• Title/Summary/Keyword: $CO_2$ diffusion coefficient equation

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The study of electron transport coefficients in pure $CO_2$ by 2-term approximation of the Boltzmann equation (2항근사 볼츠만 방정식을 이용한 $CO_2$분자가스의 전자수송계수의 해석)

  • Jeon, Byung-Hoon;Kim, Ji-Yeon;Kim, Song-Gang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05c
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    • pp.164-167
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    • 2001
  • The electron transport coefficients, the electron drift velocity W, the longitudinal diffusion coefficient $ND_L$ and $D_L/{\mu}$, in pure $CO_2$ were calculated over the wide E/N range from 0.01 to 500 Td at 1 Torr by two-term approximation of the Boltzmann equation for determination of electron collision cross sections set and for quantitative characteristic analysis of $CO_2$ molecular gas. And for propriety of two-term approximation of Boltzmann equation analysis, the calculated results compared with the electron transport coefficients measured by Nakamura.

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Influence of Porosity on the CO2 Diffusion Characteristic in Concrete (공극률을 고려한 콘크리트 중의 이산화탄소 확산특성에 관한 연구)

  • Oh, Byung-Hwan;Jung, Sang-Hwa;Lee, Myung-Kue
    • Journal of the Korea Concrete Institute
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    • v.15 no.3
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    • pp.443-453
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    • 2003
  • The diffusivity of carbon dioxide in concrete is very important in that it directly affects the degree of carbonation in concrete structures. The purpose of the present study is to explore the diffusivity of carbon dioxide and to derive a realistic equation to estimate the diffusion coefficient of carbon dioxide in concrete. For this purpose, several series of concrete specimens have been tested. Major test variables were the water-cement ratios. The total porosities and the diffusion coefficients of carbon dioxide were measured for the specimens. The present study indicates that the measured porosities agree well with the calculated ones. The effects of porosity and relative humidity on the diffusion coefficient of carbon dioxide were examined. A prediction equation to estimate the diffusion coefficient of carbon dioxide was derived and proposed in this study. The proposed equation shows reasonably good correlation with test data on the $CO_2$ diffusion coefficient of concrete

A Molecular Dynamics Study on the Gas Permeation of Glassy Polymer

  • Goo, Hyung Seo;Kim, In Ho;Ha, SeongYong;Cho, Dae Myeong;Rhim, Ji Won;Nam, SangYong
    • Korean Membrane Journal
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    • v.6 no.1
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    • pp.30-36
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    • 2004
  • The gas permeation performance of commercially available polyetherimide (Ultem$\^$/) is simulated by means of molecular dynamics methods. By the observation of trajectory, long distance hopping of gas molecules is needed to transverse from top to bottom of membrane. Two possibilities mechanism of diffusion phenomena through glassy polymers can be issued. Diffusion coefficients were calculated by Einstein relation equation. In solubility simulation, the value of the constants C'$\_$H/ and b for O$_2$ at 300 K were calculated. The diffusion and solubility coefficient of He for PEI were simulated in this simulation work. the permeability coefficient is 9.88 Barrer. This value is closed to experimental value of 9.4 Barrer.

The Prediction Model of Carbonation Process by CO2 Diffusion Using the Air Permeability Coefficient for Concrete (콘크리트의 투기계수를 이용한 CO2확산 탄산화진행 예측모델)

  • Kang, Suk-Pyo;Kim, Young-Sun;Song, Ha-Won;Kim, Gyu-Yong
    • Journal of the Korea Concrete Institute
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    • v.22 no.2
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    • pp.209-217
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    • 2010
  • Recently, some mathematical models for the prediction on progress of carbonation of concrete were reported. These models take account for $CO_2$ diffusion and chemical reaction between $Ca(OH)_2$ and $CO_2$. Based on the assumption that $CO_2$ diffuses in the carbonation zone and reacts with $Ca(OH)_2$ at the outer face of carbonation zone and non-carbonation zone. In this study, a mathematical model to predict the progress of carbonation of concrete has been established based on the reducing concentration of $Ca(OH)_2$ in the carbonation progress zone, where $Ca(OH)_2$ reacts with $CO_2$ and $Ca(OH)_2$ and $CaCO_3$ coexist. Also, the prediction model of carbonation progress rate of concrete using the air permeability coefficient regarding to $CO_2$ diffusion is developed. As a result of this study, an expression, the model equation is obtained for the prediction of carbonation based on the time and interaction velocity between $CO_2$ and Ca(OH)$_2$ dependent air permeability coefficient. The prediction by the model satisfied the experimental data of the accelerated carbonation for painted concrete. Consequently, the model can predict the rate of carbonation and the potential service life of concrete structure exposed to atmosphere.

Oxidation Mechanism of SiC (SiC의 산화반응 기구)

  • 최태운;이홍림
    • Journal of the Korean Ceramic Society
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    • v.18 no.2
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    • pp.79-82
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    • 1981
  • SiC powder was heated in air over the temperature range of 1100-135$0^{\circ}C$. $\beta$-cristobalite was formed to cover the surfaces of SiC particles by the reaction: $SiC(s)+20_2(g)=SiO_2(s)+CO_2(g)$. It is assumed that the diffusion of oxygen ion through the formed surface layer of $\beta$-cristobalite controls the oxidation of the SiC particles. The diffusion coefficient of oxygen ion through the $\beta$-cristobalite layer was obtained as the following equation: $D=3.84{\times}10^{-17}$exp(-14.7/RT)

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A Study on the Carburization Mechanism of Iron by Solid Carbon (고체탄소(固體炭素)에 의한 철(鐵)의 침탄기구(浸炭機構)에 대(對)한 연구(硏究))

  • Kwon, Ho-Young;Cho, Tong-Rae;Kang, Sei-Sun
    • Journal of Korea Foundry Society
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    • v.8 no.3
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    • pp.287-295
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    • 1988
  • The experiment was carried out for the purpose of studying the carburization of pure iron ingot and sintered iron powder by solid carbon in the atmosphere of CO gas. The volocity of carburization was estimaed by the diffusion coefficient D calculated by carburization equation. The results obtained were as follow: 1. The higher the carburization temperature, carburization depth and carbon concentration were increased, and the melting zone which had $2.8{\sim}3.4%C$ at the $3{\sim}4mm$ from interface of carburization was formed at $1300^{\circ}C$. 2. The main carburization mechanism of pure iron ingot and the sintered iron powder were proceeded by CO gas up to $1100^{\circ}C$, solid carbon over than $1300^{\circ}C$, respectively. 3. The main carburization mechanism of pure iron ingot at $1200^{\circ}C$ was proceeded by solid carbon, and sintered iron powder was proceeded bs CO gas, however, in case the reaction time, the carburization was proceeded by solid carbon over than 5hrs. 4. The diffusion coefficient D of carbon were $0.559{\times}10^{-6}cm^2.sec^{-1}$ at $1100^{\circ}C$, $0.237{\times}10^{-6}cm^2.sec^{-1}$ at $1200^{\circ}C$, $0.087{\times}10^{-6}cm^2.sec^{-1}$ at $1300^{\circ}C$, in case of pure iron ingot carburized. 5. The diffusion coefficient D of carbon were $0.124\;cm^2.sec^{-1}$ at $1100^{\circ}C$, $0.102\;cm^2.sec^{-1}$ at $1200^{\circ}C$, $0.480\;{\times}10^{-6}cm^2.sec^{-1}$ at $1300^{\circ}C$, in the case of sintered iron carburized at the pressuring $4ton\;/\;cm^2$.

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The Prediction model of Carbonation Process Using the Air Permeability Coefficient for Concrete (콘크리트의 투기계수를 이용한 중성화진행 예측모델)

  • Lim, Chang-Hyuck;Kim, Gyu-Yong;Lee, Tae-Gyu;Lee, Eui-Bae;Didolkar, Rahul B.;Kang, Suk-Pyo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.221-222
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    • 2010
  • In this study an expression is obtained the model equation for the prediction of carbonation based on the time and interaction velocity between $CO_2$ and $Ca(OH)_2$ diffusion coefficient.

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Magneto-transport properties of CVD grown MoS2 lateral spin valves

  • Jeon, Byeong-Seon;Lee, Sang-Seon;Hwang, Chan-Yong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.336-336
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    • 2016
  • We have investigated magneto-transport properties in a MoS2 lateral spin-valve structures for different ferromagnetic CoFe electrode shapes and MoS2 channel lengths. For these devices, high quality and large-scale MoS2 thin films were synthesized through sulfurization of epitaxial MoO3 films and these sulfurized-MoO3 thin films properties are in good agreements with measurements on exfoliated MoS2 film. Magneto-transport measurements show a clear rectangular magnetoresistance signal of 0.16% and a spin polarization of 0.00012%. By using the one-dimensional spin diffusion equation, we extracted the spin diffusion length and coefficient, finding them to be 12 nm and $1.44{\times}10-3cm2/s$, respectively. These small values of magnetoresistance and spin polarization could be enhanced by appeasement of conductivity mismatch between the ferromagnet and semiconductor interface.

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Evaluation of Parameters in Hydrodynamic Model (동수역학모형의 매개변수 산정)

  • Yun, Tae-Hun;Lee, Jong-Uk;Jagal, Sun-Dong
    • Journal of Korea Water Resources Association
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    • v.33 no.1
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    • pp.39-50
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    • 2000
  • Generally speaking, a hydrodynamic model needs a friction coefficient (Manning coefficient or Chezy coefficient) and eddy viscosity. For numerical solution the coefficients are usually determined by recursive calculations. The eddy viscosity in numerical model plays physical diffusion in flow and also acts as numerical viscosity. Hence its value has influence on the stability of numerical solution and for these reasons a consistent evaluation procedure is needed. By using records of stage and discharge in the downstream reach of the Han river, I-D models (HEC-2 and NETWORK) and 2-D model (SMS), estimated values of Manning coefficient and an empirical equation for eddy viscosity are presented. The computed results are verified through the recorded flow elevation data.n data.

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Modeling of Pulsed Laser Heating of Tissue: Implications or Skin Resurfacing (Pulsed Laser를 이용한 생체조직 가열을 위한 모델링 : Skin Resurfacing을 위한 연관성)

  • Kwon, Y.H.;Rastegar, S.
    • Proceedings of the KOSOMBE Conference
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    • v.1997 no.11
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    • pp.375-379
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    • 1997
  • Pulsed Er:YAG and $CO_2$ lasers induced temperature rise of tissue are studied using axisymmetric, two-dimensional, and transient Pennes' bio-heat equation or the implications of skin resurfacing. Model results indicate that Er:YAG laser induced temperature has much higher but more shallow distribution in tissue than that of the $CO_2$ laser because of its higher absorption coefficient. The increase of repetition rate does not affect the temperature rise too much because these laser modalities have much shorter heat diffusion time than the temporal length of each off-pulse. This model works as a tool to understand the photothermal effect in the laser-tissue interaction.

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