• 제목/요약/키워드: $CO_2$ 폼

검색결과 42건 처리시간 0.021초

SCR반응에서 세라믹 폼 지지제를 이용한 NOx 제거 (Removal of NOx by Selective Catalytic Reduction Using Ceramic Foam Supports)

  • 한요섭;김현중;박재구
    • 한국대기환경학회:학술대회논문집
    • /
    • 한국대기환경학회 2003년도 추계학술대회 논문집
    • /
    • pp.141-142
    • /
    • 2003
  • 최근 자동차 수요증가 및 산업용 보일러 둥 급증하는 추세이며 이로 인한 대도시 대기오염 문제는 위험수위에 도달해 있다. 이러한 산업용 보일러, 화력발전소등 고정배출원과 자동차에서 발생하는 배기가스에는 인체에 유해한 일산화탄소(CO), 질소산화물(NOx), 황산화물(SOx)등이 다량 함유되어 있다. 유독성 가스중 질소산화물(NOx) 저감방법에는 특히 선택적 촉매환원법(Selective Catalytic Reduction, SCR)이 가장 널리 적용되고 있다. SCR법은 촉매하에서 NH$_3$, CO, 탄화수소(메탄, 에탄올, 프로판 등)의 환원제를 사용하여 NOx를 $N_2$로 전환하시키는 기술이다. (중략)

  • PDF

무인항공기 및 다중분광센서를 이용한 하천부유쓰레기 탐지 기법 연구 (Detection Method of River Floating Debris Using Unmanned Aerial Vehicle and Multispectral Sensors)

  • 김흥민;윤홍주;장선웅;정용현
    • 대한원격탐사학회지
    • /
    • 제33권5_1호
    • /
    • pp.537-546
    • /
    • 2017
  • 본 연구는 무인항공기 및 다중분광센서를 이용한 부유쓰레기 탐지 알고리즘을 개발하고자 하였다. 또한 알고리즘을 적용하여 하천의 부유쓰레기 발생 범위를 산정하였다. 부유쓰레기 탐지 구간을 대상으로 무인항공기를 이용한 항공촬영을 통해 면적 계산이 가능한 정사영상을 생성하였으며, 분광조사를 수행하여 하천수, 스티로폼, 초목류 등의 분광학적 특성을 이용한 부유쓰레기 탐지 지수식을 산출하였다. 그리고 산출된 지수식을 이용한 센서의 밴드 조합을 통해 스티로폼을 비롯한 부유쓰레기를 탐지하였다. 탐지 지수식 적용 결과 정사영상 내 총 3지점에서 대량의 부유쓰레기 집적 구간이 확인되었으며, 탐지 대상 면적 중 집적구간을 포함한 3.6%에 해당하는 0.82 ha($8,200m^2$)에서 스티로폼과 초목류를 포함한 대량의 부유쓰레기가 발생한 것으로 추정되었다.

폴리우레탄 폼용 옥시에틸렌 변성 폴리실록산계 계면활성제의 합성 및 미세 셀 발포 특성 (Synthesis of Oxyethlyene Modified Silixoane Surfactants for Polyurethane Foam and the Characteristics of Fine Cell Formation)

  • 김대흠;박승우;여승병
    • 공업화학
    • /
    • 제17권3호
    • /
    • pp.260-266
    • /
    • 2006
  • 메모리 기능의 미세 셀 폴리우레탄 폼용 옥시에틸렌변성실록산 계면활성제의 합성을 위해 폴리메틸하이드로겐실록산(D = 75, D' = 15)의 수소작용기에 수소규소화반응을 이용하여 다양한 폴리알킬렌옥사이드를 치환하여 합성하였다. 폴리알킬렌 옥사이드는 에틸렌옥사이드(EO) 또는 EO와 프로필렌옥사이드(PO)의 혼합성분이 반복되는 구조에 말단기는 메틸 또는 하이드록실기를 갖는 물질들을 이용하였다. NMR과 GPC 분석을 이용하여 분자 구조와 분자량 변화를 통하여 합성반응의 진행 여부 및 생성물 수율(98%)을 파악하였다. EO 12 반복단위로 합성된 계면활성제의 첨가량을 0.6~2.0 part per hundred polyol (pphp)까지 증가시켜 메모리 기능의 우레탄 폼 발포에 적용하여 폼의 물리적 특성을 측정한 결과 셀 사이즈(최소 $0.868{\mu}m$), 공기유량(air flow, -78 KPa), 복원시간(recovery time, 8 sec) 등의 결과를 나타내었다.

폐스티로폼과 조강시멘트를 혼입한 경량기포콘크리트의 특성 (Properties of Lightweight Foamed Concrete with Waste Styrofoam and Crude Steel Cement)

  • 박채울;이상수
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2020년도 봄 학술논문 발표대회
    • /
    • pp.77-78
    • /
    • 2020
  • In Korea, more than 30,000 tons of waste Styrofoam are produced every year. Styrofoam is spent more than 500 years decomposing during the reclamation process, so it needs to be recycled. The recycling rate of waste styrofoam continues to be the third highest in the world, but it is lower than that of Germany and Japan. Therefore, measures are needed to increase the recycling rate of waste Styropol. Another problem is that cement is mainly used in existing lightweight foam concrete. However, large amounts of CO2 from cement-producing processes cause environmental pollution. Currently, Korea is increasing its greenhouse gas reduction targets to cope with energy depletion and climate change, and accelerating efforts to identify and implement reduction measures for each sector. In 2013 alone, about 600 million tons of carbon dioxide was generated in the cement industry. Therefore, this study replaces CO2 generation cement with furnace slag fine powder, uses crude steel cement for initial strength development of bubble concrete, and manufactures hardening materials to study its properties using waste styrofoam. As a result of the experiment, the hardening agent replaced by micro powder of furnace slag was less intense and more prone to absorption than cement using ordinary cement. Further experiments on the segmentation and strength replenishment of furnace slag are believed to contribute to the manufacture of environmentally friendly lightweight foam concrete.

  • PDF

CORBA 기반의 보안 플렛폼과 그 응용 (A Security Platform based on CORBA and its Application)

  • 나중찬;김영균;김경범;김명준
    • 한국정보처리학회논문지
    • /
    • 제6권11S호
    • /
    • pp.3278-3288
    • /
    • 1999
  • This paper proposes a security platform, called SCAP(Security platform for CORBA based APplication), to cope with potential threats in a distributed object system. SCAP supports CORBA security specification announced by OMG. SCAP is comprised of four functional blocks, which co-work with ORB to provide security services: Authentication Block, Association Block, Access Control Block, and Security Information Management Block. It is designed to support Common Secure Interoperability Functionality Level 2, which is useful for large-scale intra-, or inter-network based applications. Actual security services, which are dependent on supporting security technology, will be provided as external security service for replace ability. Implementation issues such as how to simulate an interceptor mechanism using a commercial ORB product without source code, and how to extend Current object required for security services are also described. At the end of the paper, the SCAP applied to the web environment is described to show its practical utilization.

  • PDF

실내공기질을 고려한 유치원 보육실의 적정 환기량 검토 (Minimum Ventilation Rate of Kindergarten in the respect of IAQ)

  • 정창헌;이윤규;김태연;이승복
    • 대한설비공학회:학술대회논문집
    • /
    • 대한설비공학회 2006년도 하계학술발표대회 논문집
    • /
    • pp.283-288
    • /
    • 2006
  • Indoor Air Quality Guideline of Kindergarten in korea didn't consider the vulnerable properties of children to indoor air pollutants. For this reason, Suggestion for the IAQ guideline of formaldehyde and minimum ventilation rate was made in this study. Suggested IAQ guidelines for formaldehyde in the respect of children's vulnerable immune system is $30{\mu}g/m^3$ and $50{\mu}g/m^3$, and for the ventilation rate 11.9 ACH, 5.8 ACH, respectively. This value is based only formaldehyde and CO2 concentrations in child-care room of Kindergarten and needed to be verified by further investigations and studies. However it is discovered that lower formaldehyde concentration can do mal-effects to children's health by literature review.

  • PDF

망상형 탄소폼의 열처리 온도가 기계적 물성에 미치는 영향 (Effects of Heat-treatment Temperature on Mechanical Properties of Reticulated Carbon Foams)

  • 한윤수;이성민;김형태
    • 한국세라믹학회지
    • /
    • 제49권3호
    • /
    • pp.236-240
    • /
    • 2012
  • The reticulated carbon foam have been used for their excellent properties in terms of thermal management which is getting important in industrial field currently. In this study, we measure the mechanical properties of the reticulated carbon foam which is heat-treated at various temperature from the prepared low-density phenol foam. Simultaneously, we observe microstructures with high resolution transmission microscope and measure the residual oxygen content of carbon foams to figure out the relationship between the apparent change of properties such as weight loss and linear shrinkage during heat treatment. In conclusion, the carbon foam heat-treated at $1400^{\circ}C$ shows the highest strength, and the mechanical behavior is believed to be strongly related to the creation of nano-size graphite crystals from the amorphous carbon during heat treatment. On the other hand, it is turned out that the weight loss occurred at the temperature under $1400^{\circ}C$ comes from the elimination of oxygen in the form of $CO_2$ or CO, but no evidence is found on weight loss mechanism at the temperature above $1400^{\circ}C$.

다공성 폼에 코팅된 $CeO_2/ZrO_2$ 를 이용한 고온 태양열 합성가스 및 수소 생산 연구 (Syngas and Hydrogen Production from $CeO_2/ZrO_2$ coated Foam Devices under Simulated Solar Radiation)

  • 장종탁;윤기준;한귀영
    • 한국태양에너지학회:학술대회논문집
    • /
    • 한국태양에너지학회 2012년도 춘계학술발표대회 논문집
    • /
    • pp.260-266
    • /
    • 2012
  • Syngas and hydrogen from the $CeO_2/ZrO_2$ coated foam devices were investigated under simulated solar radiation. The $CeO_2/ZrO_2$ coated SiC, Ni and Cu foam device were prepared using drop-coating method. Syngas production step was performed at $900^{\circ}C$, and hydrogen production process was performed for ten repeated cycles to compare the CeO2 conversion in syngas production step, $H_2$ yield in hydrogen production step and cycle reproducibility. The produced syngas had the $H_2$/CO ratio of 2, which was suitable for methanol synthesis or Fischer-Tropsch synthesis process. In addition, syngas and hydrogen production process is one of the promising chemical pathway for storage and transportation of solar heat by converting solar energy to chemical energy. After ten cycles of redox reaction, the $CeO_2/ZrO_2$ was analyzed using XRD pattern and SEM image in order to characterize the physical and chemical change of metal oxide at the high temperature.

  • PDF

Octamethylcyclotetrasiloxane를 이용한 광섬유 클래드 프리폼 형성 (Formation of Optical Fiber Preform Using Octamethylcyclotetrasiloxane)

  • 최진석;이태균;박성규;이가형;전구식;안성진
    • 한국재료학회지
    • /
    • 제28권1호
    • /
    • pp.6-11
    • /
    • 2018
  • There are various manufacturing processes for pure $SiO_2$ that is used as abrasives, chemicals, filters, and glasses, and in metallurgy and optical industries. In the optical fiber industry, to produce $SiO_2$ preform, $SiCl_4$ is utilized as a raw material. However, the combustion reaction of $SiCl_4$ has caused critical environmental issues, such as ozone deficiency by chlorine compounds, the greenhouse effect by carbon dioxide and corrosive gas such as hydrochloric acid. Thus, finding an alternative source that does not have those environmental issues is important for the future. Octamethylcyclotetrasiloxane (OMCTS or D4) as a chlorine free source is recently promising candidate for the $SiO_2$ preform formation. In this study, we first conducted a vaporizer design to vaporize the OMCTS. The vaporizer for the OMCTS vaporization was produced on the basis of the results of the vaporizer design. The size of the primary particle of the $SiO_2$ formed by OMCTS was less than 100 nm. X-ray diffraction patterns of the $SiO_2$ indicated an amorphous phase. Fourier-transform infrared spectroscopy analysis revealed the Si-O-Si bond without the -OH group.

Fe-doped β-Ni(OH)2의 산소발생반응 증가를 위한 Mo의 동시도핑효과 (Effects of Mo co-doping into Fe doped β-Ni(OH)2 microcrystals for oxygen evolution reactions)

  • 박제홍;유시범;안태광;김병준;유정호
    • 한국결정성장학회지
    • /
    • 제34권1호
    • /
    • pp.30-35
    • /
    • 2024
  • 수소에너지 생산을 위한 물분해 시스템의 효율을 향상시키기 위해서는, 수소발생반응(HER)과 산소발생반응(OER) 각각에서 촉매로 인한 전기화학적 반응에서의 높은 과전압의 감소가 수반되어야 한다. 그 중에서도 전이금속 기반의 화합물들은 현재 상용되고 있는 백금 등의 귀금속을 대체할 촉매 재료로써 주목받고 있다. 본 연구에서는, 저렴한 금속 다공성 소재인 니켈폼(Ni foam)을 지지체로 사용하고, 수열합성 공정을 통해 Fe-doped β-Ni(OH)2 마이크로결정을 합성하였다. 또한 OER 특성을 향상시키기 위하여 Mo을 동시도핑하여 합성된 Fe-Mo co-doped β-Ni(OH)2 마이크로결정의 형상, 결정구조 및 수전해 특성의 변화를 관찰하였으며, 상용 수전해 시스템의 촉매로서의 적용가능성을 검토하였다.