• Title/Summary/Keyword: $CO_2$ emitted

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Effect of Diluents and Oxygen-Enrichness on the Stability of Nonpremixed Flame (산소부화와 희석제에 따른 비예혼합 화염의 안정성)

  • 배정락;이병준
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.10
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    • pp.1458-1464
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    • 2002
  • $CO_2$ is well known greenhouse gas which is the major source of global warming. Reducing $CO_2$ emission in combustion process can be achieved by increasing combustion efficiency, oxygen enriched combustion and recirculation of the emitted $CO_2$ gas. Stability of non-premixed flame in oxygen enriched environment will be affected by the amount of oxygen, kind of diluents and fuel exit velocity. The effects of these parameters on flame liftoff and blowout are studied experimentally oxidizer coflowing burner. Experiments were divided into three cases according as where $CO_2$gas was supplied. - 1) to coflowing air, 2) to fuel with 0$_2$-$N_2$ coflow, 3) to coflowing oxygen. Flame in air coflowing case was lifted in turbulent region. Flame lift and blowout in laminar region with the increase in $CO_2$ volume fraction in $CO_2$-Air mixture makes flame lift and blowout in laminar region. Increase in oxygen volume fraction makes flame stable-i.e. flame liftoff and blowout occur at higher fuel flowrates. Liftoff height was non-linear function of nozzle exit velocity and affected by the $O_2$ volume fraction. It was found that the flame in $O_2$-$N_2$ coflow case was more stable than $O_2$-$CO_2$ case, Liftoff heights vs (nozzle exit velocity/laminar burning velocity)$^{3.8}$ has a good correlation in $O_2$-$CO_2$ oxidizer case.

CO Two-photon Laser Induced Fluorescence Measurements in High Temperature and Pressure Conditions (고온고압 조건에서 Two-Photon LIF를 이용한 CO 측정에 관한 연구)

  • Oh, Seung-Mook;Kim, Duk-Sang;Miles, Paul C.;Colban, Will F.
    • Journal of the Korean Society of Combustion
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    • v.12 no.4
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    • pp.1-7
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    • 2007
  • Carbon monoxide (CO) is not only an important intermediate species in chemical reaction mechanisms of hydrocarbon fuel combustion, but also a crucial pollutant species emitted from automotive engines. To better understand the physical processes impacting CO emissions, the development of laser-based measurement techniques that can visualize in-cylinder CO distributions is desirable. Among these techniques, Laser-Induced Fluorescence (LIF) is a sensitive and species-selective detection technique capable of good spatial resolution. However, some technical matters such as deep UV excitation, severe pressure dependency of the LIF signal, and potential interference from other species have been major challenges for CO LIF application. This study is focused on investigating the feasibility of CO two-photon LIF in a direct-injection diesel engine operating at typical pressure and temperature conditions with commercial grade diesel fuel. Spectroscopic analysis shows that the CO fluorescence signal can be separated from $C_2$ Swan band or broadband fluorescence from PAHs when the signal is collected near 483 nm. The signal-to-noise ratio of CO LIF deteriorate rapidly as pressure is increased, following $P^{-1.49}$ which matches the theoretical signal pressure dependency.

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Recent Research Trends on Separation of CO2 Emitted From Steelmaking Process using Gas Hydrate Technology (가스 하이드레이트 형성 원리를 이용한 철강공정 배기가스 중 CO2 분리기술에 대한 최근 연구 동향)

  • Lee, Bo Ram;Ryu, Jun-Hyung;Han, Kunwoo;Park, Da-Hye;Lee, Kun-Hong;Lee, In-Beum
    • Korean Chemical Engineering Research
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    • v.48 no.2
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    • pp.232-243
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    • 2010
  • Gas hydrates are crystalline solids composed of water and gas molecules. Water molecules are linked through hydrogen bonding and create cavities(host lattice) that can capture a large variety of guest molecules under appropriate conditions, generally high pressure and low temperature. Recently, many researchers try to apply gas hydrates to industrial processes to capture greenhouse gases due to the facts that the process is eco-friendly and target gas molecules can be preferentially captured. In this paper, we introduced recent studies on $CO_2$ and $CO_2-N_2$ mixture hydrates to evaluate the feasibility of industrial application of gas hydrate technology to $CO_2$ capture process. Specifically, we put emphasis on the technical feasibility of $CO_2$ separation in steel industry using gas hydrate formation principles.

An Estimation of Direct and Indirect GHG-AP Integrated Emissions from Energy Sector in Seoul (2010) (서울시 에너지부문 직·간접 온실가스-대기오염 통합 배출량(2010) 산정)

  • Jung, Jaehyung;Kwon, O-Yul
    • Journal of Korean Society for Atmospheric Environment
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    • v.30 no.2
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    • pp.150-160
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    • 2014
  • Greenhouse gas (GHG) and Air Pollution (AP) emission inventories have been constructed and estimated independently up-to-date in Seoul. It causes difficulty in GHG and AP integrated management due to a difference in emission inventories. In this study, we constructed GHG and AP integrated emission inventories for direct and indirect sources in Seoul during the year 2010 in Energy activities for estimating GHG and AP emissions were derived from IPCC guideline, guidelines for local government greenhouse inventories, air pollutants calculation manual, and Indirect Emission Factors (IEF) reported by Korea Power Exchange. The annual GHG emission was estimated as 50,530,566 $tonCO_{2eq}$, of which 54.8% resulted from direct sources and the remaining 45.2% from indirect sources. Among direct sources, transportation sector emitted the largest GHG, accounting for 47.3% of the total emission from direct sources. As with indirect sources, purchased electricity sector only emitted 98.6% of the total emission from indirect sources. The annual AP emission was estimated as 283,701 tonAP, of which 85.9% was contributed by the combined AP emissions of transportation and fugitive sectors. Estimation of individual air pollutant showed that the largest source were transportation sector for CO, $NO_x$, TSP, $PM_{10}$ and NH3, non-energy sector for $SO_x$, and fugitive sector for VOCs. This study found some limitations in estimating GHG and AP integrated emissions, such as nonconforming emission inventories between GHG and AP, and no indirect AP emission factor of purchased electricity, and so on. Those should be further studied and improved for more effective GHG and AP integrated management.

A Study on Carbon Footprint and Mitigation for Low Carbon Apple Production using Life Cycle Assessment (전과정평가법을 이용한 사과의 탄소발생량 산정과 저감 연구)

  • Lee, Deog Bae;Jung, Sun Chul;So, Kyu Ho;Kim, Gun Yeob;Jeong, Hyun Cheol
    • Journal of Climate Change Research
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    • v.5 no.3
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    • pp.189-197
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    • 2014
  • Carbon footprint of apple was a sum of $CO_2$ emission in the step of manufacturing waste of agri-materials, and greenhouse gas emission during apple cultivation. Input amount of agri-materials was calculated on 2007 Income reference of Apple by Rural Development Administration. Emission factor of each agri- materials was based on domestic data and Ecoinvent data. $N_2O$ emission factor was based on 1996 IPCC guideline. Carbon dioxide was emitted 0.64 kg $CO_2$ to produce 1 kg apple fruit, and carbon dioxide was emitted 43.6% in the step of the manufacturing byproduct fertilizer, 1.3% in the step of the manufacturing single fertilizer, 4.7% in the step of the manufacturing composite fertilizer, 6.3% in the step of the manufacturing agri-chemicals, 14.6% in the step of the manufacturing fuel, 11.5% in the step of the fuel combustion, 17.7% of $N_2O$ emission by nitrogen application and 0.18% of disposal of agri-materials. It is needed for farmers to use fertilization recommendation based on soil testing (soil. rda.go.kr) because scientific fertilization is a major tools to reduce carbon dioxide of apple production. The fertilization recommendation could be also basic data in Measurable-ReporTablele-Verifiable (MRV) system for carbon footprint.

Comprehensive Environmental Impact Assessment for CO2 Emitted from Sailing Ship (선박의 운항에 의해 배출되는 이산화탄소에 대한 포괄적 환경영향평가)

  • Lee, Hee-Su;Park, Jong-Chun;Cho, Yong-Jin;Jeong, Se-Min;Yu, Jeoung-Seok
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.16 no.3
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    • pp.181-188
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    • 2013
  • The increase of carbon dioxide ($CO_2$) emission is known as one of the major causes of global warming, and it has a strong influence on the global environment. Therefore many researchers and politicians have tried to regulate the $CO_2$ emission. In regards to the matter, the IMPACT (Inclusive Marine Pressure Assesment and Classification Technology) committee under the Japan Society of Naval Architects and Ocean Engineers (JASNAOE) has developed an inclusive environmental impact assessment index, so-called "Triple I(III)", in order to assess the environmental impact including economic factors due to the artificial development of marine. In this study, III was applied to compare between the environmental impact of $CO_2$ emitted by container vessels during their life-cycle period and economic benefit due to their operating. Furthermore, III was also applied to assess the comprehensive environmental impact for the cases with various capacities of container vessels and different sailing route. From the results, the case for shortening of the sailing route is more effective to get the advantageous assessment results of III than the case for varying the size of vessels.

Analysis of Emission Characteristics and Emission Factors of Carbon Monoxide and Nitrogen Oxide Emitted from Wood Pellet Combustion in Industrial Wood Pellet Boilers Supplied According to the Subsidy Program of Korea Forest Service (산림청 지원사업에 따라 보급된 산업용 목재펠릿보일러에서 목재펠릿 연소 시 배출되는 일산화탄소와 질소산화물의 배출 특성 및 배출계수 분석)

  • Kang, Sea Byul;Choi, Kyu Sung;Lee, Hyun Hee;Han, Gyu-Seong
    • Journal of the Korean Wood Science and Technology
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    • v.46 no.5
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    • pp.597-609
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    • 2018
  • Korea Forest Service has supplied 76 industrial wood pellet boilers from 2011 to 2015 through subsidy programs. Since carbon monoxide (CO) and nitrogen oxides ($NO_x$) generated during boiler combustion are substances that lead to death in the case of acute poisoning, it is very important to reduce emissions. Therefore, the CO and $NO_x$ emission values of 63 boilers excluding the hot air blower and some boilers initially supplied were analyzed. The emission factor was also calculated from the measured exhaust gas concentration (based on exhaust gas $O_2$ concentration of 12%). The average value of CO emitted from industrial wood pellet boilers was 49 ppm and it was confirmed that the CO concentration was decreasing as the years passed. The emission factor of CO was 0.73 g/kg. The average value of $NO_x$ emitted from industrial wood pellet boilers was 67 ppm and the emission factor of $NO_x$ was 1.63 g/kg. Unlike CO, there was no tendency to decrease according to the installation year. Both CO and $NO_x$ measurements met the limits of the Ministry of Environment. These $NO_x$ emission factors were compared with the $NO_x$ emission factors produced by certified low $NO_x$ burners. The $NO_x$ emission factor of industrial wood pellet boilers was about 1.9 times that of certified low $NO_x$ LNG combustors and about 0.92 times that of coal combustion.

A Study on Characteristics of Exhaust Emissions from Domestic Used Diesel Engines (國産 디이젤機關의 汚染物質 排出特性에 關한 硏究)

  • 趙康來;金良均;董宗仁;嚴明道
    • Journal of Korean Society for Atmospheric Environment
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    • v.1 no.1
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    • pp.83-92
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    • 1985
  • In odrder to survey the emission level of air pollutants from diesel vehicles, was measured CO, HC, NOx and smoke of 4 types of domestic-use diesel engines under various conditions. The emission of CO, HC and NOx tested by 6-Mode test method and smoke emission by full load test met the permissible vehicle emission standard. Pollutant emission rates of diesel engines were different according to engine operating conditions, that is, engine load and engine speed. Generally, CO and HC was emitted more at low load and NOx at high load but the trend was quite different by the type of engines. In exhaust gas, $NO_2$ portion of NOx emission was high, specially at low speed and low load. The correlation equation between CLD(NOx) and NDIR(NO) method of nitrogen of nitrogen oxides analysis was y = 1.10x - 3.48 (y: CLD method) as a result of 6-mode test.

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Analysis of ISO Solenoid Valve for Electrical Characteristic (ISO 솔레노이드 밸브 전기적 특성 분석)

  • Jeon, Yong-Sik;Oh, Yeong-Cheol;Ju, Min-Jin
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.663-664
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    • 2008
  • In this study, A special quality analysis and experiment for low power consumption type pneumatic on-off micro valve was performed. And flow characteristics of the micro valve by stroke change was numerically investigated. As a result, it is shown that magnetic force(2.4N) is exerted enough to move poppet with 0.3mm stroke with 0.01 seconds of response time, and that there is no magnetic force emitted by yoke.

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Removal Efficiency of Harmful Substances in Side-stream Tobacco Smoke by the Doping Components of Commercial TiO2 Photocatalysts (시판용 TiO2 광촉매의 doping 성분에 따른 비주류 담배연기의 유해물질 제거효율)

  • Kim, Tae-Young;Cho, Yeong-Tae;Moon, Gi-Hak;Kim, Jae-Yong
    • Applied Chemistry for Engineering
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    • v.28 no.5
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    • pp.565-570
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    • 2017
  • Tobacco smoke emitted during smoking is divided into a main-stream and side-stream smoke. Most of the tobacco smoke that spreads to a room while smoking is a side-stream one. The side-stream tobacco smoke is two to three times more harmful than that of the main-stream tobacco smoke. In this study, the removal efficiency of CO, $H_2S$, $NH_3$ and HCHO in a side-stream tobacco smoke using the doping component of $TiO_2$ photocatalysts was confirmed. As a result, CO was removed up to 78.37%, which indicated that the $TiO_2$ photocatalytic process is effective for CO removal. Also, the removal efficiencies of CO, $H_2S$ and HCHO were greatly affected by the amount of doped O and Si components of the $TiO_2$ photocatalyst. In conclusion, the more doped O and Si components had, the higher removal efficiencies of harmful substances were achieved.