• Title/Summary/Keyword: $CO_2$ intensity reduction

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Expansion of Operating Range and Reduction of Engine out Emission in Low Temperature Diesel Combustion with Boosting (과급을 이용한 저온 디젤 연소의 운전영역 확장 및 배기 배출물 저감)

  • Shim, Eui-Joon;Han, Sang-Wook;Jang, Jin-Young;Park, Jung-Seo;Bae, Choong-Sik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.17 no.5
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    • pp.31-38
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    • 2009
  • Supercharging system was adopted to investigate the influence of boost pressure on operating range and exhaust emissions by using a supercharger at low temperature diesel combustion (LTC) condition in a 5-cylinder 2.7 L direct injection diesel engine. The experimental parameters such as injection quantity, injection timing, injection pressure and exhaust gas recirculation (EGR) rate were varied to find maximum operating range in LTC condition. As a result of adopting increased boost pressure in LTC, wider operating range was achieved compared with naturally aspirated condition due to increased mixing intensity. Increased boost pressure resulted in lower hydrocarbon (HC) and carbon monoxide (CO) emissions due to increased swirl rate and mixing intensity, which induced complete combustion. Moreover, increased boost pressure in LTC resulted in much lower soot emissions compared with high speed direct injection (HSDI) condition.

A Study on the Effects of Hydrogen Addition and Swirl Intensity in CH4-Air Premixed Swriling Flames (메탄-공기 예혼합 선회화염에서 수소첨가와 선회강도 영향에 관한 연구)

  • KIM, HAN SEOK;CHO, JU HYEONG;KIM, MIN KUK;HWANG, JEONGJAE;LEE, WON JUNE
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.6
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    • pp.593-600
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    • 2019
  • The combustion characteristics of methane/hydrogen pre-mixed flame have been investigated with swirl stabilized flame in a laboratory-scale pre-mixed combustor with constant heat load of 5.81 kW. Hydrogen/methane fuel and air were mixed in a pre-mixer and introduced to the combustor through a burner nozzle with different degrees of swirl angle. The effects of hydrogen addition and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using particle image velocimetry (PIV), micro-thermocouples, various optical interference filters and gas analyzers to provide information about flow velocity, temperature distributions, and species concentrations of the reaction field. The results show that higher swirl intensity creates more recirculation flow, which reduces the temperature of the reaction zone and, consequently, reduces the thermal NO production. The distributions of flame radicals (OH, CH, C2) are dependent more on the swirl intensity than the percentage of hydrogen added to methane fuel. The NO concentration at the upper part of the reaction zone is increased with an increase in hydrogen content in the fuel mixture because higher combustibility of hydrogen assists to promote faster chemical reaction, enabling more expansion of the gases at the upper part of the reaction zone, which reduces the recirculation flow. The CO concentration in the reaction zone is reduced with an increase in hydrogen content because the amount of C content is relatively decreased.

An Analysis of Long-Term Scenarios for The GHG Emissions Projections Considering Economic Growth and Industrial Structure Change (경제성장과 산업구조 변화에 따른 장기 온실가스 배출량 전망 시나리오 분석)

  • Kwon, Seung Moon;Jeon, Eui Chan
    • Journal of Climate Change Research
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    • v.7 no.3
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    • pp.257-268
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    • 2016
  • Both economic growth and industrial structure have great influence on energy consumption and GHG emissions. This study analyzed long-term scenarios for GHG emissions projections considering economic growth and industry value added change. In consideration of 3 GDP and 3 industry value added outlook, total 9 scenarios were set; 'Assembly Industry Baseline(AI)', 'Assembly KEIT industry(AK)', 'Assembly Advanced Country industry(AA)', 'KDI Industry Baseline(KI)', 'KDI KEIT industry(KK)', 'KDI Advanced Country industry(KA)', 'OECD Industry Baseline(OI)', 'OECD KEIT industry(OK)', and 'OECD Advanced Country industry(OA)' scenarios. In consideration of the GDP increase rate and industry value added outlook, it is estimated that AI scenario's GHG emissions would be 777 million tons of $CO_2eq$ in 2030. On the other hand, in the case of OA scenario, GHG emissions would be 560.2 million tons of $CO_2eq$ in 2030. Differences between AI scenario's and OA scenario's were 216.8 million tons of $CO_2eq$. It can be identified by that GDP and industry value added change have great influence on GHG emissions. In view of the fact that Korea's amount of GHG emission reduction targets in 2030 were 218.6 million tons of $CO_2eq$ that the result of this research could give us valuable insight.

[ $^{14}CO_2$ ] Assimilation and Metabolism of $^{14}C-$Assimilates in Whole Plants of Spring Barley In Relation to Adult-Plant Resistance to Powdery Mildew (흰가루병에 대해 성체식물 저항성을 지닌 봄보리에서 $^{14}CO_2$ 동화와 $^{14}C-$동화산물의 대사)

  • Hwang Byung Kook;Ibenthal Wolf-Dieter;Heitefuss Rudolf
    • Korean Journal Plant Pathology
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    • v.2 no.1
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    • pp.22-30
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    • 1986
  • The effect of powdery mildew infection on the $^{14}CO_2$ assimilation and metabolism of $^{14}C-$assimilates was studied with spring barley cultivars, susceptible Peruvian and adult-plant resistant Asse at the four-leaf stage. No consistent differences between Peruvian and Asse were revealed in $^{14}CO_2$ assimilation and metabolism of $^{14}C-$assimilates in healthy whole plants. In the two cultivars, $^{14}CO_2$ assimilation and translocation of assimilates decreased as the number of infected leaves increased. Despite the same infection intensity, $^{14}CO_2$ assimilation was less inhibited in Asse than Peruvian. Infection reduced the fixation of $^{14}CO_2$ in noninfected fourth leaves of Peruvian more severely than that of Asse. Infection of the lower 3 leaves also inhibited the incorporation of 14 C into carbohydrates such as fructose and glucose in noninfected fourth leaves and their translocation into leaf sheathes, the inhibitions being greater in Peruvian than Asse. In the infected third leaves, there was a reduction of 14 C-activity in carbohydrates, more $^{14}C-$labeled fructose and glucose being retained in Peruvian. The stimulation of $^{14}C-$organic acid synthesis in all plant organs was more pronounced in Peruvian than Asse. Powdery mildew markedly increased the incorporation of $^{14}C$ into amino acids in infected third and noninfected fourth leaves, but reduced their translocation to the leaf sheathes. A greater rise of $^{14}C-$ activity in some amino acids in the two leaves was found in Peruvian than Asse.

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Quantitative Determination of Total Bile Acids from Bezoar and Bezoar-containing Liquid Preparation by Enzymatic Technique (효소반응법을 이용한 우황 및 우황함유 액상 제제 중 총담즙산의 정량)

  • Ha, In-Sik;Kim, Seung-Hwan;Cha, Bong-Jin;Kwon, Jong-Won;Yang, Joong-Ik;Min, Shin-Hong
    • Journal of Pharmaceutical Investigation
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    • v.21 no.2
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    • pp.67-71
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    • 1991
  • A simple and sensitive method was developed for the quantification of free and conjugated bile acids in bezoar without prior hydrolysis. $3{\alpha}-Hydroxy$ bile acids are first oxidized to 3-keto bile acids in the reaction catalyzed by $3{\alpha}-hydroxysteroid$ $dehydrogenase(3{\alpha}-HSD)$. During this oxidative reaction, an equimolar quantity of nicotinamide adenine dinucleotide(NAD) is reduced to NADH and subsequently oxidized to NAD with concomitant reduction of nitrotetrazolium blue(NTB) to diformazan by the catalytic action of diaphorase. The diformazan has an absorbance maximum at 540 nm. The intensity of the color produced is directly proportional to bile acids concentration in the bezoar extracts. The optimum conditions for the enzymatic reaction such as effects of reaction time, reaction temperature and pH, and stability were investigated. Calibration plots for the sodium chelate observed to be linear and intra-, inter-assay analytical recovery of bile acids averaged $97.65{\pm}3.4%(S.D.)$. Therefore, it is considered that the quality control of total bile acids from bezoar or bezoar-containing liquid preparation using this simple and sensitive assay system will be acceptable. Also current bezoars and bezoar-containing liauid preparations were examined their total bile acids from this method.

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Analysis of CO2 Emission Pattern by Use in Residential Sector (가정 부문 이산화탄소 배출량 추이 분석)

  • Yoon, So Won;Lim, Eun Hyouk;Lee, Gyoung Mi;Hong, You Deok
    • Journal of Climate Change Research
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    • v.1 no.3
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    • pp.189-203
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    • 2010
  • The objective of this study is the estimate of $CO_2$ emissions by the energy consumption of functional technology introduced by classifying energy use in households according to functions as well as energy resources. This study also intends to provide the practical basis data in order to establish specific alternatives for GHG mitigation in residential sector with examining the cause analysis affecting $CO_2$ emission increases from 1995 to 2007. The results of this study show a 6.6% increase in the total $CO_2$ from 60,636 thousand tons in 1995 to 64,611 thousand tons in 2007 by using energy in residential sector. Heating is the greatest $CO_2$ emission sector by use, followed electric appliances, cooking, lighting and cooling. Heating sector shows 56.6% reductions from 71.5% in 1995 and as do cooling and electric home appliances, with a 2.4% increase from 0.6% and a 21.8% increase from 14.2% respectively. To analyze factors resulted in $CO_2$ emissions in residential sector, the relevant indicator change rate from 2005 to 2007 was examined. The results find that population, the number of household, housing areas, family patterns, and family income resulted in the $CO_2$ emissions increase in residential sector from 1995 to 2007. On the other hand, carbon intensity and energy intensity contribute to $CO_2$ reduction in residential sector with -2% and -38.7% respectively because of the energy conversion and the improvement of energy efficiency in electronic appliances. This study can be used as a reference when taken account of the reality and considered the introduction of highly effective measures to increase the possibility of mitigation potential in residential sector hereafter.

Region-wide Road Transport CO2 Emission Inventory (지역단위 도로교통 탄소배출 인벤토리구축 방법론)

  • Shin, Yong Eun;Ko, Kwang Hyee
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.1
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    • pp.297-304
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    • 2013
  • Due to its excessive $CO_2$ emissions, road transport sector becomes a target for emission reduction strategies. Although precise and reliable emissions inventories are necessary for evaluating plans and strategies, developing the region-wide inventory is a difficult task mainly because of a lack of data including travel patterns and modal volumes in the reginonal context. Most existing inventory methodologies employ fuel sale data within the target region, which ignores actual regional traffic patterns and thus not suited to its geographical context. To overcome these problems, this study develops region-wide $CO_2$ emissions inventory methodology by utilizing the Korea Transport DB (KTDB). KTDB provides a number of useful information and data, such as road network with which one can identify in and out trips over the entire region, traffic volumes of various modes, distance of travel, travel speed and so on. A model of equations that allow the computation of volume of $CO_2$ emitting from the road transport activities within the target region is developed. Using the model, numerical analyses are performed for the case of Busan Metropolitan City to demonstrate the applicability of the developed model. This study is indeed exploratory in the sense that using the existing data, it develops the $CO_2$ emissions inventory methodology which can produce better results than those from conventional fuel sales methodology. This study also suggests further reresarch directions to develop more refined methodologies in region-wide basis.

Properties of Low-Molecular Alginate by Ultrasound

  • Kim Sang-Moo;Park Seong-Min;Lee Keun-Tae;Bae Tae-Jin
    • Fisheries and Aquatic Sciences
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    • v.2 no.2
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    • pp.149-154
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    • 1999
  • Response Surface Methodology was applied for optimizing the processing parameters of ultrasound treatment in order to produce low-molecular alginate. The use of ultrasound significantly reduced viscosity of alginate solutions. Suggested parameters of ultrasound treatment for maximum reduction of alginate molecular weight were: specific intensity, 115.81 $W/cm^2$ at 20kHz frequency; treatment time, 35.55 min; temperature, $20.08^{\circ}C$; alginate concentration, $2.5\%$. Low-molecular alginate obtained by ultrasound had two peaks on Sepharose CL-6B gel filtration. The viscosities of control, fraction I, and fraction II at $0.1\%$ concentration and $25^{\circ}C$ were 3.07, 1.23, and 0.82cps, respectively. Molecular weights of control, fraction I, and fraction II alginates were 336,500, 70,400, and 52,800 daltons, and their solubilities were 3, 6, and $14\%$, respectively. The lower molecular weight of alginate, the lower the alcohol precipitation and the higher $Ca^{2+}$ ion binding capacities. Heavy metal ion binding capacities of alginates were high in the following order of Pb, Cd, Zn, and Co.

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New Liquid Crystal-Embedded PVdF-co-HFP-Based Polymer Electrolytes for Dye-Sensitized Solar Cell Applications

  • Vijayakumar, G.;Lee, Meyoung-Jin;Song, Myung-Kwan;Jin, Sung-Ho;Lee, Jae-Wook;Lee, Chan-Woo;Gal, Yeong-Soon;Shim, Hyo-Jin;Kang, Yong-Ku;Lee, Gi-Won;Kim, Kyung-Kon;Park, Nam-Gyu;Kim, Suhk-Mann
    • Macromolecular Research
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    • v.17 no.12
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    • pp.963-968
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    • 2009
  • Liquid crystal (LC; E7 and/or ML-0249)-embedded, poly(vinylidenefluoride-co-hexafluoropropylene) (PVdF-co-HFP)-based, polymer electrolytes were prepared for use in dye-sensitized solar cells (DSSCs). The electrolytes contained 1-methyl-3-propylimidazolium iodide (PMII), tetrabutylammonium iodide (TBAI), and iodine ($I_2$), which participate in the $I_3^-/I^-$ redox couple. The incorporation of photochemically stable PVdF-co-HFP in the DSSCs created a stable polymer electrolyte that resisted leakage and volatilization. DSSCs, with liquid crystal(LC)-embedded PVdF-co-HFP-based polymer electrolytes between the amphiphilic ruthenium dye N719 absorbed to the nanocrystalline $TiO_2$ photoanode and the Pt counter electrode, were fabricated. These DSSCs displayed enhanced redox couple reduction and reduced charge recombination in comparison to that fabricated from the conventional PVdF-co-HFP-based polymer electrolyte. The behavior of the polymer electrolyte was improved by the addition of optimized amounts of plasticizers, such as ethylene carbonate (EC) and propylene carbonate (PC). The significantly increased short-circuit current density ($J_{sc}$, $14.60\;mA/cm^2$) and open-circuit voltage ($V_{oc}$, 0.68 V) of these DSSCs led to a high power conversion efficiency (PCE) of 6.42% and a fill factor of 0.65 under a standard light intensity of $100\;mW/cm^2$ irradiation of AM 1.5 sunlight. A DSSC fabricated by using E7-embedded PVdF-co-HFP-based polymer electrolyte exhibited a maximum incident photon-to-current conversion efficiency (IPCE) of 50%.

Study on CFD Methodology for a Open Channel Type UV Reactor (전산유체역학을 활용한 개수로형 UV소독장비의 해석기법 연구)

  • Hwang, Woochul;Bak, Jeong-Gyu;Kim, Hyunsoo;Lee, Kunghyuk;Cho, Jinsoo
    • The KSFM Journal of Fluid Machinery
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    • v.18 no.2
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    • pp.54-59
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    • 2015
  • The performance of UV reactor which is used in water treatment is strongly affected by UV fluence rate and water flow in the UV reactor. Therefore, CFD tools are widely used in designing process of UV reactors. This paper describes the development of a computational fluid dynamics (CFD) methodology that can be used to calculate the performance of open channel type UV reactor used in wastewater treatment plant. All computations were performed using commercial CFD code, CFX, by considering three dimensional, steady, incompressible flow. The Eulerian-Eulerian multi-phase method were used to capture the water-air interface. The MSSS model, provided by UVCalc3D, was used to calculate the UV intensity field. The numerical predictions and calculated UV Dose were compared with experimental dataset to validate the CFD methodology. The reactor performance based on MS2 log reduction was well matched with measurements within 6%.