침지법(浸漬法)에 의한 CCA처리합판(處理合板)의 약제분포(藥劑分布)에 관한 연구(硏究) (Studies on Distribution of Toxic Element in Commercial Plywood treated with CCA Preservative by the Soaking Method)

  • 안세희;신동소
    • Journal of the Korean Wood Science and Technology
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    • 제13권2호
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    • pp.35-44
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    • 1985
  • The purposes of this study were, first, to investigate retention levels of toxic elements and oxide individual plies for each panel and, second, to examine disproportioning of individual toxic elements Thirty five water gum plywood panels were treated with a copper-chromium-arsenic preservative (CCA) by the soaking process as the treament time were applied. Such individual plies at a distance of 2.5cm, 7.5cm from the edge were assayed for CuO, $CrO_3$, and $As_2O_5$ on the basis of copper, chromium and arsenic content by Atomic Absorption Spectrophotometry. In these experiments, 12mm thickness plywood panels made of water gum, which were selling, were selected for the preservative treatment. Treating solutions were prepared for 10%, dilute solution of copper-chromium-arsenic preservative and then 1, 3, 6, 12 and 24 hours soaking trements in CCA preservative were applied. The results obtained are as follows: 1. The retention of total oxide in the face and back plies (1+7) retained more than the retention of total oxide in the other plies. The total oxide retention for the individual plies except the face and back plies (1+7) was showed in the following orders; cross plies (3+5), cross plies (2+6), core ply (4). 2. The retentions of total oxide increased as the increase of treatment time. The CCA treated plywood retained high levels of total oxide retention in the face and back plies (1+7). 3. All the retentions in the face and back plies (1+7) is over 5Kg/$m^3$, New Zealand Timber Preservation Standards Specification, and after 6 hours, the retentions in the cross plies (3+5) is over 4. The relative penetration of copper, chromium, and arsenic were not affected by the treatment time. The proportion of arsenic decreased in relation to both copper and chromium and the proportion of copper increased in relation to both chromium and arsenic. 5. A disproportioning of copper, chromium occurred with longer distance from edge, and with longer distance from edge the leachability resistance of CCA treated specimens decreased. After 6 hours (soaking time), the proportion of active elements at a distance of 2.5cm from the edge was consistent. And after 24 hours-soaking, the proportion of active elements at a distance of 7.5cm from the edge was consistent.

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전국(全國) 산업장(産業場)에서 배출(排出)되는 오염물질량(汚染物質量)에 관(關)한 연구(硏究) (A Study on the Status of Air and Water Pollutants Emission from Industries in Korea)

  • 차철환;장창섭;김형원;성영자
    • Journal of Preventive Medicine and Public Health
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    • 제6권1호
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    • pp.27-41
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    • 1973
  • In order to provide some basic data for the control of air and water pollution in Korea, the authors have estimated the amount of air and water pollutants emitted from industries which are employed over 20 employees. This study have done from July 1, 1972 to the end of March 1973. The results are as followings; 1. Total number of establishments with over 20 employees is 5,197 in Korea and the largest group establishments was the manufacturing of textiles with 1,363 establishments (26.2%). 2. By order of number of employees it was observed that there 2,800 industries with 20-59(53.9%) employees, 1,101 with 50-99 (21.2%), 571 with 100-199 (11.0%), 501 with 200-499 (9.6%) and 225 with over 500 (4.3%) respectively. 3. By order of regional distribution, it was observed that there were 2,257 industries in Seoul (43.2%) and 736 industries in Pusan(14.2%). 4. Industrial coal consumption was 596,154 M/T in 1972, but it' 11 be 315,000 M/T in 1980. Fuel consumption was 4,972,000 K1 in 1972, and estimated volume will be 19,370,000 K1 in 1980. 5. Total amounts of air polutants entitled from industries by fuel combustion were sulfur oxides 79,459 tons, carbon monoxide 33,908 tons, particulate 31,304 tons and hydrocarbon 30,280 tons in 1972 but in 1990 there will be sulfur oxides 1,010,474 tons, nitrogen oxides 204,575 tons, carbon monoxide 68,014 tons, particulate 64,820 tons and hydrocarbon 67,622 tons, respectively. 6. Annual emitted air pollutants through the working processes were sulfur oxides 91,250 tons and nitrogen oxides 32,485 tons in 1972, but sulfur oxides 118,625 tons and nitrogen oxides 42,555 tons will be present in 1980, respectively. 7. Annual emitted air pollutants by national unit area amounted to $0.77ton/km^2/year$ in 1965 and $14.7ton/km^2/year$ in 1980. 8. Total industrial wastes from all industries in Korea were estimated at 810,360 tons/day in 1972; manufacturing of chemicals and plastic products showed the highest amount of wastes at 470,000 tons/day. 9. The amounts of water pollutants due to industrial wastes were the B.O.D., 471.5 tons/day, suspended solid 331.5 tons/day, CN, 2.3 tons/day, and Cr. 3.4 tons/day in 1972, but it might be evident of a B.O.D. of 3,388 tons/day, suspended solid 2,544 tons/day, CN 20.1 tons/day, and 26.5 tone/day in 1990. 10. Total population equivalent of B.O.D. was 943,000 in 1972, and the estimated value in 1950 will be 6,780,000.

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Butachlor의 4종 담수조류(freshwater algae)에 대한 생장영향 (Effects of Butachlor on Growth of Four Freshwater Algae)

  • 박연기;배철한;김병석;박경훈;이제봉;신진섭;홍순성;조경원;이규승;이정호
    • 농약과학회지
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    • 제12권1호
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    • pp.82-87
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    • 2008
  • 우리나라에서 사용되고 있는 벼재배용 제초제인 butachlor의 담수조류에 대한 생장영향을 알아보고자 녹조류 Selenastrum capriconutum, Scenedesmus subspicatus, Chlorella vulgaris 3종과 규조류 Nitzschia palea 1종에 대해 72시간 생장저해시험(growth inhibition test)을 수행하였다. 시험결과 butachlor에 대한 S. capricornutum, S. subspicatus, C. vulgaris, 그리고 N. palea의 생장율 기준 반수영향농도($EC_{50}$)는 각각 0.0022, 0.019, 8.67 그리고 $4.94\;mg\;L^{-1}$이었고, 무영향농도(NOEC)는 0.0008, 0.0016, 5.34 그리고 $2.92\;mg\;L^{-1}$로 나타나 S. capricornutum가 가장 높은 감수성을 보였다. 양성대조물질인 $K_2Cr_2O_7$에 대한 S. capricornutum, S. subspicatus, C. vulgaris 그리고 N. palea의 생장율 기준 $EC_{50}$은 각각 0.91 0.78, 0.85 그리고 0.57 mg $EC_{50}$이었고, NOEC는 각각 0.2, 0.2, 0.2 그리고 0.18 mg $EC_{50}$였다. butachlor를 논에 살포하였을 때 논물에 전량 용해된 후 배수로를 통해 농수로에 배출될 때를 가정한 환경추정농도(Predicted Environmental Concentration; PEC)에 따른 생장저해율을 계산한 결과, S. capricornutum와 S. subspicatus는 각각 100%와 75%의 생장율 저해를 보였으나 C. vulgaris와 N. palea는 영향이 없었다.

Analysis of in vitro 2D-COSY on Human Brain Metabolites for Molecular Stereochemistry

  • Kim, Sang-Young;Woo, Dong-Cheol;Bang, Eun-Jung;Kim, Sang-Soo;Lim, Hyang-Sook;Choi, Chi-Bong;Choe, Bo-Young
    • 한국자기공명학회논문지
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    • 제12권1호
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    • pp.14-25
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    • 2008
  • To investigate the 3-bond connectivity of human brain metabolites by scalar coupling interaction through 2D-correlation spectroscopy (COSY) techniques using high field NMR spectroscopy. All NMR experiments were performed at 298K on Unity Inova 500 or 600 (Varian Inc.) equipped with a triple resonance probe head with z-shield gradient. Human brain metabolites were prepared with 10% $D_2O$. Two dimensional 2D COSY spectra were acquired with 4096 complex data points in $t_2$ and 128 or 256 increments in $t_1$ dimension. The spectral width was 9615.4 Hz and solvent suppression was achieved using presaturation using low power irradiation of the water resonance during 2s of relaxation delay. NMR data were processed using VNMRJ (Varian Instrument) software and all the chemical shifts were referenced to the methyl resonance of N-acetyl aspartate (NAA) peak at 2.0 ppm. Total 10 metabolites such as N-acetyl aspartate (NAA), creatine (Cr), choline (Cho), glutamine (Gln), glutamate (Glu), myo-inositol (Ins), lactate (Lac), taurine (Tau), ${\gamma}$-aminobutyricacid (GABA), alanine (Ala) were included for major target metabolites. Symmetrical 2D-COSY spectra were successfully acquired. Total 14 COSY cross peaks were observed even though there were parallel/orthogonal noisy peaks induced by water suppression. Except for Cr, all of human brain metabolites produced COSY cross peaks. The spectra of NAA methyl proton at 2.02 ppm and Glu methylene proton ($CH_2(3)$) at 2.11 ppm and Gln methylene proton ($CH_2(3)$) at 2.14 ppm were overlapped in the similar resonance frequency between 2.00 ppm and 2.15 ppm. The present study demonstrated that in vitro 2D-COSY represented the 3-bond connectivity of human brain metabolites by scalar coupling interaction. This study could aid in better understanding the interactions between human brain metabolites in vivo 2D-COSY study. Also it would be helpful to determine the molecular stereochemistry in vivo by using two-dimensional MR spectroscopy.

디젤 개질을 위한 페로브스카이트 구조 촉매와 연료주입 시스템의 개발 (Preparation of perovskite-based catalysts and fuel injection system for high durability of diesel reforming)

  • 이준기;박상선;설용건
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 추계학술대회 초록집
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    • pp.115.2-115.2
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    • 2010
  • Autothermal reforming(ATR) processes of hydrocarbon liquids such as diesel fuels are spotlighted as methods to produce hydrogen for Fuel cell. However, the use of heavy hydrocarbons as feedstocks for hydrogen production causes some problems which increase the catalyst deactivation by the carbon deposition. Coking can be inhibited by increasing the water dissociation on the catalyst surface. This results in catastrophic failure of whole system. Performance degradation of diesel autothermal reforming leads to increase of undesirable hydrocarbons at reformed gases and subsequently decrease the performance. In this study, perovskite-based catalysts were investigated as alternatives to substitute the noble metal catalyst for the ATR of diesel. The investigated perovskite structure was based on LaCrO3. and metals were added at the A-site to enhance oxygen ion mobility, transition metals were doped on the B-site to enhance the reformation. Substituted Lanthanum chromium perovskite were made by aqueous combustion synthesis, which can produce high surface area. And for the homogeneous fuel supply, we made ultrasonic injection system for reforming. We compared durability of evaporation system and ultrasonic system for fuel injection.

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석탄화력발전소 주변해역 퇴적물 내의 중금속원소의 함량과 지화학적 존재형태 (Concentration and Geochemical Phases of Heavy Metals in Marine Sediments in the Vicinity of the Coal-fired Power Plant of Korea)

  • 이두호;정연태
    • 환경영향평가
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    • 제9권4호
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    • pp.301-314
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    • 2000
  • Marine surface sediments in the vicinity of Samcheonpo coal-fired power plant were analyzed by a total analysis($HF+HNO_3+HClO_4$) and sequential extraction procedure for heavy metals in order to investigate the total concentrations and geochemical phases of heavy metals. The result showed that the concentrations of Cr, Cu, Fe and Zn were within ranges typical for coastal areas, which reflected the mineralogical composition of the sediments in the studied area. However, the distributions of Cd, Co, Mn, Ni and Pb were rather different from the former, indicating that these heavy metals had a different origin, or that they were affected by a different geochemical mechanism. Chemical partitioning of heavy metals using sequential extraction procedure revealed that Cu, Fe, Pb, Zn were significantly bound to the residual phases of the sediments, whereas carbonate phases contained considerable amounts of Mn. The significant association of Pb with the exchangeable fraction also indicated that Pb was more mobile and bioavailable than Cu, Fe, Mn, Zn.

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부실식 정적연소실내 층상혼합기의 연소특성( I ) (Combustion Characteristics of Stratified Mixture in a Constant Volume Combustion Chamber with Sub-chamber( I ))

  • 김봉석;권철홍;류정인
    • 한국자동차공학회논문집
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    • 제3권1호
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    • pp.65-75
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    • 1995
  • The present study was investigated combustion characteristics of methane-air mixtures at stratified charge in a constant volume combustion chamber. The results indicated that even the vety lean mixture, which is normally not flammable in single chamber type, could be burned within. a comparatively short time by using sub-chamber with stratified charge method. And the lean inflammability limit of mixture in a main chamber was about ($\phi_m$cr=O.46, when the equivalence ratio of a sub-chamber was $\phi_s$= 1.0. Initial time of pressure increase and total burning times were decreased and maximum combustion pressure. was increased as the equivalence ratio of both sub and main chamber approached unity. Specifically, initial time of pressure increase and total burning times were greatly affected rather by. the equivalence ratio of sub-chamber than that of main chamber. The maximum combustion pressure was little affected if the total equivalence ratio lies in the same range.

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국내 토양공정법과 산처리 방법의 비교: 최종 pH와 용출률의 관계

  • 이평구;최선규;오창환;이재영
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2000년도 창립총회 및 춘계학술발표회
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    • pp.46-51
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    • 2000
  • Environmental quality regulations are used to establish the maximum permissible concentrations of heavy metals before a site can be deemed to be polluted or contaminated. This paper compares the results obtained by 0.IN HCl extraction and acid extraction method(HNO$_3$+HClO$_4$.HCl). The leaching efficiency of 0.1N HCl extraction is directly proportional to the final pH of leachate, due to the different solubilities of the heavy metals at different pH values, The severe differences between 0.1N HCl-extractable and total metal contents result mainly from the buffering effect of carbonates, present in sediment. samples. Application of sequential extraction experiments to some sediments collected from gully pot in Seoul illustrates a much stronger scavenging effect by Fe and Mn-hydroxides, carbonates and organic phases. As deduced from both sequential extraction and leaching experiments, the relative mobility of heavy metals is found to be: Mn>Zn>>Co>Cd>>Cu>Pb>Cr>Fe, in spite of large differences in heavy metal content and localization. Changes in the physicochemical environments (such as acidification) caused by a traffic accident may result in the severe environmental pollution of heavy metals of surrounding area( surface water and rivers).

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