• Title/Summary/Keyword: $CO_2$ 양생

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Properties of Cement Paste Containing High Volume γ-C2S and MgO Subjected to CO2 Curing (γ-C2S 및 MgO를 다량 혼입한 시멘트 페이스트의 CO2 양생유무에 따른 특성변화)

  • Sung, Myung-Jin;Cho, Hyeong-Kyu;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.3
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    • pp.281-289
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    • 2015
  • Carbonation of concrete causes reduction of pH and subsequently causes steel corrosion for reinforced concrete structure. However, for plain concrete structure or PC product, it can lead to a decrease in porosity, high density, improvement of concrete, shrinkage-compensation. Recently, based on this theory, research of $CO_2$ curing effect has been performed, but it was mainly focused on its effects on compressive strength using only ordinary portland cement. Researches on $CO_2$ curing effect for concrete containing $CO_2$ reactive materials such as ${\gamma}-C_2S$, MgO haven't been investigated. Therefore, this study has performed experiments under water-binder ratio 40%, and the replacement ratios of ${\gamma}-C_2S$ and MgO were 90%. Micro-chemical analysis, measurement of compressive strength according to admixtures and $CO_2$ curing were investigated. Results from this study revealed that higher strength was measured in case of $CO_2$ curing compared with none $CO_2$ curing for plain specimen indicating difference between 1.08 and 1.26 times, in case of ${\gamma}-C_2S$ 90, MgO 90 specimen, incorporating high volume replaced as much as 90%, it was proven that when applying $CO_2$ curing, higher strength which has difference between 14.56 and 45.7 times, and between 6.5 and 10.37 times was measured for each specimen compared to none $CO_2$ curing. Through micro-chemical analysis, massive amount of $CaCO_3$, $MgCO_3$ and decrease of porosity were appeared.

Carbonation Evaluation After CO2 Curing of Concrete Bricks Using Industrial by-products (산업부산물을 사용한 콘크리트 벽돌의 CO2 양생 후 탄산화 평가 )

  • Hoon Moon;Namkon Lee;Jung-Jun Park;Gum-Sung Ryu;Gi-Joon Park;Indong Jang
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.4
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    • pp.373-380
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    • 2023
  • This study investigated the carbonation of concrete brick cured in a CO2 environment for the utilization of CO2 captured in power plants. Concrete brick specimens were produced with electric arc furnace reducing slag (ERS) and electric arc furnace oxidizing slag (EOS), and cured for 3 days in a CO2 chamber with a concentration of 20 % or in a constant temperature and humidity chamber. The weight change, compressive strength, flexural strength and carbonation depth of concrete bricks were measured. From the results, it was found that when subjected to CO2 curing, CO2 was absorbed at the level of 2.4 % of the weight of the specimen. The specimen incorporating ERS showed the highest carbonation depth, and satisfied KS F4004 standards for the concrete brick. Therefore, it is expected that the captured CO2 can be utilized in the CO2 curing process of concrete brick.

Fundamental Characteristics of CO2-cured Mortar with Varied Rates of Blast Furnace Slag Fine Powder Substitution (고로슬래그 미분말 치환율에 따른 이산화탄소 양생 모르타르의 기초 물성)

  • Ryu, Ji-Su;Jang, Kyung-Su;Na, Hyeong-Won;Hyung, Won-Gil
    • Journal of the Korea Institute of Building Construction
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    • v.24 no.1
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    • pp.11-21
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    • 2024
  • This research elucidates the fundamental properties of carbon dioxide (CO2)-cured mortar as influenced by varying substitution rates of blast furnace slag fine powder. The findings indicate that CO2 curing enhances the formation of calcium carbonate (CaCO3), contributing to pore reduction and the early development of strength. While calcium hydroxide (Ca(OH)2) plays a more pivotal role in the primary development of strength compared to CaCO3, an increase in the substitution rate of blast furnace slag fine powder results in reduced production of Ca(OH)2. Nonetheless, the maintenance of strength through CaCO3 formation is observed even after the depletion of Ca(OH)2, suggesting that the required performance can be sustained post-exposure to the atmosphere following CO2 curing. It is noted that substitution rates exceeding 50% lead to performance deterioration due to CO2, highlighting the necessity for careful adjustment of the substitution ratio.

Mechanical Properties According to Curing Conditions of Mortar Using CO2 Hardening Cement (CO2 반응경화 시멘트 활용 모르타르의 양생조건에 따른 역학적 특성)

  • Ji-Seok Seo;Sun-Gyu Tae;Jun Lee;Bong-Chun Lee
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.4
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    • pp.307-315
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    • 2023
  • In this study, mortar test specimens were produced by varying the mixing ratio of CO2 reaction hardening cement (CSC) and general cement (OPC), and the mechanical and carbonation characteristics were evaluated by controlling the primary curing temperature and secondary curing CO2 pressure. Under all curing conditions, it was observed that the higher the CSC ratio in the binder, the lower the mechanical properties. Specifically, a first curing temperature of 60 ℃ yielded higher mechanical properties compared to the case of 20 ℃, and a greater carbonation penetration depth was also observed. At a first curing temperature of 60 ℃, it was noted that the curing pressure and bending strength during the second CO2 curing were inversely proportional, while the compressive strength showed a proportional relationship. This phenomenon is believed to be due to excessive carbonation, which reduces mechanical properties, and the fact that flexural strength is more sensitive to these properties compared to compressive strength. However, based on the evaluation of the limited curing conditions, it is evident that future test conditions need to be expanded and reviewed more thoroughly.

Strength Properties of Mortar According to Types of Binders for Reducing Curing Process of Concrete Secondary Products for Reduction CO2 (CO2 절감을 위한 콘크리트 2차제품 양생단계저감용 결합재 종류에 따른 모르타르 강도특성)

  • Kim, Ha-Seog;Baek, Dae-Hyun;Lee, Sea-Hyun
    • Resources Recycling
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    • v.23 no.4
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    • pp.37-46
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    • 2014
  • Carbon dioxide generated from construction materials and construction material industry among the fields of construction is approximately 67 million tons. It is about 30% of the carbon dioxide generated in the fields of construction. In order to reduce carbon dioxide in the fields of construction, it is necessary to control the use of fossil fuel consumed and decrease carbon emission by reducing the secondary and tertiary curing generating carbon dioxide in construction material industry. Therefore, this study manufactured mortar by having cement as the Plain and substituting three binding materials up to 50% and then adopted different curing methods to analyze congelation and strength characteristics. Test results for strength property by changing binding materials showed that specimens with blast furnace slag, CSA 15% and CAMC 5% resulted in positive effect for strength.

An Experimental Study on Carbonation Induction in Paste with CO2 Reactive Cement (CO2 반응경화 시멘트를 혼입한 페이스트의 탄산화 양생에 관한 실험적 연구)

  • Kim, Young-Jin;Ryu, Dong-Woo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.79-80
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    • 2023
  • After the Second Industrial Revolution, as global warming caused by environmental issues has intensified, the CO2 emissions from the cement industry have become an urgent challenge. Therefore, this study aimed to reduce and utilize CO2 emissions by using CO2-reducing Calcium Silicate Cement.

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A Study on the Cementitious Materials as Carbon Capture Materials-Micro-Structure Change by Carbonation Curing (시멘트계 재료의 탄소포집 건설재료로 활용연구 - 탄산화 양생에 의한 미세구조 변화)

  • Moon, Eun-Jin;Kim, Sang Jun;Park, Hong Gi;Choi, Young Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.6
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    • pp.123-129
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    • 2018
  • Recently, there has been a growing interest in the study of treatment of $CO_2$ generated by industrial activities and resource recycling of industrial byproducts. The aim of this study is to investigate the applicability of industrial byproducts that can be used as concrete mixed materials by carbonation curing. For this purpose, the physical and chemical changes of the pastes with research cement(RC), blast furnace slag powder (GGBFS) and circulating fluidized bed combustion ashes (CFBC) were evaluated by carbonation curing. XRD and SEM analyzes were performed to investigate micro-structural changes. As a result, it was confirmed that calcium carbonate, which is a reaction product produced by carbonation curing, filled the space inside the paste and formed a dense micro-structure. Also, as the $CO_2$ curing time increased, it was confirmed that calcium carbonate crystals were grown together to form a dense micro-structure.

A Fundamental Study on Supercritical CO2 Curing of Resource-Recycling Concrete Containing Concrete Sludge Waste as Main Materials (레미콘 슬러지 고형분을 주재료로 한 자원순환형 콘크리트의 초임계 CO2 양생에 관한 기초적 연구)

  • Sim, Sang-Rak;Lee, Young-Do;Ryu, Dong-Woo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.27-28
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    • 2022
  • In this study, the mechanical properties of resource-recycling concrete containing concrete sludge waste as main materials was compared depending on whether supercritical CO2 curing was applied for the realization of CCU technology. After supercritical CO2 curing, the compressive strength of the steam-cured specimen was lowered, but it was confirmed that the compressive strength of the underwater-cured specimen was improved.

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Optimum Mix of Extrusion panel Using Low Energy Curing Admixture (LA) based on Ground Granulated Blast-Furnace Slag and Ladle Furnace Slag (고로슬래그와 환원슬래그를 기반으로 한 저에너지양생용 결합재를 사용한 압출성형패널의 최적배합)

  • Kim, Ha-Seog;Baek, Dae-Hyun;Lee, Sea-Hyun
    • Resources Recycling
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    • v.24 no.2
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    • pp.13-22
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    • 2015
  • $CO_2$ emitted from building materials and construction materials industry reaches about 67 million tons, which occupy about 30 % of $CO_2$ emitted from the construction field. Controls on the use of consumed fossil fuels and reduction of emission gases are essential for the reduction of $CO_2$ in the construction area as we reduce the second and third curing to emit $CO_2$ in the construction materials industry. Accordingly, this study applied the low energy curing admixture (hereinafter "LA") to the extruded panels to observe the physical properties, depending on the mixing amount of fiber, type of fiber and mixing ratio of fiber. The type of fiber did not appear to be a main factor to affect strength, while the LA mixing ratio and mixing amount of fiber appeared to be major factors to affect strength. Especially, the highest strength was developed when the LA mixing ratio was 40%, whereas the test object with the mixing ratio of 50% resulted in the decrease of strength. In addition, it appeared that the mixing ratio of fiber greatly affected flexural strength and strength increased as the mixing ratio increased.

A study on the compressive strength development of mortar containing MgO by CO2 curing (CO2 양생에 의한 MgO 혼입 모르타르의 압축강도 발현에 관한 연구)

  • Sung, Myung-jin;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.11a
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    • pp.23-24
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    • 2014
  • Currently, cement and concrete industries have been contributing to the CO2 emission worldwide. Because of that, the efforts to minimize CO2 have been the subject of many researches. This study focus on the use of GGBFS and fly ash in mortar specimens as a patial replacement of cement. Because of the limitation of the initial compressive strength, the newly efforts to enhance the strength through CO2 Curing was adapted. To accelerate the reaction with CO2, MgO was replaced by percentage from 0 to 100%. Results showed that compressive strength values at 7 days with CO2 curing done on specimens was higher than that with no CO2 curing. Similar trend was observed at 14 days too. It is therefore appeared that CO2 curing has an obvious effect on compressive strength development of mortar specimens.

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