• Title/Summary/Keyword: $COD_{cr}$

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Characteristics of Manure and Estimation of Nutrient and Pollutant of Holstein Dairy Cattle (홀스타인 젖소 분뇨의 특성과 비료성분 및 오염물질 부하량 추정)

  • Choi, D.Y.;Choi, H.L.;Kwag, J.H.;Kim, J.H.;Choi, H.C.;Kwon, D.J.;Kang, H.S.;Yang, C.B.;Ahn, H.K.
    • Journal of Animal Science and Technology
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    • v.49 no.1
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    • pp.137-146
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    • 2007
  • This study was conducted to determine fertilizer nutrient and pollutant production of Holstein dairy cattle by estimating manure characteristics. The moisture content of feces was 83.9% and 95.1% for urine. The pH of feces and urine were in the ranges of 7.0~7.4 and 7.5~7.8, respectively. The average BOD5, COD, SS, T-N, T-P concentrations of the dairy feces were 18,294, 52,765, 102,889, 2,575, and 457mg/ℓ, respectively. Dairy urine showed lower levels of BOD5(5,455mg/ℓ), COD(8,089mg/ℓ), SS(593mg/ℓ), T-N(3,401mg/l), and T-P(13mg/ℓ) than feces. The total daily produced pollutant amounts of a dairy cow were 924.1g(Milking cow), 538.8g(Dry cow), 284.4g(Heifer) of BOD5, 2,336.5g (Milking cow), 1,651.8g(Dry cow), 734.1g(Heifer) of COD and 4,210.1g(Milking cow), 2,417.1g(Dry cow), 1,629.1g(Heifer) of SS and 194.8g(Milking cow), 96.4g(Dry cow), 58.3g(Heifer) of T-N and 24.0g(Milking cow), 10.2g(Dry cow), 6.1g(Heifer) of T-P. The calculated amount of pollutants produced by a 450kg dairy cow for one year were 181.3kg of BOD5, 492.5kg of COD, 899.9kg of SS, 36.0kg of T-N and 4.1kg of T-P. The total yearly estimated pollutant production from all head(497,261) of dairy cattle in Korea is 90,149 tons of BOD5, 244,890 tons of COD, 447,491 tons of SS, 17,898 tons of T-N and 2,008 tons of T-P. The fertilizer nutrient concentrations of dairy feces was 0.26% N, 0.1% P2O5 and 0.14% K2O. Urine was found to contain 0.34% N, 0.003% of P2O5 and 0.31% K2O. The total daily fertilizer nutrients produced by dairy cattle were 197.4g (Milking cow), 97.4g(Dry cow), and 57.9g(Heifer) of Nitrogen, 54.2g(Milking cow), 22.2g(Dry cow), and 14.2g(Heifer) of P2O5 and 110.8g(Milking cow), 80.4g (Dry cow), and 39.5g(Heifer) of K2O. The total yearly estimated fertilizer nutrient produced by a 450kg dairy animal is 36.2kg of N, 8.8kg of P2O5, 24.6kg of K2O. The estimated yearly fertilizer nutrient production from all dairy cattle in Korea is 18,000 tons of N, 4,397 tons of P2O5, 12,206 tons of K2O. Dairy manure contains useful trace minerals for crops, such as CaO and MgO, which are contained in similar levels to commercial compost being sold in the domestic market. Concentrations of harmful trace minerals, such as As, Cd, Hg, Pb, Cr, Cu, Ni, Zn, met the Korea compost standard regulations, with some of these minerals being in undetected amounts.

Characterization of Runoff Properties of Non-point Pollutant at a Small Rural Area considering Landuse Types (토지이용 특성을 고려한 소규모 농촌유역의 비점오염물질 유출특성 해석)

  • Bae, Sang-ho;Kim, Weon-jae;Yoon, Young H.;Lim, Hyun-man;Kim, Eun-ju;Park, Jae-roh
    • Journal of Korean Society on Water Environment
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    • v.26 no.4
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    • pp.654-663
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    • 2010
  • Attention has increasingly focused on the pollutant load discharged from rural area since the enforcement of total maximum daily loads (TMDLs) in korea. As one of the methods to control the inflow of pollutant load during wet weather events, local governments are attempting to apply non-point source control facility. To design those facilities appropriately, it is essential to understand the runoff characteristics of pollutants such as TSS, $BOD_5$, $COD_{Cr}$, TP and TN. In the paper, the quantitative analyses for pollutant runoff characteristics were examined in a small rural watershed with the area of about 53 hectares. For a dry weather day and wet weather events, variation patterns of dry weather flow and runoff characteristics of wet weather flows were monitored and investigated. The runoff model using XP-SWMM reflecting the landuse types of the watershed in detail was simulated to perform the sensitivity analyses for several factors influencing on their hydrograph and pollutographs. As a result, for the case of medium and small rainfall events (i. e. total rainfall of 35.8 and 17.5 mm), the impervious area including green house, roof and road which covers relatively low portion of total area (i. e. 16%) caused substantial first flush and the majority of total runoff load. Therefore, it has been concluded that the runoff characteristics of each pollutant and distribution of impervious area should be considered for the establishment of the control strategy of non-point pollutant runoff at a rural area.

Comparison of Electricity Generation and Microbial Community Structure in MFCs Fed with Different Substrates (미생물연료전지에서 공급기질에 따른 전기발생량 및 미생물 군집구조 비교)

  • Yu, Jaecheul;Cho, Haein;Cho, Sunja;Lee, Taeho
    • Journal of Korean Society on Water Environment
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    • v.26 no.4
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    • pp.608-613
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    • 2010
  • Electricity generation of microbial fuel cells (MFC) is greatly affected by the kind of feed substrates because substrates would change microbial community of electrochemically active bacteria (EAB) able to transfer electrons to electrode. The effect of different substrates on electricity generation and microbial community of MFC was investigated. Two-chamber MFCs fed with acetate (A-MFC), butyrate (B-MFC), propionate (P-MFC), glucose (G-MFC) and a mixture (M-MFC) of the 4 substrates (acetate : butyrate : propionate : glucose = 1 : 1 : 1 : 1 as $COD_{Cr}$ base) were operated under continuous mode. The maximum power density was found from the M-MFC ($190W/m^3$) which showed the lowest internal resistance ($89{\Omega}$). The maximum power densities of the pure substrates feed MFCs were in order of A-MFC ($25W/m^3$), P-MFC ($21W/m^3$), B-MFC ($20W/m^3$) and G-MFC ($9W/m^3$). In DGGE analysis, the microbial community structure in suspension was quite different from each others depending on feed substrates, while the community structure in the biofilm was relatively similar regardless of the substrates. This result suggests that the feed substrates would affect the microbial community of suspended growth bacteria than attached growth bacteria resulting in difference of electricity generation in MFCs.

A study on the characteristics of wastewater flowrate in land-use of Sogwipo-city in Cheju (제주도 서귀포시지역의 용도지역별 하수발생량 특성에 관한 연구)

  • Jeong, Gwang Ok;Ryu, Seong Pil
    • Journal of Environmental Science International
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    • v.13 no.3
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    • pp.251-262
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    • 2004
  • To identify the characteristics of wastewater flow generated in treatment basins of Seogwipo-city, we selected 3 stations representing the basin and performed 7 times of field survey including 5 times in dry periods and 2 times in wet periods from Feb. 25 to May 27, 2002 for the selected stations. From the analysis of flow data measured for more than 60 days in the interval of 5 minutes and concentration data obtained from laboratory analysis, we can draw several conclusions. First, in the analysis of diurnal variation of wastewater flow for land-use types, we could find the following results: in the residential area, it is observed that wastewater flow rates rise early in the morning for the office-going hour and fall gradually and rise again after the office-leaving hour, showing typical residential wastewater flow pattern, while for the residential and commercial area flow rates rise early in the morning at the office-going hour and move up and down repeatedly within wide range and last till the office-leaving hour, which can be resulted from wastewater that is generated by tourists activated after early in the afternoon, while for the touristy area flow rates rise early in the morning and fall gradually and rise again within wide range. Second, in the analysis of temporal variation of wastewater flow for monthly, it can be observed that in the residential area, in the residential and commercial areas the flow rate of May is higher than that of Feb., March, while for the touristy area flow rate is without monthly because it reflects the movement of population, Third, in wet periods concentration of water-quality item such as SS, BOD, and COD_{cr}$ is high in the beginning of rainfall by first flush, and falls down gradually to reach the steady state, which is the level of wastewater in dry periods after the cease of storm water due to diluting effect resulting from additional runoff water through storm sewers.

Positive Pilot Research of SBR Process with Flexible Vertical (가변형 간벽을 이용한 SBR 공정의 실증 Pilot 연구)

  • Kim, Man-Soo;Park, Jong-Woon;Park, Chul-Whi
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.4
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    • pp.438-444
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    • 2005
  • This study is to install the flexible vertical in order to separate not only the time but also the space in the single reactor by opening and closing the flexible vertical, and to intensify the aerobic, anaerobic and anoxic reactions by reducing the time to activate the microorganism for nitrification, denitrification, release of organic phosphate and luxury uptake of ortho-phosphate. Eventually the result of this study obtained each 90.9%, 76.4% for the removal efficiency of total nitrogen and phosphate. Also, content rate of phosphate at excess sludge was higher $25{\sim}30%$ for SBR reactor with the flexible verticals than existing SBR process. It would be concluded that SBR reactor with flexible verticals is promising for nitrogen and phosphate removal conditions than conventional SBR processes.

Assessment of the Organic and Nitrogen Fractions in the Sewage of the Different Sewer Network Types by Respirometric Method (미생물 호흡률 측정에 의한 관거시스템 유형별 하수의 기질 분율 평가)

  • Park, Jong-Bu;Hur, Hyung-Woo;Kang, Ho;Chang, Sung-Oun
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.8
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    • pp.649-654
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    • 2009
  • Respirometric analysis of domestic sewage by measuring oxygen uptake rate(OUR) was carried out for the experimental assessment of the organic and biomass fractions. The data of the organic and biomass fractions in sewage is essential for the activated sludge model to optimize the biological treatment plant. As a result of this study, the fractions of readily biodegradable substrate($S_S$), slowly biodegradable substrate($X_S$), inert soluble substrate($S_I$), inert particular substrate($X_I$) and heterotrophic biomass($X_{HAB}$) were about 26.6%, 41.5%, 8.5%, 14.7% and 8.7% on the basis of chemical oxygen demand($COD_{Cr}$), respectively. And the fractions of nitrogen were also studied. The fractions of soluble nitrate nitrogen($S_{NO}$), soluble ammonia nitrogen($S_{NH}$), soluble nonbiodegradable organic nitrogen($S_{NI}$), soluble biodegradable organic nitrogen($S_{ND}$) and slowly biodegradable organic nitrogen($X_{ND}$) were about 3.7%, 64.9%, 4.7%, 9.4% and 17.4%, respectively.

Efficient aerobic denitrification in the treatment of leather industry wastewater containing high nitrogen concentration

  • Kang, Kyeong Hwan;Lee, Geon;Kim, Joong Kyun
    • Environmental Engineering Research
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    • v.20 no.1
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    • pp.79-87
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    • 2015
  • To treat leather industry wastewater (LIW) containing high nitrogen concentration, eight aerobic denitrifiers were isolated from sludge existing in an LIW-treatment aeration tank. Among them, one strain named as KH8 had showed the great ability in denitrification under an aerobic condition, and it was identified as Pseudomonas aeruginosa R12. The aerobic denitrification ability of the strain KH8 was almost comparable to its anaerobic denitrification ability. In lab-scale aerobic denitrifications performed in 1-L five-neck flasks for 48 hr, denitrification efficiency was found to be much improved as the strain KH8 held a great majority in the seeded cells. From the nitrogen balance at the cell-combination ratio of 10:1 (the strain KH8 to the other seven isolates) within the seeded cells, the percentage of nitrogen loss during the aerobic denitrification process was estimated to be 58.4, which was presumed to be converted to $N_2$ gas. When these seeded cells with lactose were applied to plant-scale aeration tank for 56 day to treat high-strength nitrogen in LIW, the removal efficiencies of $COD_{Cr}$ and TN were achieved to be 97.0% and 89.8%, respectively. Under this treatment, the final water quality of the effluent leaving the treatment plant was good enough to meet the water-quality standards. Consequently, the isolated aerobic denitrifiers could be suitable for the additional requirement of nitrogen removal in a limited aeration-tank capacity. To the best of our knowledge, this is the first report of aerobic denitrifiers applied to plant-scale LIW treatment.

Removal of Nutrients from Domestic Wastewater Using Intermittently Aerated Activated Sludge Systems Supplemented with Fermented Settled Sludge (발효된 1차 침전슬러지를 공급하여 간헐폭기조를 이용한 도시하수의 영양염류 처리)

  • Weon, Seung-Yeon;Lee, Sang-Ill
    • Journal of Korean Society on Water Environment
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    • v.20 no.1
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    • pp.18-23
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    • 2004
  • In this research, a 2-stage intermittently aerated activated sludge system(IA) and intermittently aerated dynamic flow activated sludge system(DF) were investigated for the removal of nutrients in domestic wastewater. Wastewater was characterized by low C/N( organics/nitrogen) ratio. $COD_{cr}$, $BOD_s$, TKN and TP concentrations of domestic wastewater were 235, 47, 32 and 5.4 mg/L, respectively. Three sets of IA and one set of DF were operated. Three of four systems were added with fermented settled sludge taken from primary settling tank as an external electron donor and the other(IA) for control reactor was operated without addition of electron donor. All systems were operated at same sludge retention time of 20 days and hydraulic retention time of 12hrs. The supplemental electron donor was supplied into the anoxic mode. A higher denitrification rate was observed from the reactors with fermented settled sludge as an electron donor for denitrification compared to that of without addition of organic source. The result of this study indicates that the settled primary sludge, if the fermented at the acid stage, was an excellent electron donor for denitrification. 81 % of TN and 80% of TP were removed from the systems with the supplemental organic source added. However, the control reactor without addition of electron donor showed only 39% of TN and 43% of TP.

Applicability of the SBR Process Using Aerobic Granular Sludge (AGS) in Municipal Wastewater Treatment (호기성 그래뉼 슬러지를 이용한 연속 회분식 공정의 도시하수처리에 대한 적용)

  • Yae, Jae-Bin;Ryu, Jae-Hoon;Hong, Seong-Wan;Kim, Hyun-Gu;Ahn, Dae-Hee
    • Journal of Environmental Science International
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    • v.27 no.4
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    • pp.233-240
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    • 2018
  • The purpose of this study was to confirm the applicability of aerobic granular sludge (AGS) in the advanced sewage treatment process. Simulated influent was used in the operation of a laboratory scale reactor. The operation time of one cycle was 4 h and the reactor was operated for six cycles per day. The volume exchange ratio was 50%. The influent was injected in divisions of 25% to increase the removal efficiency of nitrogen in every cycle. As a result, the removal efficiencies of $COD_{Cr}$ and TN in this reactor were 98.2% and 76.7% respectively. During the operation period, the AGS/MLVSS concentration ratio increased from 70.0% to 86.7%, and the average $SVI_{30}$ was 67 mL/g. The SNR and SDNR were 0.073-0.161 kg $NH_4{^+}$-N/kg MLVSS/day and 0.071-0.196 kg $NO_3{^-}$-N/kg MLVSS/day respectively. These values were higher or similar to those reported in other studies. The operation time of the process using AGS is shorter than that of the conventional activated sludge process. Hence, this process can replace the activated sludge process.

A Study on Autocontrolled SBR for Biological Nutrient Removal with External Carbon Sources (외부탄소원 주입시 영양염류의 생물학적 제거를 위한 자동제어 SBR 공정에 관한 연구)

  • Lee, Byung-hun;Kang, Seong-jae;Lim, Sung-il;Yoo, Pyung-jong
    • Journal of Korean Society on Water Environment
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    • v.18 no.4
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    • pp.371-377
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    • 2002
  • The purpose of this study is to develop effective operating process in order to achieve more suitable conditions of Anoxic-Oxic-Anoxic-Stripper(AOAS) SBR through real-time control. To improve the removal efficiency, glucose, methanol and synthetic food waste acid fermentant were added as an external carbon source, In the case of glucose and synthetic food waste acid fermentant, TN, TP were removed to average 86.9%, 73.0% respectively. Methanol was removed to average 64.6%, 55.4% respectively. The synthetic food waste acid fermentant proved to be the most efficient and allowed for the substitution of an external carbon source. The removal rate of $COD_{Cr}$, was approximately 90% at all cases. The results of the study that a correlation between ORP (Oxidation-Reduction Potential), pH and DO and nitrification or denitrification when an external carbon source is added and when it isn't was showed that ${\Delta}ORP$ is suitable parameter. ORP reacted properly to denitrification (${\Delta}ORP<-10$) and nitrification (${\Delta}ORP<0$). The use of real-time control saved anywhere between 61 and 67 minutes at the anoxic(1) stage and 26 to 52 minutes at the oxic(1) stage. When the time saved from the anoxic(1) and oxic(1) was added to the anoxic(2) stage for the removal efficiency of TN and TP increased from 0.7 to 13.9% and 12 to 35 % respectively.