• Title/Summary/Keyword: $C^{*}$-적분

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Reductive degradation of Chlorinated compounds by using Iron Minerals (철 광물에 의한 염소계 유기화합물의 환원적분해)

  • Kim, Sung-Kuk;Park, Sang-Won
    • Journal of Soil and Groundwater Environment
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    • v.9 no.2
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    • pp.11-19
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    • 2004
  • Chlorinated and nitroaromatic compounds are non-degradable substances that are extremely toxic and are known to be carcinogens and mutation causing agents. Moreover, the half-lives of substances such as carbon tetrachloride, hexachloroethane and nitroaromatic compounds are several decades. In this study, the optimal conditions to detoxify chlorinated compounds by the reductive degradation were investigated. The following results were obtained in the reductive degradation of CCl$_4$, C$_2$Cl$\_$6/, C$_2$HCl$\_$5/, C$_2$Cl$_4$, and C$_2$HCl$\_$5/ by using Fe, FeS and FeS$_2$ as mediators. CCl$_4$ was reduced to CH$_2$Cl$_3$ and CH$_2$Cl$_2$in anaerobic conditions when FeS was used as a mediator. While the reduction of CCl$_4$ to CHCl$_3$ was rapidly proceeded, the reduction of CHCl$_3$ to CH$_2$Cl$_2$ was occurred slowly. Further reduction to CH$_3$Cl was not observed. Unlike CCl$_4$, C$_2$Cl$\_$6/ was degraded to C$_2$HCl$\_$5/, C$_2$Cl$_4$. C$_2$HCl$_3$ and cis-1,2-C$_2$H$_2$Cl$_2$ by complicated pathways such as hydrogenolysis, dehalo-elimination and dehydrohalogenation. A small amount of C$_2$HCl$\_$5/ was detected only in the early stages of the reduction. However, majority of the C$_2$Cl$\_$6/ was reduced to C$_2$Cl$_4$. cis-1,2-C$_2$H$_2$C1$_2$ was the only product among other possible isomers.

Design of Low Noise Readout Circuit for 2-D Capacitive Microbolometer FPAs (정전용량 방식의 이차원 마이크로볼로미터 FPA를 위한 저잡음 신호취득 회로 설계)

  • Kim, Jong Eun;Woo, Doo Hyung
    • Journal of the Institute of Electronics and Information Engineers
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    • v.51 no.10
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    • pp.80-86
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    • 2014
  • A low-noise readout circuit is studied for 2-D capacitive microbolometer focal plane arrays (FPAs). In spite of the merits of the integration method, a simple and effective pixelwise readout circuit without integration is used for input circuit because of a small pixel size and narrow noise bandwidth. To reduce the power consumption and the kT/C noise, which is the dominant noise of the capacitive microbolometer FPAs with small capacitance, a new correlated double sampling (CDS) is used for columnwise circuit. The proposed circuit has been designed using a $0.35-{\mu}m$ 2-poly 4-metal CMOS process for a microbolometer array with a pixel size of $50{\mu}m{\times}50{\mu}m$. The proposed circuit effectively reduces the kT/C noise and the other low-frequency noise of microbolometer, and the noise characteristics of the fabricated chip have been verified by measurements. The rms noise voltage of the proposed circuit is reduced from 30 % to 55 % compared to that of the simple readout input circuit, and the noise equivalent temperature difference (NETD) of the proposed circuit is very low value of 21.5 mK.

The Seasonal Variation of Primary Productivity in the Antarctic Coastal Ecosystems (남극 연안생태계에서 일차생산력의 계절변화)

  • Kim, Hae-Cheol;Yang, Sung-Ryull;Pae, Se-Jin;Shim, Jae-Hyung
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.3 no.2
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    • pp.80-89
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    • 1998
  • To understand the temporal variation of phytoplankton community in the Antarctic coastal ecosystem, physicochemical parameters, chlorophyll a, and primary productivity were measured as a component of the 7th KARP (Korea Antarctic Research Program) in 1994. Data were collected every month between February and December except four months (June-September) when the study area was frozen. Chlorophyll a concentrations ranged from negligible to 3.03 ${\mu}g/l$, averaging 0.63 ${\mu}g/l$. The primary productivity ranged 0.53-18.95 mg C/$m^3{\cdot}day$, and the depth-integrated primary productivity ranged 41.28-560.20 mg C/$m^3{\cdot}day$. A positive relationship was observed between the phytoplankton biomass and irradiance ($r^2$=0.29, p < 0.01). The degree of correlation between the primary productivity and irradiance ($r^2$=0.85, p < 0.001) was significantly higher than that between the phytoplankton biomass and irradiance. However, neither temperature nor inorganic nutrients seem to affect the temporal variation of primary productivity.

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Na3PO4 Flame Retardant Treatment on Lyocell Fiber for Thermal Stability and Anti-oxidation Properties (라이오셀의 열 안정 및 내산화 특성 향상을 위한 Na3PO4 내염화 처리)

  • Kim, Hyeong Gi;Kim, Eun Ae;Lee, Young-Seak;In, Se Jin
    • Fire Science and Engineering
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    • v.29 no.2
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    • pp.25-32
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    • 2015
  • The improved thermal stability and anti-oxidation properties of lyocell fiber were studied based on flame retardant treatment by using $Na_3PO_4$ solution. The optimized conditions of flame retardant treatment were studied on various concentrations of $Na_3PO_4$ and the mechanism was proposed through experimental results of thermal stability and anti-oxidation. The integral procedural decomposition temperature (IPDT), limiting oxygen index (LOI) and activation energy ($E_a$) increased 30, 160% respectively via flame retardant treatment. It is noted that thermal stability and anti-oxidation improved based on char and carbon layer formation by dehydrogenation and dissociation of C-C bond resulting the hindrance of oxygen and heat energy into polymer resin. The optimized conditions for efficient flame retardant property of lyocell fiber were provided using $Na_3PO_4$ solution and the mechanism was also studied based on experimental results such as initial decomposition temperature (IDT), IPDT, LOI and $E_a$.

Dosimetric Properties of LiF:Mg,Cu,Na,Si TL pellets (LiF:Mg,Cu,Na,Si TL 소자의 선량계적 특성)

  • Nam, Young-Mi;Kim, Jang-Lyul;Chang, Si-Young
    • Journal of Radiation Protection and Research
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    • v.26 no.1
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    • pp.7-12
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    • 2001
  • Sintered LiF:Mg,Cu,Na,Si thermoluminescence (TL) pellets were developed for application in radiation dosimetry. In the present study, the TL dosimetric properties of LiF:Mg,Cu,Na,Si TL pellets have been investigated for emission spectrum, dose response, energy response, and fading characteristics. LiF:Mg,Cu,Na,Si TL pellets were made by using a sintering process, that is, pressing and heat treatment from TL powders. Photon irradiations for the experiments were carried out using X-ray beams and a $^{137}Cs$ gamma source at the Korea Atomic Energy Research Institute (KAERI). The average energies and the dose were in the range of 20-662 keV and $10^{-6}-10^{-2}\;Gy$, respectively. The glow curves were measured with a manual type TLD reader(System 310, Teledyne) at a constant nitrogen flux and a linear heating rate. For a constant heating rate of $5^{\circ}C\;s^{-1}$, the main dosimetric peak of glow curve appeared at $234^{\circ}C$, the activation energy was 2.34 eV and frequency factor was $1.00{\times}10^{23}$. TL emission spectrum is appeared at the blue region centered at 410 nm. A linearity of photon dose response was maintained up to 100 Gy. The photon energy responses relative to $^{137}Cs$ response were within ${\pm}20%$ at overall photon energy region. The fading of TL sensitivity of the pellets stored at the room temperature was not found for one year.

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Improvement in Regional-Scale Seasonal Prediction of Agro-Climatic Indices Based on Surface Air Temperature over the United States Using Empirical Quantile Mapping (경험적 분위사상법을 이용한 미국 지표 기온 기반 농업기후지수의 지역 규모 계절 예측성 개선)

  • Chan-Yeong, Song;Joong-Bae, Ahn;Kyung-Do, Lee
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.24 no.4
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    • pp.201-217
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    • 2022
  • The United States is one of the largest producers of major crops such as wheat, maize, and soybeans, and is a major exporter of these crops. Therefore, it is important to estimate the crop production of the country in advance based on reliable long- term weather forecast information for stable crops supply and demand in Korea. The purpose of this study is to improve the seasonal predictability of the agro-climatic indices over the United States by using regional-scale daily temperature. For long-term numerical weather prediction, a dynamical downscaling is performed using Weather Research and Forecasting (WRF) model, a regional climate model. As the initial and lateral boundary conditions of WRF, the global hourly prediction data obtained from the Pusan National University Coupled General Circulation Model (PNU CGCM) are used. The integration of WRF is performed for 22 years (2000-2021) for period from June to December of each year. The empirical quantile mapping, one of the bias correction methods, is applied to the timeseries of downscaled daily mean, minimum, and maximum temperature to correct the model biases. The uncorrected and corrected datasets are referred WRF_UC and WRF_C, respectively in this study. The daily minimum (maximum) temperature obtained from WRF_UC presents warm (cold) biases over most of the United States, which can be attributed to the underestimated the low (high) temperature range. The results show that WRF_C simulates closer to the observed temperature than WRF_UC, which lead to improve the long- term predictability of the temperature- based agro-climatic indices.

SNU 1.5MV Van de Graaff Accelerator (IV) -Fabrication and Aberration Analysis of Magnetic Quadrupole Lens- (SNU 1.5MV 반데그라프 가속기 (IV) -자기 4극 렌즈의 제작과 수차의 분석-)

  • Bak, H.I.;Choi, B.H.;Choi, H.D.
    • Nuclear Engineering and Technology
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    • v.18 no.1
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    • pp.1-8
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    • 1986
  • A magnetic quadrupole doublet was fabricated for use at the pre-target position of SNU 1.5MV Van de Graaff accelerator and then its optical characteristics were measured and analysed. The physical dimensions are: pole length 180mm, aperture radius 25mm, pole tip radius 28.75mm. Material for poles and return yokes is carbon steel KS-SM40C. Coils have 480 turns per one pole and air-cooling is adopted. Applying the d.c. current 2.99$\pm$0.03A to the lens, and using the Hall probe, magnetic field elements $B_{\theta}$ , $B_{\gamma}$, were measured at the selected Points along each coordinate direction r,$\theta$, z. From the area integration and orthogonal polynomial fitting for the measured data, the magnetic Field gradient G=566.3$\pm$2.1 gauss/cm at lens center, the effective length L=208.3$\pm$1.44mm along the lens axis have been obtained. The harmonic contents were determined up to 20-pole from the generalized least squares fitting. The results indicate that sextupole/quadrupole is below 1.4$\pm$0.9% and all the other multipoles are below 0.5% in the region within 18mm radius at the center of lens.

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Low power 3rd order single loop 16bit 96kHz Sigma-delta ADC for mobile audio applications. (모바일 오디오용 저 전압 3 차 단일루프 16bit 96kHz 시그마 델타 ADC)

  • Kim, Hyung-Rae;Park, Sang-Hune;Jang, Young-Chan;Jung, Sun-Y;Kim, Ted;Park, Hong-June
    • Proceedings of the IEEK Conference
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    • 2005.11a
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    • pp.777-780
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    • 2005
  • 모바일 오디오 적용을 위한 저전력 ${\Sigma}{\Delta}$ Modulator 에 대한 설계와 layout 을 보였다. 전체 구조는 3 차 단일 피드백 루프이며, 해상도는 16bit 을 갖는다. 샘플링 주파수에 따른 Over-sampling Ratio 는 128(46kHz) 또는 64(96kHz) 가 되도록 하였다. 차동 구조를 사용한 3 차 ${\Sigma}{\Delta}$ modulator 내의 적분기에 사용된 Op-Amp 는 DC-Gain 을 높이기 위해서 Gain-boosting 기법이 적용되었다. ${\Sigma}{\Delta}$ modulator 의 기준 전압은 전류 모드 Band-Gap Reference 회로에서 공급이 되며, PVT(Process, Voltage, Temperature) 변화에 따른 기준 전압의 편차를 보정하기 위하여, binary 3bit 으로 선택하도록 하였다. DAC 에서 사용되는 단위 커패시터의 mismatch 에 의한 성능 감소를 막기 위해, DAC 신호의 경로를 임의적으로 바꿔주는 scrambler 회로를 이용하였다. 4bit Quantizer 내부의 비교기 회로는 고해상도를 갖도록 설계하였고, 16bit thermometer code 에서 4bit binary code 변환시 발생하는 에러를 줄이기 위해 thermometer-to-gray, gray-to-binary 인코딩 방법을 적용하였다. 0.18um CMOS standard logic 공정 내 thick oxide transistor(3.3V supply) 공정을 이용하였다. 입력 전압 범위는 2.2Vp-p,diff. 이며, Typical process, 3.3V supply, 50' C 시뮬레이션 조건에서 2Vpp,diff. 20kHz sine wave 를 입력으로 할 때 SNR 110dB, THD 는 -95dB 이상의 성능을 보였고, 전류 소모는 6.67mA 이다. 또한 전체 layout 크기는 가로 1100um, 세로 840um 이다.

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A Study on the Slowly Varying Wave Drift Force Acting on a Semi-Submersible Platform in Waves (반잠수식 시추선에 작용하는 장주기 표류력에 관한 연구)

  • S.Y.,Hong;P.M.,Lee;D.C.,Hong
    • Bulletin of the Society of Naval Architects of Korea
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    • v.26 no.2
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    • pp.49-63
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    • 1989
  • Wave drift forces which are small in magnitudes compared to the first order wave exciting forces can cause very large motion of a vessel in waves. In this paper a theoretical and experimental analysis is made of the mean and slowly varying wave dirft forces on the semi-submersible platform. Theoretical calculations are performed by using near field method with three dimensional diffraction theory and model tests are carried out in regular and irregular waves with a 1/60 semi model. Test results are compared with theoretical calculations and the mooring spring effects in the test are discussed.

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Generalized BER Performance Analysis for Uniform M-PSK with I/Q Phase Unbalance (I/Q 위상 불균형을 고려한 Uniform M-PSK의 일반화된 BER 성능 분석)

  • Lee Jae-Yoon;Yoon Dong-Weon;Hyun Kwang-Min;Park Sang-Kyu
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.31 no.3C
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    • pp.237-244
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    • 2006
  • I/Q phase unbalance caused by non-ideal circuit components is inevitable physical phenomenons and leads to performance degradation when we implement a practical coherent M-ary phase shift keying(M-PSK) demodulator. In this paper, we present an exact and general expression involving two-dimensional Gaussian Q-functions for the bit error rate(BER) of uniform M-PSK with I/Q phase unbalance over an additive white Gaussian noise(AWGN) channel. First we derive a BER expression for the k-th bit of 8, 16-PSK signal constellations when Gray code bit mapping is employed. Then, from the derived k-th bit BER expression, we present the exact and general average BER expression for M-PSK with I/Q phase unbalance. This result can readily be applied to numerical evaluation for various cases of practical interest in an I/Q unbalanced M-PSK system, because the one- and two-dimensional Gaussian Q-functions can be easily and directly computed using commonly available mathematical software tools.