• Title/Summary/Keyword: $COD_{cr}$

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Development of small constructed wetland for urban and roadside areas (도시 및 도로 조경공간을 활용한 소규모 인공습지 조성 기술)

  • Kang, Chang-Guk;Maniquiz, Marla C.;Son, Young-Gyu;Cho, Hye-Jin;Kim, Lee-Hyung
    • Journal of Wetlands Research
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    • v.13 no.2
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    • pp.231-242
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    • 2011
  • Recently, the green spaces in the urban areas were greatly reduced due to urbanization and industrialization. As urban structures such as roads and buildings are built, the amount of impervious area within a watershed increases. High impervious surfaces are the common causes of high runoff volumes as the soil infiltration capacity decreases and the volume and rate of runoff increase thereby decreasing the groundwater recharge. These effects are causing many environmental problems, such as floods and droughts, climate change, heat island phenomenon, drying streams, etc. Most cities attempted to reduce sewer overflows by separating combined sewers, expanding treatment capacity or storage within the sewer system, or by replacing broken or decaying pipes. However, these practices can be enormously expensive than combined sewer overflows. Therefore, in order to improve these practices, alternative methods should be undertaken. A new approach termed as "Low Impact Development (LID)" technology is currently applied in developed countries around the world. The purpose of this study was to effectively manage runoff by adopting the LID techniques. Small Constructed Wetland(Horizontal Subsurface Flow, HSSF) Pilot-scale reactors were made in which monitoring and experiments were performed to investigate the efficiency of the system in removing pollutants from runoff. Based on the results of the Pilot-plant experiments, TSS, $COD_{Cr}$, TN, TP, Total Pb removal efficiency were 95, 82, 35, 91 and 57%, respectively. Most of the pollutants were reduced after passing the settling tank and the vertical filter media. The results of this study can contribute to the conservation of aquatic ecosystems and restoration of natural water cycle in the urban areas.

Treatment of Spent ion-Exchange Resins from NPP by Supercritical Water Oxidation(SCWO) Process (초임계수 산화공정에 의한 원전 폐수지 처리기술)

  • Kim, Kyeong-Sook;Son, Soon-Hwan;Song, Kyu-Min;Han, Joo-Hee;Han, Kee-Do;Do, Seung-Hoe
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.7 no.3
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    • pp.175-182
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    • 2009
  • The spent cationic exchange resins and anionic exchange resins were separated from mixed spent exchange resins by a fluidized bed gravimetric separator. The separated resins were identified by an elemental analysis and thermogravimetric analysis. The each test sample was prepared by diluting the slurry made by wet ball milling the cationic exchange resins and the anionic exchange resins separated as a spherical granular form for 24 hours. The resulting test samples showed a slurry form of less than $75{\mu}m$ of particle size and 25,000ppm of $COD_{cr}$. The decomposition conditions of each test samples from a thermal power plant were obtained with a lab-scale(reactor volume : 220mL) supercritical water oxidation(SCWO) facility. Then pilot plant(reactor volume : 24 L) tests were performed with the test samples from a thermal power plant and a nuclear power plant successively. Based on the optimal decomposition conditions and the operation experiences by lab-scale facility and the pilot plant, a commercial plant(capacity : 150kg/h) can be installed in a nuclear power plant was designed.

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Effect of Food Waste Direct Landfilling Prohibition on Characteristics of Landfill Gas and Leachate (음식물류폐기물 직매립금지가 매립지 가스 및 침출수 특성에 미치는 영향)

  • Ko, Jae-Young;Phae, Chae-Gun;Park, Joon-Seok
    • Applied Chemistry for Engineering
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    • v.18 no.6
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    • pp.612-617
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    • 2007
  • This research was performed to evaluate the effect of 'Food Wastes (FW) Direct Landfilling Prohibition' on characteristics of landfill gas (LFG) and leachate and the appropriateness of current legislation. Approximately 45% (Exp.45) and 15% (Exp.15) of FW were filled in two lysimeters. During 570 days, 1400 L of LFG was generated from Exp.45%, which was much more than 906 L of Exp.15. There was no significant difference of LFG composition between Exp.15 and Exp.45. 2~30 ppmv of odorous hydrogen sulfide was detected in Exp.45, while 2~7 ppmv was in Exp.15. There was also no significant difference in the leachate generation between the two. On day 570, $BOD_5$ of Exp.45 and Exp.15 were 37000 mg/Land 25630 mg/L and $COD_{Cr}$ of Exp.45 and Exp.15 were 45480 mg/L, 30294 mg/L. TOC of Exp.45 was 2~3 times higher than Exp.15. Higher portion of FW in landfilling increased LFG generation. However, it generated more odor and made the quality of leachate. Therefore, 'FW direct Landfilling Prohibition' was evaluated as an appropriate legislation.

Pollutants Characteristics of Surface Runoff from the Industrial Complex (산업공단에서의 지표유출수 오염물질 특성)

  • Kim, Youn-Kwon;Shin, Eung-Bai;Lee, Doo-Jin;Pae, Yo-sop;Yoon, Hyun-Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.4
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    • pp.689-698
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    • 2000
  • The quality of stormwater runoff has been a major concern in water quality preservation. Characteristics of heavy metals and conventional pollutants in surface runoff from industrial complex, during the first flush, were not completely understood, Generally, separated sewer system is known for their water quality with untreated wastewater during storm events. In this study, the quality and characteristics of surface runoff from the industrial complex were investigated. The target area in the industrial complex catchment was divided 4 sub-areas, and the quality of stormwater runoff from the selected drainage areas was investigated using a grab sampling method. The petro-chemical industry and the junkyard discharged relatively high concentration of conventional pollutants, such as BOD, COD, SS, and TN through the first flush runoff samples. On the other hand, a higher level of heavy metals was found in the first flush runoff from the metal-mechanical industry and the scrap storage yard. For metals, Fe, Zn and Cu were the most prevalent species found in the first flush runoff from all sites for every surface runoff samples, while Pb, As, Cd, Cr and Ni were the least prevalent species and Hg was not found in any sample at any site. These results suggest that the nature of pollutants in surface runoff from the industrial complex was related to the type of industry, and the concentration of pollutants was determinated by the degree of exposed pollutant sources and the characteristic of rainfall events at the sites.

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Estimation of Kinetic Coefficient in Submerged Membrane Bioreactor for Biological Nutrient Removal (도시 하수의 생물학적 고도처리를 위한 분리막 공정의 개발 및 동역학적 계수 산정 연구)

  • Park, Jong-Bu;Park, Seung-Kook;Hur, Hyung-Woo;Kang, Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.2
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    • pp.109-113
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    • 2009
  • This study was performed to investigate the characteristics of nutrient removal of municipal wastewater in membrane bioreactor system. Membrane bioreactor consists of four reactors such as the anaerobic, the stabilization, the anoxic and the submerged membrane aerobic reactor with two internal recycles. The hydraulic retention time (HRT), sludge retention time (SRT) and flux were 6.2 h, 34.1 days and 19.6 L/$m^2$/hr (LMH), respectively. The removal efficiency of $COD_{Cr}$, SS, TN and TP were 94.3%, 99.9%, 69.4%, and 74.6%, respectively. The estimated true biomass yield, specific denitrification rate (SDNR), specific nitrification rate (SNR), specific phosphorus release rate (SPRR) and specific phosphorus uptake rate (SPUR) were 0.653 kgVSS/kgBOD/d, 0.044 $mgNO_3$-N/mgVSS/d, 0.035 $mgNH_4$-N/mgVSS/d, 51.0 mgP/gVSS/d and 5.4 mgP/gVSS/d, respectively. The contents of nitrogen and phosphorus of biomass were 8.86% and 3.5% on an average.

A Study on Characteristics of Solubilization and Biogas Production for Sewage Sludge using Thermal Pretreatment (열적가용화공정을 이용한 하수슬러지의 가용화 특성 및 바이오가스 생산량 평가)

  • Jeong, Seong-Yeob;Yeon, Ho-Suk;Lee, Chang-Yeol;Lee, Jong-In;Chang, Soon-Woong
    • Resources Recycling
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    • v.24 no.2
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    • pp.46-54
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    • 2015
  • In this study, an applicability of thermal pretreatment for primary and secondary sludge, which are generated in a sewage treatment plant, was evaluated. The efficiency and charateristics was investigated with each sludge after pretreatment under the condition of $100{\sim}220^{\circ}C$ for 30 minutes. As the result, it was found that $SCOD_{Cr}$, $NH_4{^+}$, VFAs concentrations increased as the pre-treatment temperature increased. For COD solubilization, it was also highly dependent on an increase of temperature resulting in acceleration on hydrolysis and acid fermentation. In the BMP (Biochemical Methane Potential) experiment, for the primary sludge, it showed the higher biogas production rate at a temperature of $220^{\circ}C$, however, the effect was insignificant (5.6%). Whereas, for the secondary sludge, the increase on biogass production rate was 38.8% ($180^{\circ}C$) and this means that the secondary sludge is more suitable for an applicability of thermal pretreatment.

Wastewater Treatment and Microbial Structure Analysis by Fluorescence In Situ Hydridizationin a Biofilm Reactor (생물막 반응키에서의 폐수 처리 및 Fluorescence In Situ Hybridization에 의한 복합 미생물계 구조 해석)

  • Kim, Dong-Jin;Han, Dong-Woo;Lee, Soo-Choul;Park, Byeong-Gon;Kwon, Il;Sung, Chang-Keun;Park, Wan-Cheol
    • KSBB Journal
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    • v.17 no.1
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    • pp.80-87
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    • 2002
  • Laboratory scale aerobicfanaerobic biofilm reactor was used for simultaneous and stable removal of organics, N and P components to investigate optimum design and operation parameters and to analyze the microbial distribution and consortium structure of nitrification and denitrification bacteria in aerobic and anaerobic biofilm systems. The biofilm reactor was successfully operated for 143 days to show $COD_{cr},\;BOD_5$, SS removal efficiencies of 88, 88, and 97%, respectively. During the experiment period, almost complete nitrification efficiency of 96% was achieved. Denitrification efficiency was about 45% without addition of any external carbon sources. In case of total phosphorus removal, 74% of the inlet phosphorus was removed. Fluorescence in situ hybridization (FISH) results showed that most of the ammonia oxidizing bacteria in the aerobic nitrification zone was found to be Nitrosomonas species while Nitrospira was the representative nitrite oxidizing bacteria. For the denitrification, Rhodobacter, Rhodovulum, Roseebacter and Paracouus were the dominant denitrification bacteria which was 10 to 20% of the total bacteria in numbers.

Optimal Condition for Decomposition of Ethylenediaminetetraacetic Acid (EDTA) in Supercritical Water Oxidation (초임계수 산화공정에서 Ethylenediaminetetraacetic Acid (EDTA) 분해 최적화 연구)

  • Lee, Hyeon-Cheol;In, Jung-Hyun;Kim, Jong-Hwa;Lee, Chang-Ha
    • Korean Chemical Engineering Research
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    • v.43 no.2
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    • pp.318-323
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    • 2005
  • Supercritical water oxidation (SCWO, P>221 bar, T>$374^{\circ}C$) is a promising method for the decomposition of refractory organic compounds. In this study, the SCWO of Ethylenediaminetetraacetic acid (EDTA) was carried out in a tubular-type continusous reactor system with an $H_2O_2$ oxidant at $387-500^{\circ}C$, 250 bar and residence time (RT) of 15.9-88.9 s. The decomposition efficiencies increased with increasing temperature and oxidant amount, while it was inversely proportional to feed flow rate. The decomposition efficiency of 99.6% was obtained at $500^{\circ}C$, 250 bar, oxidant amount of 400% and residence time of 40.1 s. The effect of temperature on the decomposition efficiency was more significant than that of oxidant amount. In the case of the decomposition efficiency of 5,000 mg/L of EDTA (3,063 mg/L as $COD_{Cr}$), the decompostion of 99% or higher was obtained at the condition of over 40.1 s (RT) and 200 stoichiometric % of $H_2O_2$ in the supercritical water of $500^{\circ}C$ and 250 bar.

Concurrency Control and Consistency Maintenance of Cached Spatial Data in Client-Server Environment (클라이언트-서버 환경에서 캐쉬된 공간 데이터의 동시성 제어 및 일관성 유지 기법)

  • Shin, Young-Sang;Hong, Bong-Hee
    • Journal of KIISE:Databases
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    • v.28 no.3
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    • pp.512-527
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    • 2001
  • In a client-server spatial database, it is desirable to maintain the cached data in a client side to minimize the communication overhead across a network. This paper deals with the issues of concurrency and consistency of map updates in this environment. A client transaction to update map data is an interactive work and takes a long time to complete it. The map update in a client site may affect the other sites'updates because of dependencies between spatial data stored at different sites. The concurrent updates should be propagated to the other clients as well as the server to keep the consistency of map replicated in a client cache, and also the communication overhead of the update propagation should be minimized not to lose the benefit of caching. The newly proposed cache region locking with CR lock and CX lock controls the update dependency due to spatial relationships. CS lock and COD lock are suggested to use optimistic detection-based approaches for guaranteeing the consistency of cached client data. The cooperative update protocol uses these extended locking primitives and Spatial Relationship-based 2PC (SR-based 2PC). This paper argues that the concurrent updates of cached client spatial data can be achieved by deciding on collaborative updates or independent updates based on spatial relationships.

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Removal of Ammonia Nitrogen and Organics from Piggery Wastewater Using BACC Process-I. Comparison of Activated Sludge Process (BACC를 이용한 축산폐수의 암모니아성 질소 및 유기물의 제거 I. 활성슬러지 공정과의 비교)

  • 성기달;류원률;김인환;조무환
    • KSBB Journal
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    • v.16 no.2
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    • pp.133-139
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    • 2001
  • To treat piggery wastewaters containing refractory compounds including nitrogen, biological treatments were investigated. In biological treatment, the removal efficiencies of organics and nitrogen by the activated sludge process and bioreactor using a BACC (Biological Activated Carbon Cartridge) media filled with granular activated carbon were examined. The results were as follows; in the biological process, when the approximate influent BOD concentration of 620 mg/L, through dilution, was treated by the activated sludge process, the process should be operated at a HRT of over 8 days to maintain an effluent BOD concentration of lower than 100 mg/L. In the treatment of piggery wastewater using a BACC bioreactor, when the HRT was 200 hours, the BOD, COD(sub)cr, and TKN removal efficiency of the effluent were 94, 75 and 64.3%, respectively. Comparing the BACC bioreactor with the activated sludge process, when the volumetric loading rate was 0.3 g BOD/L.day, the specific substrate removal rate of BOD was 0.14 g BOD removed/L.day in the activated sludge process which compared with 0.27 g BOD removed/L$.$day in the BACC bioreactor. The BACC bioreactor showed on average a 2-fold higher removal rate and was superior to the activated sludge process in wastewater treatment in terms of variations of loading time and high loading time. Therefore, the BACC process can effectively treat piggery wastewater containing high concentrations of nitrogen and organic compounds.

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