• Title/Summary/Keyword: $CH_4/N_2$

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Flora and Ecological Characteristics Before and After Construction of the Binae Marsh, Namhan River (남한강 비내늪의 공사전후 관속식물상과 생태적 특성)

  • You, Ju-Han;Ahn, Young-Sup;Lee, Cheol-Hee
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.15 no.4
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    • pp.61-80
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    • 2012
  • This study is to offer the basic data for restoration and conservation of wetland ecosystem by surveying and analysing the flora distributed in the Binae marsh, Namhan River, Chungju-si. The flora in the Binae marsh were verified 204 taxa including 48 families, 152 genera, 179 species, 23 varieties and 2 forms. In flora, pteridophyta were 2 taxa including 1 family, 1 genus and 2 species, among angiospermae, dicotyledonae were 153 taxa including 37 families, 110 genera, 138 species, 13 varieties and 2 forms and monocotyledonae were 49 taxa including 10 families, 41 genera, 39 species and 10 varieties. In the result of classifying the life form of flora, megaphanerophytes (M), nanophanerophytes (N) and chamaiphytes (Ch) were each 9 taxa (4.4%), 37 taxa (18.1%) of hemicryptophytes (H), 19 taxa (9.3%) of geophytes (G), 97 taxa (47.6%) of therophytes (Th) and 24 taxa (11.8%) of hydrophytes (HH). The rare plant designated by Korea Forest Service was 1 taxa (Aristolochia contorta), and the endemic plant was 1 taxa (Salix koriyanagi) too. The specific plants by floristic region were 6 taxa. From among these, the species of degree I were 5 taxa including Salix chaenomeloides, Aristolochia contorta, Artemisia selengensis, Cirsium pendulum and Vallisneria natans, and degree III was 1 taxa including Alisma orientale. The naturalized plants were 45 taxa and the invasive alien plants were 3 taxa including Sicyos angulatus, Ambrosia artemisiifolia and Ambrosia trifida. The naturalized index (NI) was about 22.1%, 16.1% of urbanized index (UI) and 27.3% of disturbed index (DI). The extinct species by construction were 17 taxa including Persicaria sagittata, Typha orientalis, Zizania latifolia and so forth. The new-occured species were 14 taxa including Brassica juncea, Thlaspi arvense, Carduus crispus and so forth. The important species among the extinct species were Aristolochia contorta, Alisma orientale and Vallisneria natans.

Preparation of Hafnium Oxide Thin Films grown by Atomic Layer Deposition (원자층 증착법으로 성장한 HfO2 박막의 제조)

  • Kim Hie-Chul;Kim Min-Wan;Kim Hyung-Su;Kim Hyug-Jong;Sohn Woo-Keun;Jeong Bong-Kyo;Kim Suk-Whan;Lee Sang-Woo;Choi Byung-Ho
    • Korean Journal of Materials Research
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    • v.15 no.4
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    • pp.275-280
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    • 2005
  • The growth of hafnium oxide thin films by atomic layer deposition was investigated in the temperature range of $175-350^{\circ}C$ using $Hf[N(CH_3)_2]_4\;and\;O_2$ as precursors. A self-limiting growth of $0.6\AA/cycle$ was achieved at the substrate temperature of $240-280^{\circ}C$. The films were amorphous and very smooth (0.76-0.80 nm) as examined by X-ray diffractometer and atomic force microscopy, respectively. X-ray photoelectron spectroscopy analysis showed that the films grown at $300^{\circ}C$ was almost stoichiometric. Electrical measurements performed on $MoW/HfO_2$(20 nm)/Si MOS structures exhibited high dielectric constant$(\~17)$ and a remarkably low leakage current density of at an applied field of $1.5-6.2\times10^{-7}A/cm^2$ MV/cm, probably due to the stoichiometry of the films.

Study on Electrical Conductivity, Transmittance and Gas Barrier Properties of DLC Thin Films (DLC 박막의 전기전도성, 투과율 및 가스베리어 특성에 관한 연구)

  • Park, S.B.;Kim, C.H.;Kim, T.G.
    • Journal of the Korean Society for Heat Treatment
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    • v.31 no.4
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    • pp.187-193
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    • 2018
  • In this study, the electrical conductivity, transmittance and gas barrier properties of diamond-like carbon (DLC) thin films were studied. DLC is an insulator, and has transmittance and oxygen gas barrier properties varying depending on the thickness of the thin film. Recently, many researchers have been trying to apply DLC properties to specific industrial conditions. The DLC thin films were deposited by PECVD (Plasma Enhanced Chemical Vapor Deposition) process. The doping gas was used for the DLC film to have electrical conductivity, and the optimum conditions of transmittance and gas barrier properties were established by adjusting the gas ratio and DLC thickness. In order to improve the electrical conductivity of the DLC thin film, $N_2$ doping gas was used for $CH_4$ or $C_2H_2$ gas. Then, a heat treatment process was performed for 30 minutes in a box furnace set at $200^{\circ}C$. The lowest sheet resistance value of the DLC film was found to be $18.11k{\Omega}/cm^2$. On the other hand, the maximum transmittance of the DLC film deposited on the PET substrate was 98.8%, and the minimum oxygen transmission rate (OTR) of the DLC film of $C_2H_2$ gas was 0.83.

Estimation of National Greenhouse Gas Emissions in Agricultural Sector from 1990 to 2013 - Focusing on the Crop Cultivation - (1990년부터 2013년까지 농업 분야 국가 온실가스 배출량 평가 - 경종부문 중심으로 -)

  • Choi, Eun Jung;Jeong, Hyun Cheol;Kim, Gun Yeob;Lee, Sun-il;Lee, Jong Sik
    • Journal of Climate Change Research
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    • v.7 no.4
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    • pp.443-450
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    • 2016
  • The major greenhouse gases (GHGs) in agricultural sector are methane ($CH_4$), nitrous oxide ($N_2O$), carbon dioxide ($CO_2$). GHGs emissions are estimated by pertinent source category in a guideline book from Intergovernmental Panel on Climate Change (IPCC) such as methane from rice paddy, nitrous oxide from agricultural soil and crop residue burning. The methods for estimation GHGs emissions in agricultural sector are based on 1996 and 2006 IPCC guideline, 2000 and 2003 Good Practice Guidance. In general, GHG emissions were calculated by multiplying the activity data by emission factor. The total GHGs emission is $10,863Gg\;CO_2-eq$. from crop cultivation in agricultural sector in 2013. The emission is divided by the ratio of greenhouse gases that methane and nitrous oxide are 64% and 34%, respectively. Each gas emission according to the source categories is $7,000Gg\;CO_2-eq$. from rice paddy field, $3,897Gg\;CO_2-eq$. from agricultural soil, and $21Gg\;CO_2-eq$. from field burning, respectively. The GHGs emission in agricultural sector had been gradually decreased from 1990 to 2013 because of the reduction of cultivation. In order to compare with indirect emissions from agricultural soil, each emission was calculated using IPCC default factors (D) and country specific emission factors (CS). Nitrous oxide emission by CS applied in indirect emission, as nitrogen leaching and run off, was lower about 50% than that by D.

Changes of Nitrogen-Fixation Activity and Environmental Factors of Growth in Lespedeza bicolor Turcz (싸리(Lespedeza bicolor Turcz.)의 공생 질소고정활성과 생육환경요인의 변화)

  • 송승달
    • Journal of Plant Biology
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    • v.35 no.4
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    • pp.317-322
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    • 1992
  • The nitrogen fixation activity and environmental factors of Lespedeza bicli!oy Turcz, forming annual root nodules by symbiotic Rhizobium sp. were analyzed in the field conditions during the growing period. Seasunal changes of $N_2-fixation$ activity showed the maximum value of $120\;\mu\textrm{M}\;C_2_H4{\cdot}noduie\;g\;fw^{-1}{\cdot}hr^{-1}$ during the active growing period (June) and varied significantly depending on the growth phase and environmental factors. The maximum activities were attained at the conditions of pH 7, $30^{\circ}C$ of temperature, 18 Kpa of oxygen partial pressure and inhibited by water stress and nitrogen sources. The habitat soil was weak acidic and poor in nitrogen, phosphorus and organic matter contents. The leaf area ratios and chlorophyll contents were ranged from 442 to $48;\textrm{cm}^2{\cdot}g\;dw^{-1}$ and from 33 to $38\;\mu\textrm{g}\;chI{\cdot}\textrm{cm}^2$. Nitrogen contents in each organ showed the maximum of 46, 19 and $11\;mg{\cdot}g\;dw^{-1}, respectively for leaf, rool and stem in the early period. The highest phosphorus contents were 4.2, 1.2 and $0.6\;mg{\cdot}g\;dw^{-1}$, respectively for leaf. root and stem in early growing period. The allocation ratios of nitrogen quantity showed 60% for leaves and 73% for roots during the active and late growth period, and 22% [or stems in average. The allocalion ralios o[ phosphorus quantity showed 58% for leaves during the most productive period, 70% for roots in the pre-growth stage and 26% for stems in average.verage.

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A Study on the Biogasification of Municipal and Industrial Wastewater Sludge (도시 하수 및 공장 폐수 슬러지의 바이오가스화에 관한 연구)

  • Kim, Jahyun;Kim, Seogku;Hwang, Injoo;Ahn, Jaehwan;Kang, Sungwon;Lee, Wontae;Lim, Junhyuk;Lee, Jeakun;Lee, Taeyoon
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.9
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    • pp.5-12
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    • 2014
  • Anaerobic digestion was investigated for the stabilization of sludge, decrease of volatile solids, production of biogas for wastewater sludge. In this study, total solids and volatile solids, elemental analysis were conducted to determine characteristics of various types of sludges and investigate the feasibility of biogas production of Municipal Wastewater Sludge (MWS), Industrial Wastewater Sludge (IWS), mixed sludge (Mix), and Municipal Wastewater Sludg Cake (MWSC). Total solids, volatile solids, and C/N ratio were determined in the range of 11.2~20.6 %, 62.1~83.1 % of TS and 4.96~8.33 %. Using the biochemical methane potential (BMP test), mixed sludge and wastewater sludge finished the methane production within approximately 20 day and 16~17 day. Sludge cake finished within 10 day. Mixed sludge produced 395.5 mL $CH_4$ per g of Volatile Solid (VS) and resulted in the highest methane production. For carbon dioxide production, five sludges had similar value of accumulated carbon dioxide production except for sludge cake.

Identification of Polymorphisms in CYP2E1 Gene and Association Analysis among Chronic HBV Patients

  • Chun, Ji-Yong;Park, Byung-Lae;Cheong, Hyun-Sub;Kim, Jason-Y.;Park, Tae-Joon;Lee, Jin-Sol;Lee, Hyo-Suk;Kim, Yoon-Jun;Shin, Hyoung-Doo
    • Genomics & Informatics
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    • v.7 no.4
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    • pp.187-194
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    • 2009
  • Cytochrome P450 2E1 (CYP2E1) is a member of the cytochrome P450 superfamily, and it is a key enzyme responsible for the metabolic activation of many smallmolecular-weight compounds such as alcohol, which is classified as a human carcinogen. In this study, we identified 19 single nucleotide polymorphisms (SNPs) in CYP2E1 in Korean population. In these SNPs, we examined possible genetic association of CYP2E1 polymorphisms with HBV clearance and the risk of hepatocellular carcinoma (HCC). Five common polymorphic sites were selected, CYP2E1 polymorphisms at rs381-3867, rs3813870, rs2070673, rs2515641 and rs2480257, considering their allele frequencies, haplotype-tagging status and LDs for genotyping in larger-scale subjects (n=1,092). Statistical analysis demonstrated that CYP2E1 polymorphisms and haplotypes show no significant association with HBV clearance, HCC occurrence and onset age of HCC (p>0.05). Previous studies, however, have shown contradictory findings on associations of CYP2E1 polymorphisms with CYP2E1 activities and HCC risk. Comparing the contrasting results of previous researches suggest that CYP2E1 polymorphism is associated with CYP2E1 activity induced by ethanol, but is not directly associated with HCC risk. CYP2E1 variation/haploype information identified in this study will provide valuable information for future studies on CYP2E1.

A Study on Separation Process for Over 95 wt% DME Recovery from DME Mixture Gases (DME 혼합가스로부터 95 wt% 이상의 DME 회수를 위한 분리공정 연구)

  • Lim, Gye-Gyu;Park, Seung-Kyu;Rho, Jea-Hyun;Baek, Young-Soon
    • Clean Technology
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    • v.15 no.4
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    • pp.287-294
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    • 2009
  • In order to separate the fuel-grade DME from the product of a direct DME synthesise reaction, containing 19~20% of DME, an absorption column and a purification column were employed. In the DME absorption column, the flow rate of the methanol required to recover more than 99% of DME at 50 bar was estimated by the correlation obtained from the lab-scale experiments. In the DME purification column, the maximum DME recovery of 98.2% could be obtained even from the side stream at the 3rd stage above the feed stage, since the feed stream originated from the product of the absorption column had already contained a large amount of DME (20~30 mol%) and only a small amount of light products such as $CO_2$ and $N_2$ (5~10 mol%).

Association between smartphone overdependence and mental health in South Korean adolescents: a secondary data analysis

  • Hyeseon Yun;Eun Kyoung Choi
    • Child Health Nursing Research
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    • v.30 no.2
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    • pp.87-96
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    • 2024
  • Purpose: The rising prevalence of smartphone overdependence among adolescents and its detrimental impact on mental health have become a growing concern. This study aimed to investigate the association between smartphone overdependence and the mental health of Korean adolescents. Methods: Participants were drawn from the 16th Korea Youth Risk Behavior Web-based Survey conducted in 2020. The dependent variable as smartphone overdependence, while the main exposure of interest was mental health, encompassing generalized anxiety disorder (GAD), perceived stress, sources of perceived stress, perceived loneliness, and perceived depressive symptoms. The study employed the Rao-Scott chi-square test and multiple logistic regression using IBM SPSS version 26.0. Results: The participants comprised 54,948 adolescents aged 13 to 18 years. Among them, 25.1% (n=13,775) were categorized as smartphone overdependence group. Specifically, 20.3% of adolescents who reported GAD ≥10 and 22.5% of those who reported experiencing high levels of perceived loneliness were identified as smartphone overdependent. The GAD increased a risk of smartphone overdependence by 2.61 times (95% confidence interval [95% CI]: 2.46-2.77). Perceived loneliness was associated with 1.98-fold (95% CI: 1.87-2.09) increased risk of smartphone overdependence. Additionally, conflict with peers was found to increase the risk of smartphone overdependence by 4.63-fold (95% CI: 3.89-5.52), followed by conflict with parents (odds ratio [OR]: 4.52, 95% CI: 3.84-5.31), and family environment (OR: 4.52, 95% CI: 3.75-5.46). Conclusion: The findings underscore a significant association between smartphone overdependence and mental health in Korean adolescents. Healthcare services to improve their emotional coping and interpersonal skills are necessary.

Large Scale SWAT Watershed Modeling Considering Multi-purpose Dams and Multi-function Weirs Operation - For Namhan River Basin - (다목적 댐 및 다기능 보 운영을 고려한 대유역 SWAT 모형 구축기법 연구 - 남한강 유역을 대상으로 -)

  • Ahn, So Ra;Lee, Ji Wan;Jang, Sun Sook;Kim, Seong Joon
    • Journal of The Korean Society of Agricultural Engineers
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    • v.58 no.4
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    • pp.21-35
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    • 2016
  • This study is to evaluate the applicability of SWAT (Soil and Water Assessment Tool) model for multi-purpose dams and multi-function weirs operation in Namhan river basin ($12,577km^2$) of South Korea. The SWAT was calibrated (2005 ~ 2009) and validated (2010 ~ 2014) considering of 4 multi-purpose dams and 3 multi-function weirs using daily observed dam inflow and storage, evapotranspiration, soil moisture, and groundwater level data. Firstly, the dam inflow was calibrated by the five steps; (step 1) the physical rate between total runoff and evapotranspiration was controlled by ESCO, (step 2) the peak runoff was calibrated by CN, OV_N, and CH_N, (step 3) the baseflow was calibrated by GW_DELAY, (step 4) the recession curve of baseflow was calibrated by ALPHA_BF, (step 5) the flux between lateral flow and return flow was controlled by SOL_AWC and SOL_K, and (step 6) the flux between reevaporation and return flow was controlled by REVAPMN and GW_REVAP. Secondly, for the storage water level calibration, the SWAT emergency and principle spillway were applied for water level from design flood level to restricted water level for dam and from maximum to management water level for weir respectively. Finally, the parameters for evapotranspiration (ESCO), soil water (SOL_AWC) and groundwater level fluctuation (GWQMN, ALPHA_BF) were repeatedly adjusted by trial error method. For the dam inflow, the determination coefficient $R^2$ was above 0.80. The average Nash-Sutcliffe efficiency (NSE) was from 0.59 to 0.88 and the RMSE was from 3.3 mm/day to 8.6 mm/day respectively. For the water balance performance, the PBIAS was between 9.4 and 21.4 %. For the dam storage volume, the $R^2$ was above 0.63 and the PBIAS was between 6.3 and 13.5 % respectively. The average $R^2$ for evapotranspiration and soil moisture at CM (Cheongmicheon) site was 0.72 and 0.78, and the average $R^2$ for groundwater level was 0.59 and 0.60 at 2 YP (Yangpyeong) sites.