• Title/Summary/Keyword: $CO_2$ gas injection

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A Study on the Performance of Ni Catalysts in Biogas Steam Reforming: Impact of Supports and Precipitation Agent Injection Rates (바이오가스 수증기 개질 반응용 Ni 촉매 성능 연구: 지지체 및 침전제 주입 속도에 따른 영향)

  • Ji-Hyeon Gong;Min-Ju Kim;Kyung-Won Jeon;Won-Jun Jang
    • Clean Technology
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    • v.29 no.4
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    • pp.327-332
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    • 2023
  • This study investigated synthesis gas production via steam reforming of biogas. Ni-Al2O3 and Ni-CeO2 catalysts were synthesized using the co-precipitation method, with controlled precipitation agent injection rates. Catalytic performances were tested at various temperatures, with a gas composition ratio of CH4:CO2:H2O = 1:0.67:3 and a gas hourly space velocity (GHSV) of 647,000 mL h-1 gcat-1. The rate of precipitation agent injection influenced the characteristics of the catalysts depending on the type of support used. As the temperature increased, both the CO2 reforming of methane and the reverse water gas shift reactions occurred. The Ni-Al2O3 catalyst, synthesized with a single injection of the precipitation agent, exhibited the best catalytic activity under conditions with sufficient steam supply among the prepared catalysts, due to its high Ni dispersion.

An Experimental Study on Variations of Exhaust Gas Temperature and Concentration with Synthetic Gas Combustion in Exhaust Manifold (배기관에서의 합성가스 연소에 따른 배기가스 온도 및 농도 변화에 관한 실험적 연구)

  • Cho, Yong-Seok;Lee, Seang-Wock;Yang, Seung-Il;Song, Chun-Sub;Park, Young-Joon
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.4
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    • pp.56-62
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    • 2008
  • A synthetic gas reformed from hydrocarbon-based fuels consists of $H_2$, CO and $N_2$. Hydrogen contained in the synthetic gas is a very useful species in chemical processes, due to its wide flammability range and fast burning speed. The ESGI (Exhaust Synthetic Gas Injection) technology is developed to shorten the light-off time of three way catalysts through combustion of the synthetic gas in the exhaust manifold during the cold start period of SI engines. Before the ESGI technology is applied to the test engine, the authors set a test rig that consists of gas temperature and composition controllers, an exhaust pulse generator and an exhaust manifold with a visualization window, in order to optimize the point and conditions of injection of the synthetic gas. Through measuring burned gas temperatures and taking photographs of synthetic gas combustion at the outlet of the exhaust manifold, the authors tried to find the optimal injection point and conditions. Analysis of burned gas composition has been performed for various $O_2$ concentrations. As a result, when the synthetic gas is injected at the port outlet of the cylinder No. 4 and $O_2$ concentration exceeds 4%, combustion of the synthetic gas is strong and effective in the exhaust manifold.

The Effect of Fuel Injection Timing on Combustion and Power Characteristics in a DI CNG Engine (직분식 CNG 엔진에서 연료 분사시기의 변화가 연소 및 출력 특성에 미치는 영향)

  • Kang, Jeong-Ho;Yoon, Soo-Han;Lee, Joong-Soon;Park, Jong-Sang;Ha, Jong-Yul
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.1
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    • pp.193-200
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    • 2007
  • Natural gas is one of the most promising alternatives to gasoline and diesel fuels because of its lower harmful emissions, including $CO_2$, and high thermal efficiency. In particular, natural gas is seen as an alternative fuel for heavy-duty Diesel Engines because of the lower resulting emissions of PM, $CO_2$ and $NO_x$. Almost all CNG vehicles use the PFI-type Engine. However, PFI-type CNG Engines have a lower brake horse power, because of reduced volumetric efficiency and lower burning speed. This is a result of gaseous charge and the time losses increase as compared with the DI-type. This study was conducted to investigate the effect of injection conditions (early injection mode, late injection mode) on the combustion phenomena and performances in the or CNG Engine. A DI Diesel Engine with the same specifications used in a previous study was modified to a DI CNG Engine, and injection pressure was constantly kept at 60bar by a two-stage pressure-reducing type regulator. In this study, excess air ratios were varied from 1.0 to the lean limit, at the load conditions 50% throttle open rate and 1700rpm. The combustion characteristics of the or CNG Engine - such as in-cylinder pressure, indicated thermal efficiency, cycle-by-cycle variation, combustion duration and emissions - were investigated. Through this method, it was possible to verify that the combustion duration, the lean limit and the emissions were improved by control of injection timing and the stratified mixture conditions. And combustion duration is affected by not only excess air ratio, injection timing and position of piston but gas flow condition.

The effects of primary gas physical properties on the performance of annular injection type supersonic ejector (주유동 기체의 물리적 특성이 환형 분사 초음속 이젝터의 성능에 미치는 영향)

  • Jin, Jung-Kun;Kim, Se-Hoon;Park, Geun-Hong;Kwon, Se-Jin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.33 no.12
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    • pp.68-75
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    • 2005
  • The effects of the physical properties of primary flow on the performance of a supersonic ejector were investigated. Axisymmetric annular injection type supersonic ejector was used for the study of the effects of molecular weight and the specific heat at constant pressure on the ejection performance. Test gases include; air, $CO_{2}$, Ar, $C_{3}H_{8}$, and $CCl_{2}F_{2}$ for different values of gas properties. As the molecular weight and CP of the primary gas increase, the secondary flow pressure increases at the same primary stagnation pressure and this behavior results from the combined effects of molar specific heat or specific heat ratio.

Development of Low NOx Gas Burner Absorption Chiller/Heater Unit (흡수식 냉온수기용 저 NOx 가스버너 개발)

  • 최정환;오신규
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.1
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    • pp.277-283
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    • 1995
  • For the development of low NO$_{x}$ gas burners aimed for absorption chiller/heater unit, three proto type burners of different capacity (265000, 498000, and 664000 kcal/h) have been manufactured through a combustion method of step-by-step air injection. In order to characterize the overall features of the flame and the properties of the emission gas, the temperature of the flame and the concentration of NO$_{x}$ and CO were determined. The main factors in the design of burners (the area of primary air injection, the diameter of secondary air injection hole, fuel nozzle diameter) were observed to increase linearly with the scale-up of burner capacity. The flame temperature profiles of the burners were observed to be almost similar, irrespective of their capacity. However, as their capacity increased, the flame temperature slightly increased and the hot region of the flames moved to ward the flame tip along with the expansion to the direction of radius. From the proto type units, the amount of their NO$_{x}$ emission was determined to be around 25 - 30 vppm(3% )$_{2}$) and the CO emission was less than 19 vppm (3% $O_{2}$).TEX>).

Programmed Conditions of Supplying Carbon Dioxide to Keep its Desired Concentration in Kimchi Container (김치용기에서의 이산화탄소 농도 제어를 위한 주입 프로그램 조건 설정)

  • An, Duck Soon;Jo, Min Gyeong;Park, Su Yeon;Lee, Dong Sun
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.25 no.2
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    • pp.31-35
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    • 2019
  • Kimchi is a refreshing sour food which gives sour and carbonic acid taste of carbon dioxide produced during the fermentation process. So, carbon dioxide injection was tried to raise carbonic acid taste of kimchi stored in the airtight container. First, carbon dioxide injection times of a given gas supply system were determined experimentally to attain initial concentration of 80% for different solid/liquid ratios. Since carbon dioxide is dissolved in kimchi to decrease its concentration during storage, periodical carbon dioxide injection conditions were needed and determined to keep the $CO_2$ concentration above 70%. For the initial flushing to 80% $CO_2$ concentration in model system filled with water, the injection time ranged from 40 to 89 seconds for free volumes of 2-8 L. $CO_2$ injection conditions for the under-ripened storage at $10^{\circ}C$ consisted of longer time at more frequent cycles for watery kimchi than for Chinese cabbage kimchi. At $0^{\circ}C$ of subsequent ripened stage storage of watery kimchi, the periodical injection at 3 hour interval was required because of continuous dissolution of carbon dioxide. However, Chinese cabbage kimchi did not require subsequent $CO_2$ injection during the ripened state storage and needed only flushing to 80% $CO_2$ at time of the container opening and closing. These results can be used as basic information for the programmed control of $CO_2$ injection in the kimchi container system.

Study on Emission Reduction with Injection Strategy and Exhaust-Gas Recirculation in Gasoline Direct Injection Engine (직접분사식 가솔린 엔진의 분사전략 변경 및 EGR 적용을 통한 배기저감에 관한 연구)

  • Park, Cheol-Woong;Kim, Hong-Suk;Woo, Se-Jong;Kim, Yong-Rae
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.3
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    • pp.335-342
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    • 2012
  • Nowadays, automobile manufacturers are focusing on the reduction of exhaust-gas emissions because of the harmful effects on humans and the environment, such as global warming by greenhouse gases. Gasoline direct injection (GDI) combustion is a promising technology that can improve fuel economy significantly compared to conventional port fuel injection (PFI) gasoline engines. In the present study, ultra-lean combustion with an excess air ratio of over 2.0 is realized with a spray-guided-type GDI combustion system, so that the fuel consumption is improved by about 13%. The level of exhaust-gas emissions and the operation performance with the multiple injection strategy and exhaust-gas recirculation (EGR) are examined in comparison with the emission regulations and from the point of view of commercialization.

Study on the Separation of CO2 from Flue Gas Using Polysulfone Hollow Fiber Membrane (폴리설폰 중공사막을 이용한 연소 배기가스 중 이산화탄소 분리에 관한 연구)

  • Kim, Seongcheon;Chun, Jeonghyeon;Chun, Youngnam
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.2
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    • pp.147-152
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    • 2014
  • In this research, polysulfone hollow fiber membrane was used to recover $CO_2$ which is one of greenhouse gases from flue gas stream being emitted after the combustion of fossil fuels. The prerequisite requirement is to design the membrane process producing high-purity $CO_2$ from flue gas. For separation of $CO_2$, a membrane module and flue gas containing 10% carbon dioxide was used. The effects of operating conditions such as pressure, temperature, feed gas composition and multi-stage membrane on separation performance were examined at various stage cuts. Higher operating pressure and temperature increased carbon dioxide concentration and recovery ratio in permeate. Recovery ratio and separation efficiency increased if a higher content of $CO_2$ injection gas composition. Three-stage membrane system was producing a 95% $CO_2$ with 90% recovery from flue gas. The separation efficiency of three-stage membrane system was higher than one-stage system.

Geophysics for Carbon Capture and Storage in Korea (국내 CO2 지중저장과 지구물리탐사의 역할)

  • Hwang, Se-Ho;Park, Kwon-Gyu
    • 한국지구물리탐사학회:학술대회논문집
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    • 2009.10a
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    • pp.16-19
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    • 2009
  • Recently, CO2 geologic storage (geologic sequestration) has been concerned as one of methodologies for reducing greenhouse gas. We expect that geophysical approach plays an important role in the site selection, characterization, and monitoring during CO2 injection or post-injection. Especially we believe that monitoring and verification technologies such as surface and borehole geophysical methods are an important part of making CO2 geologic storage an acceptable method.

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Effect of Carbon Materials on the Slag Foaming in EAF Process (전기로 슬래그 포밍에 미치는 가탄재 종류의 영향)

  • Kim, Young-Hwan;Yoo, Jung-Min;Um, Hyung-Sic
    • Resources Recycling
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    • v.28 no.2
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    • pp.40-45
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    • 2019
  • During steelmaking in EAF, recycled scraps is used as a main material, melted by arc, and electricity use as a main energy. Slag foaming is an important technology for reducing electrical energy. CO gas generated by the reaction between injection carbon and (FeO), [C] and injection {$O_2$}. CO gas generated by this reaction is collected in slag, resulted in slag foaming. In general, the carbon materials used in the EAF process is anthracite and coke. This study investigated the effects of the carbon materials used on slag foaming in the steelmaking process. As a result of this study, the slag foaming height is increased by cokes rather than anthracite, and with an increase in the amount of particles samller than $500{\mu}m$. Based on these results, the application to the operation resulted in increase of slag forming height, reduction of injection carbon, and reduction of electrical energy.