• 환경위생공학
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• 제23권2호
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• pp.35-45
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• 2008

In order to recommend criteria for the administration law on indoor air quality, this study was conducted to examine the distribution and the concentration of indoor air pollutants ($PM_{10},\;CO_2$, CO, HCHO, TBC, $NO_2$, Rn, VOCs, asbestos, $O_3$) in public facilities in the Chung-Nam area. The concentrations of indoor air pollutants were obtained from sixty seven public facilities such as a cinema, an office, a restaurant, a theater and an academy. This study was performed from August to December, 2005. The results of this study showed that the concentrations of indoor air pollutants such as $PM_{10},\;CO_2$, CO, HCHO, TBC, Rn and $O_3$ were less than the recommended limits. However, the average concentration of VOCs was $521.73{\mu}g/m^3$ (GM : $221.69{\mu}g/m^3$), which was higher than the recommended limit of $400{\mu}g/m^3$. Moreover, the average concentration of $NO_2$ was 345.66ppb (GM : 69.95ppb), which was higher than the recommended limit of 50 ppb. The correlation between the concentrations of indoor air pollutants and the type of facilities with respect to $CO_2$, TBC and Rn was statistically low (p<0.05). However, the correlation was high in terms of the CO and $O_3$ concentrations (p<0.01). No relationship between the indoor air pollutants and the type of facilities was observed for $PM_{10}$, VOCs and $NO_2$. The year of construction was compared to the concentrations of indoor air pollutants. Specifically, when the construction date was less than 3 years, the HCHO, VOCs and TBC concentrations were $44.75{\mu}g/m^3,\;555.07{\mu}g/m^3$ and $337.79CFU/m^3$, respectively. These concentrations were $120{\mu}g/m^3$ and $211.84CFU/m^3$ higher for VOCs and TBC than the concentrations obtained from the facilities more than 3 years. However, the concentration of HCHO was similar between the facilities older and younger than 3 years of age. Year, temperature, humidity and indoor air pollutant correlation analyses showed that temperature and humidity, temperature and TBC, temperature and $O_3,\;PM_{10}$ and $NO_2$, HCHO and VOCs, $CO_2$ and Rn had positive relationships. However temperature and Rn, humidity and $CO_2,\;CO_2$ and $O_3,\;O_3$ and Rn had negative relationships. Accordingly, it will be necessary to manage the factors affecting indoor air quality so that the residents can have a more comfortable and healthier living environment. Ultimately, the results of this study are expected to be utilized as baseline data.

• 자원리싸이클링
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• 제11권6호
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• pp.12-17
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• 2002

$CuCl_2$-$NiCl_2$-$CoCl_2$용액으로부터 구리를 분리하기 위해 추출제로 Alamine336과 LIX84를 사용하여 추출실험을 하였다. 염산용액에서 Alamine336과 LIX84에 의한 구리, 코발트, 니켈의 분배계수와 구리의 분리계수는 금속이온과 염소이온간에 형성되는 착물의 농도에 큰 영향을 받았다. 염소이온농도가 0.5에서 4.0M사이인 용액에서 코발트로부터 구리의 분리성은 LIX84가 Alamine336보다 우수하였다. 염소이온농도가 1.0M인 용액에서 LIX84와 Alamine336의 부피백분율을 5에서 40%까지 변화시켜 추출한 결과 LIX84로 추출하는 경우 Alamine336에 비해 더 높은 구리의 분리계수를 얻었다.

• 한국수소및신에너지학회논문집
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• 제26권5호
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• pp.445-452
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• 2015

A tubular packed bed reactor for the steam-$CO_2$ combined reforming of natural gas to produce the synthesis gas of a target $H_2/CO$ ratio 2.0 was simulated. The effects of the reactor dimension, the feed gas composition, and the gas feeding temperature upon the possibility of coke formation across the catalyst bed were investigated. For this purpose, 2-dimensional heterogeneous reactor model was used to determine the local gas concentrations and temperatures over the catalyst bed. The thermodynamic potential distribution of coke formation was determined by comparing the extent of reaction with the equilibrium constant given by the reaction, $CH_4+2CO{\Leftrightarrow}3C+2H_2O$. The simulation showed that catalysts packed in the central region nearer the entrance of the reactor were more prone to coking because of the regional characteristics of lower temperature, lower concentration of $H_2O$, and higher concentration of CO. With the higher feeding temperature, the feed gas composition of the increased $H_2O$ and correspondingly decreased $CO_2$, or the decrease in the reactor diameter, the volume fraction of the catalyst bed subsequent to coking could be diminished. Throughout the simulation, reactor dimension and reaction condition for coking-free operation were suggested.

• 대한금속재료학회지
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• 제46권4호
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• pp.227-232
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• 2008

Solvent extraction reaction of cobalt by Alamine336 from strong hydrochloric acid solution was identified by analyzing the solvent extraction data reported in the literature. Analysis of the data by graphical method revealed that Alamine336 took part in the solvent extraction reaction as a monomer in the concentration ranges, [Co(II)] : 0.0169 - 0.102 M, [Alamine336] ; 0.02- 1.75 M, and [HCl ] : 5 - 10 M. The following solvent extraction reaction and equilibrium constant was obtained from the experimental data by considering the activity coefficients of chemical species present in the aqueous phase. $Co^{2+}+2Cl^{-}+R_3NHCl_{org}=CoCl_3\;R_3NH_{org}$, $K_{ex}=2.21$ The distribution coefficients of cobalt predicted in this study agreed well with those reported in the literature.

• 상하수도학회지
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• 제19권2호
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• pp.228-237
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• 2005

The main purpose of this study was to investigate the red water reducing effects of phosphate based inhibitor when it was applied to water distribution system. The effects of pH, alkalinity, calcium concentration in the reduction of the red water also studied. The most finished water in Korea showed relatively high corrosiveness and was required to introduce some types of corrosion reducing methods such as addition of alkalinity. The precipitation of $CaCO_3$ by addition of $Ca(OH)_2$ formed porous film on the surface of the carbon steel pipes and was displaced easily from the surface of the pipes; on the other hand, addition of zinc phosphate (ZOP) formed reliable film on the surface and reduced iron release and color. Although the main function of ZOP was to suppress the release of Pb and Cu, it also reduced iron concentration released from water distribution pipes.

• 자원리싸이클링
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• 제21권5호
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• pp.65-71
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• 2012

용융 PbO-$SiO_2$계 슬래그와 Bi를 $775{\sim}850^{\circ}C$의 마그네시아 도가니 중에서 평형시켜 Pb와 Bi의 평형분배에 대하여 조사하였다. 분위기 중의 산소분압은 $P_{CO2}/P_{CO}$의 비율을 조정하여 제어하였다. Pb의 분배비인 (%PbO)/[%Pb]는 슬래그 중의 $SiO_2$ 농도가 증가함에 따라 증가하였으며, Bi의 분배비인 ($%Bi_2O_3$)/[%Bi]는 슬래그 중의 $SiO_2$ 농도가 증가함에 따라 감소하였다. 그리고 반응 온도가 높을수록 금속 상중의 Pb 농도는 증가하였다. 이러한 결과는 열역학적으로 예측한 결과와 잘 일치하였다.

• Macromolecular Research
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• 제16권2호
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• pp.120-127
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• 2008

Glycidyl methacrylate linked poly(dimethylsiloxane) (GMA-PDMS) was synthesized and used as a stabilizer for the dispersion polymerization of methyl methacrylate (MMA) in supercritical $CO_2$. This study examined the effect of the concentrations of the stabilizer, 2,2'-azobisisobutyronitrile (AIBN) initiator, and MMA on the yield, molecular weight, and morphology of the poly(methyl methacrylate) (PMMA) product. PMMA was obtained in 94,6% yield using only 0,87 wt% GMA-PDMS, When the AIBN concentration was increased from 025 to 1.06 wt%, the molecular weight and particle size of the PMMA decreased from 56,600 to 21,600 and from 4.1 to $2.7{\mu}m$, whereas the particle size distribution increased from 1.3 to 1.9. The $M_n$ of the PMMA product ranged from 41,600 and 55,800 under typical polymerization conditions. The PMMA particle diameter ranged from 1.8 to $11.0{\mu}m$ and the particle size distribution ranged from 1.4 to 1.8.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2017년도 춘계 학술논문 발표대회
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• pp.165-166
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• 2017

Corrosion of reinforcement is the main factors affecting the durability of reinforced concrete in the world which lead to the failure of structures of reinforced concrete buildings. In this research, mixed brucite(Mg(OH)₂) into ordinary portland cement paste in ratio of 5, 10 and 15% as a kind of CO₂ fixation material. Samples were exposed to an accelerated carbonation enslavement of 20% CO₂ concentration, 60% relative humidity, and a temperature of 20℃ until tested at 3d, 7d, 14d and 28d. After 28d CO₂ accelerated curing, in the paste containing MH megnesian calcite was found by XRD and SEM-EDX. Meanwhile, paste containing Mg(OH)₂ exhibit the better pore distribution than ordinary portland cement paste and relatively good compressive strength.

• 한국물환경학회지
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• 제27권6호
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• pp.896-904
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• 2011

The features of the capture reaction of $CO_2$ by ammonia solution have been investigated along with the effect of temperature on the reaction based upon computer program-utilizing calculation and thermodynamic estimation. The stable region of $CO{_3}^{2-}$ was observed to increase with temperature and the change of the stable region of $CO{_3}^{2-}$ with temperature was greater than the temperature variation of the stable region of other carbonate species. The distribution diagram for $NH_4{^+}-NH_3$ system was constructed and the rise of temperature resulted in the decrease of the stability of $NH_4{^+}$ ion, which was thought to be due to the endothermic nature of its acidic dissociation. Considering the introduction of $Ca^{2+}$ ion in the carbon capture reaction by $NH_4{^+}$, the temperature was observed to be important in the determination of the order of reaction between carbonate ion and these cations. The removal process of $CO_2$ gas by ammonia solution was presumed to occur in open system and the temperature variations of the concentration of carbonate system species along with their total concentration were calculated for the proper control and design of the real process.

• 한국대기환경학회지
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• 제30권5호
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• pp.423-433
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• 2014

This study examined the short-term variability of $CO_2$ concentrations measured at the Gosan site ($33^{\circ}17^{\prime}N$, $126^{\circ}10^{\prime}E$) in Jeju, Korea for the last 9 years from 2002 to 2010. The weekly distribution shows higher $CO_2$ concentrations during weekends than weekdays which implies the impact of local emissions because Jeju Island is one of the top tourist attraction in Korea. In diurnal variation, $CO_2$ concentration reached the maximum at 6 am and the minimum at 1 pm. The high $CO_2$ concentrations were mostly associated with lower wind speed (below 4 m/s) and easterlies, which was typical of summer night. In other seasons, however, the high concentrations were encountered under strong westerlies (8~16 m/s), which implies the influence of Chinese outflows. $CO_2$ concentrations were found to be highly correlated with meteorological parameters including wind speed, temperature, humidity, and solar radiation except for winter.