• Title/Summary/Keyword: $CO_2$ concentration distribution

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Changes of Smoke Components with Stalk Position and Grade of Korean Leaf Tobacco (국내 원료잎담배의 착엽위치 및 가공등급에 따른 연기성분 변화)

  • 황건중;이문수
    • Journal of the Korean Society of Tobacco Science
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    • v.24 no.1
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    • pp.38-45
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    • 2002
  • This study was conducted to determine the smoke component concentration and the smoke distribution in the cambridge filter pad and cigarette filter with stalk position and grade of Korean leaf tobaccos. 12 grades of flue-cured and burley leaf tobaccos which were taken from the Kim-cheon and Ock-cheon leaf tobacco processing factory were used for this study. Six kinds of smoke components such as tar, nicotine, water, carbon monoxide(CO), carbon dioxide($CO_2$) puff No. collected in the cambridge filter pad and cigarette filter were analyzed. Also, nicotine/tar, CO/tar ratio were calculated from the analytical data. Puff no., CO, and $CO_2$ concentration of flue-cured and burley tobacco leaves at high stalk position were higher than those of low stalk position, and these components were increased in high grade of leaf tobacco. Compared with flue-cured tobacco, burley tobacco showed a little values of puff no., nicotine, and tar concentration. The pH range of burley tobaccos was broader than that of flue-cured tobaccos, and the ammonia concentration of burley tobaccos was significantly higher than that of flue-cured tobaccos. The pH value and ammonia concentration of burley tobaccos were decreased as stalk position of leaf tobaccos decreased. The distribution of smoke components collected in the cambridge filter pad and cigarette filter was different with a different grade and stalk position of tobacco leaves. In high stalk position of tobacco leaves, the portion of smoke components collected in the cambridge filter pad was also increased. The average nicotine, water, and tar removal efficiency by a cigarette filter in a flue-cured tobacco were 37%, 64%, and 48%, respectively. Compared with flue-cured tobaccos, smoke components of burley tobaccos had high nicotine and low water removal efficiency by a cigarette filter. The average ratio of nicotine/tar and CO/tar of flue-cured tobaccos and burley tobaccos were 0.097, 1.22, 0.094, and 0.97, in order. Nicotine/tar ratio was decreased and CO/tar ratio was increased in low stalk position.

A Study of Long-term Change in Carbon Dioxide Concentrations within and Across the Korean Peninsula between 1996 and 1997 (국내외 관측점간의 비교분석을 통한 이산화탄소의 장주기적 농도변화 특성에 관한)

  • 김기현;윤용훈;송기범
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.1
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    • pp.105-115
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    • 2001
  • This study was conducted to analyzed the pattern of $CO_2$ concentration changes in various time scale within and across the Korean Peninsula. We compared that data sets obtained from Moo-Ahn(NAN) station in Korea with those determined from major background observatory stations around the world from the periods of Aug. 1995 to Dec. 1997. The mean $CO_2$concentrations of the MAN area, if computed using the total of 884 daily mean values, were computed to by 374.5$\pm$6.6 ppm. When the background data for MAN were compared with those of other background site, the concentration of MAN was systematically higher than any other comparable sites. Results of correlation analysis between MAN and other background sites generally showed up the existence of strong correlations, indicating that the relative effect of $CO_2$ concentration change can proceed similarly over the globe. However, notable differences in annual growth rate of $CO_2$ between MAN and all the comparative sites suggested that its concentration in th MAN area be regulated in more complicated manners than those in the other areas. It is thus suspected that the data collected form MAN area be not effective enough to represent areal distribution characteristics of $CO_2$in the Korean Peninsula.

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Nitrogen Dioxide Measurement with Diffusive Passive Samplers at the Curbside Points in Daejeon (확산측정기를 이용한 대전시 도로변에서의 이산화질소 측정)

  • Yim, Bong-Been;Kim, Sun-Tae;Yang, Heung-Mo
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.2
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    • pp.143-152
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    • 2008
  • This study investigates the variation and spatial distribution of nitrogen dioxide($NO_2$) concentrations measured with passive diffusive samplers at 40 curbside points in Daejeon. Average $NO_2$ concentration was $39.8{\pm}18.0\;ppb$ (n=1,127) and the significant difference in concentrations by regional groups (Dong-gu, Jung-gu, Seo-gu, Daedeok-gu, Yuseong-gu) was not observed. The frequency distribution of $NO_2$ concentration was found to be a normal distribution with the high frequency in the concentration range of 30 to 40 ppb (20 to 25%). Average $NO_2$ concentration measured during the rainy periods was lower than that measured during the non-rainy periods and the decrease of concentration by rainfall was about 16% (7 ppb). The variation of $NO_2$ concentrations measured by passive diffusive samplers during the sampling period was similar to that continuously measured at the air quality monitoring station.

The Study on Structural Change and Improvement of Electrochemical Properties by Co-precipitation Condition of Li[Ni0.8Co0.15Al0.05]O2 Electrode (Li[Ni0.8Co0.15Al0.05]O2 전극의 공침 조건을 통한 구조적 변화와 전기적 특성의 향상 고찰)

  • Im, Jung-Bin;Son, Jong-Tae
    • Journal of the Korean Electrochemical Society
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    • v.14 no.2
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    • pp.98-103
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    • 2011
  • [ $Li[Ni_{0.8}Co_{0.15}Al_{0.05}]O_2$ ]cathode material for lithium secondary battery is obtained using co-precipitation method. To determine the optimal metal solution concentration value, the CSTR coprecipitation was carried out at various concentration values(1-2 mol/L). The surface morphology of coated samples was characterization by SEM(scanning electron microscope) and XRD (X-Ray Diffraction)analyses. Impedance analysis and cyclic voltammogram presented that internal resistance of the cell was dependent upon the concentration of metal solution. such data is very helpful in determining the optimal content of metal solution concentration to enhancing electrochemical property by adjusting powder size distribution and crystal structure.

Combustion of RDF and RPF in a Lab-Scale Circulating Fluidized Bed (실험실규모 순환유동층에서 RDF와 RPF의 연소 특성에 관한 연구)

  • Lee, J.S.;Lee, E.L.;An, M.H.;Park, S.U.;Shin, D.H.;Hwang, J.H.
    • 한국연소학회:학술대회논문집
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    • 2004.06a
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    • pp.173-179
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    • 2004
  • Combustion of refuse derived fuel(RDF) and refuse plastic fuel (RPF) was carried out in a lab-scale circulating fluidized bed. Experiment was investigated cold flow visualization. RDF was made by C & tech and RPF was made by KRS. The results include distribution of temperature in the combustion chamber, and concentrations of flue gas such as $O_2$, $CO_2$, CO, $NO_x$ and HCs Micro G.C(gas chromatograph) was employed to find out concentration of He Temperature distribution was different when RDF and RPF were burnt respectably. As air ratio became increased, $CO_2$, CO, and total of HCs emissions were decreased. According to the number of carbon atom of HCs, HC were classified as five kinds of HC.

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The CO Gas Concentration Characteristics in a Sound Proof Road Tunnel According to the Upper Opening Installation Distance Interval (방음터널 내부의 상부배출구 간격에 따른 CO 농도분포 특성)

  • Park, Myung Sig
    • Journal of ILASS-Korea
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    • v.21 no.3
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    • pp.162-169
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    • 2016
  • When we construct a road near an apartment complex, we consider a soundproof wall. To make residential places quieter, we may consider a soundproof road tunnel. Such a tunnel, however, would become highly concentrated with soot from vehicles whenever a traffic jam might occur. To create an optimum design, this study utilizes the PHOENICS-VR software. The work considers three cases: (1) no openings (2) openings at 30m intervals, and (3) openings at 60m intervals on the upper side of the tunnel. The study finds that in the second case shows CO concentration distributions were 15% less than those without openings. And the CO concentration distributions of the second and third cases are almost the same. The findings suggest that we should make the soundproof tunnel to reduce construction fees.

Toluene Removal Using Surface Discharge Induced Plasma Chemical Process (연면방전 플라즈마를 이용한 톨루엔 처리에 관한 연구)

  • 부문자;봉춘근;김신도
    • Journal of Korean Society for Atmospheric Environment
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    • v.13 no.4
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    • pp.297-305
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    • 1997
  • The experimental study by use of SPCP was fulfilled to remove toluene emitted from various industrial processes. First of all, discharge characteristic was experimented as the change of applied voltage and frequency. Then toluene removal characteristic was tested with the analysis of by-products. As a result, optimum electrical discharge condition was from 20.0 kHz to 25.0 kHz of frequency and from 3.5 kV to 4.0 kV of voltage range. The variation of applied voltage had a more important effect on the removal characteristic of toluene than the frequency variation. The toluene removal efficiency was proportioned to ozone concentration and retention time on discharge plate. It was dropped as increase of toluene concentration, but total treated volume of tolene per power consumption was high. The decomposed toluene was transformed to $CO, CO_2$ and particulates, and the rate of transformation to particulates was higher than CO and $CO_2$ at high toluene concentration. Particulates were increased from 0.017 $\mum$ to 0.3 $\mum$ range of size distribution.

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Microstructure and Magnetic properties of $Ti_{1-x}Co_xO_2$ Magnetic semiconductor thin films by Metal Organic Chemical Vapor Deposition (유기금속화학기상증착법으로 제조된 자성반도체 $Ti_{1-x}Co_xO_2$ 박막의 미세구조 및 자기적 특성)

  • Seong, Nak-Jin;Yoon, Soon-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.155-159
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    • 2003
  • Polycrystalline $Ti_{1-x}Co_xO_2$ thin films on $SiO_2$ (200 nm)/Si (100) substrates were prepared using liquid-delivery metalorganic chemical vapor deposition. Microstructures and ferromagnetic properties were investigated as a function of doped Co concentration. Ferromagnetic behaviors of polycrystalline films were observed at room temperature, and the magnetic and structural properties strongly depended on the Co distribution, which varied widely with doped Co concentration. The annealed $Ti_{1-x}Co_xO_2$ thin films with $x{\leq}0.05$ showed a homogeneous structure without any clusters, and pure ferromagnetic properties of thin films are only attributed to the $Ti_{1-x}Co_xO_2$ (TCO) phases. On the other hand, in case of thin films above x=0.05, Co clusters formed in a homogeneous $Ti_{1-x}Co_xO_2$ Phase, and the overall ferromagnetic (FM) properties depended on both $FM_{TCO}$ and $FM_{Co}$. Co clusters with about 10nm-150nm size decreased the value of Mr (the remanent magnetization) and increased the saturation magnetic field.

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Effects of alkali species and concentration on the size distribution of the co-precipitated magnetite particles used for phosphate adsorption (인 흡착용 마그네타이트 합성 시 알칼리 종류 및 농도가 공침 입자크기에 미치는 영향)

  • Lee, Minhyeong;Doliente, Jonica Ella;Nam, Haiuk;Kim, Yunjung;Choi, Younggyun
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.4
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    • pp.409-415
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    • 2016
  • Magnetite particles were synthesized by co-precipitation of water-soluble 밀 스케일-derived precursor by various concentrations of (0.5, 0.67, 1, 2 N) NaOH and (0.6, 0.8, 1.2, 2.4 N) $NH_4OH$. It is theoretically known that as the concentration of the alkaline additive used in iron oxide synthesis increases, the particle size distribution of that iron oxide decreases. This trend was observed in both kind of alkaline additive used, NaOH and $NH_4OH$. In addition, the magnetite synthesized in NaOH showed a relatively smaller particle size distribution than magnetite synthesized in $NH_4OH$. Crystalline phase of the synthesized magnetite were determined by X-ray diffraction spectroscopy(XRD). The particles were then used as an adsorbent for phosphate(P) removal. Phosphorus adsorption was found to be more efficient in NaOH-based synthesized magnetite than the $NH_4OH$-based magnetite.

Evaluation of the Concentration Distribution and the Contamination Influences for Beryllium, Cobalt, Thallium and Vanadium in Soil Around the Contaminated Sources (오염원 인근 토양 중 베릴륨(Be), 코발트(Co), 탈륨(Tl), 바나듐(V)의 농도분포 및 오염영향 평가)

  • Lee, Hong-gil;Noh, Hoe-Jung;Yoon, Jeong Ki;Lim, Jong-hwan;Lim, Ga-Hee;Kim, HyunKoo;Kim, Ji-in
    • Journal of Soil and Groundwater Environment
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    • v.23 no.4
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    • pp.48-59
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    • 2018
  • Beryllium (Be), cobalt (Co), thallium (Tl) and vanadium (V) are candidates of 21 priority soil pollutants in Korea. The distribution of their concentration in soils from three contamination sources including industrial, roadside and mining areas was investigated. Concentrations of the metals were evaluated quantitatively using pollution indices and the fractionation of metals was conducted using modified SM&T (Standards Measurements and Testing programme) sequential extraction. Concentrations of the metals for all samples from industrial and roadside soils were within the range of natural background levels, while some of Be in soils from abandoned mines exceeded that the range. Enrichment Factor (EF) and Nemerow Integrated Pollution Index (NIPI) for Be, Co, Tl and V showed that there are effects or possibilities of anthropogenic activities. Pollution Load Index (PLI) analyses indicated all investigated sites needed further monitoring. The results of sequential extractions indicated mobile fractions (F1+F2) of Be, Tl and V were below 30% except some of Co in soil, which implies their low mobility to neighboring environment media. Variable tools like sequential extraction, comparison with background/actual concentration and pollution indices, as well as aqua regia extraction should be considered when evaluating Be, Co, Tl, V in soil.