• 제목/요약/키워드: $C_{22}H_{13}N_3$

검색결과 118건 처리시간 0.02초

Small group of protostellar objects: L1251C

  • 김정하;이정은;최민호
    • 천문학회보
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    • 제38권1호
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    • pp.51.1-51.1
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    • 2013
  • We present molecular line observations of a small group of Young Stellar Objects (YSOs), L1251C. Observations by Spitzer Space Telescope legacy program "From Molecular Cores to Planet Forming Disks"(c2d; Evans et al. 2003) revealed that there are three YSOs within ~15" in L1251C: IRS1 (Class I), IRS2 (Class II), and IRS3 (Class II). In order to understand the molecular environment around these YSOs, we carried out the KVN single-dish observations in $HCO^+$ J=1-0, $H^{13}CO^+$ J=1-0, $N_2H^+$ J=1-0 and HCN J=1-0. CO J=1-0 was also mapped in L1251C with the TRAO 14m telescope. Integrated intensity maps of high density tracers such as $H^{13}CO^+$ J=1-0, $N_2H^+$ J=1-0 and HCN J=1-0 show similar emission distributions, whose peaks are off from the positions of YSOs. However, $HCO^+$ J=1-0, which is believed to trace both infall and outflow, presents its emission distribution different from those of other molecular transitions. The line profile of $HCO^+$ J=1-0 is superimposed by two velocity (narrow and broad) components. The $HCO^+$ outflow map reveals multiple structures while the CO outflow map elongates mainly along the EW direction. With the KVN single dish, the 22 GHz $H_2O$ maser emission has been also monitored toward L1251C to find variations of the systemic velocity and intensity with time.

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Ni80Fe20/[Ir22/Mn78-Mn]/Co75Fe25 다층박막에서 Mn 함유량에 의존하는 교환결합력과 열적안정성 (Exchange Coupling Field and Thermal Stability of Ni80Fe20/[Ir22/Mn78-Mn]/Co75Fe25 Multilayer Depending on Mn Content)

  • 김보경;이진용;김순섭;황도근;이상석;황재연;김미양;이장로
    • 한국자기학회지
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    • 제13권5호
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    • pp.187-192
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    • 2003
  • IrMn에 Mn을 첨가시킨 N $i_{80}$F $e_{20}$/[I $r_{22}$M $n_{78}$-Mn] $Co_{75}$F $e_{25}$ 다층박막을 상온에서 이온빔 증착(ion beam deposition: IBD)법으로 제작하여 그 자기적 및 열적 특성을 연구하였다. Mn이 첨가된 NiFe/[IrMn-Mn]/CoFe다층박막은 Mn이 첨가되지 않은 순수 합금 IrMn 박막 위의 CoFe 고정층 보다 큰 교환결합력( $H_{ex}$)과 방해온도(blocking temperature: $T_{b}$)을 가지고 있었다. Mn이 첨가되지 않는 I $r_{22}$M $n_{78}$ 와 CoFe 사이의 $H_{ex}$는 상온에서 거의 없었으나, 25$0^{\circ}C$ 열처리 후 100 Oe로 나타났다. IrMn 내에서 76.8-78.1 vol% Mn일 때, $H_{ex}$$T_{b}$는 크게 향상되었고, Mn이 0.6 vol%씩 증가함에 따라 크게 줄어들었다. NiFe/[IrMn-Mn]/CoFe 다층박막 구조에서 [(111)CoFe, NiFe]/(111)IrM $n_3$인 x-선 회절 피크비 평균값은 75.5, 77.5, 79.3 vol% Mn일 때 각각 1.4, 0.8, 0.6였다. 특히, 열처리 전 77.5과 78.7 vol% Mn일 때, $H_{ex}$는 각각 259와 150 Oe였다. 77.5 vol% Mn인 경우, $H_{ex}$가 열처리 온도 35$0^{\circ}C$까지 475 Oe였으며, 450 $^{\circ}C$에서는 200 Oe로 크게 감소하였다. 따라서 합금형 반강자성체 IrMn에서 높은 $H_{ex}$$T_{b}$을 얻을 수 있는 최적의 Mn 함유량의 존재를 확인하였다.다.다. 확인하였다.다.하였다.다.

${\gamma}$-Linolenic acid 함유 곰팡이 지질에 관한 연구 2. Mucor sp.의 ${\gamma}$-Linolenic Acid 생산에 미치는 배양조건의 영향 (Studies on Fungal Lipids Containing ${\gamma}$-Linolenic Acid 2. Influence of Cultural Conditions on The Production of ${\gamma}$-Linolenic Acid by Mucor sp.)

  • 송근섭;김충기;권용주;양희천;이태규
    • 한국식품영양과학회지
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    • 제19권6호
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    • pp.641-645
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    • 1990
  • In order to study the influence of culture conditions on cell growth and lipid formation by Mucor sp, various carbon and nitrogen sources initial pH and C./N ratio of medium were investigated. Glucose was found to be suitable carbon source in terms of lipid yield and ${\gamma}$-linolenic acid(GLA) content. When NH4Cl and (NH4)2SO4 were used as nitrogen source lipid content was high(19-21%) but GLA content was low(15-17%) On the other hand when NaNO3 and KNO3 were used lipid content was low(about 13%) but GLA content was high(22-23%). The highest production of lipid was obtained at a C/N ratio of 40 using glucose and (NH4)2SO4 as carbon and nitrogen source respectively. it was found that lipid yield was high at pH4.6 Also this fungus did not grow at 35$^{\circ}C$ and lipid yield was highr at 15$^{\circ}C$ than $25^{\circ}C$.

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독활로부터 항치아우식 활성을 가진 stigmasterol 분리 (Isolation of Anti-cariogenic Agent, Stigmasterol, from Aralia continentali)

  • 유현희;문해닮아;황지영;김선영;정승일;전병훈;유용욱
    • 동의생리병리학회지
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    • 제21권1호
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    • pp.70-75
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    • 2007
  • In the present study, we has been isolated the anti-cariogenic component, stigmasterol, from Aralia continentalis (A. continentalis) and identified by MS, $^1$H-NMR and $^{13}$C-NMR and also investigated the anti-cariogenic properties of stigmasterol. The methanol extract of ,A. continentalis showed concentration-dependent inhibitory activity against the growth and acid production of S. mutans. The MeOH extract was suspended in H$_2$O and sequentially partitioned with n-hexane, CHCl$_3$, EtOAc, and n-BuOH. The CHCl$_3$ fraction showed remarkable antibacterial activity against S. mutans. The anti-cariogenic compound, stigmasterol, has been isolated successively through the screening system and various chromatography methods. Anti-cariogenic properties of stigmasterol were also investigated. From this active chloroform subfraction, isolation and identification finally gave (24E)-stigmasta-5,22-dien-3${\beta}$-ol (stigmasterol) {[a]$_D\;^{25}$ -48.33$^{\circ}C$(C 0.28, CHCl$_3$)} by spectroscopic methods (MS, $^1$H-NMR and $^{13}$C-NMR) as an active principle. The compound, stigmasterol, showed significant growth, acid production, adhesion and water-insoluble glucan synthesis inhibitory effect against S. mutans. These results suggest that stigmasterol from ,A. continentalis may inhibit cariogenic properties of S. mutans and these properties may provide some scientific rationales that the local inhabitants used the extracts for treatment of dental diseases.

질소구배에 따른 대두개체군의 생장 및 일차생산성 (Effect of Nitrogen Applications on the Growth and Primary Production of Soybean Population)

  • Song, Seung-Dal;Seung-Won Yu
    • The Korean Journal of Ecology
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    • 제3권1_2호
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    • pp.11-16
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    • 1980
  • 무시비구, 질소시비구(6.67gN/$m^2$) 및 과질소비구(13.34gN/$m^2$)의 질소구배처리에 따른 대두개체군의 생육과정별 제 생장해석적특징 및 일차생산성을 비교검토하였다. 질소시비구 및 과질소시비구에서는 대조구에 비해 8~10배의 순질소흡수율과 비교적 높은 생산성 및 최대 LAI의 도달이 2주정도 빨리 나타났고 SLA의 증가를 보였으나, 근립의 형성은 1/3~1/4의 감소를 보였다. 그러나, H, F/C, T/R, RGR, NAR, 및 CGR 등 생장해석적특징에는 큰 유의차가 없었다.

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Various Fatty Acids Induce Cell Damages Differently in CYP2E1-transduced HepG2 Cells, E47 Cells, Compared to C34 Cells

  • Lee, Myoung-Sook;Bae, Myung-Ae
    • Nutritional Sciences
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    • 제9권1호
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    • pp.9-13
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    • 2006
  • The differential effects of various fatty acids such as n-3 and n-6 types or degrees of unsaturation on the CYP2E1 induction and the production of lipid peroxidation (LPO) were investigated. The CYP2E1-transduced human hepatoma HepG2 cells (E47) were cultured in RPMI 1640 media containing different concentrations of various fatty acids up to 48 h incubation compared to 04 cells and CYP2E1-null cells. Treated fatty acids were linoleic acid (LA:n-6, C18:2), arachidonic acid (AA:n-6, C20:4) and docosahexaenoic acid (DHA:n-3, C22:6). The cell survival rate was decreased corresponding to the degree of unsaturation (LA>AA $\cong$DHA) and to LPO production in E47 and 04 cells. The four or five unsaturation degree of fatty acids, AA and DHA, caused time- and dose-dependent cell death in E47 cells but not as much as in C34 (without CYP2E1), suggesting an important role of CYP2E1 in the DHA mediated damage. In the levels of lipid peroxides (LPO), AA also elevated LPO by 3- and 5- fold compared to DHA or LA treated E47 cells. However, AA did not increase LPO until 48 h incubation in C34 cells. In conclusion, the polyunsaturated fatty acids induced CYP2E1 induction might be changed by the elevated levels of lipid peroxide (LPO) and oxidative stress through the connection of CYP2E1 and degrees of unsaturated fatty acids.

Crystal and Molecular Structure of 4,6-Dimethyl-9-phenyl-8,12-dioxa-4,6-diazatetracyclo [8.8.0.02,7.013,18]octadeca-2(7),13,15,17-tetraene-3,5,11-trione 2-ethoxyphenyl (2E)-but-2-enoate

  • Ganapathy, Jagadeesan;Damodharan, Kannan;Manickam, Bakthadoss;Sanmargam, Aravindhan
    • 통합자연과학논문집
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    • 제6권4호
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    • pp.197-204
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    • 2013
  • The crystal structure of the potential active 4,6-dimethyl-9-phenyl-8,12-dioxa-4,6-diazatetracyclo [8.8.0.02,7.013,18] octadeca-2(7),13,15,17-tetraene-3,5,11-trione 2-ethoxyphenyl (2E)-but-2-enoate ($C_{22}H_{18}N_2O_5$) has been determined from single crystal X-ray diffraction data. In the title compound crystallizes in the monoclinic space group $P_12_1/c_1$ with unit cell dimension a=15.2039(8), b=12.3888(6) and c= 9.8162(5) [alpha & $gamma=90^{\circ}$ beta=98.113(2)]. In the structure fused pyrone and pyran rings each adopt a sofa/envelop conformation. The crystal structure is stabilized by intramolecular C-H... O hydrogen bond interaction.

경산지역 토양 및 수질오염에 관한 연구 (A Study of Soil and Water Pollutions in Kyungsan Province)

  • 김용태;이부용;김동석;양소영;이동훈;박병윤
    • 한국환경과학회지
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    • 제11권7호
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    • pp.713-720
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    • 2002
  • In order to provide the basic information on the environmental pollution of Kyungsan province, the contents of Pb, Cd, Cr, Cu, Mn and Zn in soil, stream water, aquatic sediment and groundwater were investigated, and also the values of pH, COD, $KMnO_4-C$,\;NH_3-N,\;NO_2-N,\;NO_3-N$ and $Cl^-$ of stream water and groundwater were determined. The results were as follows. The values of COD, $NH_3-N,\;NO_2-N$ and $NO_3-N$ of the stream waters were very low. The contents of Pb, Cd, Cr, Cu and Zn in the stream waters were respectively at range of $0.014~0.063 mg/{\ell},\;0.004~0.007 mg/{\ell$\mid$, 0~0.045 mg/{\ell},\;0~0.008 mg/{\ell}$\;and\;$0.001~0.175 mg/{\ell}$, and these values were much lower than those of contaminated stream water in Korea. The contents of Cd, Cr, Cu and Zn in the soils were respectively at range of 0.12~O.71 ppm, 0.88~2.65 ppm, 2.86~22.33 ppm and 3.89~26.39 ppm, and these values were much lower than those of ordinary polluted areas in Korea. The contents of Cd, Cr, Cu, As, Zn and Mn in the aquatic sediments were respectively at range of 3.05~3.81 ppm, 14.6~70.6 ppm, 13.74~61.59 ppm, 76.8~465.5 ppm, 12.56~190.83 ppm and 333.3~l188.3 ppm. The values of pH, $KMnO_4-C,\;NH_3-N$, and $NO_3-N$ of the groundwaters were respectively at range of 7.6~8.4, $0~3.95{\ell}$, 0.05~0.15 mg/{\ell}$ and 0.05~0.42 $mg/{\ell}$. The contents of Pb, Cd and Cr in the groundwaters were respectively at range of 0.015~0.061 $mg/{\ell}$, 0.O06~0.009 $mg/{\ell}$ and 0.005~0.045 $mg/{\ell}$.

발생 해역별 태풍의 수와 세기에 관한 연구 (A Study on Typhoon Numbers and Intensity According to the Sea Areas of Occurrence)

  • 설동일
    • 한국항해항만학회지
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    • 제33권10호
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    • pp.679-683
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    • 2009
  • 최근 22년간(1986-2007년)의 기상청 자료를 이용하여 태풍의 발생 해역별(A해역: 캐롤라인 마샬군도 부근 해역, B해역 : 북위 20도 이북 해역, C해역 : 필리핀 근해, D해역 : 남중국해)로, 태풍의 발생 수 및 세기에 관하여 분석하였다. 태풍의 연평균 발생 수는 26.3개로, 모든 해역에서 공통적으로 감소하는 추세를 보인다. 특히, A해역에서 감소 추세가 현저하고, D해역에서는 감소 추세가 미미하다. 태풍이 가장 많이 발생하는 해역은 A해역(연평균 13.8개, 전체의 약 53%)이고, 그 다음은 C해역(5.6개, 약 21%), B해역(3.8개, 약 14%), D해역(3.1개, 약 12%)의 순서이다. 태풍의 세기는 A해역에서 발생하는 것이 가장 강하고(중심최저기압의 평균 951hPa), 그 다음은 C해역(970hPa), B해역(975hPa), D해역(983hPa)의 순서이다. 그리고 전 해역을 대상으로 하여 연평균 중심최저기압의 시계열 분포를 살펴보면, 태풍의 중심최저기압은 미세하게 하강하는 추세를 보인다. 이는 태풍의 세기가 서서히 강해지고 있음을 의미한다. 금번의 연구 결과는 지구 온난화에 따른 태풍의 수와 세기의 변화에 대한 여러 수치실험 결과와 일치한다.

Crystal and Molecular Structure of 12-(2-Methoxyphenyl)-9-[(4-methylbenzene)sulfonyl]-22-oxo-13,21-dioxa-9-azapentacyclo [12.8.0.02,11.03,8.015,20]docosa-1(14),3,5,7,15(20),16,18-heptaene-11-carbonitrile

  • Ganapathy, Jagadeesan;Damodharan, Kannan;Manickam, Bakthadoss;Sanmargam, Aravindhan
    • 통합자연과학논문집
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    • 제7권3호
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    • pp.149-158
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    • 2014
  • The crystal structure of the title compounds with both coumarin and sulfonamide moieties were examined. These two groups have very special for their pharmaceutical and medicinal properties have been determined from single crystal X-ray diffraction data. In the title compound crystallizes in the monoclinic space group $P2_1/c$ with unit cell dimension a=$8.5775(4){{\AA}$, b=$24.9943(13){\AA}$ and c=$13.7319(7){\AA}$ [alpha & gamma=$90^{\circ}$ beta=$103.558(2)^{\circ}$]. In the structure The S1 atom shows a distorted tetrahedral geometry, with O1-S1-O2 [$121.08(1)^{\circ}$] and N1-S1-C5 [$105.85(1)^{\circ}$] angles deviating from ideal tetrahedral values are attributed to the Thrope-Ingold effect. The sum of bond angles around N1 ($354.9^{\circ}$) indicates that N1 is in $sp^2$ hybridization. The Pyridine ring adopts boat conformation and pyran rings adopt a sofa conformation. Crystal structure is stabilized by C-H...O intra molecular hydrogen bond interactions.