• Title/Summary/Keyword: $CO_2$ standard gas

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The distribution of the molecular hydrogen in the Milky way

  • Jo, Young-Soo;Seon, Kwang-Il;Min, Kyoung-wook
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.2
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    • pp.40.1-40.1
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    • 2016
  • We present the far-ultraviolet fluorescent molecular hydrogen ($H_2$) emission map observed with FIMS/SPEAR for ~76% of the sky. The fluorescent $H_2$ emission is found to be saturated by strong dust extinction at the optically thick, Galactic plane region. However, the extinction-corrected intensity of fluorescent $H_2$ emission is found to have strong linear correlations with the well-known tracers of the cold interstellar medium, such as the E(B-V) color excess, neutral hydrogen column density N(HI), $H{\alpha}$ emission, and CO $J=1{\rightarrow}0$ emission. The all-sky molecular hydrogen column density map is also obtained using a photodissociation region model. We also derive the gas-to-dust ratio, hydrogen molecular fraction ($f_{H2}$), and $CO-to-H_2$ conversion factor ($X_{CO}$) of the diffuse interstellar medium. The gas-to-dust ratio is consistent with the standard value $5.8{\times}10^{21}atoms\;cm^{-2}mag^{-1}$, and the $X_{CO}$ tends to increase with E(B-V), but converges to the Galactic mean value $1.8{\times}10^{20}cm^{-2}K^{-1}km^{-1}s$ at optically thick regions with E(B-V)>2.0.

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Development of a Noble Gas Isotope Dilution Mass Spectrometric System Combined with a Cryogenic Cold Trap (초저온 냉각 트랩을 결합한 비활성기체 동위원소 희석 질량분석 시스템의 제작)

  • HONG, BONGJAE;SHIN, DONGYOUB;PARK, KEYHONG;HAHM, DOSHIK
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.27 no.3
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    • pp.144-157
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    • 2022
  • Noble gases, which are chemically inert and behave conservatively in marine environments, have been used as tracers of physical processes such as air-sea gas exchange, mixing of water masses, and distribution of glacial meltwater in the ocean. For precise measurements of Ne, Ar, and Kr, we developed a mass spectrometric system consisting of a quadrupole mass spectrometer (QMS), a high vacuum preparation line, an activated charcoal cryogenic trap (ACC), and a set of isotope standard gases. The high vacuum line consists of three sections: (1) a sample extraction section that extracts the dissolved gases in the sample and mixes them with the standard gases, (2) a gas preparation section that removes reactive gases using getters and separates the noble gases according to their evaporation points with the ACC, and (3) a gas analysis section that measures concentrations of each noble gas. The ACC attached to the gas preparation section markedly lowered the partial pressures of Ar and CO2 in the QMS, which resulted in a reduced uncertainty of Ne isotope analysis. The isotope standard gases were prepared by mixing 22Ne, 36Ar, and 86Kr. The amounts of each element in the mixed standard gases were determined by the reverse isotope dilution method with repeated measurements of the atmosphere. The analytical system achieved precisions for Ne, Ar, and Kr concentrations of 0.7%, 0.7%, and 0.4%, respectively. The accuracies confirmed by the analyses of air-equilibrated water were 0.5%, 1.0%, and 1.7% for Ne, Ar, and Kr, respectively.

Measurement of Indoor Air Quality for Ventilation with the Existence of Occupants in Schools

  • Shin Hee-Soo;Lee Jai-Kwon;Ahn Young-Chull;Yeo Chang-Shin;Byun Sang-Hyun;Lee Jae-Keun;Kang Tae-Wook;Lee Kam-Gyu;Park Hyo-Soon
    • Journal of Mechanical Science and Technology
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    • v.19 no.4
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    • pp.1001-1005
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    • 2005
  • This paper evaluates the performance of ventilation for the removal of indoor pollutants as a function of ventilation rate and the number of occupants in a test room and school classroom. An experimental apparatus consists of a test room, a tracer gas supply system, a gas detector, and a fan for ventilation air supply with a controller. The ventilation performance is evaluated in a step-down method based on ASTM Standard E741-83 using $CO_{2}$ gas as a tracer gas in the test room of 35 $m^{3}.$ For the ventilation air flow rate of 1.0 ACH, a recommended ventilation flow rate of Korea school standard for acceptable indoor air quality in the case of one person, CO_{2}$ gas concentration decreases up to $55{\%}$ within 50 minutes without occupancy and increases up to $75{\%}$ in the case of one occupant. Also indoor air quality at the school classroom is investigated experimentally.

A Study on the Development and Accuracy Improvement of an IR Combustible Gas Leak Detector with Explosion Proof (방폭형 적외선 가연성가스 누출검지기 개발 및 정확도 향상 연구)

  • Park, Gyou-Tae;Lyu, Geun-Jun;Jo, Young-Do;Kwon, Jeong-Rock;Ahn, Sang-Guk;Kim, Hie-Sik
    • Journal of the Korean Institute of Gas
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    • v.18 no.3
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    • pp.1-12
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    • 2014
  • In this paper, we developed an explosion proof type and portable combustible gas leak detector and proposed an algorithm to improve the accuracy for measuring gaseous concentrations. The nation's first we developed an infrared gas leak detector with explosion proof standard(Ex d ib) and improved measuring accuracy by using linearization recursion equation and 2nd Lagrange interpolation polynomial. Together, we advanced their performances and added their easy functions after investigating field demands. To compare our and other company's detectors, we performed measurement tests with eight standard gases made by Korea Gas Safety Corporation. We demonstrated the excellence of our instruments in measuring accuracy other than detecters through experimental results.

Numerical Simulation on Ventilation Characteristics of an Underground Bus Parking Lot (버스전용 지하주차장의 환기 특성에 관한 수치해석적 연구)

  • Seung, Sam-Sun;Lee, Seung-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.8 no.2
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    • pp.179-184
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    • 2007
  • In this paper, the ventilation characteristics of an underground parking lot with 17 buses has been investigated for two cases by computational fluid dynamics. It has been found that the average concentration of CO and $NO_x$ gas in the parking lot were 1.3 and 0.3 ppm respectively, when four buses operated. When the fifteen vehicles stopped in the parking lot, the average concentration of CO and $NO_x$ gas was 2.9 and 0.8 ppm respectively. The average concentration of two pollutants$(CO,\;NO_x)$ are lower than the standard values. Therefore the facilities and its location is proper to ventilation.

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What Determines Star Formation Rates?

  • Evans, Neal
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.2
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    • pp.29.4-29.4
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    • 2016
  • The relations between star formation and properties of molecular clouds are studied based on a sample of star forming regions in the Galactic Plane. Sources were selected by having radio recombination lines to provide identification of associated molecular clouds and dense clumps. Radio continuum and mid-infrared emission were used to determine star formation rates, while 13CO and submillimeter dust continuum emission were used to obtain masses of molecular and dense gas, respectively. We test whether total molecular gas or dense gas provides the best predictor of star formation rate. We also test two specific theoretical models, one relying on the molecular mass divided by the free-fall time, the other using the free-fall time divided by the crossing time. Neither is supported by the data. The data are also compared to those from nearby star forming regions and extragalactic data. The star formation "efficiency," defined as star formation rate divided by mass, spreads over a large range when the mass refers to molecular gas; the standard deviation of the log of the efficiency decreases by a factor of three when the mass of relatively dense molecular gas is used rather than the mass of all the molecular gas.

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Induction of the High Order Calibration Equation of Metal Oxide Semiconductor Gas Sensors (산화물 반도체식 가스센서의 입출력 고차 캘리브레이션 방정식 도출)

  • Park, Gyoutae;Kim, Kangmin;Lee, Hyeonggi;Yoon, Myeongsub
    • Journal of the Korean Institute of Gas
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    • v.24 no.2
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    • pp.44-49
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    • 2020
  • In this paper, a measuring circuit is designed through analyzing manufacture specification of the sensor based on MOS. And the best input-output polynomial are induced that really gas sensors are used in gas safety management industrial fields. Response characteristics of a MOS gas sensor is analysed by through sensor's output voltages are measured after standard gases with six kinds of concentrations are manufactured and are injected to the sensor. A lookup table is created by relations of sensor's output voltages by injecting gases with other concentrations. Because data of the formed lookup table are equal interval, a polynomial can be induced of method of approximation function. So the 5th polynomial of input-output for a sensor is defined, coefficients are calculated by using least squares method, and the 5th polynomial is completed for representing characteristics of the sensor. If the proposed polynomial is applied to gas leak detectors, an inverse transformation of polynomial and programing of array codes are recreated. In this research, polynomial is implemented with array types that intervals of values of a lookup table are one-fifth sampled and interpolated. The performance of proposed 5th calibration equation is verified that errors are reduced than a linear expression when tests are performed by measurement of concentrations against injection of standard gases.

Concentration and Seasonal Variation of Gaseous Nitrous Acid in Seoul Air (서울대기중 아질산기체의 계절별 농도변화)

  • 이용근;김종욱;이동수;백선영
    • Journal of Korean Society for Atmospheric Environment
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    • v.10 no.1
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    • pp.24-31
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    • 1994
  • Hourly variation of gaseous nitrous acid( HNO$_2$) concentration in Seoul air was monitored from Jan. 11 to SeP. 12, Nitrous acid concentration was determined by DS/IC over nine months of observation, HNO$_2$ range from 0.04 ppb to 5.5 ppb. Gor-tex tube as gaseous HNO$_2$generator in this study is thought to be more convenient and reproducible device than previous generator. As a result of NaOH instead of Na$_2$ CO$_3$/NaHCO$_3$ solution as the IC eluent, we could obtain more stable baseline. The concentration of the NaOH eluent was 15 mM . The limit of detection(3$\sigma$) of the liquid- Phase and gas phase nitrous acid of this method are 1.1ng/$m\ell$ , 0.04 n $\ell$ / $\ell$, respectively. The precisions evaluated by 10 replicate analysis of standard solution and standard gas generated are $\pm$1.59, $\pm$2. 89% RSD, respectively. Due to the lack of standard material for air, direct assessment of the accuracy was not possible. This study was applied to the analysis of Seoul ambient air and their results are reported herein.

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The Estimation of Greenhouse Gas Reductions from Renewable Energy (Photovoltaic, Wind Power) : A Case Study in Korea (재생에너지(태양광, 풍력) 기술의 온실가스 감축산정: 국내를 대상으로)

  • Jung, Jaehyung;Kim, Kiman
    • Journal of Environmental Science International
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    • v.29 no.7
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    • pp.729-737
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    • 2020
  • This study estimates the greenhouse gas (GHG) emissions reduction resulting from photovoltaic and wind power technologies using a bottom-up approach for an indirect emission source (scope 2) in South Korea. To estimate GHG reductions from photovoltaic and wind power activities under standard operating conditions, methodologies are derived from the 2006 IPCC guidelines for national GHG inventories and the guidelines for local government greenhouse inventories of Korea published in 2016. Indirect emission factors for electricity are obtained from the 2011 Korea Power Exchange. The total annual GHG reduction from photovoltaic power (23,000 tons CO2eq) and wind power (30,000 tons CO2eq) was estimated to be 53,000 tons CO2eq. The estimation of individual GHGs showed that the largest component is carbon dioxide, accounting for up to 99% of the total GHG. The results of estimation from photovoltaic and wind power were 63.60% and 80.22% of installed capacity, respectively. The annual average GHG reductions from photovoltaic and wind power per year per unit installed capacity (MW) were estimated as 549 tons CO2eq/yr·MW and 647 tons CO2eq/yr·MW, respectively. Finally, the results showed that the level of GHG reduction per year per installed capacity of photovoltaic and wind power is 62% and 42% compared to the CDM project, respectively.

Flavor Components of the Fruit Peel and Leaf Oil from Zanthoxylum piperitum DC (초피(Zanthoxylum piperitum DC)의 과피와 잎의 방향성분)

  • Kim, Jung-Han;Lee, Kyung-Seok;Oh, Won-Taek;Kim, Kyoung-Rae
    • Korean Journal of Food Science and Technology
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    • v.21 no.4
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    • pp.562-568
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    • 1989
  • The essential oils from ripe fruit peel and leaf of Zanthoxylum piperitum DC were extracted by gas co-distillation method and analyzed by gas chromatography/mass spectrometry (GC/ MS) and retention index matching. The experimental results revealed the presence of over 100 volatile components. Major components were 1,8-cineol (25.47%), limonene (11.91%), geranyl acetate (9.01%), myrcene (6.15%) in fruit peel and citronellal (23.11%), 1,8-cineol (18.38%), citronellol (6.04%) in leaf. Among the components identified were the following; in fruit peel, ${\alpha}-pinene$ and 13 hydrocarbons, linalool and 8 alcohols, citronellal and 3 aldehydes, carvone and 2 kotones, methyl salicylate and 7 esters, and 1,8-cineol and oxides, and in leaf, ${\alpha}-pinene$ and 7 hydrocarbons, linalool and 7 alcohols, citronellyl acetate and 5 esters, citronellal and 1 aldehyde, carvone, and 1,8-cineol and 1 oxide.

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