• Title/Summary/Keyword: $CO_2$ dilution

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Preparation of Lead Titanate by Sol-Gel Method and Characteristic of Organic Acid Adsorption (졸겔법에 의한 티탄산납 제조 및 유기산 흡착특성)

  • Kim, Ju-Ho;Song, Jee-Hoon;Shin, Bo-Chul;Han, Sang-Oh;Song, Kun-Ho;Lee, Kwang-Rae
    • Journal of Industrial Technology
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    • v.21 no.B
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    • pp.133-139
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    • 2001
  • Generally $PbTiO_3$ is manufactured in a form of thin films which is useful for the application of infrared sensors and non-volatile memory devices. Moreover $PbTiO_3$ has a characteristic of adsorption for organic acid as well as electronic property. Organic acid adsorption properties of $PbTiO_3$ powder prepared by sol-gel method was compared with the powder purchased from Aldrich Co. Crystallization and particle size of $PbTiO_3$ are influenced by process variables, such as dilution of sol solution, catalysis, calcination temperature, calcination time, etc. As the size of $PbTiO_3$ power decreased until several nanometers, adsorption of acetic acid and formic acid was increased 1.5-fold and 1.2-fold respectively.

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Heat input effects on microstructure quenched and tempered steel ASTM A517 to stainless steel AISI 316L

  • Pezeshkian, Rouhollah Mohsen;Shafaiepour, Saiedeh
    • Journal of Welding and Joining
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    • v.33 no.1
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    • pp.41-48
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    • 2015
  • In this study, the effect of heat input on weld metal microstructure and the effects of dissimilar weld heat affected zone in quenched and tempered ASTM A517 on the stainless steel AISI 316L is investigated through the optimization of welding parameters. For this purpose, two welding techniques are used, tungsten-conventional gas and pulsed gas with weld wire ER 309MoL with Diameter 2.4 mm. Research showed that the grain size of the heat affected zone in pulsed welding is less compared with conventional welding; weld metal structure is fully austenitic, it has a finer structure in the pulsed method. Additionally, the growth of weld metal adjacent steel A517 is different from steel 316L. Further, investigation showed that the rate of dilution is less in the pulsed method and the impact energy is increased in each three regions of the weld metal and heat affected zones in the pulsed method; the fracture in the weld metal and heat affected zone of steel 316L is quite soft and it is semi-crispy in the heat affected zone of steel A517.

Survey of the Secondary Effluents from Municipal Wastewater Treatment Plants in Korea (우리나라 하수처리장 방류수 수질현황 및 특성)

  • Kim, Youngchul;An, Ik-Sung;Kang, Min-Gi
    • Journal of Korean Society on Water Environment
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    • v.21 no.2
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    • pp.158-168
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    • 2005
  • In this study, the discharging effluents from have been 9 municipal wastewater treatment plants surveyed for 1 year-period. Statistics including probability distribution, cumulative occurrence concentration and other statistical parameters were presented. In addition, treatment performance and its stability were also discussed. Most of the plants, have an operational problem of high soluble organic content in the secondary effluent which may be associated with the integrated treatment of human and livestock manures. Nitrogen concentration in the effluents were usually higher during the period of summer and winter. It was found that this is mainly due to lack of the proper C/N ratio during the summer, or/and the effects of low temperature and less dilution by dry weather during the winter. Phosphorus concentration is sharply increased in June. Discussion with plant operators told that it is due to the dissolution of phosphate from the sludge accumulated in the primary settling tanks from the early spring to june. During this period, usually, sludge treatment line is highly overloaded with flush-outs of the sediments also stored in the bottom of combined sewer due to the low flow during winter season. Most of the plants can meet new effluent discharge limits of the nitrogen and phosphorus, and total coliform without further treatment.

The Acute Toxicity Effect of Triotganotin on the Growth of Microalgae and Shellfish and A Design of A Chemostat System for the Chronic Toxicity Experiment (미세조류와 패류의 성장에 미치는 Triorganotin의 급성 독성영향 및 만성독성 실험을 위한 Chemostat System의 설계)

  • Tak, Keon-Tae;Lee, Hyong-Ho;Hong, Yoog-Ki;Kim, Joong Kyun
    • Journal of Life Science
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    • v.7 no.4
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    • pp.377-383
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    • 1997
  • The acute toxicity effect of triorganotin of trioganotin on the growth of microalgae and shellfish was investigated through flask culture. The value of 120 hr-LC$_{50}$ that is the median lethal concentration of TBTO on the shellfish (R. philipinarum) was found to be 6 $\mu$g/L. The acute toxicity effect of TBTO on T. suecica was obviously shown even at the concentration of 0.5 $\mu$g/L, and the effect diminished as the initial cell density increased. The effect also diminished less in the experiment done under aeration than in that done under non-aeration. To design a chemostat system for the test of chronic toxicity, the culture of T. suecica was executed in photobioreactor. In batch culture, the profiles of chlorophyII a and D.C.W. showed the growth of T. suecica very well, and the maximum specific growth rate was estimated to be 0.54 d$^{-1}$. with this value, as a dilution rate in contimuous culture, pH was nicely maintained between 7 and 9 when air was supplied with 3% CO$_{2}$. From all results and the natural environment of clam, a novel chemostat system was invented. Through this system, we can observe each independent toxicity effect of TBTO and plankton and combined toxicity effect as well.

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The Flow and Water Quality Estimation of CSOs Using EC Data and Civil Engineering Research Model (전기전도도 및 토연모델을 이용한 CSOs 유량 및 수질 추정)

  • Choi, Wonsuk;Chung, Chulkwon;Nam, Jungyoon;Koo, Wonseok;Jung, Kwangsu
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.3
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    • pp.178-184
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    • 2014
  • In this study, monitoring method which is more economic and easier in maintenance comparing to existing monitoring system was scrutinized for application to sewer intercepting chamber of 10.2 ha basin area by estimating CSOs (Combined Sewer Overflows) quantity and quality with 2 rainfall events using electrical conductivity data and civil research model. The result showed that determination coefficient of flow estimation by EC (Electrical Conductivity) dilution ratio and observed data was over 0.86 for all cases and the accuracy of estimation was improved from 0.5 to 0.8 for determination coefficient ($R^2$) and from 54.1% to 68.5% for accumulation frequency of relative error by considering antecedent dry days and rainfall duration. CSOs water quality estimation results by civil research model showed that determination coefficients were 0.64~0.97 for BOD and 0.70~0.95 for SS.

Evaluation of Ventilation Performances for Various Combinations of Inlets and Outlets in a Residential Unit through CO2 Tracer-Gas Concentration Decay Method (CO2 추적가스 농도감소법을 이용한 공동주택의 급·배기구 조합에 따른 환기 성능 분석)

  • Sang Yoon Lee;Soo Man Lee;Jong Yeob Kim;Gil Tae Kim;Byung Chang Kwag
    • Land and Housing Review
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    • v.14 no.4
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    • pp.111-120
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    • 2023
  • Indoor air quality has become increasingly important with the increase in time spent in residential environments, impact of external fine dust, yellow dust, and the post-COVID 19 pandemic. Residential mechanical ventilation plays a key role in addressing indoor air quality. The legal standard for residential air changes per hour in Korea is 0.5 ACH. However, there are no standards for the location of supply and return vents. This study atempts to analyze the impact of ventilation performance based on the location of supply and return vents. An experiment was conducted using the CO2 tracer gas concentration decay method in a mock-up house set inside a large chamber to minimize external influences. The experimental results indicated that the commonly used combination of 2 supply and 2 return vents in living room spaces had a lower mean age of air than the combination of 1 supply and 2 return vents. Using multiple supply and return vents had lower mean age of air than using just 1 supply and 1 return vent.

Geochemistry of Stream Water around the Abandoned Boeun Coal Mine, Hoenam Area (보은제일폐탄광 주변 하천수의 지구화학적 특징)

  • Jeon, Seo-Ryeong;Shin, Ik-Jong;Lee, Kyu-Seung
    • Korean Journal of Environmental Agriculture
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    • v.20 no.1
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    • pp.20-27
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    • 2001
  • Stream water chemistry in the abandoned Boeun Jeil coal mine area was studied for a period of 3 months, including rainy and dry season. The stream waters were a nearly neutral and slightly alkali condition, and $Mg-SO_4$ type with Mg>Ca>Na>K and $SO_4>HCO_3>Cl>NO_3$. Chemical composition of the stream water was quite irregular during the experimental period. Concentrations of Na, K, $HCO_3$, U, Sr, and Cr decreased by $10{\sim}30%$ during rainy season, caused by dilution effects with rain. The concentration of Ca, Mg, $NO_3$, Cd, and Co increased during the rainy season, caused by more easily dissolved from bedrocks or mine drainage with slightly acidic condition than dry season. The stream water was enriched in Mg, Ca, $HCO_3$, $SO_4$, Al, Fe, Zn, Ni, Co, Cr, Cd, Sr and U. Concentrations of Na, Mg, Ca, $SO_4$, $HCO_3$, Fe, Zn, Ni, Sr, and U decreased linearly with distance from the mine adit. These elements were strongly controlled by dilution of unpolluted water influx and/or adsorption on the clay minerals and iron oxyhydroxide precipitates. This mine area exhibited two main weathering processes ; 1) oxidation with acidification derived from Fe sulphides, and 2) pH buffering due to Ca and Mg carbonate dissolution. This weathering processes were followed by adsorption of metals on iron oxyhydroxides and precipitation.

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Hydrological Significance on Interannual Variability of Cations, Anions, and Conductivity in a Large Reservoir Ecosystem (대형 인공호에서 양이온, 음이온 및 전기전도도의 연변화에 대한 수리수문학적 중요성)

  • An, Kwang-Guk
    • Korean Journal of Ecology and Environment
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    • v.34 no.1 s.93
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    • pp.1-8
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    • 2001
  • During April 1993 to November 1994, cations, anions, and conductivity were analyzed to examine how summer monsoon influences the ionic content of Taechung Reservoir, Korea. Interannual variability of ionic content reflected hydrological characteristics between the two years(high-flood year in 1993 vs. draught year in 1994). Cations, anions and conductivity were lowest during peak inflow in 1993 and highest during a drought in 1994. Floods in 1993 markedly decreased total salinity as a result of reduced Ca$^{2+}$ and HCO$_{3}\;^{-}$ and produced extreme spatial heterogeneity (i.e., longitudinal, vertical, and horizontal variation) in ionic concentrations. The dominant process modifying the longitudinal (the headwaters-to-downlake) and vertical (top-to-bottom) patterns in salinity was an interflow current during the 1993 monsoon. The interflow water plunged near a 27${\sim}$37 km-location (from the dam) of the mid-lake and passed through the 10${\sim}$30m stratum of the reservoir, resulting in an isolation of epilimnetic high conductivity water (>100 ${\mu}$S/cm) from advected river water with low conductivity (65${\sim}$75 ${\mu}$S/cm), During postmonsoon 1993, the factors regulating salinity differed spatially; salinity of downlake markedly declined as a result of dilution through the mixing of lake water with river water, whereas in the headwaters it increased due to enhanced CaCO$_{3}$ (originated from limestone/metamorphic rock) of groundwaters entering the reservoir. This result suggests an importance of the basin geology on ion compositions with hydrological characteristics. In 1994, salinity was markedly greater (p<0.001) relative to 1993 and ionic dilution did not occur during the monsoon due to reduced inflow. Overall data suggest that the primary factor influencing seasonal ionic concentrations and compositions in this system is the dilution process depending on the intensity of monsoon rainfall.

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Effect of Intake Pressure on Emissions and Performance in Low Temperature Combustion Operation of a Diesel Engine (디젤 저온연소 운전 영역에서 흡기압이 엔진 성능에 주는 영향)

  • Lee, Sun-Youp;Chang, Jae-Hoon;Lee, Yong-Gyu;Oh, Seung-Mook;Kim, Yong-Rae;Kim, Duk-Sang
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.1
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    • pp.88-94
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    • 2012
  • One of the effective ways to reduce both $NO_x$ and PM at the same time in a diesel CI engine is to operate the engine in low temperature combustion (LTC) regimes. In general, two strategies are used to realize the LTC operation-dilution controlled LTC and late injection LTC - and in this study, the former approach was used. In the dilution controlled regime, LTC is achieved by supplying a large amount of EGR to the cylinder. The significant EGR gas increases the heat capacity of in-cylinder charge mixture while decreasing oxygen concentration of the charge, activating low temperature oxidation reaction and lowering PM and $NO_x$ emissions. However, use of high EGR levels also deteriorates combustion efficiency and engine power output. Therefore, it is widely considered to use increased intake pressure as a way to resolve this issue. In this study, the effects of intake pressure variations on performance and emission characteristics of a single cylinder diesel engine operated in LTC regimes were examined. LTC operation was achieved in less than 8% $O_2$ concentration and thus a simultaneous reduction of both PM and $NO_x$ emission was confirmed. As intake pressure increased, combustion efficiency was improved so that THC and CO emissions were decreased. A shift of the peak Soot location was also observed to lower $O_2$ concentration while $NO_x$ levels were kept nearly zero. In addition, an elevation of intake pressure enhanced engine power output as well as indicated thermal efficiency in LTC regimes. All these results suggested that LTC operation range can be extended and emissions can be further reduced by adjusting intake pressure.

Stable Isotope and Fluid Inclusion Studies of the Daebong Gold-silver Deposit, Republic of Korea (대봉 금-은광상에 대한 유체포유물 및 안정동위원소 연구)

  • 유봉철;이현구;김상중
    • Economic and Environmental Geology
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    • v.36 no.6
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    • pp.391-405
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    • 2003
  • The Daebong gold-silver deposit consists of mesothermal massive quartz veins thar are filling the fractures along fault shear (NE, NW) Bones within banded or granitic gneiss of Precambrian Gyeonggi massif. Based on vein mineralogy, ore textures and paragenesis, ore mineralization of this deposits is composed of massive white quartz vein(stage I) which was formed in the same stage by multiple episodes of fracturing and healing, and transparent quartz vein(stage II) which is separated by a major faulting event. Stage I is divided into the 3 substages. Ore minerals of each substages are as follows: 1) early stage I=magnetite, pyrrhotite, arsenopyrite, pyrite, sphalerite, chalcopyrite, 2) middle stage I=pyrrhotite, arsenopyrite, pyrite, marcasite, sphalerite, chalcopyrite, galena, electrum and 3) late stage I=pyrite, sphalerite, chalcopyrite, galena, electrum, argentite, respectively. Ore minerals of the stage II are composed of pyrite, sphalerite, chalcopyrite, galena and electrum. Systematic studies (petrography and microthermometry) of fluid inclusions in stage I and II quartz veins show fluids from contrasting physical-chemical conditions: 1) $H_2O-CO_2-CH_4-NaCl{\pm}N-2$ fluid(early stage I=homogenization temperature: 203∼3$88^{\circ}C$, pressure: 1082∼2092 bar, salinity: 0.6∼13.4 wt.%, middle stage I=homogenization temperature: 215∼28$0^{\circ}C$, salinity: 0.2∼2.8 wt.%) related to the stage I sulfide deposition, 2) $H_2O-NaCl{\pm}CO_2$ fluid (late stage I=homogenization temperature: 205∼2$88^{\circ}C$, pressure: 670 bar, salinity: 4.5∼6.7 wt.%, stage II=homogenization temperature: 201-3$58^{\circ}C$, salinity: 0.4-4.2 wt.%) related to the late stage I and II sulfide deposition. $H_2O-CO_2-CH_4-NaCl{\pm}N_2$ fluid of early stage I is evolved to $H_2O-NaCl{\pm}CO_2$ fluid represented by the $CO_2$ unmixing due to decrease in fluid pressure and is diluted and cooled by the mixing of deep circulated meteoric waters ($H_2O$-NaCl fluid) possibly related to uplift and unloading of the mineralizing suites. $H_2O-NaCl{\pm}CO_2$ fluid of stage II was hotter than that of late stage I and occurred partly unmixing, mainly dilution and cooling for sulfide deposition. Calculated sulfur isotope compositions ({\gamma}^{34}S_{H2S}$) of hydrothermal fluids (3.5∼7.9%o) indicate that ore sulfur was derived from mainly an igneous source and partly sulfur of host rock. Measured and calculated oxygen and hydrogen isotope compositions ({\gamma}^{18}O_{H_2O}$, {\gamma}$D) of ore fluids (stage I: 1.1∼9.0$\textperthousand$, -92∼-86{\textperthansand}$, stage II: 0.3{\textperthansand}$, -93{\textperthansand}$) and ribbon-banded structure (graphitic lamination) indicate that mesothermal auriferous fluids of Daebong deposit were two different origin and their evolution. 1) Fluids of this deposit were likely mixtures of $H_2O$-rich, isotopically less evolved meteoric water and magmatic fluids and 2) were likely mixtures of $H_2O$-rich. isotopically heavier $\delta$D meteoric water and magmaticmetamorphic fluids.