• Title/Summary/Keyword: $C_{14}H_{14}O_4N_2$

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High Efficiency Solar Cell(I)-Fabrication and Characteristics of $N^+PP^+$ Cells (고효율 태양전지(I)-$N^+PP^+$ 전지의 제조 및 특성)

  • 강진영;안병태
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.18 no.3
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    • pp.42-51
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    • 1981
  • Boron was predeposited into p (100) Si wafer at 94$0^{\circ}C$ for 60minutes to make the back surface field. High tempreature diffusion process at 1145$^{\circ}C$ for 3 hours was immediately followed without removing boron glass to obtain high surface concentration Back boron was annealed at 110$0^{\circ}C$ for 40minutes after boron glass was removed. N+ layer was formed by predepositing with POCI3 source at 90$0^{\circ}C$ for 7~15 minutes and annealed at 80$0^{\circ}C$ for 60min1es under dry Of ambient. The triple metal layers were made by evaporating Ti, Pd, Ag in that order onto front and back of diffused wafer to form the front grid and back electrode respectively. Silver was electroplated on front and back to increase the metal thickness form 1~2$\mu$m to 3~4$\mu$m and the metal electrodes are alloyed in N2 /H2 ambient at 55$0^{\circ}C$ and followed by silicon nitride antireflection film deposition process. Under artificial illumination of 100mW/$\textrm{cm}^2$ fabricated N+PP+ cells showed typically the open circuit voltage of 0.59V and short circuit current of 103 mA with fill factor of 0.80 from the whole cell area of 3.36$\textrm{cm}^2$. These numbers can be used to get the actual total area(active area) conversion efficiency of 14.4%(16.2%) which has been improved from the provious N+P cell with 11% total area efficiency by adding P+ back.

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Crystal and Molecular Structure of 12-(2-Methoxyphenyl)-9-[(4-methylbenzene)sulfonyl]-22-oxo-13,21-dioxa-9-azapentacyclo [12.8.0.02,11.03,8.015,20]docosa-1(14),3,5,7,15(20),16,18-heptaene-11-carbonitrile

  • Ganapathy, Jagadeesan;Damodharan, Kannan;Manickam, Bakthadoss;Sanmargam, Aravindhan
    • Journal of Integrative Natural Science
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    • v.7 no.3
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    • pp.149-158
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    • 2014
  • The crystal structure of the title compounds with both coumarin and sulfonamide moieties were examined. These two groups have very special for their pharmaceutical and medicinal properties have been determined from single crystal X-ray diffraction data. In the title compound crystallizes in the monoclinic space group $P2_1/c$ with unit cell dimension a=$8.5775(4){{\AA}$, b=$24.9943(13){\AA}$ and c=$13.7319(7){\AA}$ [alpha & gamma=$90^{\circ}$ beta=$103.558(2)^{\circ}$]. In the structure The S1 atom shows a distorted tetrahedral geometry, with O1-S1-O2 [$121.08(1)^{\circ}$] and N1-S1-C5 [$105.85(1)^{\circ}$] angles deviating from ideal tetrahedral values are attributed to the Thrope-Ingold effect. The sum of bond angles around N1 ($354.9^{\circ}$) indicates that N1 is in $sp^2$ hybridization. The Pyridine ring adopts boat conformation and pyran rings adopt a sofa conformation. Crystal structure is stabilized by C-H...O intra molecular hydrogen bond interactions.

The Effect of a small amount of Impurity gas on Luminance/Discharge Characteristics of AC PDP (ac PDP에서 미량 불순물 가스가 광학적 및 전기적 특성에 미치는 영향)

  • Heo, Jeong-Eun;Kim, Young-Kee;Choi, Joon-Young;Kim, Joon-Yeon;Shin, Joong-Hong;Lee, Ho-Jun;Park, Chung-Hoo
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1585-1587
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    • 2001
  • ac PDP 동작에 있어 미량 불순물 가스는 panel 내의 휘도 및 방전 특성에 많은 영향을 미칠것으로 생각된다. $O_2$, O, C 및 $H_2$와 같은 불순물 가스는 ac PDP의 제조 공정 중에 발생하거나, 충전된 방전가스에 혼합되어 발생하는 등 여러 가지 원인으로 나타난다. 이 논문에서는, ac PDP의 동작 가스 중에 미량의 불순물 가스(Ar, $N_2$, $O_2$, $H_2$, $CO_2$)를 주입하여, 이 미량의 불순물 가스로 인한 ac PDP의 휘도 및 방전의 특성변화에 대한 관계를 조사하였다. 그 결과, $O_2$ 가스의 분압이 $2{\times}10^{-3}$/He+Ne+Xe(4%)일 경우, 방전전압은 12% 증가하였고, 휘도는 60% 감소하였다. 또한, $CO_2$ 가스의 경우는 방전전압은 14% 증가하였고, 휘도는 44% 감소하였다.

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Effects of Aluminum Sulfate and Protein Levels on Broiler Performance

  • Park, I. H.;K. H. Nahm
    • Proceedings of the Korea Society of Poultry Science Conference
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    • 2002.11a
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    • pp.103-105
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    • 2002
  • This study was conducted to determine how broiler performance with the level of crude protein(23 CP%, 21 CP% and 19 CP%) can be changed and affected, adding Alum(Al$_{2}$(SO$_{4}$)$_{3}$ㆍ14H$_{2}$O) and no Alum in litter(two ALUM levels and 3 Protein levels with 2$\times$3 factorial design). Alum was added as a top dressing to the litter at a rate of 200g ALUM / kg of rice bran. With the exception of the protein levels for feed :gain(P〈 0.05), there were no significant differences in feed intake, weight gain and feed :gain of chicks. For ammonia gas emission, both the main effects of Alum and protein(P〈 0.01 and 0.05) at 3weeks and interaction between Alum and protein(P〈 0.05), the main effect of Alum(P〈 0.01) at 6weeks did affected them. In litter excluded the main effects of Alum(P〈 0.05), there was a significant difference among N contents ranged from pH to the rate of C: Organic-N(P〈 0.01).

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The Characteristics of Biopellet Produced Upon Reactor Configuration in UASB System (UASB 공법에 있어서 반응조의 형상변화에 따른 입상슬러지의 특성에 관한 연구)

  • Min, Kyung Sok;Ahn, Young Ho
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.14 no.3
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    • pp.679-688
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    • 1994
  • Physicochemical and morphological characteristics of biopellets produced in "control" and modified UASB reactor were investigated to compare the reactor performance with regard to the hydrogen partial pressure. The characteristics of biopellet produced in modified UASB reactor operated with high hydrogen partial pressure were better than those of "control" reactor operated with relatively lower hydrogen partial pressure, therefore the hydrogen partial pressure effected greatly on the formation and stability of the biopellet. Furthermore, pellets from the UASB system with modified settler showed a better settleability and biomass holding capacity. The chemical composition of biopellet was distinctively different from that of common bacterial formula, $C_5H_7O_2N$. Biopellets was composed the large fraction of nitrogen in comparison with common anaerobic microbes. These results implicated the existence possibility of polypeptide-type extracellular polymer. The morphological characterization with SEM showed that microorganisms observed at surface of biopellet produced in modified UASB reactor operated with high $P_{H_2}$ condition were very similar in shape and size to the Methanobrevibactor arboriphilus-$H_2$ utilizing methanogen. The microorganisms was distinguished from those of "control" reactor operated with low $P_{H_2}$ condition. From these results, it could be explained the hydrogen partial pressure effects on pelletization mechanism.

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Crystal and Molecular Structure of Methyl 12-(3-bromophenyl)-9-[(4-methylbenzene)sulfonyl]-22-oxo-13,21-dioxa-9-azapentacyclo[12.8.0.02,11.03,8.015,20]docosa-1(14),3,5,7,15(20),16,18-heptaene-11-carboxylate

  • Kothandan, Gugan;Ganapathy, Jagadeesan;Damodharan, Kannan;Sanmargam, Aravindhan
    • Journal of Integrative Natural Science
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    • v.7 no.2
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    • pp.92-102
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    • 2014
  • The crystal structure of the title compounds with both coumarin and sulfonamide moieties were examined. These two groups have very special for their pharmaceutical and medicinal properties have been determined from single crystal X-ray diffraction data. In the title compound crystallizes in the monoclinic space group C2/c with unit cell dimension a = 28.633(3) ${\AA}$, b= 9.3215(7) ${\AA}$ and c= 24.590(2) ${\AA}$ [alpha & gamma=$90^{\circ}$ beta= $115.976(3)^{\circ}$]. In the structure The S1 atom shows a distorted tetrahedral geometry, with O1-S1-O2 [119.74 $(2)^{\circ}$] and N1-S1-C5 [$105.57(1)^{\circ}$] angles deviating from ideal tetrahedral values are attributed to the Thrope-Ingold effect. The sum of bond angles around N1 ($316.2(1)^{\circ}$) indicates that N1 is in sp2 hybridization. The Pyridine ring adopts boat conformation and pyran rings adopt a sofa conformation. The carboxylate group of atoms were disordered over two positions with site occupancy factors 0.598 (9):0.402 (9). Crystal structure and packing is stabilized by $C-H{\ldots}O$ intra and inter molecular hydrogen bond interactions.

Growth and Survival Rate of Abalone, Sulculus aquatilis in a Closed Recirculating Sea Water System (폐쇄식 순환사육수조에서 오분자기, Sulculus aquatilis 치패의 체중별 성장 및 생존율)

  • 강경호;김재우;김용만;김병학
    • The Korean Journal of Malacology
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    • v.16 no.1_2
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    • pp.31-34
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    • 2000
  • A series of rearing experiments have been conducted to determine the growth and survival rate in accordance with body size in closed recirculating sea water system. The abalone, Sulculus aquatilis, spat of 10.24${\pm}$0.85 mm, 0.36${\pm}$0.l g and 24.9${\pm}$1.07 mm 2.07${\pm}$0.57 g in shell length and body weight were used in this study Ranges of water temperature and pH during the rearing period of 90 days were 10.0-24.2$^{\circ}C$ and 7.8-8.2, respectively. Dissolved oxygen during the experiment period was 6.13-7.21 ml/l and inorganic nitrate was 0.68-3.72 $\mu\textrm{m}$ in NH$_4$$\^$+/-N, 0.17-7.79 fm in NO$_2$-N and 0.4-11.52 $\mu\textrm{m}$ in NO $_2$-N, Growth in shell length and body weight of the spat in large group and small group at the end of the experiment were 30.80${\pm}$3.14 mm, 17.98${\pm}$2.61 mm and 3.20${\pm}$0.8 g, 0.36${\pm}$0.1 g, and survival rate of spat in large group and small group at the end of the rearing experiment were 96.0% and 90.0% , respectively.

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Production of Methane from Anaerobic Fermentation of Marine Macro-algae (해조류의 혐기성 발효를 이용한 메탄 생산)

  • Kim, Jeong-Min;Lee, Yeung-Ho;Jung, Sung-Hoon;Lee, Jin-Tae;Cho, Moo-Hwan
    • Clean Technology
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    • v.16 no.1
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    • pp.51-58
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    • 2010
  • Methane was produced from the anaerobic digestion of marine macro-algae. Elemental analysis was first performed to estimate the theoretical methane production of three macro-algae (Undaria pinnatifida, Laminaria japonica, Hizikia fusiformis). Three algae were found to contain C 34 ~ 36%, H 5%, O 37 ~ 43%, N 2 ~ 4%, S 0.4 ~ 0.7%, and ash 14~21%, and the theoretical methane content was in the range of 56 ~ 60%, which can produce 442 ~ 568 mL $CH_4$ per g of volatile solid (VS). Using the biological methane potential (BMP) test, we found that L. japonica resulted in the highest yield of methane (52%). Moreover, various operational conditions, such as algae amount, pH, salinity, particle size, and pre-treatment, were investigated in order to find an optimal condition of anaerobic digestion. At pH 8.0, the autoclaved L. japonica (5g VS/200 mL), when used without washing salt, produced 268.5 mL/g VS which is 65% of the theoretical methane productions. Furthermore, using a CSTR (with the working volume of 7 L out of the total volume of 10 L), we have successfully operated the reactor for 65 days and obtained maximum methane production rate of 1.4 L/day with purity of 70%.

Changes of Physico-chemical Properties and Microflora of Pig Manure due to composting with some Bulking Agents (보조재료별 돈분 퇴비화 과정중 이화학적 특성과 미생물상 변화)

  • Lee, Jong-Tae;Nam, Yeun-Gyu;Lee, Jin-Il
    • Korean Journal of Soil Science and Fertilizer
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    • v.34 no.2
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    • pp.134-144
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    • 2001
  • This study was conducted to investigate physicochemical and microbiological properties during composting process when pig manure was composted with some bulking agents(Saw dust, Rice hull, Crushed wood). The pig manure consisted of 2.95% total nitrogen, 4.55% $P_2O_5$, 2.07% $K_2O$, 81.2% organic matter and 14.0 C/N, dry base. The inorganic content of bulking agents were similar one another, and C/N ratio was Saw dust 392. Rice hull 91.5, Crushed wood 266. The temperature of Saw dust composting slowly increased at initial stage, whereas one of Rice hull and Crushed wood rapidly increased and stabilized similarly to outdoor temperature after about 2 month. The pH of compost increased during initial 1 month after decreasing, but thereafter decreased rapidly. The C/N ratio rapidly decreased at initial stage, and it slowly decreased after 1 month. Total nitrogen somewhat increased according to composting process. Ammonium-nitrogen increased until 60th day, and thereafter it was rapidly inclined to decrease. The population of aerobic bacteria, Bacillus spp., actinomycetes and fungi increased up to > $10^{10}cfu\;g^{-1}$ fresh weight, > $10^7$, > $10^8$ and > $10^6$, respectively in Rice hull and Crushed wood composting, and more than ones in Saw dust composting, and specially actinomycetes. The persuasive Bacillus spp. isolated from composting process were B. lentimorbus, B. licheniformis, B. pumilus, B. megaterium, etc.

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Isolation and Quantitative Analysis of BACE1 Inhibitory Compounds from Cirsium maackii Flower

  • Bhatarrai, Grishma;Seong, Su Hui;Jung, Hyun Ah;Choi, Jae Sue
    • Natural Product Sciences
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    • v.25 no.4
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    • pp.326-333
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    • 2019
  • The purpose of our study was to evaluate anti-AD potential of Cirsium maackii flowers. MeOH extract, CH2Cl2, EtOAc, and n-BuOH fraction of this flower notably inhibited BACE1 (IC50 = 76.47 ± 1.66, 22.98 ± 1.45, 8.65 ± 0.63, and 72.47 ± 3.04 ㎍/mL, respectively). β-amyrenone (49.70 mg) (1), lupeol acetate (1.43 g) (2), lupeol (1.22 g) (3), lupenone (23.70 mg) (4), β-sitosterol (1.01 g) (6), and β-sitosterol glucoside (13.00 mg) (7) from CH2Cl2, apigenin (100.20 mg) (8), luteolin (19.00 mg) (9), apigenin 7-O-glucuronide methyl ester (21.30 mg) (14), and tracheloside (53.70 mg) (5) from EtOAc, apigenin 5-O-glucoside (11.00 mg) (10), luteolin 5-O-glucoside (11.00 mg) (11) and apigenin 7-O-glucuronide (91.00 mg) (12) from n-BuOH, and luteolin 7-O-glucuronide (22.00 mg) (13) from H2O fraction were isolated. HPLC showed high levels of 8, 9 and 12 in MeOH extract (33.07 ± 0.07, 31. 44 ± 0.17 and 16.89 ± 0.33 mg/g, respectively), EtOAc (161.01 ± 1.78, 96.93 ± 0.34 and 73.38 ± 0.06 mg/g, respectively), and n-BuOH fraction (32.18 ± 0.33, 44.31 ± 0.32 and 105.94 ± 0.36 mg/g, respectively). Since, 3 and 9 are well-known BACE1 inhibitors, the anti-AD activity of C. maackii flower might be attributable to their presence.