• Title/Summary/Keyword: $CO_2$ 고정

Search Result 738, Processing Time 0.025 seconds

Removal CO2 Using Na2CO3, K2CO3 and Li2CO3 Impregnated Activated Carbon -Characteristics of CO2 Adsorption in Fixed Bed Reactor- (Na2CO3, K2CO3 및 Li2CO3 첨착활성탄을 이용한CO2 제거 -고정층 반응기에서의 CO2 흡착특성-)

  • Choi, Won-Joon;Jung, Jong-Hyeon
    • Journal of Environmental Health Sciences
    • /
    • v.34 no.3
    • /
    • pp.240-246
    • /
    • 2008
  • The purpose of this study was to gain basic information on the characteristics of $CO_2$ adsorption in relation to $Na_2CO_3$, $K_2CO_3$, $Li_2CO_3$-impregnated activated carbon in a Fixed Bed Reactor. From the results of this study the following conclusions were made: $Na_2CO_3$, $K_2CO_3$, $Li_2CO_3$-impregnated activated carbon had a longer breakthrough time and more enhanced adsorption capacity than activated carbon alone. When tested with isothermal adsorption and tested for $CO_2$ adsorption the amount of $CO_2$ adsorbed varied with temperature, $CO_2$ inlet concentration, gas flow rate, aspect ratio, etc. Based on the results, when Langmuir, Freundlich and Dubinin-Polanyi adsorption isotherms were used for linear regression of isothermal adsorption data, Langmuir adsorption isotherm was the most suitable. And, the optimum condition for $Na_2CO_3$ and $K_2CO_3$ impregnated activated carbon make-up was 1N and $Li_2CO_3$ was 0.1N. It could be concluded that adsorption capacity was decreased with adsorption temperature and increased gas concentration. When the aspect ratio (L/D) was varied 0.5, 1.0 and 2.0, the significant drop of adsorption amount was observed below 1.0 and breakthrough time was shortened with gas flow rate.

Development of High Temperature $CO_2$ Separation and Utilization Technology by Ceramic Membranes -Recent Research Trends in Japan- (세라믹막을 이용한 이산화탄소 고온분리 및 회수 재이용 기술 개발 -일본의 연구 개발 현황-)

  • 정상진;이용택
    • Membrane Journal
    • /
    • v.8 no.2
    • /
    • pp.59-68
    • /
    • 1998
  • 고정발생원으로 부터 배출되고 있는 이산화탄소를 분리하여 회수 및 재이용하는 기술개발이 에너지 보전 측면에서 뿐만 아니라 환경오염 문제 등을 해결할 수 있는 중요한 과제이다. 특히 내열성, 내식성 및 기계적 강도가 뛰어난 세라믹의 특성을 이용한 기체분리막을 응용한다면 고온으로부터 저온까지의 폭넓은 온도, 압력, 가스조성의 배기가스로부터 이산화탄소를 분리하는 것이 가능해 진다. 따라서 본 총설에서는 현재 일본에서 국책과제로 진행되고 있는 이산화탄소의 고온분리에 대한 연구개발(이하, '$CO_2$ 프로젝트'로 약칭) 현황을 소개하고자 한다.

  • PDF

The Extraction of Ca in Electric arc Furnace Slag for CO2 Sequestration (CO2고정화(固定化)를 위한 전기로제강(電氣爐製鋼)슬래그의 칼슘성분(成分) 침출(浸出))

  • Youn, Ki-Byoung
    • Resources Recycling
    • /
    • v.22 no.1
    • /
    • pp.64-71
    • /
    • 2013
  • Mineral carbonation has been proposed as a possible way for $CO_2$ sequestration. The electric arc furnace slags consist of calcium, magnesium and aluminum silicates in various combinations. If they could be used instead of natural mineral silicates for carbonation, considerable energy savings and $CO_2$ emissions reductions could be achieved. Indirect aqueous carbonation of the slags consists of two steps, extraction of calcium and carbonation. Acetic acid leaching of electric arc furnace slags had been already studied to extract Ca in them, but it was reported that the carbonation of the extracted $Ca^{2+}$ in the leached solution would suffer from too slow kinetics, even at high pressure of $CO_2$. In this work, to develop more efficient extraction of the electric arc furnace slags, hydrochloric acid leaching to separate calcium from them was studied, and the results were compared with the acetic acid ones. The phase boundary between $Ca^{2+}$ and $CaCO_3$ in the solution with pH was determined by thermodynamic calculations. Hydrochloric acid was more effective than acetic acid for the extraction of Ca in electric arc furnace slag, and there is a possibility to recycle an unreacted hydrochloric acid in the leached solution by electrolysis or evaporation.

Mineral Carbonation of High Carbon Dioxide Composition Gases Using Wollastonite-distilled Water Suspension (규회석-증류수 현탁액을 이용한 고농도 CO2 가스의 탄산염 광물화)

  • Song, Haejung;Han, Sang-Jun;Wee, Jung-Ho
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.36 no.5
    • /
    • pp.342-351
    • /
    • 2014
  • The present paper investigates the performance of direct wet mineral carbonation technology to fix carbon dioxide ($CO_2$) from relatively high $CO_2$ concentration feeding gas using wollastonite ($CaSiO_3$)-water (and 0.46 M acetic acid) suspension solution. To minimize the energy consumed on the process, the carbonation in this work is carried out at atmospheric pressure and slightly higher room temperature. As a result, carbon fixation is confirmed on the surface of $CaSiO_3$ after carbonation with wollastonite-water suspension solution and its amount is increased according to the $CO_2$ composition in the feeding gas. The leaching and carbonation ratio of wollastonite-water suspension system obtained from the carbonation with 50% of $CO_2$ composition feeding gas is 13.2% and 10.4%, respectively. On the other hand, the performance of wollastonite-acetic acid in the same condition is 63% for leaching and 1.39% for carbonation.

The impact of urbanization on per capita CO2 emissions (도시화가 1인당 탄소 배출에 미치는 영향)

  • Hwang, Minsup;Lee, Eungkyoon
    • Journal of Environmental Impact Assessment
    • /
    • v.25 no.5
    • /
    • pp.307-318
    • /
    • 2016
  • This research examines the impacts of urban population growth on per capita $CO_2$ emissions with particular focus on the interaction effect between urbanization and income levels. Employing the Panel Fixed Effects model together with the Pooled LS and Panel GLS models, the research reported here analyzes the relevant data on 84 countries. The statistical results show a nonlinear(an inverted-U) relationship between urbanization and per capita $CO_2$ emissions; that is, while the urban agglomeration leads to increases in per capita $CO_2$ emissions for low income countries, this adverse impact does not hold true for high income countries. The research findings can contribute to addressing broad issues of urban compactness and patterns of energy consumption that should be considered by those concerned about the sustainable urban development.

Continuous Production of Transglucosylated Steviosides Using Immobilized Cyclodextrin Glucanotransferase (고정화 Cyclodextrin Glucanotransferase에 의한 당전이 스테비오사이드의 연속생산)

  • In, Man-Jin;Chae, Hee-Jeong;Kim, Min-Hong
    • Korean Journal of Food Science and Technology
    • /
    • v.29 no.5
    • /
    • pp.969-973
    • /
    • 1997
  • In order to produce transglucosylated steviosides continuously, some types of bioreactors were investigated with cyclodextrin glucanotransferase immobilized on a high porous anion exchange resin, Diaion HPA75. Among the bioreactors, the packed-bed reactor (PBR) showed the highest specific productivity. The effect of linear velocity in a PBR on the stevioside conversion was not significant in the range of $10{\sim}60\;cm/hr$ at the same space velocity of $1.2\;hr^(-1)$. When the space velocity of bioreactor was varied from 0.2 to $1.1\;hr^{-1}$, the optimal velocity of substrate solution was determined as $0.7\;hr^(-1)$. The stevioside conversion of more than 70% was maintained during 20 days in the continuous operation, if about 20% of immobilized enzyme was replaced in the top of reactor after two weeks operation as the one of the control methods in bioreactor. The specific production, which refers to as the amount of commercially valuable transglucosylated steviosides produced by a unit amount of immobilized cyclodextrin glucanotransferase, was found to be ca. 150g product/g immobilized enzyme.

  • PDF

양측 성대 마비 환자에서 레이저를 이용한 내측 피열연골 절제술

  • 김영모;조정일;김영진;정동학
    • Proceedings of the KSLP Conference
    • /
    • 1997.11a
    • /
    • pp.258-258
    • /
    • 1997
  • 전체 성대 마비 환자의 약 10%에서 발생하는 것으로 알려진 양측 성대 마비는 안정 혹은 경미한 운동시에도 호흡 장애를 초래하는 경우라면 이에 대한 치료가 요구되는 질환이다. 이에 대한 치료 방법으로는 성문 기도를 넓히면서 흡인이 되지 않고 음성장애를 일으키지 않는데 목적을 두고 피열연골 고정술, 피열연골 절제술, CO2, 레저 피열연골 절제술, 성대 측방 고정술, 후성대 절제술, 점막하 성대 절제술, 근-신경식술 등 다양한 방법이 사용되어져 왔다. (중략)

  • PDF

Effects of Se flux on CIGS thin film solar cell (Se 증기압이 CIGS 박막 태양전지에 미치는 영향에 관한 연구)

  • Kim, Daesung;Kim, Chaewoong;Kim, Taesung
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2010.06a
    • /
    • pp.71.2-71.2
    • /
    • 2010
  • CIS(CuInSe2)계 화합물 태양전지는 높은 광흡수계수와 열적 안정성으로 고효율의 태양전지 제조가 가능하여 화합물 태양전지용 광흡수층으로서 매우 이상적이다. 또한 In 일부를 Ga으로 치환하여 밴드갭을 조절할 수 있는 장점이 있다. 미국 NREL에서는 Co-evaporation 방법을 이용해 20%의 에너지 변환 효율을 달성하였다고 보고된바가 있다. 본 연구에서는 미국의 NREL과 같은 3 stage 방식을 이용하여 광흡수층을 제조하고자 한다. 본 실험에서는 Se 증기압을 각각 $200^{\circ}C$, $230^{\circ}C$, $240^{\circ}C$, $245^{\circ}C$로 달리 하며 실험을 실시하였다. 이때 1st stage의 시간은 15분으로 고정하였으며 기판온도는 약 $250^{\circ}C$로 고정 하였다. 2nd stage는 실시간 온도 감지 장치를 이용하여 Cu와 In+Ga의 조성비가 1:1이 되는 시간을 기준으로 Cu의 조성을 30%더 높게 조절하였으며 기판 온도는 약 $520^{\circ}C$로 고정 후 실험을 실시하였다. 3rd stage의 경우 Cu poor 조성으로 조절하기 위해 모든 조건을 10분으로 고정 후 실험을 실시하였다. 각각의 Se 증기압에 따른 물리적, 전기적 특성을 알아보기 위해 FE-SEM, EDS, XRD 분석을 실시하였다. 본 연구에서 기판은 Na이 첨가되어있는 soda-lime glass를 사용 하였으며 후면 전극으로 약60nm 두께의 Mo를 DC Sputtering 방법을 이용해 증착 하였다.

  • PDF

Design and Function Analysis of Dust Measurement Platform based on IoT protocol (사물인터넷 프로토콜 기반의 미세먼지 측정 플랫폼 설계와 기능해석)

  • Cho, Youngchan;Kim, Jeongho
    • Journal of Platform Technology
    • /
    • v.9 no.4
    • /
    • pp.79-89
    • /
    • 2021
  • In this paper, the fine dust (PM10) and ultrafine dust (PM2.5) measurement platforms are designed to be mobile and fixed using oneM2M, the international standard for IoT. The fine dust measurement platform is composed and designed with a fine dust measurement device, agent, oneM2M platform, oneM2M IPE, and monitoring system. The main difference between mobile and fixed is that the mobile uses the MQTT protocol for interconnection between devices and services without blind spots based on LTE connection, and the fixed uses the LoRaWAN protocol with low power and wide communication range. Not only fine dust, but also temperature, humidity, atmospheric pressure, volatile organic compounds (VOC), carbon monoxide (CO), sulfur dioxide (SO2), nitrogen dioxide (NO2), and noise data related to daily life were collected. The collected sensor values were managed using the common API provided by oneM2M through the agent and oneM2M IPE, and it was designed into four resource types: AE and container. Six functions of operability, flexibility, convenience, safety, reusability, and scalability were analyzed through the fine dust measurement platform design.

Optimization of γ-Aminobutyric Acid (GABA) Production Using Immobilized Lactobacillus plantarum K154 in Submerged Culture of Ceriporia lacerata (Ceriporia lacerata 배양액과 고정화 Lactobacillus plantarum K154를 이용한 감마아미노뷰티르산 생산 최적화)

  • Lee, Eun-Ji;Lee, Sam-Pin
    • Korean Journal of Food Science and Technology
    • /
    • v.47 no.4
    • /
    • pp.438-445
    • /
    • 2015
  • The production of GABA was optimized by co-cultivation of immobilized Lactobacillus plantarum K154 (ILK) with Ceriporia lacerata cultures. The mycelial culture of C. lacerata was performed in a defined medium containing 3% glucose, 3% soybean flour, and 0.15% $MgSO_4$ in a submerged condition for 7 days at $25^{\circ}C$, resulting in the production of 29.7 g/L mycelia, 3.1 g/L exopolysaccharides, 2% (w/w) ${\beta}$-glucan, 68.96 unit/mL protease, and 10.37 unit/mL ${\alpha}$-amylase. ILK in C. lacerata culture showed viable cell counts of $3.13{\time}10^9CFU/mL$ for immobilized cells and $1.48{\time}10^8CFU/mL$ for free cells after 1 day. GABA production in the free and immobilized cells was 9.96 mg/mL and 6.30 mg/mL, respectively, after 7 days. A recycling test of ILK in the co-fermentation was consequently performed five times at $30^{\circ}C$ for 15 days, resulting in the highest production of GABA. GABA could also be efficiently overproduced by co-cultivation with the produced polysaccharides, ${\beta}$-glucan, peptides, and probiotics.