• Title/Summary/Keyword: $CaFe_2O_4$

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Studies on the Ouality of Boxthorn in Korea(Lycium chinense Miller) (한국 구기 품종의 품질에 관한 연구)

  • 이상래
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.28 no.2
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    • pp.267-271
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    • 1983
  • The southern parts varieties have shown higher content of Oleic acid, Linoleic acid, Vitamin A, Alcaloid, Ca, P and Fe than northern parts Varieties. The $N.\;P_2O_5\;and\;K_2O content of narrow leaf were higher than wide leaf, on the other hand the Ca, Mg, Fe and $SiO_2$ content of wide leaf were higher than narrow leaf. The content of $N, \;P_2O_5, \;K_2O$ have shown higher in first yellow leaf date, the content of Ca has shown higher in first falling leaf date and the content of Mn and Cu content have shown higher in second new leaf date.

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Thermodynamic of Phosphorus in FeO-MnO-CaO-SiO2-MgOsatd. Slag Systems (FeO-MnO-CaO-SiO2-MgOsatd. 슬래그에서의 P의 열역학적 거동)

  • Cho, Moon Kyung;Park, Kyung Ho;Min, Dong Joon
    • Korean Journal of Metals and Materials
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    • v.47 no.3
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    • pp.188-194
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    • 2009
  • Recently, new extraction technology for manganese nodule has been developed as alternative noble metallic resources. It is important to understand thermodynamic behaviors of phosphorus in low basic slag system from the viewpoint of the refining processing optimization. Thermodynamic behaviors of phosphorus in the $FeO-MnO-CaO-SiO_2-MgO_{satd.}$ slag system were investigated at 1723 K with various oxygen potential and slag composition of low basicity. The experimental results for dependence of phosphorus on oxygen potential and slag basicity indicated that the dissolution mechanism of phosphorus into slag of low basicity could be derived as follows; $[P]+5/4O_2+(O^{2-})=({PO_{3.5}}^{2-})$ Present experimental results implied that stability of phosphorus in slag would be depended on both of $O^{2-}$ (basicity) and content of $Ca^{2+}$ in molten slag. The thermodynamic effect of FeO, MnO and $Na_2O$ on low basicity on phosphate capacity was discussed.

Relation of the Skarnized Calcareous Nodules in the Hwajeol Formation and the Deep Concealed Orebody (화절층내 석회질 단괴(團塊)의 스카른화와 심부잠두(深部潛頭) 광체와의 관계)

  • Moon, Kun-Joo
    • Economic and Environmental Geology
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    • v.24 no.4
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    • pp.335-346
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    • 1991
  • It is observed that calcareous nodules of the Hwajeol Formation are locally skarnized in the Sangdong district, in which the skarn mineralization extends 5 Km westward from the Sangdong mine area to the Hwajeolchi area. After a hidden granite beneath the Sangdong mine was discovered by exploration drillings, the exploration teams of the Sangdong mine and the Korean Mining Promotion Corporation have assumed that the skarn nodule of the Hwajeol Formation was derived from emplacement of a granite in deep place and the occurrence of hidden ore bodies below the skarn, and they have discovered high grades of tungsten orebody in the same horizon of the Sangdong ore body. Mutual genetic relatioships between epidote and garnet may be explained by following chemical reactions $Ca_2FeA_{12}$ $Si_3O_{12}(OH)+CaCO_3=Ca_3(Fe,\;Al)_2$ $SiO_{12}+1/2CO_2+1/2H^+Ca_3FeSi_3O_{12}+SiO_2+CO_2=2CaFeSi_{12}O_6+CaCO_3+1/2O_3$. It is concluded that epidote and garnet are useful as target minerals indicating a potential occurrence of deep seated hidden ore body. Since the epidote may inform the emplacement of the granite, while the garnet in the skarn nodule of the Hwajeol Formation may reflect a strong hydrothermal mineralization taking place from the depth.

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Characteristics and Standards of Domestic Tidal Flat Mud Marine Healing Resources (국내 갯벌머드 해양치유자원의 특성 및 기준에 관한 연구)

  • Seonyoung Park;Jeongwon Kang;Yonggi Jeong;Yeonje Cho
    • Journal of Wetlands Research
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    • v.25 no.4
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    • pp.386-393
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    • 2023
  • The domestic marine healing industry is undergoing significant revitalization efforts, with a focus on understanding the efficacy and effectiveness of marine healing resources. This study establishes utilization and management standards through a detailed analysis of the active components within well-recognized marine healing mud materials. Samples of mud materials were collected from domestic tidal flats. These samples exhibited an average composition of 7.87% sand, 74.95% silt, and 17.17% clay, with a combined mud content (silt+clay)(silt+clay) consistently exceeding 90%. Notably, SiO2 emerged as the most prevalent effective ingredient at 68.4%, followed by Al2O3 (13.3%)>Fe2O3 (4.0%)>K2O (2.9%)>Na2O (2.3%)>MgO (1.6%)>CaO (1.0%)>TiO2 (0.7%), in terms of average content. Subsequently, through an analysis of effective ingredients, Si, Al, Fe, K, Na, Mg, and Ca were identified as elements demonstrating significant functionality. Among these, key indicator ingredients were selected for quality control, all of which were found to possess efficacious properties. Notably, K, Mg, and Ca exhibited particularly high concentrations. Based on these findings and referencing existing literature, it is recommended that domestic tidal flat mud resources earmarked for utilization as marine healing resources should possess a raw material mud content of no less than 70.0%. Moreover, the cumulative index components K2O+MgO+CaO should meet or exceed a threshold of 5.0% for optimal effectiveness.

Effect of $ SO_3$ on Calciumsilicate Formation(II) (Calciumsilicate의 생성반응에 미치는$ SO_3$의 영향(II))

  • 임은극;박병철
    • Journal of the Korean Ceramic Society
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    • v.21 no.2
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    • pp.113-120
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    • 1984
  • In this study a comparative investigation for the effect of $K_2SO_4$ and $CaSO_4$ on the decomposition of $C_3S$ was made. When pure $C_3S$ which was synthesized in the laboratory was mixed with $K_2SO_4$ and oxides such as MgO $Al_2O_3$ and $Fe_2O_3$ and then reburned at the temperature range between 135$0^{\circ}C$ and 145$0^{\circ}C$ no decompo-sition occurred, But when $CaSO_4$ and $Fe_2O_3$ were added to $C_3S$ and then reburned at below 130$0^{\circ}C$ $C_3S$ was partly decomposed to $C_2S$and CaO composing $2C_2S$.$CaSO_4$ When $CaSO_4$ and $Al_2O_3$were added $C_3S$ was entirely decomposed to $C_2S$ and CaO at 1300~140$0^{\circ}C$ but it was not decomposed at 145$0^{\circ}C$.

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Effects of MgO content of Spinel on the Reaction of Spinel with CaO-Al$_2$O$_3$-SiO$_2$ Slag (CaO-Al$_2$O$_3$-SiO$_2$계 슬래그와 스피넬의 반응에 미치는 스피넬중의 MgO함유량의 영향)

  • 조문규;홍기곤
    • Journal of the Korean Ceramic Society
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    • v.36 no.4
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    • pp.410-416
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    • 1999
  • The reactivity of three kinds of spinels which CaO-Al2O3-SiO2 slag was investigated in terms of mineral phases and microstructures. New crystal products were not formed by reaction of 12CaO.7Al2O3 in the slag with spinels and free MgO components was preferenctially dissolved into slag for MgO-rich spinel and stoichiometric spinel. Meanwhile mineral phase was changed from 12CaO.7Al2O3 to CaO.Al2O3 to CaO.2Al2O3 finally to CaO.6Al2O3 having high melting point for Al2O3 -rich spinel. The Fe-oxide component of the slag was taken up by only stoichiometric spinel grains within the spinel clinker and the trapped amount of Fe-oxide was independent of MgO content of MgO in spinel clinker the more th resistance to slag corrosion but the less resistance to slag penetration.

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A study for use a vanadium oxide in steel manufacture (제강 공정중 산화바나듐활용 연구)

  • Choi, Young-Key
    • Journal of environmental and Sanitary engineering
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    • v.24 no.3
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    • pp.55-61
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    • 2009
  • Fe-V is used as raw material of vanadium in the steel making process. The purpose of this study, Fe-V is to replace the $VO_{4}$. So the distribution behavior of vanadium in $VO_{4}$ of the steel investigated. The distribution ratio of the vanadium where potential of the free oxygen ion will increase in slag decreased. When CaO and MgO content which is a basic oxide from CaO-$SiO_2$-FetO-MgOsatd. slag increases, S distribution ratio increases. CaO-$SiO_2$-FetO-MgOsatd. slag better than CaO-$SiO_2$-$Al_2O_3$-MgO slag is the recovery of vanadum and desulfurization.

Electrochemical Properties of $LiFePO_4-LiCoO_2$ Cathode Materials in Lithium Secondary Batteries (리튬이차전지 정극활물질용 $LiFePO_4-LiCoO_2$의 전기화학적 특성)

  • Kong, Ming-Zhe;Kim, Hyun-Soo;Kim, Ke-Tack
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.241-242
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    • 2006
  • In this work, the $LiFePO_4-LiCoO_2$ mixed cathode electrodes were prepared and their electrochemical performances were measured in different current density. The cell of $LiFePO_4-LiCoO_2$ observed two voltage plateau regions at 3.4 and 3.9V. The cell of $LiFePO_4-LiCoO_2$ (90:10 wt%) mixed cathode delivered a discharge capacity of ca. 139.8 mAh/g at a 0.2C rate. The capacity of the cell decreased with the current rate and a useful capacity of ca 85.7mAh/g was obtained at a 2C rate.

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Gahnite-Sillimanite-Garnet Mineral Assemblage from the Host Rocks of the Cannington Deposit, North Queensland, Australia: Relationship between Metamorphism and Zn-Mineralization (호주 퀸즈랜드 주 캔닝턴 광상 모암의 아연-첨정석-규선석-석류석에 관한 연구 :변성작용과 아연-광화작용에 대해서)

  • Kim Hyeong Soo
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.4
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    • pp.309-325
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    • 2004
  • The Cannington Ag-Pb-Zn deposit, northwest Queensland, Australia developed around the host rocks composing banded and migmatitic gneisses, sillimanite-garnet schist and amphibolite. Three crystal habits of sillimanite, gahnite (Zn-spinel) and garnet porphyroblasts occurred on the host rocks of the Cannington deposit could be used to delineate metamorphism that closely associated with Zn-mineralization in the deposit. Linkages the metamorphism to Zinc-mineralization is determined in four chemical systems, KFMASH (K$_2$O-FeO-MgO-Al$_2$O$_3$-SiO$_2$-$H_2O$), KFMASHTO (K$_2$O-FeO-MgO-Al$_2$O$_3$-SiO$_2$-$H_2O$-TiO$_2$-Fe$_2$O$_3$), NCKFMASH (Na$_2$O-CaO-K$_2$O-FeO-MgO-AlO$_3$-SiO$_2$-$H_2O$) and MnNCK-FMASH (MnO-Na$_2$O-CaO-K$_2$O-FeO-MgO-AlO$_3$-SiO$_2$-$H_2O$), using THERMOCALC program (version 3.1; Powell and Holland 1988). Partial melting in MnNCKFMASH and NCKFMASH systems occurs at lower temperature than in the KFMASH and KFMASHTO systems. The partial melting temperature decreases with increasing of Na/(Na+Ca+K) of the bulk rock compositions in the MnNCKFMASH system. The host rocks have melted ca 15 vol.% in the MnNCKFMASH system at peak metamorphic conditions (634$\pm$62$^{\circ}C$ and 4.8$\pm$1.3 kbar), but partial melting have not occurred in KFMASHTO system. Based on calculations of sillimanite isograd in different systems and sillimanite modal pro-portion, prismatic and rhombic sillimanite and gahnite porphyroblasts including prismatic sillimanite inclusion probably have resulted from pressure and temperature increasing through partial melting (from 550~$600^{\circ}C$, 2.0~3.0 kbar to 700~75$0^{\circ}C$, 5.0~7.0 kbar), furthermore have experienced N-S then W-E crustal shortening during D$_1$ and D$_2$ deformation. Consequently, Zinc mineralization related to gahnite growth occurred during D$_2$ and was redistributed and upgraded by partial melting and retrograde metamorphism into structural and rheological sites during shearing in D$_3$.

Effect of Blast Furnace Slag and Desulfurized Gypsum on Hardening of CFBC Boiler Coal Ash (CFBC 보일러 석탄회의 경화에 대한 고로슬래그, 탈황석고의 영향)

  • Lee, Woong-Geol;Kim, Jin-Ho;Kim, Kyung-Nam;Song, Myong-Shin
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.443-450
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    • 2021
  • The effects of blast furnace slag(BFS) and desulfurized gypsum(FDG) on the compressive strength of CFBA, and self-hydration of CFBA were studied. CFBA has self-hydrating and hardening properties, and it can be seen that the compressive strength of CFBA can be improved by using appropriate amounts of BFS and FDG. In addition, the self-hardening properties of CFBA are similar to the hydration reaction of 4CaO·Al2O3·Fe2O3 (C4AF), a cement clinker mineral, and when free-CaO, CaSO4 and CaCO3 coexist, Compressive strength of CFBA is expressed by the formation of calcium carbo compounds and hydrates of ettringite, calcium silicate, and calcium aluminate.