• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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• pp.335-338
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• 1998

The effect of glass flit addition on microwave dielectric properties of BaTiO$_3$-3TiO$_2$ ceramic was studied. Addition of glass frit to this system obtained sintered sample below sintering temperature 105$0^{\circ}C$. At BaTiO$_3$-3TiO$_2$+ g1ass frit 3wt% + BaWO$_4$6 wt%m, this ceramic showed excellent microwave properties of dielectric constant 34, Q$\times$f 8,100, temperature coefficient of resonant frequency 4 ppm/$^{\circ}C$ .

• E2M - 전기 전자와 첨단 소재
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• 제10권3호
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• pp.274-283
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• 1997

These days, according to surprising development of communication enterprises, every soft of devices is getting smaller and cheaper. Among these Devices, microwave dielectric ceramics are studied and progressed briskly as the materials of dielectric resonator. Dielectric properties of BaO-S $M_{2}$ $O_{3}$-Ti $O_{2}$, one of the BaO Lnsub 2/ $O_{3}$-Ti $O_{2}$ (Ln=La, Sm, Nd, Pr…) system, synthesized by solid-reaction and coprecipitation method were investigated. Disk-type samples were sintered at 1250-1400.deg. C for 2hrs. As a result, single phase was not synthesized in both method. First created the second phase of S $M_{2}$ $Ti_{2}$ $O_{7}$, and then the last phase of $Ba_{3.75}$S $m_{9.5}$ $Ti_{18}$ $O_{54}$, Ti $O_{2}$, and $Ba_{2}$ $Ti_{9}$ $O_{20}$. When the sample was sintered at 1280.deg. C (in solid reaction method) and at 1310.deg. C (in coprecipitation method), it obtained highest dielectric constant (72.96 and 71.70, respectively) and high Q value. Above that temperature, dielectric constant and Q value decreased because of lattice defect according to oxygen vacancies........

• 한국세라믹학회지
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• 제31권10호
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• pp.1240-1246
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• 1994

While sintering the Pb(Mg1/3Nb2/3)O3-PbTiO3-BaTiO3 system through solid-reaction route, pyrochlore(Pb3Nb4O13) phase while reduces the dielectric constant is inevitably formed. Substitution of Pb(Mg1/3Nb2/3)O3 with PbTiO3 and BaTiO3 can retard the occurrence of pyrochlore phase. The perovskite solid-solution without containing pyrochlore phase can be obtained when we consolidated the materials consisting of PbTiO3 and BaTiO3 at 1200℃ for 2 hours. The sintered body composed of 0.8Pb(Mg1/3Nb2/3)O3-0.1PbTiO3-0.1BaTiO3 composition showed the diffused phase transition(DPT) phenomena and the maximum value of dielectric constant at 0℃ (Tc') with the value of 1.3×104.

• 한국세라믹학회지
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• 제38권3호
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• pp.245-250
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• 2001

BaO-TiO$_2$계의 TiO$_2$-rich 조성영역에 대한 상평형 관계를 완전 고상 반응법을 통하여 재평가하였다. 출발 시료로는 이 계의 end-member인 BaO와 TiO$_2$(rutile)를 이용하였다. 각 시료들은 대기 중에서 800~120$0^{\circ}C$의 온도구간에서 선택적으로 열처리되었다. 열처리된 시편들은 상온까지 급냉 처리되었으며, 상 분석은 X-ray 회절 분석을 통하여 이루어졌다. 연구결과에서 BaTi$_2$O$_{5}$(1:2)상과 BaTi$_{5}$O$_{11}$(1:5)상이 저온에서의 고상 반응을 통해서도 쉽게 형성될 수 있음을 알 수 있었으며, 각 저온 상들의 불변 반응 온도를 열처리 온도에 따른 상 분석을 통하여 확인할 수 있었다.

• 한국세라믹학회지
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• 제35권12호
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• pp.1274-1279
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• 1998

The glass forming ability of the PbO-B2O3-TiO3-BaO system was investigated in relation to transitieon tem-peratures and the atomic ratio between constituents. Glass forming tendency was improved as the tem-peratures and the atomic ratio between constituents. Glass forming tendency was improved as the tem-perature differences between liquidus temperature and crystallization(or glass transition) temperature de-creased and the temperature difference between crystallization and glass transition temperature increases. The atomic ratio could be used as a criterion to deign glass systems. The interposition of B and Ba atoms between Pb and Ti atoms was one of important factors in glass formation.

• 전자공학회논문지 IE
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• 제43권4호
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• pp.8-12
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• 2006

본 논문에서는 $SiO_2-ZnO-B_2O_3$ 계 및 $P_2O_5$-ZnO-BaO 계의 반사율과 유전특성을 $TiO_2$의 양에 따라 조사하였다. 반사율은 $TiO_2$ 함량이 증가함에 따랴 감소하였다 여기서 $P_2O_5$-ZnO-BaO계는 $SiO_2-ZnO-B_2O_3$ 계보다 더 낮은 반사율을 나타내었으며, 유전상수는 $P_2O_5$-ZnO-BaO 계가 $SiO_2-ZnO-B_2O_3$ 계보다 높았다. 두 계 모두 유전상수는 $TiO_2$의 양에 따라 증가하는 특성을 보였다. 이 결과는 높은 반사율과 항복특성이 요구되는 PDP디스플레이의 후면 유전층에 적용할 수 있을 것으로 생각된다.

• 한국세라믹학회지
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• 제40권4호
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• pp.365-370
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• 2003

The phase development process of $Ba_2$ $Ti_{9}$ $O_{20}$ ceramics is not clearly known and frequently accompanies second phases which deteriorate dielectric properties. In synthesizing $Ba_2$ $Ti_{9}$ $O_{20}$ ceramics, in order to trace the reaction sequence during conventional solid-state reaction in BaO-Ti $O_2$ system, different barium sources of BaC0$_3$ and BaTi0$_3$ precursor were used as starting materials. From the analysis of XRD patterns, different secondary phases could be identified depending on the barium source used, which might mean that the equilibrium phases in BaO-Ti $O_2$ system are very difficult to be synthesized. Because the BaTi0$_3$ precursor provides short diffusion paths of ions, the system revealed less secondary phases during solid state reaction. In synthesizing BaO-xSm$_2$0$_3$-4.5Ti0$_2$ system using different barium sources, different secondary phases were developed also. Microstructure and dielectric properties were examined and discussed in terms of secondary phase development.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 추계학술대회 논문집
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• pp.12-12
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• 2009

We weal know that PbO was poisonous and prone to volatilize, then to pollute the circumstance and hurt to people, so we should dope other innocuous additives instead of lead to increase Tc of composite PTC material. In order to prepare lead-free $BaTiO_3$-based PTC with middle Curie point, the incorporation on $(BaNaK)(TiNb)O_3$ into $BaTiO_3$-based ceramics was investigated on samples containing 0.05, 0.07 and 0.1mol% of $(BaNaK)(TiNb)O_3$. $(BaNaK)(TiNb)O_3$ was compounded as standby material by conventional solid-state reaction technique. The starting materials were $Na_2O_3$,$K_2CO_3$, $BaCO_3$, $TiO_2$ and $Nb_2O_5$ powder, and using solid-state reaction method, too. The microstructure of samples were investigated by SEM, DSC, XRD and dielectric properties. Phase composition and lattice parameters were investigated by X-ray diffraction. Also, we are measure the resistivity of sintered bodies with calcinations condition.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.314-314
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• 2011

Using first principles calculations, we investigated the interface structure effects on the magnetic properties of the Fe/BaTiO3 system. On the BaO-terminated surface, a Fe monolayer is formed as two Fe atoms are adsorbed on the top sites of Ba and O in the ($1{\times}1$) surface unit and a Fe ML is formed on the TiO2-terminated surface as two Fe atoms are adsorbed on the two O top sites. The magnetic anisotropy energy of Fe was higher on the TiO2?-erminated surface (1.5 eV) than on the BaO-terminated surface (0.5 eV). The decomposed electron density of the states showed that the stronger hybridization of Fe with the TiO2 layer than with the BaO layer is the most important reason for the higher magnetic anisotropy energy.

• 한국세라믹학회지
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• 제35권7호
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• pp.665-670
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• 1998

Ferroelectric anomaly in PbO-{{{{ { {B }_{2 }O }_{3 } }}-{{{{ {TiO }_{3 } }}-BaO glasses which is observed in DAT measurements was in-vestigated together with the effect of BaO content on the shift of Cuire temperature. The temperature where the ferroelectric anomaly apperars on cooling in DTA decreased in proportion with increasing BaO content,. For as-crystallized samples the ferroelectric anomaly was not observed on heating but on cooling whilist for powder samples leached chemically from the crystallized samples both endothermic and ex-otehrmic peaks were observed. This fact suggests that the appearance of the ferroelectric anomaly in DAT largely depends on glassy phases surrounding individual {{{{ {PbTiO }_{3 } }} crystals rather than effects of grain size and crystallinity.