• Journal of the Korean Society of Marine Environment & Safety
• /
• v.28 no.6
• /
• pp.1063-1069
• /
• 2022

According to domestic air pollutant emission statistics, a considerable amount of air pollutants is generated by ships. Therefore, various policies are being implemented to limit air pollutant emissions from ships and improve the air quality in ports. In addition, international conventions are carried out for the prevention of marine pollution by ships. However, because few studies and experiments have been conducted on the measurement of air pollutants emitted from actually operating ships, this study presented a method and possibility for evaluating air pollutant emissions from a 9,196GT ship actually operating using a portable emission measurement system (PEMS). A difference in emission occurred depending on the RPM and load, and the emission of NO_X was 497-2,060ppm, CO₂ was 1.55-6.9%, and CO was 0.002-0.14%. The emission specified in the shop test provided by the engine manufacturer differed from the actual emission measured. This study proved that the maximum emission of each air pollutant generated in the entire sailing section of the ship was included in the PEMS measurement range, and the possibility of using PEMS for ships within 10,000GT was verified.

• Korean Journal of Remote Sensing
• /
• v.35 no.6_3
• /
• pp.1187-1195
• /
• 2019

We, for the first time, developed a Raman lidar system which can remotely detect surface CO₂ volume mixing ratio (VMR). The Raman lidar system consists of the Nd: YAG laser of wavelength 355 nm with 80 mJ, an optical receiver, and detectors. Indoor CO₂ cell measurements show that the accuracy of the Raman lidar system is calculated to be 99.89%. We carried out the field measurement using our Raman lidar at Pukyong National University over a seven-day period in October 2019. The results show good agreement between CO₂ VMRs measured by the Raman lidar (CO₂ Raman Lidar) and those measured by in situ instruments (CO₂ In situ) which located 300 m and 350 m away from the Raman lidar system. The correlation coefficient (R), mean absolute error (MAE), and root mean square error (RMSE) between CO₂ In situ and CO₂ Raman Lidar are 0.67, 2.78 ppm, and 3.26 ppm, respectively.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.13 no.1
• /
• pp.51-59
• /
• 2005

Co-flow laminar diffusion flames' temperature has been studied experimentally for ethylene$(C_2H_4)$ using a co-flow burner in order to investigate the characteristics of diffusion flame's temperature distribution. The temperature distributions in the flame were measured by rapid insertion of a R-type thermocouple. The measurement area was divided into three zones. 1st area was expect to created PAH zone, Il nd area was expect to form soot zone, which is known to generate most soot volume fraction, and III rd area was expect to from soot oxidization zone. Also The temperature along the flame y-axis as a fuel quantity was measured. As a results, we have measured temperature neglecting the effect of soot particles attached to the thermocouple junction, which is close to the nozzle and upstream zone has a unstable flow in co-flow diffusion flame and acquires that the flame y-axis temperature has a uniform temperature in the generated soot volume fraction zone(II nd).

• Proceedings of the Korean Vacuum Society Conference
• /
• 2016.02a
• /
• pp.272.2-272.2
• /
• 2016

Copper-Tin (CuSn) thin films were synthsized by rf magnetron co-sputtering method with pure Cu and Sn metal targets with various rf powers and sputtering times. The obtained CuSn thin films were characterized by a surface profiler (alpha step), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), X-ray induced Auger electron spectroscopy (XAES), and contact angle measurement. The deposition rates were calculated by the thickness of CuSn thin films and sputtering times. We observed hexagonal Cu20Sn6 and cubic Cu39Sn11 phases from the films by XRD measurement. From the survey XPS spectra, the Cu and Sn main peaks were observed. Therefore, we could conclude CuSn thin films were successfully fabricated on the substrate in this study. The changes of oxidation states and chemical environment of the films were investigated with high resolution XPS spectra in the regions of Cu 2p, Cu LMM, and Sn 3d. Surface free energy (SFE) and wettability of the CuSn thin films were studied with distilled water (DW) and ethylene glycol (EG) using the contact angle measurement. The total SFE of CuSn thin films decreased as rf power on Cu target increased. The contribution to the total SFE of dispersive SFE was relatively superior to polar SFE.

• Journal of Soil and Groundwater Environment
• /
• v.14 no.3
• /
• pp.1-13
• /
• 2009

Alkalinity and total carbon contents were measured by acid neutralizing titration (ANT), back titration (BT), gravitational weighing (GW), non-dispersive infrared-total carbon (NDIR-TC) methods for assessing precision and accuracy of alkalinity and total carbon concentration in $CO_2$-rich water. Artificial $CO_2$-rich water(ACW: pH 6.3, alkalinity 68.8 meq/L, $HCO_3^-$ 2,235 mg/L) was used for comparing the measurements. When alkalinity measured in 0 hr, percent errors of all measurement were 0~12% and coefficient of variation were less than 4%. As the result of post-hoc analysis after repeated measure analysis of variance (RM-AMOVA), the differences between the pair of methods were not significant (within confidence level of 95%), which indicates that the alkalinity measured by any method could be accurate and precise when it measured just in time of sampling. In addition, alkalinity measured by ANT and NDIR-TC were not change after 24 and 48 hours open to atmosphere, which can be explained by conservative nature of alkalinity although $CO_2$ degas from ACW. On the other hand, alkalinity measured by BT and GW increased after 24 and 48 hours open to atmosphere, which was caused by relatively high concentration of measured total carbon and increasing pH. The comparison between geochemical modeling of $CO_2$ degassing and observed data showed that pH of observed ACW was higher than calculated pH. This can be happen when degassed $CO_2$ does not come out from the solution and/or exist in solution as $CO_{2(g)}$ bubble. In that case, $CO_{2(g)}$ bubble doesn't affect the pH and alkalinity. Thus alkalinity measured by ANT and NDIR-TC could not detect the $CO_2$ bubble although measured alkalinity was similar to the calculated alkalinity. Moreover, total carbon measured by ANT and NDIR-TC could be underestimated. Consequently, it is necessary to compare the alkalinity and total carbon data from various kind of methods and interpret very carefully. This study provide technical information of measurement of dissolve $CO_2$ from $CO_2$-rich water which could be natural analogue of geologic sequestration of $CO_2$.

• Korea-Australia Rheology Journal
• /
• v.18 no.2
• /
• pp.83-90
• /
• 2006

Supercritical carbon dioxide ($scCO_2$) has advantages of being incorporated in polymer with high solubility and of being recovered easily by depressurizing. $scCO_2$ reduces the viscosity of polymer melt and it is expected to be use as a plasticizing agent. In this work, we studied on the effect of $scCO_2$ on the rheological properties of polymer melts during extrusion process. Slit die attached to twin screw extruder was used to measure the viscosity of polymer melts plasticized by supercritical $CO_2$. A gas injection system was devised to accurately meter the supercritical $CO_2$ into the extruder barrel. Measurements of pressure drop within the die, confirmed the presence of a one phase mixture and a fully developed flow during the measurements. The viscosity measurement of polypropylene was performed at experimental conditions of various temperatures, pressures and $CO_2$ concentrations. We observed that melt viscosity of polymer was dramatically reduced by $CO_2$ addition.

• Journal of Climate Change Research
• /
• v.4 no.4
• /
• pp.359-369
• /
• 2013

In this paper, correlations between driving parameters and $CO_2$ of light-duty vehicles have been analyzed. Three test vehicles equipped with PEMS (Portable Emission Measurement System) have been driven in real-road in urban areas of Seoul. Averaged vehicle speed, RPA(Relative Positive Acceleration) and stop ratio have been selected as main driving parameters. The analysis have been conducted in interrupted and uninterrupted road types. Averaged values in various driving conditions have been calculated with distance based moving averaging window method. The multiple linear regression method have been applied to account for correlation between driving parameters and $CO_2$ emissions. This approach has shown statistically that $CO_2$ emission per distance (g/km) have tendencies to be increased as decreased averaged vehicle speed and increased RPA and stop ratio. Compared with uninterrupted traffic, interrupted traffic have shown the lower vehicle speed and the higher RPA and stop ratio. These characteristics of driving parameters in interrupted traffic should cause the higher $CO_2$ emission per distance.

• Journal of Bio-Environment Control
• /
• v.29 no.2
• /
• pp.161-170
• /
• 2020

There is systematic spatial variations in environmental properties due to sensitive reaction to external conditions at plastic greenhouse occupied 99.2% of domestic agricultural facilities. In order to construct 3 dimensional distribution of temperature, relative humidity, CO₂ and illuminance, measurement matrix as 3 by 3 by 5 in direction of width, height and length, respectively, dividing indoor space of greenhouse was designed and tested at experimental site. Linear regression analysis was conducted to evaluate optimal estimation method in terms with horizontal and vertical variations. Even though sole measurement point for temperature and relative humidity could be feasible to assess indoor condition, multiple measurement matrix is inevitably required to improve spatial precision at certain time domain such as period of sunrise and sunset. In case with CO₂, multiple measurement matrix could not successfully improve the spatial predictability during a whole experimental period. In case with illuminance, prediction performance was getting smaller after a time period of sunrise due to systematic interference such as indoor structure. Thus, multiple sensing methodology was proposed in direction of length at higher height than growing bed, which could compensate estimation error in spatial domain. Appropriate measurement matrix could be constructed considering the transition of stability in indoor environmental properties due to external variations. As a result, optimal measurement matrix should be carefully designed considering flexibility of construction relevant with the type of property, indoor structure, the purpose of crop and the period of growth. For an instance, partial cooling and heating system to save a consumption of energy supplement could be successfully accomplished by the deployment of multiple measurement matrix.

• Textile Coloration and Finishing
• /
• v.32 no.4
• /
• pp.208-216
• /
• 2020

In this study, C.I. Disperse Red 60 (DR60), C.I. Disperse Yellow 54 (DY54) dyes were used to investigate the washing fastness characteristics of PET fibers according to supercritical CO2 and aqueous dyeing process. The changes in K/S values and L⁎ values before and after washing of dyed PET fibers were observed according to the KS K ISO 105 washing fastness measurement method. In addition, it was confirmed by changing the ΔE⁎ and ΔL⁎ values of control PET fibers. Overall, it was confirmed that both the supercritical CO2 and aqueous dyeing process had excellent washing fastness ratings of 4-5 for DR60 and DY54 dyes. Comparatively, the K/S and L⁎ values for before and after washing of PET fibers with supercritical CO2 dyeing process was higher than that of the aqueous dyeing process and the ΔE⁎ and ΔL⁎ values of the control PET fibers were low. From the results, we observed that the supercritical CO2 dyeing process of PET fibers has better washing fastness characteristics than the aqueous dyeing process.

• Advances in environmental research
• /
• v.11 no.1
• /
• pp.17-30
• /
• 2022

Road transport allows all forms of land conditions to be met at less cost. Because of this function, despite numerous disadvantages, it becomes the most frequently used method of transport, especially in underdeveloped or developing countries. One of the most significant factors used in evaluating the atmosphere's air quality is the amount of CO₂, increasing people's density in indoor spaces. The amount of CO₂ indoors is, therefore, vital to determine. In this study, CO₂ and temperature measurements made on nine different bus journey was made in Turkey. The minimum and maximum values were recorded as 555 ppm and 3000 ppm CO₂, respectively, in the measurements. On all journeys, the average concentration is 1088.72 ppm. The minimum and maximum values were measured as 17.4℃ and 32.7℃ in the temperature measurements, and the average of all trips was calculated to be 25.76℃. In this study conducted before the Covid-19 pandemic, it was determined that the amount of CO₂ increased with the density and insufficient ventilation in the buses. The risk of infection increases in places with high human density and low clean air. For situations such as pandemics, CO₂ measurement is a rapid indicator of determining human density.