• Journal of environmental and Sanitary engineering
• /
• v.12 no.2
• /
• pp.29-35
• /
• 1997

Phenol, often discharged from petroleum and fine chemical industries is potential carcinogen and was classified into priority pollutant by EPA in USA. It causes serious environmental and health problem if discharged to the environment such as soil or aquifer. The removal efficiency of phenol and COD using Fenton treatment(Hydrogen Peroxide and Ferrous Sulfate) was observed and biodegradability (BOD$_{5}$/COD$_{cr}$) of reaction products were also examined. When 50 mg/l of phenol was treated by Fenton's Reagent(50 mg/l of hydrogen peroxide and 900 mg/l of ferrous sulfate), the removal efficiency of phenol and COD was 100% and 80% respectively in 10 minutes, which suggested this method can be used as actual phenol removal process. The initial biodegradability of 500 mg/l phenol solution was 0.7 but decreased as hydrogen peroxide was increased.

• Journal of Korea Technical Association of The Pulp and Paper Industry
• /
• v.40 no.5
• /
• pp.53-59
• /
• 2008

This study was carried out to investigate the effect of photocatalysis using $TiO_2$ and UV applied for the COD reduction of wastewater in linerboard mill. Trials were done to obtain the optimum addition amounts of $TiO_2$ and $H_2O_2$ to the wastewater and find an appropriate pH condition for photocatalysis on $TiO_2$ for degrading COD. The photocatalytic reaction was applied to the wastewater collected after secondary activated sludge treatment in WWTP of linerboard mill. The optimum application of photocatalysis reaction was obtained under the addition conditions of 2 g/L of $TiO_2$ and 200 mg/L of $H_2O_2$ at pH 3.0, respectively. The removal efficiency of $SCOD_{Cr}$ by photocatalytic treatment was 86.4 % and higher than Fenton treatment in which removal efficiency was 67.4 %. It was concluded that the photocatalytic process using $TiO_2$ and UV could be applied to the wastewater treatment in linerboard mill and also to the dramatic drop-off in NBDCOD load from wastewater of tertiary treatment in WWTP.

• Journal of Korean Society of Water and Wastewater
• /
• v.21 no.4
• /
• pp.375-383
• /
• 2007

Treatment efficiency research was performed using Fenton process and the electrochemical process in the presence of ferrous ion and hydrogen peroxide for the industrial wastewater including 1,4-Dioxane produced during polymerization of polyester. The Fenton process and the electrochemical Iron Redox Reaction (IRR) process were applied for this research to use hydroxyl radical as the powerful oxidant which is continuously produced during the redox reaction with iron ion and hydrogen peroxide. The results of $COD_{Cr}$ and the concentration of 1,4-Dioxane were compared with time interval during the both processes. The rapid removal efficiency was obtained for Fenton process whereas the slow removal efficiency was occurred for the electrochemical IRR process. The removal efficiency of $COD_{Cr}$ for 310 minutes was 84% in the electrochemical IRR process with 1,000 mg/L of iron ion concentration, whereas it was 91% with 2,000 mg/L of iron ion concentration. The lap time to remove all of 1,4-Dioxane, 330 mg/L in the wastewater took 150 minutes with 1,000 mg/L of iron ion concentration, however it took 120 minutes with 2,000 mg/L of iron ion concentration in the electrochemical IRR process.

• Membrane Journal
• /
• v.10 no.4
• /
• pp.213-219
• /
• 2000

In order to resolve the problem of aged land[jlJ leachate treatment, limitation in removal of non-biodegradable materials and denitrification caused by carbon source shortage, we applied combined process consisted of 5MBR and RO to leachate treatment. We perfonned 5MBR pilot plant tests on Yongin City for a period of about lOOdays, demonstrated the performance of the SlVlUR process (($NH_3$-N removal efficiency; 90%). But there was also limitation to removal of non-biodegradable materials and denitrification. In full-scale plant we observed the IXrformance of combined process (SMI3R + R/O) in order to confirm the expected treatment efficiencies. Their results were approximately 98%, 94% of treatment efficiency in case of $COD_{Cr}$(<3 mg/L) and TN(<50 mg/L)respectively and the results of treatment were stable.

• Journal of Environmental Impact Assessment
• /
• v.15 no.5
• /
• pp.299-308
• /
• 2006

To utilize a closed municipal solid waste landfill site in environmentally secure conditions, it is necessary to verify the stabilization level of landfill leachate. To assess leachate stabilization of an open-dumping municipal solid waste landfill site (Salmi Landfill) which is located at the vicinity of Chungju Reservoir which flows into Paldang Reservoir utilized as Seoul Metropolitan water supplies, the landfill history and surrounding characteristics of the landfill site were surveyed. In this investigation, waste, leachate, groundwater and surfacewater samples from this landfill were physically and chemically analyzed, and the analysis results were evaluated by 'The Criteria of Landfill Waste Stabilization (CLWS)', 'Discharge Criteria of Landfill Leachate', 'The Criteria of Domestic Use in Groundwater Quality', and 'The Criteria of Domestic Use in Surfacewater Quality' that promulgated by Korean Ministry of Environment. From the analysis results on the Salmi open-dumping landfill, C/N ratio was 18.9 and $BOD/COD_{Cr}$ ratios in leachate were higher than 1/10. Based on the CLWS, this results seemed to imply that the process of leachate stabilization at this landfill was still proceeding.

• Journal of Korean Society on Water Environment
• /
• v.26 no.4
• /
• pp.580-584
• /
• 2010

As water becomes more scarce around the world the reuse of treated wastewater is being recenlty considered as indispensible trend we need to follow. Especially, industrial area consuming large amount of water has been encouraged to reuse the treated wastewater to secure sufficient water for the production of merchandise. In this study, a study of advanced oxidation process for treatment of industrial wastewater. The treatment performance of UV and ozoznation and five types advanced oxidation processes such as UV/AC, UV/Catalyst, $O_3$/Catalyst, UV/$O_3$/Catalyst was experimentally investigated for reuse of industrial wastewater. The removal efficiency of $COD_{Cr}$, color were relatively evaluated in each treatment unit simulated outflow water of wastewater treatment area. UV/$O_3$/Catalyst process showed the highest $COD_{Cr}$ remaval and color remaval among proposed oxidation process.

• Journal of Environmental Science International
• /
• v.6 no.5
• /
• pp.521-529
• /
• 1997

In the study, we Investigated the behavior and removal efficiency of organics, nitrogen. phosphorus with operating conditions in SBRs. Substrate used was synthetic wastewater in which the ratio of $COD_{cr}$. : N : P was 100 : 12 : 2. The cycling the in SBRs was adjusted at 6 hours and 8 hours, and then certainly Included anaerobic and aerobic conditions. Also, for each cycling time. we performed 2 series of experiment simultaneously which was set up 10 days and 20 days as SRT. The removal efficiency of $COD_{cr}$. was over 97% in all operating conditions. In the 6 hours cycling time, the removal efficiency of $PO_4^{3-}-P$ reached almost 100% in steady state. And then we could observe a typical phonemena of phosphorus release and uptake, and the removal efficiency of N was 67%, Residual N source was almost TKN and most of the rest remained as $NO_2-N$. Also the difference in both SRTs was not observed practically. In the 8 hours cycling time, dissolution of sludge appeared. and, $PO_4^{3-}-P was not nearly removed but nitrogen was removed up to 75%, And the residual nitrogen was accumulated as $NO_2^--N$.

• Journal of Environmental Science International
• /
• v.15 no.4
• /
• pp.359-364
• /
• 2006

Two sites with different average daily traffic volume at an intersection were selected in order to investigate water quality of the first flushes in the surface runoffs. The effects of rainfall intensities and accumulated non-rainy days before rainfall events on the water quality were also delineated. Samples were collected at every 2 min. interval from each first flush from February to May, 2004 for 4 major rainfall events. $COD_{cr}$ or SS concentrations at the site with an average daily traffic volume (ADTV) of 23,000 vehicles were 2-7 times higher than those at the site with an ADTV of 1,400 vehicles. The longer the accumulated non-rainy days were, the higher the concentration of heavy metals were than those of $COD_{cr}$ and SS in the first flushes.

• Journal of Korean Society of Water and Wastewater
• /
• v.7 no.1
• /
• pp.20-28
• /
• 1993

The Wastewater from the weight reduction process of polyester is more difficult to be treated biologically than the general wastewater from dyeing and finishing processes in textile industries. Above wastewater shows high pH, high organic strength and wide variation of organic loading. These characteristics are due to TPA and EG resulting from alkaline weight-reduction process and make trouble in the operation of activated sludge process. Therefore, the objective of this study is to develop the pretreatment method for the successful operation of treatment process. For the successful pretreatment process, the wastewater from weight-reduction process should be segregated from other wastewater stream and then acidified with concentrated sulfuric acid to precipitate out TPA from DST solution. At the optimum pH of 2. 2, the initial $COD_{cr}$ 60,000mg/l is reduced to 11,500mg/l and the removal efficiency of $COD_{cr}$ is 81.1%. The required amount of sulfuric acid for pretreatment is not greater than the amount for the the existing neutralization process. Moreover, the supernatant of pretreatment process can be reused in acidification of wastewater.

• Environmental Engineering Research
• /
• v.17 no.1
• /
• pp.3-8
• /
• 2012

A scaled-up bioconversion of fishmeal wastewater (FMW) into liquid fertilizer was performed five times in a $1m^3$ reactor in order to examine the feasibility of commercialization. The importance of aeration was marked. Analyses indicated that dissolved oxygen (DO) level was closely related to the value of oxidation-reduction potential (ORP) and it was crucial to achieve high-quality liquid fertilizer. When pure oxygen was supplied through four diffusers into the reactor, DO levels and ORP values were maintained over 1.2 mg/L and 0.2 mV, respectively all the time during 52 hr of bioconversion. The pH changed from 6.8 to 5.9. The average removal percentages of chemical oxygen demand ($COD_{Cr}$) and total nitrogen (TN) were 75.0% and 71.6%, respectively. Compared to the result acquired in a 5-L reactor, bioconversion of FMW into liquid fertilizer was achieved in a shorter time under the same removal percentages of $COD_{Cr}$ and TN. The 52-hr culture of inoculated FMW was phytotoxic-free and it possessed comparable fertilizing ability to a liquid fertilizer made from the fish waste in hydroponic culture with amino acid contents of 5.93 g/ 100 g sample. From all the above results, transferring lab-scale data to large-scale production appeared to be successful. As a result, the commercialization of a liquid fertilizer made from FMW was feasible.