• Title/Summary/Keyword: $Bi_2Sr_2CaCu_2O_y$

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Magnetic Suspension Effect of Oxide Superconductor (산화물 초전도체의 자기효과)

  • Lee, Sangl-Heon;Lee, Sung-Gap;Lee, Young-Hie
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.04b
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    • pp.199-202
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    • 2004
  • Suspension effect has been studied by using superconductor of BiPbSrCaCuO ceramics containing $Ag_2O$. It has been c1eared that $Ag_2O$ acts as pinning center which plays an important role to the suspension effect. Magnetic repulsive force which affects a superconductor located in magnetic flux from toroidal magnet has been investigated. It has been concluded that the suspension effect arises from the interaction between the pinning effect and the diamagnetic effect.

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Electromagnetic Characteristics of Ceramics Superconductor (초전도체의 전기자기적 특성)

  • Lee, Sang-Heon;Lee, Sung-gap;Kim, Young-Kuk;Yoo, Jae-Mu;Lee, Young-Hie
    • Proceedings of the KIEE Conference
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    • 2004.11a
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    • pp.203-204
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    • 2004
  • Suspension effect has been studied by using superconductor of BiPbSrCaCuO ceramics containing $Ag_2O$. It has been cleared that $Ag_2O$ acts as pinning center which plays an important role to the suspension effect. Magnetic repulsive force which affects a superconductor located in magnetic flux from toroidal magnet has been investigated. It has been concluded that the suspension effect arises from the interaction between the pinning effect and the diamagnetic effect.

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Isolation and Analysis of Micro-Regions Having Possibly Higher Tc in Oxide Superconductors (산화물계 초전도체의 고변이 송도부근의 곡출과 이의 성분 분석에 관한 연구)

  • 이규용
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.25 no.3
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    • pp.143-153
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    • 1989
  • In conclusion, a high-Tc superconducting YBa sub(2) Cu sub(3) O sub(y) phase with zero resistance at about 90K was successfully prepared by nitrate solution method with densed micro structure. The result of the EDAX analysis on the isolated particles using the microscopic meissner effect showed that the particles were isolated at higher temperature due to the differences in O vacances rather than the differences in chemical compositions. The composition of the isolated particles were almost identical to the starting compositions on the samples prepared by the solid reaction and nitrate solution method but the Ba-rich composition were seen in the coprecipitated sample. The isolation process on Bi system was not successful due to the weak dimagnetism even though its high Tc above the liquid nitrogen temperature.

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Influence of Milling Condition on the Phase Formation and Jc of Ag/Bi 2223 Superconducting Tapes (분말의 분쇄조건이 Ag/Bi-2223 초전도 선재의 상전이와 임계전류 밀도에 미치는 영향)

  • Kim, Won-Ju;Yu, Jae;Lee, Hui-Gyun;Hong, Gye-Won
    • Korean Journal of Materials Research
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    • v.7 no.2
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    • pp.140-144
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    • 1997
  • The effects of the particle size of precursor powder on the microstructure and Jc of Ag-sheathed Ri-2223 tapes were investigated. The calcined powder with overall composition of $Bi_{1-89}Pb_{0-41}Sr_{2-01}Ca_{2-23}Cu_{3-03}O_{y}$ was milled for various times using planetary ball mill. The transport property of the tapes were found to depend strongly on the particle size of the precursor powder Enhanced reactivity of the milled powder facilitated the formation of 2223 phase and resulted in an increase of Jc. Excessive milling, however, led to the amorphisation of the powder and degraded the electrical property of the tapes.

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Molecular Beam Epitaxial Growth of Oxide Single Crystal Films

  • Yoon, Dae-Ho;Yoshizawa, Masahito
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1996.06a
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    • pp.508-508
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    • 1996
  • ;The growth of films have considerable interest in the field of superlattice structured multi-layer epitaxy led to realization of new devices concepts. Molecular beam epitaxy (MBE) with in situ observation by reflection high-energy electron diffraction (RHEED) is a key technology for controlled layered growth on the atomic scale in oxide crystal thin films. Also, the combination of radical oxygen source and MBE will certainly accelerate the progress of applications of oxides. In this study, the growth process of single crystal films using by MBE method is discussed taking the oxide materials of Bi-Sr-Ca-Cu family. Oxidation was provided by a flux density of activated oxygen (oxygen radicals) from an rf-excited discharge. Generation of oxygen radicals is obtained in a specially designed radical sources with different types (coil and electrode types). Molecular oxygen was introduced into a quartz tube through a variable leak valve with mass flowmeter. Corresponding to the oxygen flow rate, the pressure of the system ranged from $1{\;}{\times}{\;}10^{-6}{\;}Torr{\;}to{\;}5{\;}{\times}{\;}10^{-5}$ Torr. The base pressure was $1{\;}{\times}{\;}10^{-10}$ Torr. The growth of Bi-oxides was achieved by coevaporation of metal elements and oxygen. In this way a Bi-oxide multilayer structure was prepared on a basal-plane MgO or $SrTiO_3$ substrate. The grown films compiled using RHEED patterns during and after the growth. Futher, the exact observation of oxygen radicals with MBE is an important technology for a approach of growth conditions on stoichiometry and perfection on the atomic scale in oxide. The oxidization degree, which is determined and controlled by the number of activated oxygen when using radical sources of two types, are utilized by voltage locked loop (VLL) method. Coil type is suitable for oxygen radical source than electrode type. The relationship between the flux of oxygen radical and the rf power or oxygen partial pressure estimated. The flux of radicals increases as the rf power increases, and indicates to the frequency change having the the value of about $2{\times}10^{14}{\;}atoms{\;}{\cdots}{\;}cm^{-2}{\;}{\cdots}{\;}S^{-I}$ when the oxygen flow rate of 2.0 seem and rf power 150 W.150 W.

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Fabrication of BSCCO High Tc Superconducting Precursor Using Chemical Process (화학 공정법에 의한 세라믹 Nanocomposite 합성)

  • Lee, Sang-Heon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.390-391
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    • 2006
  • A high Tc superconducting with a nominal composition of $Bi_2Sr_2Ca_2Cu_3O_y$ was prepared by the citarte method. The solid precursor produced by the dehydration of the gel at $120^{\circ}C$ for 12h is not in the amorphous state as expected but in a crystalline state X-ray diffraction peaks of nearly the same angular position as the peaks of high Tc phase were observed in the precursor. After pyrolysis at $400^{\circ}C$ and calcination at $840^{\circ}C$ for 4h, the (001)peak of the high Tc phase was cleary observed. Experimental results suggest that the intermediate phase formed before the formation of the superconducting phase may be the most important factor in determining whether it is easy to form the high Tc phase or not, because the nucleation bafflers of the two superconducting phase may be altered by the variation of the crystal structures of those Intermediate phase.

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Fabrication of Superconducting Precursor for Electric Power Transmission (전력전송용 초전도 전구체의 합성)

  • Lee, Sang-Heon;Lee, Young-Hie
    • Proceedings of the KIEE Conference
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    • 2005.11a
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    • pp.77-78
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    • 2005
  • A high Tc superconducting with a nominal composition of $Bi_{2}Sr_{2}Ca_{2}Cu_{3}O_{Y}$ was prepared by the citarte method. The solid precursor produced by the dehydration of the gel at $120^{\circ}C$ for 12h is not in the amorphous state as expected but in a crystalline state. X-ray diffraction peaks of nearly the same angular position as the peaks of high Tc phase were observed in the precursor. After pyrolysis at $400^{\circ}C$ and calcination at $840^{\circ}C$ for 4h, the (001)peak of the high Tc phase was cleary observed. Experimental results suggest that the intermediate phase formed before the formation of the superconducting phase may be the most important factro in determining whether it is easy to form the high Tc phase or not, because the nucleation barriers of the two superconducting phase may be altered by the variation of the crystal structures of those intermediate phase.

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Fabrication of High Tc Superconductor for Electric power transmission (열분해법에 의한 전력기기용 고온 초전도체의 합성)

  • Lee, Sang-Heon
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.1962-1963
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    • 2005
  • A high Tc superconducting with a nominal composition of $Bi_2Sr_2Ca_2Cu_3O_Y$ was Prepared by the citarte method. The solid Precursor produced by the dehydration of the gel at $120^{\circ}C$ for 12h is not in the amorphous state as expected but in a crystalline state. X-ray diffraction peaks of nearly the same angular position as the peaks of high Tc phase were observed in the precursor. After pyrolysis at $400^{\circ}C$ and calcination at $840^{\circ}C$ for 4h, the (001)peak of the high Tc phase was cleary observed. Experimental results suggest that the intermediate phase formed before the formation of the superconducting phase may be the most important factro in determining whether it is easy to form the high Tc phase or not, because the nucleation barriers of the two superconducting phase may be altered by the variation of the crystal structures of those intermediate phase.

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Fabrication of BSCCO High Tc Superconducting Precursor (BSCCO 초전도 전구체의 합성)

  • Lee, Sang-Heon;Lee, Young-Hie
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.1964-1965
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    • 2005
  • A high Tc superconducting with a nominal composition of $Bi_2Sr_2Ca_2Cu_3O_Y$ was prepared by the citarte method. The solid precursor produced by the dehydration of the gel at $120^{\circ}C$ for 12h is not in the amorphous state as expected but in a crystalline state. X-ray diffraction peaks of nearly the same angular position as the peaks of high Tc phase were observed in the precursor. After pyrolysis at $400^{\circ}C$ and calcination at $840^{\circ}C$ for 4h, the (001)peak of the high Tc phase was cleary observed. Experimental results suggest that the intermediate phase formed before the formation of the superconducting phase may be the most important factro in determining whether it is easy to form the high Tc phase or not, because the nucleation barriers of the two superconducting phase may be altered by the variation of the crystal structures of those intermediate phase.

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